CN205505017U - High concentration contains fluoride and chloride pharmaceutical factory residue integrated treatment recovery unit - Google Patents

High concentration contains fluoride and chloride pharmaceutical factory residue integrated treatment recovery unit Download PDF

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Publication number
CN205505017U
CN205505017U CN201620042000.2U CN201620042000U CN205505017U CN 205505017 U CN205505017 U CN 205505017U CN 201620042000 U CN201620042000 U CN 201620042000U CN 205505017 U CN205505017 U CN 205505017U
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China
Prior art keywords
rotary kiln
integrated treatment
pharmaceutical factory
retracting device
kiln
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Expired - Fee Related
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CN201620042000.2U
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Chinese (zh)
Inventor
张斌
张照军
卜斌
黄锦阳
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BEIJING GUANGYAO ENVIRONMENTAL ENGINEERING Co Ltd
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BEIJING GUANGYAO ENVIRONMENTAL ENGINEERING Co Ltd
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Priority to CN201620042000.2U priority Critical patent/CN205505017U/en
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Publication of CN205505017U publication Critical patent/CN205505017U/en
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  • Incineration Of Waste (AREA)

Abstract

The utility model relates to a high concentration contains fluoride and chloride pharmaceutical factory residue integrated treatment recovery unit, press flue gas flow, the device includes pyrolysis gasification incineration furnace, the one -level rotary kiln, the second grade rotary kiln, second combustion chamber, rapid cooling exhaust -heat boiler, the deacidification tower, the dust remover, the adsorption system, fan and chimney, characterized by adopts the flue with pyrolysis gasification incineration furnace, the one -level rotary kiln, the second grade rotary kiln, second combustion chamber, the deacidification tower, the dust remover, adsorption equipment, fan and chimney concatenate the intercommunication in proper order, pyrolysis gasification incineration furnace bottom is equipped with rotatory grate, one -level rotary kiln and second grade rotary kiln bottom are equipped with the slagging -off machine respectively. This system implementation innoxious and the resourceization of the dangerous discarded object of industrial production. The gas that produces in pyrolysis oven and the rotary kiln burns through second combustion chamber's high temperature and changes harmless gas into, handles through exhaust -heat boiler, deacidification tower, sack cleaner, active carbon absorption device to reach emission standard totally.

Description

High-concentration fluorine-contained compound and chloride pharmaceutical factory residue integrated treatment retracting device
Technical field
This utility model relates to the device that a kind of commercial production danger wastes joint disposal recycle device, the danger wastes harmlessness disposing particularly produced in fine-chemical intermediate production process and resource recycle.
Background technology
China is the whole world the first big pesticide medicine and intermediate manufacturing country, and yield wide in variety is big.Production process uses Technology of Fine Chemical Industry in a large number, such as the production of fluorine chloropyridine, produces the danger wastes such as substantial amounts of bottoms, saliferous concentrating spent liquor, saliferous chemical engineering sludge.These danger wastes i.e. contain fluorine chloropyridine and derivant, phenyl ring and derivant, halogenated hydrocarbons and various heterocycle Organic substance, also contains the inorganic matter such as calcium chloride, phosphate, also have the moisture content that cannot separate in a large number simultaneously.If animals and plants can be caused injury greatly by the most treated being flowed in natural environment, cause the death of crops and trees, the pernicious environmental accident such as person poultry poisoning.If not disposing stacking, long-term after these materials stack the most nowhere, storage barrel cage of long duration also can rupture leakage, exists and big environment hidden danger, and harm is permanent.
The present invention is directed to this type of present situation, contrast incineration disposal device at all kinds of dangerous waste, the minimizing of such danger wastes, innoxious, resource aspect have been carried out substantial amounts of research.Carry out fully comparing to the investment of device, energy consumption, efficiency, operating cost, disposal effect, it is proposed that integration series connection incineration disposal device, it is achieved that danger wastes decrement, toxic organic compound thoroughly burns, salt efficient recovery resource.
Utility model content
The purpose of this utility model is to provide a kind of collection " vertical continuous pyrolysis incinerator ", " one-level rotary kiln ", " two-stage rotary kiln ", " dual firing chamber " series winding one, it is possible not only to incinerating solid danger wastes simultaneously, and saliferous concentrated solution and chemical engineering sludge can be dried roasting harmless resource utilization, the incineration disposal device that treatment effeciency is high, overcomes the deficiency of existing single incinerator technology.
This utility model is achieved in that
A kind of high-concentration fluorine-contained compound and chloride pharmaceutical factory residue integrated treatment retracting device, including incinerator for thermal decomposition, one-level rotary kiln, two-stage rotary kiln, dual firing chamber, chilling waste heat boiler, extracting tower, cleaner unit, adsorption system, blower fan and chimney, it is characterized in that using flue that incinerator for thermal decomposition, one-level rotary kiln, two-stage rotary kiln, dual firing chamber, extracting tower, cleaner unit, adsorbent equipment, blower fan and chimney carry out concatenation connection successively, it is provided with rotary fire grate, one-level rotary kiln and two-stage rotary kiln bottom portion bottom incinerator for thermal decomposition and is respectively equipped with slag remover.
Described incinerator for thermal decomposition is vertical continuous pyrolysis incinerator, and the rotary fire grate arranged bottom it is tower grate formula rotary fire grate deslagging device.
Described one-level rotary kiln is that liquid slurry-spraying pelletizing turns round calcining kiln, and the slag remover arranged bottom it is dry slag-removing machine.
Described two-stage rotary kiln is that mud turns round calcining kiln, and the slag remover arranged bottom it is dry slag-removing machine.
Chilling waste heat boiler it is provided with between described dual firing chamber and extracting tower.
Described cleaner unit is sack cleaner.
Described extracting tower is half dry type extracting tower.
To achieve these goals, this utility model includes " vertical continuous pyrolysis incinerator " " saliferous concentrates residual liquid slurry-spraying pelletizing revolution calcining kiln (one-level rotary kiln) ", " saliferous chemical engineering sludge revolution calcining kiln (two-stage rotary kiln) ", dual firing chamber, chilling waste heat boiler, half dry type extracting tower, sack cleaner, activated carbon systems, blower fan and chimney.It is characterized in using flue " vertical continuous pyrolysis incinerator ", " one-level rotary kiln ", " two-stage rotary kiln ", " dual firing chamber " to be contacted.The high-temperature flue gas produced with " vertical continuous pyrolysis incinerator " is as " saliferous concentrates residual liquid slurry-spraying pelletizing revolution calcining kiln (one-level rotary kiln) ", the thermal source of " saliferous chemical engineering sludge revolution calcining kiln (two-stage rotary kiln) "; to wherein Organic substance dry distilling out, obtain containing few organic inorganic salts.According to the difference of the useless saliferous kind of danger, by difference dry distilling respectively in a two-stage rotary kiln of the useless mobility of dry distilling danger, it is separately recovered resource.One-level rotary kiln obtains calcium chloride, and two grades are returned loading of kiln and obtain phosphate.The high-temperature flue gas using " vertical continuous pyrolysis incinerator " to produce has following advantage as thermal source: (1) calorific value is high, and heat is big, but temperature is more applicable, and the inorganic salt being not result in back in loading of kiln melts.(2) incinerator flue gas oxygen content out is extremely low, entering into one or two grades, return will not be with carbonization gas exothermic heat of reaction in kiln in loading of kiln, it is easy to the control of kiln temperature, it is to avoid in kiln, inorganic salt melts.(3) by avoiding inorganic salt to melt measure, the useless thorough dry distilling of danger in kiln can be made, obtain high-purity inorganic salt.
" saliferous concentrates residual liquid slurry-spraying pelletizing revolution calcining kiln (one-level rotary kiln) " of the present utility model, " saliferous chemical engineering sludge revolution calcining kiln (two-stage rotary kiln) " all use dry-type slag discharger; have slag tap effective; waste heat recovery; the effect of energy-saving and water-saving, decreases substantial amounts of technological process and water treatment procedure than grain slag deslagging device.Mucking machine out inorganic salt can directly recycle.
Pyrolysis oven and time loading of kiln flue gas out enter dual firing chamber's oxygen-enriched combusting again, and holdup time >=2S, Organic substance and chloride are completely decomposed into the inorganic molecules materials such as water, carbon dioxide, HCl, HF, Cl2, SO2 by ignition temperature >=1100 DEG C.
Employing waste heat boiler cooling mode of the present utility model, be cooled to≤less than 250 DEG C by two combustion high-temperature flue gas (temperature >=1100 DEG C) out in 1s, it is to avoid the generation again of dioxin.The high-temperature steam that boiler produces can be used for productive life as heat source and power steam, accomplishes twice laid.
This utility model half dry type extracting tower, with NaOH solution and calcium oxide by acid gas removals such as the halogen in flue gas, sulfur, phosphorus, forms inorganic salt, makes acid gas emissions meet " dangerous waste incineration pollutant catabolic gene standard ".
This utility model uses the inorganic salt in 2 cleaner unit removing flue gases of the using and the reserved after dust, deacidification, makes discharge≤10mg/nm3, the highest.
This utility model uses activated carbon device again to remove Organic substance and the dioxin that flue gas middle reaches separate out, and makes dioxin reach extremely low level, reaches≤the EU criteria of 0.1ng-TEQ/Nm3.
Flue gas after process is used air-introduced machine and chimney to carry out high altitude discharge by this utility model device.Discharge meets " dangerous waste incineration pollutant catabolic gene standard ".
Accompanying drawing explanation
Fig. 1 is high-concentration fluorine-contained compound and chloride pharmaceutical factory residue integrated treatment retracting device structural representation.
In figure: 1-grab bucket, 2-vertical continuous pyrolysis incinerator, 3-tower numbness formula rotary fire grate deslagging device, 4-saliferous concentrate residual liquid slurry-spraying pelletizing revolution calcining kiln (one-level rotary kiln), 5-saliferous chemical engineering sludge revolution calcining kiln (two-stage rotary kiln), 6-dry-type slag discharger (1), 7-6-dry-type slag discharger (2), 8-dual firing chamber, 9-waste heat boiler, 10-deacidify tower, 11-sack cleaner (1) (2), 12-activated-carbon device, 13-air-introduced machine, 14-chimney.
Detailed description of the invention
In order to technical characteristic of the present utility model, purpose and effect are more clearly understood from; in conjunction with case study on implementation; a kind of three-phase mixed fluidized bed desulfurizer is further detailed, is not determinate, does not limits the protection domain of this utility patent with following case study on implementation.
Embodiment 1
Below in conjunction with the accompanying drawings this utility model is described in further detail.
This utility model automatic control system selects large centralised control system (SIEMENS PLC), arranges host computer man machine interface.The technological parameters such as the air capacity in pyrolytic gasification process and retort process, exhaust gas volumn, discharge, temperature, oxygen content, pressure, material input amount, fume emission and real time data are carried out collection in worksite, transmit, analyze, judgement processes, all devices and instrument to whole device are adjusted according to this.This control system have data acquisition, transmit, store, analyze judgement, equipment fault remotely diagnoses, report form statistics, graphic data analysis function.All data and operation can achieve in host computer industrial computer, and arrange data signal output interface, with local environment monitoring IDNet Inter Departmental Net, meet the requirement of supervision department.
Vertical continuous pyrolysis incinerator includes enclosed negative pressure material pit, driving grab bucket, the big hopper of import, closed double roller crushing feeder, body of heater, tower numbness formula gyratory crusher, primary air fan, combustor, sealing structure for water, mucking machine.Danger wastes carries out compatibility uniformly at negative pressure material pit, then is sent into the big hopper of import by driving grab bucket, by closed double roller crushing feeder feeding stove.In material entrance stove, after anoxycausis gasification, remaining lime-ash is crushed by tower numbness formula gyratory crusher, and mucking machine is discharged.
One-level rotary kiln is in tilted layout, and charging aperture is arranged at low level, downflow type flue gas at a high position, slag notch.Vertical continuous pyrolysis incinerator high-temperature flue gas out enters " saliferous concentrates residual liquid slurry-spraying pelletizing revolution calcining kiln (one-level rotary kiln) "; saliferous is concentrated residual liquid and sprays into from rotary kiln entrance by high-pressure spray gun; under the effect of high-temperature flue gas, the Organic substance of moisture and low-volatile starts to flash to gas, inorganic salt and high volatile organic compounds and mixes and separate on rotary kiln.Inorganic salt in rotary kiln and Organic substance constantly roll with rotary kiln thermally equivalent, slowly mobile to outlet, make material fully be heated and decompose, obtain high-purity inorganic salt (CaCl2).The inclination angle of rotary kiln is set according to Organic substance dry distilling resolving time, the form of material.High-purity inorganic salt (CaCl2) is got rid of with dry-type slag extractor.
Two-stage rotary kiln is in tilted layout, and charging aperture is in a high position, and slag notch is at low level, and reverse-flow flue gas is arranged.One-level rotary kiln flue gas out enters " saliferous chemical engineering sludge revolution calcining kiln (two-stage rotary kiln) " from low level, saliferous chemical engineering sludge uses cage feeding machine to send into a high position for rotary kiln, first moisture is evaporated with the low-temperature flue gas of rotary kiln outlet, with the high-temperature flue gas of rotary kiln entrance, the Organic substance in mud is thoroughly being decomposed, obtain inorganic salt (phosphate), then discharge with dry-type slag extractor.
Two-stage rotary kiln flue gas out is mixed with gasification flue gas and " saliferous concentrates residual liquid slurry-spraying pelletizing revolution calcining kiln (one-level rotary kiln) " and " saliferous chemical engineering sludge revolution calcining kiln (two-stage rotary kiln) " the dry distilling flue gas of " vertical continuous pyrolysis incinerator "; oxygen content and low in flue gas, calorific value is high.This mixed flue gas enters in dual firing chamber, sends into the oxygen-enriched abundant burning of sufficient secondary wind, ignition temperature >=1100 DEG C, gas residence time >=2s, makes the dioxin poisonous and harmful substance in flue gas thoroughly be decomposed in high temperature.After flue gas goes out dual firing chamber, after the multiple tracks purified treatment such as follow-up chilling, deacidification, dehydration, dedusting are up to standard, enter air.
In this explanation, narration partial content the most in detail belongs to industry universal knowledge, and professional and technical personnel in the field the most fully grasp.
The foregoing is only the schematic detailed description of the invention of this utility model, be not limited to scope of the present utility model.Any those skilled in the art, the equivalent variations made on the premise of without departing from design of the present utility model and principle and amendment, the scope of this utility model protection all should be belonged to.

Claims (8)

  1. The most high-concentration fluorine-contained compound and chloride pharmaceutical factory residue integrated treatment retracting device, including incinerator for thermal decomposition, one-level rotary kiln, two-stage rotary kiln, dual firing chamber, chilling waste heat boiler, extracting tower, cleaner unit, adsorption system, blower fan and chimney, it is characterized in that using flue that incinerator for thermal decomposition, one-level rotary kiln, two-stage rotary kiln, dual firing chamber, extracting tower, cleaner unit, adsorbent equipment, blower fan and chimney carry out concatenation connection successively, it is provided with rotary fire grate, one-level rotary kiln and two-stage rotary kiln bottom portion bottom incinerator for thermal decomposition and is respectively equipped with slag remover.
  2. 2. residue integrated treatment retracting device in pharmaceutical factory described in claim 1, is characterized in that described incinerator for thermal decomposition is vertical continuous pyrolysis incinerator, and the rotary fire grate arranged bottom it is tower grate formula rotary fire grate deslagging device.
  3. 3. residue integrated treatment retracting device in pharmaceutical factory described in claim 1, is characterized in that described one-level rotary kiln is that liquid slurry-spraying pelletizing turns round calcining kiln, and the slag remover arranged bottom it is dry slag-removing machine.
  4. 4. residue integrated treatment retracting device in pharmaceutical factory described in claim 1, is characterized in that described two-stage rotary kiln is that mud turns round calcining kiln, and the slag remover arranged bottom it is dry slag-removing machine.
  5. 5. residue integrated treatment retracting device in pharmaceutical factory described in claim 1, is characterized in that being provided with between described dual firing chamber and extracting tower chilling waste heat boiler.
  6. 6. residue integrated treatment retracting device in pharmaceutical factory described in claim 5, is characterized in that described cleaner unit is sack cleaner.
  7. 7. residue integrated treatment retracting device in pharmaceutical factory described in claim 5, is characterized in that described adsorbent equipment is absorbent charcoal adsorber.
  8. 8. residue integrated treatment retracting device in pharmaceutical factory described in claim 5, is characterized in that described extracting tower is half dry type extracting tower.
CN201620042000.2U 2016-01-18 2016-01-18 High concentration contains fluoride and chloride pharmaceutical factory residue integrated treatment recovery unit Expired - Fee Related CN205505017U (en)

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Application Number Priority Date Filing Date Title
CN201620042000.2U CN205505017U (en) 2016-01-18 2016-01-18 High concentration contains fluoride and chloride pharmaceutical factory residue integrated treatment recovery unit

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106122983A (en) * 2016-07-01 2016-11-16 无锡雪浪环境科技股份有限公司 A kind of incinerator smoke is taken air-flow and is removed the devices and methods therefor of two English
CN108443889A (en) * 2018-02-28 2018-08-24 上海锅炉厂有限公司 A kind of discarded metal catalyst and organic sludge coprocessing device and method
CN108826319A (en) * 2018-08-16 2018-11-16 东华工程科技股份有限公司 Dangerous waste incinerator with dry colling slagging mechanism
CN114135875A (en) * 2021-11-29 2022-03-04 广州雅居乐固体废物处理有限公司 Incineration pretreatment process for high-fluorine solid waste
CN115028329A (en) * 2022-07-11 2022-09-09 沈阳理工大学 Comprehensive utilization method and system for thermal catalytic decomposition, separation and drying of sludge flue gas

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106122983A (en) * 2016-07-01 2016-11-16 无锡雪浪环境科技股份有限公司 A kind of incinerator smoke is taken air-flow and is removed the devices and methods therefor of two English
CN106122983B (en) * 2016-07-01 2018-07-20 无锡雪浪环境科技股份有限公司 A kind of incinerator smoke takes the devices and methods therefor of air-flow removing bioxin
CN108443889A (en) * 2018-02-28 2018-08-24 上海锅炉厂有限公司 A kind of discarded metal catalyst and organic sludge coprocessing device and method
CN108443889B (en) * 2018-02-28 2023-08-08 上海锅炉厂有限公司 Waste metal catalyst and organic sludge co-treatment device and method
CN108826319A (en) * 2018-08-16 2018-11-16 东华工程科技股份有限公司 Dangerous waste incinerator with dry colling slagging mechanism
CN108826319B (en) * 2018-08-16 2023-10-31 东华工程科技股份有限公司 Dangerous waste incinerator with dry cooling slag discharging mechanism
CN114135875A (en) * 2021-11-29 2022-03-04 广州雅居乐固体废物处理有限公司 Incineration pretreatment process for high-fluorine solid waste
CN115028329A (en) * 2022-07-11 2022-09-09 沈阳理工大学 Comprehensive utilization method and system for thermal catalytic decomposition, separation and drying of sludge flue gas
CN115028329B (en) * 2022-07-11 2023-08-11 沈阳理工大学 Comprehensive utilization method and system for thermal catalytic decomposition, separation and drying of sludge flue gas

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CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20160824

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