CN205472769U - Effluent treatment plant based on thin layer water film ultraviolet catalysis waste water - Google Patents

Effluent treatment plant based on thin layer water film ultraviolet catalysis waste water Download PDF

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Publication number
CN205472769U
CN205472769U CN201620012064.8U CN201620012064U CN205472769U CN 205472769 U CN205472769 U CN 205472769U CN 201620012064 U CN201620012064 U CN 201620012064U CN 205472769 U CN205472769 U CN 205472769U
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China
Prior art keywords
waste water
thin layer
nozzle
light source
reaction tank
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Expired - Fee Related
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CN201620012064.8U
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Chinese (zh)
Inventor
陈再东
解清杰
滕辰亮
赵艳超
张晗
王拉
董进波
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Jiangsu University
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Jiangsu University
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/30Wastewater or sewage treatment systems using renewable energies
    • Y02W10/37Wastewater or sewage treatment systems using renewable energies using solar energy

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  • Physical Water Treatments (AREA)
  • Catalysts (AREA)

Abstract

The utility model provides an effluent treatment plant based on thin layer water film ultraviolet catalysis waste water, including waste water reservoir, elevator pump, nozzle, light source, catalyst lamina affixad and reaction tank, waste water reservoir includes water inlet and backflow water export, and the reaction tank includes delivery port and backflow water entry, and waste water reservoir water inlet is connected with the inlet tube, and the reaction tank delivery port is connected with the outlet pipe, is equipped with the second valve on the outlet pipe, reaction tank backflow water entry is connected through pipeline A with the export of waste water reservoir backflow water, is equipped with first valve on the pipeline A, the elevator pump input passes through pipeline B and connects waste water reservoir, and the elevator pump output passes through pipeline C ligation pond, and pipeline C exit linkage has a nozzle, nozzle below is equipped with the catalyst lamina affixad, one side the catalyst lamina affixad is close to the inside wall that is fixed in the reaction tank of nozzle, the top of catalyst lamina affixad is equipped with the light source, and it has photocatalysis to adhere to on the catalyst lamina affixad. The utility model discloses the degradation mild condition, the processing procedure is low -priced, safety.

Description

A kind of wastewater treatment equipment based on thin layer moisture film ultraviolet catalytic waste water
Technical field
This utility model belongs to application field of water treatment, refers in particular to a kind of waste water based on thin layer moisture film ultraviolet catalytic waste water and processes dress Put.
Background technology
Photocatalysis waste water technology belongs to water-treatment technology field.This technology have novelty, high efficiency, to waste water non-selectivity etc. Advantage, is particularly suitable for the degraded of unsaturated hydrocarbon, and reaction condition is the gentleest, non-secondary pollution, has well application Prospect.Its operation principle is when there is semiconductor powder catalyst in organic wastewater, after the ultraviolet light of some strength irradiates, System just can produce a certain amount of, the reactive oxygen species and free radicals of various ways, owing to these reactive oxygen species and free radicals have higher Oxidizing potential, so can and Organic substance effect make it degrade, and then mineralising is water and carbon dioxide, thus reaches to administer Purpose.
The type of sewage-treating reactor mainly has: a class is to utilize nature light (sunlight) to be radiation source, use catalyst The flat-plate reactor of immobilization technology;Another kind of is to utilize artificial light source (uviol lamp) to be radiation source, use fine catalyst Suspension photo catalysis reactor.
Photocatalytic reactor and shortcoming thereof are as follows at present:
(1) flat photo catalysis reactor
Flat photo catalysis reactor is direct part and the scattered portion taking full advantage of sunlight, makes the utilization rate of luminous energy significantly Improve.Under some region and certain condition, the too scattered portion of the ultraviolet component in eye is even above direct part, because Steam not Ultraviolet radiation absorbing, so no matter this reactor is at fine day or cloudy day, has goodish treatment effect.Flat board Formula photo catalysis reactor has higher sunlight utilization rate, simple in construction, it is not necessary to sunlight tracking system, is suitable for different Weather conditions, to material without particular/special requirement.But hydraulic load is relatively low, it is difficult to apply to the process of big flow sewage.
(2) tubular type photo catalysis reactor
This is a kind of reactor that type is most, and shape is all cylinder, and catalyst has two kinds of existence forms, and one is fixed bed Formula, will TiO2It is carried on the carriers such as silica gel, bead, sandstone, glass fibre, is then filled in pipe or directly will Catalyst is carried on tube wall;Its two be slurry formula, i.e. catalyst with suspension exist with in pipe.But it is suitable only for laboratory Research, and it is suitable only for the research of suspended state liquid phase light-catalyzed reaction, there is no wide variety of prospect.
(3) chemical fibre photo catalysis reactor
It can regard the further improvement of fixed bed photocatalytic reactor as, be a kind of design exclusively for light-catalyzed reaction anti- Answer device.Titanium dioxide in chemical fibre formula reactor is supported on optical fibers outer layer by suitable method, and ultraviolet light is from optical fiber One end imports, and in optical fiber, refraction occurs thus irradiates titanium dioxide layer and make catalyst stimulation, and it is that optical fibers is as to solid phase The medium of titanium dioxide transmission luminous energy.But fibre bundle and auxiliary equipment thereof are costly, it are difficult to spread and use.
(4) fludized bed photoreactor
Fluidized-bed reactor can solve catalyst and reactant liquor contact problems well, because the catalysis of support type photo catalysis reactor The raising of efficiency is the most mainly the most fully determined by the size of specific surface area of catalyst and illumination, and fluidized-bed layer carrier is not Cutout is moved, migrates, is rolled, reactant liquor constantly between carrier granular flowing can make full use of catalyst surface, be effectively improved Catalyst effective ratio area.But there is catalyst and reclaim the problems such as difficult.
Above is that generally speaking, these reactors are according to catalyst about being above some basic conditions about reactor Existence can be basically divided into fixed and slurry formula two kinds.In outstanding slurry reactor, typically directly by catalyst granules with Pending waste water mixes, and makes catalyst be uniformly dispersed by stirring, owing to specific surface area of catalyst is big, has Organic substance preferably Adsorption and have preferably absorption to photon, therefore degradation efficiency is higher.But also exist catalyst be difficult to efficient recovery, Aqueous solution easily occur cohesion make the defects such as active ingredient loss, it is difficult to apply in reality.
For the deficiency of slurry photocatalytic reactor, the most fixed photo catalysis reactor is developed rapidly.So-called solid Fixed pattern photo catalysis reactor will be fixed on carrier or make thin film process waste water by catalyst, is not required to extras and just can make catalyst Recycling.
General uviol lamp mounting means uses " immersion " and " overflow-type ", and this installation side not only can not make full use of Ultraviolet light, and higher to the prescription of uviol lamp, have impact on the effect of reaction.
This utility model overcomes the shortcoming that catalyst is directly mixed by outstanding slurry reactor with waste water, but also improves uviol lamp peace The shortcoming being placed in waste water, uses and is placed on reaction zone by uviol lamp, react the moisture film from nozzle, not only improve The life-span of uviol lamp, it is simple to change, more improve the speed of reaction.
Utility model content
A kind of wastewater treatment equipment based on thin layer moisture film ultraviolet catalytic waste water, including waste water reservoir, elevator pump, nozzle, light Source, catalyst lamina affixa and reaction tank, described waste water reservoir includes water inlet and recirculation water outlet, and described reaction tank includes water outlet Mouthful and recirculation water entrance, and the water inlet of described waste water reservoir connects and has water inlet pipe, and the outlet of reaction tank connects outlet pipe, Outlet pipe is provided with the second valve;The recirculation water entrance of reaction tank is exported with the recirculation water of waste water reservoir and is connected by pipeline A, and Pipeline A is provided with the first valve;
The input of described elevator pump connects waste water reservoir by pipeline B, promotes delivery side of pump and passes through pipeline C coupled reaction pond, The port of export of pipeline C connects a nozzle;The lower section of nozzle is provided with catalyst lamina affixa, and catalyst lamina affixa is near nozzle While being fixed on the medial wall of reaction tank, and catalyst lamina affixa be arranged over light source, on described catalyst lamina affixa adhere to There is photocatalyst.
Further, described nozzle is Duckbill type.
Further, the width of described light source is equal with the width of described nozzle.
Further, the surface at described light source is provided with reflection shield.
Further, described reflection shield distance light source is 100~300mm.
Further, the quantity of described light source is at least the distance between 2, and arbitrary neighborhood light source is 200~500mm.
Further, described light source is cased with quartz socket tube outside being ultraviolet lamp tube, and ultraviolet lamp tube.
Further, described elevator pump is centrifugal pump or immersible pump.
Further, described photocatalyst is titanium deoxid film.
Further, described catalyst lamina affixa is hydrophobic material.
Beneficial effect:
(1) this utility model overcomes the shortcoming that catalyst is directly mixed by outstanding slurry reactor with waste water, is fixed on by catalyst On catalyst retainer plate, solve and reclaim the problem that catalyst is difficult.
But also improve the shortcoming that uviol lamp is placed in waste water, use and uviol lamp is placed on reaction zone, to from nozzle Moisture film reacts, and not only increases the life-span of uviol lamp, it is simple to changes, more improves reaction rate.
(2) this utility model utilizes thin layer moisture film ultraviolet catalytic wastewater treatment equipment, can effectively remove the COD in waste water dense Degree and colourity thereof, oxidability is strong, can complete oxidation Organic substance and do not produce secondary pollution.
(3) this utility model adaptability is good, the Organic substance to difficult for biological degradation, can be degraded by photocatalytic process.
(4) this utility model degradation condition is gentle, it is not necessary to oxidant applying, and processing procedure is cheap, safety;This utility model is also Organic pollution is processed by available sunlight as light source.
Accompanying drawing explanation
Fig. 1 is structural representation of the present utility model.
In figure: 1-water inlet pipe, 2-waste water reservoir, 3-elevator pump, 4-nozzle, 5-reflection shield, 6-light source, 7-catalyst lamina affixa, 8-outlet pipe, 9-reaction tank, 10-the first valve, 11-the second valve
Detailed description of the invention
Below in conjunction with specific embodiment, this utility model is further described:
As it is shown in figure 1, a kind of wastewater treatment equipment based on thin layer moisture film ultraviolet catalytic waste water, including waste water reservoir 2, carry Rising pump 3, nozzle 4, light source 6, catalyst lamina affixa 7 and reaction tank 9, described waste water reservoir 2 includes water inlet and recirculation water Outlet, described reaction tank 9 includes outlet and recirculation water entrance, and the water inlet connection of described waste water reservoir 2 has water inlet pipe 1, The outlet of reaction tank 9 connects has outlet pipe 8, outlet pipe 8 to be provided with the second valve 11;The recirculation water entrance of reaction tank 9 with The recirculation water outlet of waste water reservoir 2 is connected by pipeline A, and pipeline A is provided with the first valve 10;
The input of described elevator pump 3 connects waste water reservoir 2 by pipeline B, and the outfan of elevator pump 3 is connected by pipeline C Reaction tank 9, the port of export of pipeline C connects a nozzle 4;The lower section of nozzle 4 is provided with catalyst lamina affixa 7, and catalyst is attached Plate 7 near nozzle 4 while being fixed on the medial wall of reaction tank 9, and catalyst lamina affixa 7 be arranged over light source 6, It is attached with photocatalyst on described catalyst lamina affixa 7.Described nozzle 4 is Duckbill type;The width of described light source 6 and described spray The width of mouth 4 is equal;It is provided with reflection shield 5 in the surface of described light source 6;Described reflection shield 5 apart from light source 6 is 100~300mm;It is 200~500mm that the quantity of described light source 6 is at least the distance between 2, and arbitrary neighborhood light source 6;Institute Stating light source is to be cased with quartz socket tube outside ultraviolet lamp tube, and ultraviolet lamp tube;Described elevator pump 3 is centrifugal pump or immersible pump;Described Photocatalyst is titanium deoxid film;Described catalyst lamina affixa 7 is hydrophobic material.
Below this utility model is described in further detail: described nozzle 4 uses Duckbill type nozzle.Waste water is at jet expansion The water film thickness formed that is attached with on the flat board of catalysis material at place is 5~20mm.Nozzle 4 according to process waste water needs, The abundant of the moisture film of specific thicknesses, beneficially water treatment effect can be produced.
The length of described ultraviolet tube is identical with the width of nozzle, is cased with quartz socket tube outside fluorescent tube.Two ultraviolets of arbitrary neighborhood Distance between fluorescent tube is 200~500mm.Under ultra violet lamp, moisture film the urging on catalyst lamina affixa 7 of nozzle ejection Agent film surface carries out quick catalytic reaction, can be efficiently completed sewage treatment works.
Described reflection shield 5 is arranged in directly over ultraviolet lamp tube, is arranged in catalytic effect time at fluorescent tube 100-300mm more preferable. The concrete effect of reflection shield 5 is the energy assembling uviol lamp, additionally can avoid causing damage to staff.
The control of reflux ratio of described return duct 7 is 50%~150%.Backflow sewage can effectively dilute giving up in waste water reservoir 2 Water concentration, improves purification of waste water ability.
Described lifting water pump 3 can select centrifugal pump or the immersible pump of use in waste water treatment.Centrifugal pump and immersible pump are all beneficially The water pump that water is conventional in processing.Select this kind water pump can to select and be suitable for and the most economical and the most practical water pump according to actual needs.
Described catalyst lamina affixa 7 is the smooth plate of attached catalyst, selects hydrophobic material, and the waste water making catalysis complete to the greatest extent may be used Leave catalyst lamina affixa 7 energy, consequently facilitating the catalytic reaction of the follow-up waste water flowed on catalyst lamina affixa 7, promote to urge Change the raising of efficiency.
Titanium deoxid film prepared by this utility model employing sol-gel process, the shortcoming that powder photocatalyst can be overcome, and not Causing secondary pollution, metallic matrix also can be circulated utilization, can consider to make matrix similar round-shaped simultaneously, permissible Make sewage be fully contacted with photocatalyst, too much settleable solids in feeding water, will not be produced.This utility model catalytic reaction is at room temperature Can be carried out under normal pressure, observable index is relatively low, and thin layer moisture film can react fully, and makes pollutant quickly degrade, and effluent quality is bright Aobvious improving, floor space is little, can make full use of luminous energy, and titanium dioxide can catalytic purification waste water under visible light.
Specific works process of the present utility model is as follows: a kind of thin layer moisture film ultraviolet catalytic wastewater treatment equipment of the present utility model Operationally, opening the first valve 10, close the second valve 11, waste water first passes through water inlet pipe 1 and enters waste water reservoir 2, When the water yield wherein stored reach a certain height, open elevator pump 3, utilize the pressure of pump to be sprayed by Duckbill type nozzle by waste water, The catalyst lamina affixa 7 be attached with catalysis material is formed 5~20mm thick thin layer moisture films, under the irradiation of uviol lamp, Ultraviolet and catalysis material react the substantial amounts of hydroxyl of generation etc. and have the group of Strong oxdiative ability, make the pollutant in waste water be able to Efficiently removing, the waste water after process enters reaction tank 6;Detect, if water quality does not reaches through the water purified in reaction tank 6 Mark, then keep the first valve 10 to open and the second valve 11 closed, and the waste water after process continues to flow into waste water reservoir 2;If water Matter is up to standard, then close valve 10, then the water after purifying finally discharges through outlet pipe 8.

Claims (10)

1. a wastewater treatment equipment based on thin layer moisture film ultraviolet catalytic waste water, it is characterised in that include waste water reservoir (2), Elevator pump (3), nozzle (4), light source (6), catalyst lamina affixa (7) and reaction tank (9), described waste water reservoir (2) Exporting including water inlet and recirculation water, described reaction tank (9) includes outlet and recirculation water entrance, and described waste water reservoir (2) Water inlet connect and have water inlet pipe (1), the outlet of reaction tank (9) connects has outlet pipe (8), outlet pipe (8) to be provided with Second valve (11);The recirculation water entrance of reaction tank (9) is exported with the recirculation water of waste water reservoir (2) and is connected by pipeline A, And pipeline A is provided with the first valve (10);
The input of described elevator pump (3) connects waste water reservoir (2) by pipeline B, and the outfan of elevator pump (3) is by pipe C coupled reaction pond, road (9), the port of export of pipeline C connects a nozzle (4);The lower section of nozzle (4) is provided with catalyst Lamina affixa (7), catalyst lamina affixa (7) is on the medial wall being fixed on reaction tank (9) of nozzle (4), and urges Agent lamina affixa (7) be arranged over light source (6), described catalyst lamina affixa (7) is attached with photocatalyst.
A kind of wastewater treatment equipment based on thin layer moisture film ultraviolet catalytic waste water the most according to claim 1, its feature exists In, described nozzle (4) is Duckbill type.
A kind of wastewater treatment equipment based on thin layer moisture film ultraviolet catalytic waste water the most according to claim 2, its feature exists In, the width of described light source (6) is equal with the width of described nozzle (4).
A kind of wastewater treatment equipment based on thin layer moisture film ultraviolet catalytic waste water the most according to claim 1, its feature exists In, it is provided with reflection shield (5) in the surface of described light source (6).
A kind of wastewater treatment equipment based on thin layer moisture film ultraviolet catalytic waste water the most according to claim 4, its feature exists In, described reflection shield (5) distance light source (6) is 100~300mm.
A kind of wastewater treatment equipment based on thin layer moisture film ultraviolet catalytic waste water the most according to claim 1, its feature exists In, the distance that the quantity of described light source (6) is at least between 2, and arbitrary neighborhood light source (6) is 200~500mm.
7. according to a kind of based on thin layer moisture film ultraviolet catalytic waste water the wastewater treatment equipment described in claim 1~6 any one, It is characterized in that, described light source (6) is to be cased with quartz socket tube outside ultraviolet lamp tube, and ultraviolet lamp tube.
A kind of wastewater treatment equipment based on thin layer moisture film ultraviolet catalytic waste water the most according to claim 1, its feature exists In, described elevator pump (3) is centrifugal pump or immersible pump.
A kind of wastewater treatment equipment based on thin layer moisture film ultraviolet catalytic waste water the most according to claim 1, its feature exists In, described photocatalyst is titanium deoxid film.
A kind of wastewater treatment equipment based on thin layer moisture film ultraviolet catalytic waste water the most according to claim 1, its feature exists In, described catalyst lamina affixa (7) is hydrophobic material.
CN201620012064.8U 2016-01-06 2016-01-06 Effluent treatment plant based on thin layer water film ultraviolet catalysis waste water Expired - Fee Related CN205472769U (en)

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Application Number Priority Date Filing Date Title
CN201620012064.8U CN205472769U (en) 2016-01-06 2016-01-06 Effluent treatment plant based on thin layer water film ultraviolet catalysis waste water

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105439241A (en) * 2016-01-06 2016-03-30 江苏大学 Waste water treatment device based on thin-layer water film ultraviolet-light-catalyzed waste water

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105439241A (en) * 2016-01-06 2016-03-30 江苏大学 Waste water treatment device based on thin-layer water film ultraviolet-light-catalyzed waste water

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C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20160817

Termination date: 20170106

CF01 Termination of patent right due to non-payment of annual fee