CN205461100U - It smelts recovery system of flue gas to contain useless composition brass of arsenic - Google Patents

It smelts recovery system of flue gas to contain useless composition brass of arsenic Download PDF

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Publication number
CN205461100U
CN205461100U CN201620069742.4U CN201620069742U CN205461100U CN 205461100 U CN205461100 U CN 205461100U CN 201620069742 U CN201620069742 U CN 201620069742U CN 205461100 U CN205461100 U CN 205461100U
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China
Prior art keywords
flue gas
recovery system
temperature
arsenic
copper scap
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CN201620069742.4U
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Chinese (zh)
Inventor
高麟
汪涛
曾伍祥
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Intermet Technology Chengdu Co Ltd
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Intermet Technology Chengdu Co Ltd
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Abstract

The utility model discloses an it smelts recovery system of flue gas to contain useless composition brass of arsenic, include the high temperature filter that links to each other with useless composition brass smelting system exit end, the high temperature filter adopts the inorganic porous material of sintering as filtering material, high temperature filter outlet end 's gas temperature >= 320 DEG C, and high temperature filter outlet end even has heat transfer device, and heat transfer device exit end gas temperature <= 150 DEG C, heat transfer device exit end even have a dust remover, still including drive high temperature flue gas in proper order along high temperature filter, heat transfer device, the mobile fan of dust remover. Use the utility model provides the high rate of recovery that contains the useless composition brass of arsenic and smelt in the flue gas arsenic and non ferrous metal to practice thrift the cost recovery, reduced the pollution to the environment.

Description

Recovery system containing arsenic copper scap flue gas during smelting
Technical field
This utility model relates to smelting field of nonferrous metal, is specifically related to a kind of recovery system containing arsenic copper scap flue gas during smelting.
Background technology
For some areas, especially for Southwestern China area, the copper scap produced in nonferrous metallurgical process usually contains Other non-ferrous components such as arsenic and copper, lead, antimony, gold, silver.In order to reclaim the copper scap that these non-ferrous metal metallurgies produce, Prior art generally use copper scap pyrometallurgical smelting system these copper scap carry out pyrometallurgical smelting, copper scap pyrometallurgical smelting system Generally comprise be sequentially connected with blast furnace, converter, reverberatory furnace, certainly, in the case of copper scap composition is single, blast furnace and Converter can according to circumstances select to omit, and needs copper scap to obtain refined copper after passing through pyrometallurgical smelting according to smelting, in addition, This smelting process is also accompanied by high-temperature flue gas and produces, in these high-temperature flue gas containing gaseous state arsenic and the copper of some dust-like, lead, antimony, The non-ferrous metals such as gold, silver, if directly discharged these containing arsenic high-temperature flue gas, on the one hand, the arsenic in high-temperature flue gas and have coloured gold Belonging to and can not get effectively recycling, reduce the response rate of copper scap, on the other hand, the arsenic in high-temperature flue gas directly discharges meeting Cause environmental pollution, the environmental pollution brought in order to avoid the high-temperature flue gas containing arsenic in prior art, need when copper scap pyrometallurgical smelting Consume substantial amounts of soda arsenic removal, and during arsenic removal, also can take away the antimony of a part, cause the unnecessary wasting of resources.
Utility model content
Technical problem to be solved in the utility model is the recovery containing arsenic copper scap flue gas during smelting providing a kind of response rate higher System.
In order to solve above-mentioned problem of the prior art, this utility model realizes by the following technical solutions:
This utility model recovery system containing arsenic copper scap flue gas during smelting, including the high temperature being connected with the copper scap smelting system port of export Filter, high-temperature filter use sintering inorganic porous material as filtering material, the gas temperature of the high-temperature filter port of export >= 320 DEG C, the high-temperature filter port of export is connected with heat-exchanger rig, heat-exchanger rig port of export gas temperature≤150 DEG C, and heat-exchanger rig exports End is connected with cleaner unit, also includes driving high-temperature flue gas successively along high-temperature filter, heat-exchanger rig, the blower fan of cleaner unit flowing.From In the high-temperature flue gas that copper scap smelting system is discharged, containing the arsenic of gaseous state and the copper of dust-like, lead, antimony, gold, silver etc., other has Non-ferrous metal composition, when high-temperature flue gas is by high-temperature filter, is resistant to 400 DEG C owing to the filtering material of high-temperature filter uses The sintering inorganic porous material that high temperature above, filtering accuracy are higher, therefore the copper of dust-like in high-temperature flue gas, lead, antimony, gold, Silver wait other non-ferrous component can be filtered, now high-temperature flue-gas ensure that arsenic still in gaseous state, therefore high temperature Filter only intercepts the non-ferrous metal of dust-like, and arsenic can pass through high-temperature filter, after through heat-exchanger rig cool down after at a temperature of Being down to≤150 DEG C, thus arsenic is transferred to solid-state by gaseous state, is unified in cleaner unit afterwards and is collected, thus by non-ferrous metal with arsenic very Separating well, improve both response rate, in addition, and high-temperature flue gas expellant gas after double-filtration is clean Cleanliness is higher, does not results in environmental pollution.
As the further restriction of the above-mentioned recovery system containing arsenic copper scap flue gas during smelting, described heat-exchanger rig is surface cooler.Described The surface cooler coefficient of overall heat transmission is high, and water resistance is little, substantially increases heat exchange efficiency.
Further, described sintering inorganic porous material is flexible, porous metal forming, and flexible, porous metal forming is flexible, can basis Filtration needs folding to be processed into different shape, and keeps preferable filtration flux, and in addition flexible, porous metal forming is high temperature resistant, Use intensity is high.The aperture of the most described flexible, porous metal forming is 0.05 μm-100 μm, and that can filter as required is coloured The particle diameter of metallic dust particles, selects corresponding flexible, porous metal forming aperture, thus meets filtering accuracy requirement.Preferably described The thickness of flexible, porous metal forming is 5-1500 μm, and under this thickness, flexible, porous metal forming is flexible, and filtration flux is big.Excellent The porosity selecting described flexible, porous metal forming is 15-70%, and under this porosity ranges, flexible, porous metal forming performance of ventilating is good, Resistance is less.
Further, described cleaner unit is fiber bag precipitator.After heat-exchanger rig heat exchange, high-temperature flue-gas is down to≤ 150 DEG C, so herein without using other resistant to elevated temperatures defecator, using fiber bag precipitator can meet requirement, thus saving Cost recovery containing about arsenic copper scap flue gas during smelting.
Below by way of the drawings and specific embodiments, the utility model is described in further detail.
Accompanying drawing explanation
Fig. 1 is structure chart of the present utility model.
Detailed description of the invention
It is applied in copper scap smelting system below by way of by a kind of for this utility model recovery system containing arsenic copper scap flue gas during smelting, Thus the utility model is described in further detail, blast furnace that described copper scap smelting system includes being sequentially connected, converter, reflection Stove.
As it is shown in figure 1, this utility model includes the high-temperature filter 2 being connected with copper scap smelting system 1 port of export, high temperature mistake Filter 2 uses sintering inorganic porous material as filtering material, gas temperature >=320 DEG C of high-temperature filter 2 port of export, high temperature Filter 2 port of export is connected with surface cooler 3, surface cooler 3 port of export gas temperature≤150 DEG C, and surface cooler 3 port of export is connected with cloth bag Cleaner unit 4, described sack cleaner 4 port of export is connected with blower fan 5, and described sintering inorganic porous material is flexible, porous metal forming, Flexible, porous metal forming is flexible, folding can be needed to be processed into different shape according to filtration, and keep preferable filtration flux, In addition flexible, porous metal forming is high temperature resistant, uses intensity high.The aperture of the most described flexible, porous metal forming is 0.05 μ M-100 μm, the particle diameter of the non-ferrous metal dust granules that can filter as required, select corresponding flexible, porous metal forming aperture, Thus meet filtering accuracy requirement.The thickness of the most described flexible, porous metal forming is 5-1500 μm, and under this thickness, flexibility is many Mesoporous metal paper tinsel is flexible, and filtration flux is big.The porosity of the most described flexible, porous metal forming is 15-70%, in this porosity Under scope, flexible, porous metal forming performance of ventilating is good, and resistance is less.Described flexible, porous metal forming can use the applicant to apply for Number it is that the flexibility in the earlier application of 201410609038.9 earlier applications or the applicant's Application No. 201510153116.3 is many Mesoporous metal paper tinsel.
Using method of the present utility model is as follows: after fully smelting in copper scap smelting system 1 containing arsenic copper scap, starts wind Machine, from the high-temperature flue gas that copper scap smelting system port of export discharge temperature is 380 DEG C-450 DEG C, contains in high-temperature flue gas now Gaseous state arsenic and the non-ferrous metal of dust-like, high-temperature flue gas passes through high-temperature filter, high-temperature flue gas in filter process under fan action Temperature all the time >=320 DEG C, the intercepted unified collection of the non-ferrous metal of dust-like therein, high temperature cigarette under the effect of surface cooler afterwards Temperature drops to≤150 DEG C, and flue gas is through sack cleaner afterwards, and owing to temperature declines, the arsenic of gaseous state transfers solid-state to originally, Being intercepted by sack cleaner and unify to collect, final discharge meets the clean gas of country's atmosphere pollutants emission standards so that have The response rate of non-ferrous metal and arsenic improves, and simplifies smelting flow process simultaneously, it is not necessary to extra use soda arsenic removal, has saved recovery Cost.

Claims (7)

1. the recovery system containing arsenic copper scap flue gas during smelting, it is characterised in that include and copper scap smelting system (1) port of export The high-temperature filter (2) being connected, high-temperature filter (2) uses sintering inorganic porous material as filtering material, high-temperature filter (2) gas temperature >=320 DEG C of the port of export, high-temperature filter (2) port of export is connected with heat-exchanger rig, heat-exchanger rig port of export gas Temperature≤150 DEG C, the heat-exchanger rig port of export is connected with cleaner unit, also include drive high-temperature flue gas successively along high-temperature filter (2), The blower fan (5) of heat-exchanger rig, cleaner unit flowing.
2. the recovery system containing arsenic copper scap flue gas during smelting as claimed in claim 1, it is characterised in that described heat-exchanger rig is Surface cooler (3).
3. the recovery system containing arsenic copper scap flue gas during smelting as claimed in claim 1, it is characterised in that described sintering is inorganic many Porous materials is flexible, porous metal forming.
4. the recovery system containing arsenic copper scap flue gas during smelting as claimed in claim 3, it is characterised in that described flexible, porous gold The aperture belonging to paper tinsel is 0.05 μm-100 μm.
5. the recovery system containing arsenic copper scap flue gas during smelting as claimed in claim 3, it is characterised in that described flexible, porous gold The thickness belonging to paper tinsel is 5-1500 μm.
6. the recovery system containing arsenic copper scap flue gas during smelting as claimed in claim 3, it is characterised in that described flexible, porous gold The porosity belonging to paper tinsel is 15-70%.
7. the recovery system containing arsenic copper scap flue gas during smelting as claimed in claim 1, it is characterised in that described cleaner unit is cloth Sack cleaner (4).
CN201620069742.4U 2016-01-25 2016-01-25 It smelts recovery system of flue gas to contain useless composition brass of arsenic Active CN205461100U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201620069742.4U CN205461100U (en) 2016-01-25 2016-01-25 It smelts recovery system of flue gas to contain useless composition brass of arsenic

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Application Number Priority Date Filing Date Title
CN201620069742.4U CN205461100U (en) 2016-01-25 2016-01-25 It smelts recovery system of flue gas to contain useless composition brass of arsenic

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112742131A (en) * 2020-12-31 2021-05-04 成都易态科技有限公司 Treatment system and treatment method for flue gas generated in copper matte preparation by pyrogenic process

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112742131A (en) * 2020-12-31 2021-05-04 成都易态科技有限公司 Treatment system and treatment method for flue gas generated in copper matte preparation by pyrogenic process

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