CN205361215U - Carbide slag slurrying device - Google Patents

Carbide slag slurrying device Download PDF

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Publication number
CN205361215U
CN205361215U CN201620114265.9U CN201620114265U CN205361215U CN 205361215 U CN205361215 U CN 205361215U CN 201620114265 U CN201620114265 U CN 201620114265U CN 205361215 U CN205361215 U CN 205361215U
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carbide slag
slurrying
ring type
cement slurry
water
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张志贤
齐周
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ANHUI JINXING TITANIUM DIOXIDE (GROUP) Co Ltd
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ANHUI JINXING TITANIUM DIOXIDE (GROUP) Co Ltd
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Abstract

The utility model discloses a carbide slag slurrying device belongs to the carbide slag field of handling. The utility model discloses a carbide slag slurrying device, including material feeding unit, slurrying agitating unit and water supply installation, material feeding unit be used for carrying the carbide slag to agitating unit, slurrying agitating unit includes rabbling mechanism and slurrying bucket, is equipped with ring type aeration pipe in the slurrying bucket, through ring type aeration pipe to supplying compressed air in the slurrying bucket. The method of utilizing the device to carry out slurrying does: temperature back up to standard is to intaking in the slurrying bucket to appointed liquid level, then adds the carbide slag, and carbide slag slurry is made in the air agitation. The utility model discloses utilize temperature, pH, aeration to synthesize the influence to what the material ammonia nitrogen was handled, cyclic utilization heat energy source and water resource, improving energy efficiency to reduced total log raft high -volume, reduced the ammonia nitrogen total amount of bringing the neutralized system by the carbide slag into, greatly alleviateed the environmental protection and dropped into and ambient pressure.

Description

A kind of carbide slag pulping device
Technical field
This utility model relates to carbide slag processing technology field, more particularly, it relates to a kind of carbide slag pulping device.
Background technology
Carbide slag is the strong basicity waste residue that a kind of Acetylenogen. prepares the later discharge of acetylene, its main component is calcium hydroxide, because it has alkaline feature, therefore in discharge in the environment, or environment will be caused serious pollution by stacking process, earth's surface not only can be caused to pollute, also result in groundwater resources etc. all to be polluted simultaneously, therefore, in order to reduce carrying capacity of environment and save cost, the call of response " treatment of wastes with processes of wastes against one another, turn waste into wealth ", comprehensively utilizes for carbide slag, it is to avoid the environmental pollution that the discharge of carbide slag causes.At present, carbide slag is widely used to process chemical industry acid waste water.
Carbide slag presents strong basicity, for this, it can be used as field of waste water treatment, usually it can be used as the process of acid waste water, and in current prior art, the discharge capacity of acid waste water is often average annual bigger, its source is also varied, the discharge of acid waste water not only can bring pollution to earth's surface, also can bring pollution to subsoil water, causes serious ecology influence.When utilizing carbide slag treatment of acidic wastewater, in order to improve the utilization rate of carbide slag, it will usually with sand leaching water, carbide slag slurrying is become qualified carbide slag breast, for acid-base neutralization after stirring.But this method process after water in ammonia-nitrogen content higher, it is impossible to be expelled directly out, in addition it is also necessary to remove ammonia nitrogen by chemical method, be then discharged into external environment again, cause that whole technical process is loaded down with trivial details, consumption relatively costly.
China Patent No.: ZL201210310163.0, authorized announcement date: on October 22nd, 2014, this application case discloses a kind of white clay/carbide slag pulping device and technique, device includes ultrasonic washing unit, also include settlement separation tank and homogenizer, described settlement separation tank is connected with the middle part of described ultrasonic washing unit by the pipeline with pump, the charging aperture of described homogenizer connects with the bottom of described ultrasonic washing unit, the discharging opening of described homogenizer connects with the top of described ultrasonic washing unit, is provided with agitator in described settlement separation tank and ultrasonic washing unit.
China Patent No.: ZL201510484221.5, authorized announcement date: on November 11st, 2015, the apparatus and method of a kind of desulfurization ash-carbide slag mixed pulp, device includes the reinforced assembly of desulfurization ash, the reinforced assembly of carbide slag and changes slurry assembly;The reinforced assembly of desulfurization ash includes the powder cabin, star feeder and the weighing spiral feeder that are sequentially connected with;The reinforced assembly of carbide slag includes the hopper, belt weighing batcher, belt conveyor, beater and the flushing cinder pond that are sequentially connected with;Change slurry assembly includes the first change stock tank being connected with weighing spiral feeder, the second change stock tank being connected with flushing cinder pond, the 3rd change stock tank being connected with the second change stock tank, is arranged on the spin vibration sieve connected on the second pipeline changing stock tank and the 3rd change stock tank and the serosity mixing pit being connected with the first change stock tank and the 3rd change stock tank respectively.
Both the above technical scheme all gives the relevant programme of carbide slag slurrying, but does not provide simple and effective solution for how eliminating the ammonia nitrogen in serosity, need those skilled in the art and studies further, explores.
Utility model content
1. utility model to solve the technical problem that
The purpose of this utility model is in that to overcome the deficiency that when utilizing carbide slag breast process waste water in prior art, ammonia-nitrogen content is high, provide a kind of carbide slag pulping device, the technical solution of the utility model, utilize temperature, pH, the aeration combined influence to material NH_3-N treating, recycle heat energy and water resource, improved energy utilization rate, and reduce total water discharge capacity, reduce the TAN being brought into neutralized system by carbide slag, greatly alleviate Environmental Inputs and ambient pressure.
2. technical scheme
For reaching above-mentioned purpose, the technical scheme that this utility model provides is:
A kind of carbide slag pulping device of the present utility model, including pay-off, slurrying agitating device and water supply installation, described pay-off is auger pay-off or belt type feeding device, for carrying carbide slag to agitating device;Described slurrying agitating device includes rabbling mechanism and cement slurry preparing barrel, pulls an oar for carbide slag;Described cement slurry preparing barrel, built with ring type aeration tube, compresses air by ring type aeration tube to supply in cement slurry preparing barrel;Described water supply installation includes bucket, is used for storing slurrying water.
Further improve as this utility model, described belt type feeding device includes feed mechanism and hopper, feed mechanism is mainly made up of drive motor, bracing frame and feeding belt, and described feeding belt one end is arranged on the lower section of hopper, and the other end is suspended on the top of cement slurry preparing barrel.
Further improving as this utility model, described rabbling mechanism includes stirring motor and stirring paddle, and the blade-carrying one end of described stirring paddle is arranged in cement slurry preparing barrel, and stirring motor is used for driving stirring paddle to rotate.
Further improving as this utility model, described ring type aeration tube is connected with the exhaustor of air compressor by two symmetrically arranged air hoses, is provided with gas valve, is provided with at least 5 solarization air caps on ring type aeration tube on exhaustor.
Further improving as this utility model, described ring type aeration tube has an at least two, and ring type aeration tube is along the upper and lower arrangement of inwall of cement slurry preparing barrel.
Further improving as this utility model, the aperture of described solarization air cap is 10~30mm.
Further improving as this utility model, the reaction treatment aqueous phase that the water inlet pipe of described bucket and band have surplus heat leads to, and the drain pipe of bucket is connected with cement slurry preparing barrel, is provided with water pump on drain pipe;The thermometer for detecting water temperature it is provided with in described bucket.
A kind of carbide slag pulping process of the present utility model, comprises the following steps:
Step 1, utilize in carbide slag pulping device bucket to collect to produce remaining hot water, detect water temperature by thermometer;
Step 2, when in step 1 thermometer display water temperature up to standard after, be pumped in cement slurry preparing barrel to designated value by the remaining hot water in pump handle bucket;
Step 3, unlatching feed mechanism, deliver to the carbide slag in hopper in cement slurry preparing barrel by feeding belt, controls liquid level to designated value, closes feed mechanism;
Step 4, the gas valve opened on exhaustor, by air compressor to aeration in cement slurry preparing barrel.
Further improving as this utility model, the pump coolant-temperature gage in step 2 is at least 50 DEG C;The mass ratio of the carbide slag in step 3 and water is 4:1~1:4.
Further improving as this utility model, mixing time is 20~60min;Aeration time is 20~60min;Stirring and aeration carry out simultaneously, or adopt intermittent aeration.
3. beneficial effect
The technical scheme adopting this utility model to provide, compared with prior art, has the advantages that
(1) a kind of carbide slag pulping device of the present utility model, utilizes the process water with residual heat of reaction to prepare carbide slag slurries, improves temperature during slurrying;Arranging multiple ring type aeration tube on cement slurry preparing barrel, and by upper and lower for ring type aeration tube arrangement, can increase aeration rate, during for slurrying, the removal of the ammonia nitrogen in serosity provides condition, contributes to ammonia-nitrogen content in the waste water after reduction processes;
(2) a kind of carbide slag pulping device of the present utility model, the reaction treatment aqueous phase that the water inlet pipe of bucket and band have surplus heat leads to, carbide slag and acid waste water exothermic heat of reaction, with the waste water slurrying after reaction treatment, removal for ammonia nitrogen provides temperature conditions, and is greatly saved displacement;
(3) a kind of carbide slag pulping process of the present utility model, the mass ratio of carbide slag and water controls at 4:1~1:4, the slurry concentration that the quality of carbide slag and water is finally made than major control, Ca (OH) in carbide slag2Be generally 50%, then in the carbide slag slurry prepared, Ca (OH) 2 content range is 10%~40%, the thus pH value of setup control carbide slag slurries, it is provided that higher alkaline environment, it is simple to ammonia nitrogen separates;
(4) a kind of carbide slag pulping process of the present utility model, utilize the production remaining hot water slurrying in N-process, carbide slag slurries concentration and pH is controlled by the ratio of carbide slag with water, utilize temperature, pH, the aeration combined influence to material NH_3-N treating, recycle heat energy and water resource, improved energy utilization rate, and reduce total water discharge capacity, reduce the TAN being brought into neutralized system by carbide slag, greatly alleviate Environmental Inputs and ambient pressure.
Accompanying drawing explanation
Fig. 1 is the structural representation of a kind of carbide slag pulping device of the present utility model.
Label declaration in schematic diagram: 1, feed mechanism;2, hopper;3, rabbling mechanism;4, cement slurry preparing barrel;5, ring type aeration tube;6, air compressor;7, water pump;8, bucket.
Detailed description of the invention
For further appreciating that content of the present utility model, in conjunction with the accompanying drawings and embodiments this utility model is described in detail.
Embodiment 1
In conjunction with Fig. 1, a kind of carbide slag pulping device of the present embodiment, including pay-off, slurrying agitating device and water supply installation, described pay-off is auger pay-off or belt type feeding device, for carrying carbide slag to agitating device;The present embodiment selects belt type feeding device.Specifically, belt type feeding device includes feed mechanism 1 and hopper 2, feed mechanism 1 is mainly made up of drive motor, bracing frame and feeding belt, bracing frame is provided with and organizes roller more, feeding belt passes through roller tensioning, the integral inclined setting of feeding belt, feeding belt one end is arranged on the lower section of hopper 2, and the other end is suspended on the top of cement slurry preparing barrel 4.When conveying, the carbide slag added in hopper 2 drops on feeding belt hypomere, delivers to top by the turning handle carbide slag of feeding belt and falls in slurrying agitating device.
The slurrying agitating device of the present embodiment includes rabbling mechanism 3 and cement slurry preparing barrel 4, pulls an oar for carbide slag.Described rabbling mechanism 3 includes stirring motor and stirring paddle, stirring motor is arranged on cement slurry preparing barrel 4 top, the power output shaft of stirring motor is connected with stirring paddle by reductor, and the blade-carrying one end of stirring paddle is arranged in cement slurry preparing barrel 4, drives stirring paddle to rotate by stirring motor.
The cement slurry preparing barrel 4 of the present embodiment, built with ring type aeration tube 5, compresses air by ring type aeration tube 5 to supply in cement slurry preparing barrel 4.Ring type aeration tube 5 is connected with the exhaustor of air compressor 6 by two symmetrically arranged air hoses, is provided with 16 solarization air caps on ring type aeration tube 5, and the aperture of solarization air cap is 15mm.Exhaustor is provided with gas valve, controls whether to pass into compression air.
In common pulping process, it is mostly by quickly stirring quickening course of reaction, but is stirring for the serosity being difficult to make bottom to top, and few with the contact area of air, and the ammonia nitrogen within serosity is difficult to get rid of.After increasing ring type aeration tube 5, substantial amounts of air is discharged from cement slurry preparing barrel 4 bottom, and the ammonia in serosity is separated, and greatly reduces the ammonia-nitrogen content of serosity.
The water supply installation of the present embodiment includes bucket 8, is used for storing slurrying water.The reaction treatment aqueous phase that the water inlet pipe of bucket 8 and band have surplus heat leads to, the drain pipe of bucket 8 is connected with cement slurry preparing barrel 4, drain pipe is provided with water pump 7, namely obtained carbide slag slurry treatment of acidic wastewater is utilized, the waste water processed raises due to acid-base reaction temperature, the water slurrying with waste heat after utilization processes, the temperature of water when improving on the one hand slurrying, resource is made to be utilized effectively on the other hand, it is not necessary to carry out sand leaching water again and waste substantial amounts of displacement.
Additionally, in order to control water temperature during slurrying, be provided with the thermometer for detecting water temperature in bucket 8, just start draining slurrying when the temperature in bucket 8 satisfies condition, improve the removal efficiency of ammonia nitrogen.
Embodiment 2
A kind of carbide slag pulping device of the present embodiment, its basic structure is identical with embodiment 1, it is different in that: described ring type aeration tube 5 has two, and two ring type aeration tubes 5 are along the upper and lower arrangement of inwall of cement slurry preparing barrel 4, further increase the contact area of serosity and air.
Embodiment 3
A kind of carbide slag pulping device of the present embodiment, its basic structure is identical with embodiment 2, and it is different in that: in this enforcement, the aperture of solarization air cap is 12mm, is provided with 20 solarization air caps in ring type aeration tube 5 circumference.
Embodiment 4
Based on above carbide slag pulping device, present embodiments provide a kind of carbide slag pulping process, comprise the following steps:
Step 1, utilize in carbide slag pulping device bucket 8 to collect to produce remaining hot water, detect water temperature by thermometer;
Step 2, when in step 1 thermometer display after water temperature is not less than 50 DEG C, be pumped in cement slurry preparing barrel 4 to designated value by the remaining hot water in 7 buckets 8 of water pump;In the present embodiment, cement slurry preparing barrel 4 parameter is diameter 4.5 meters, and bucket is high 4 meters, is filled to liquid level 3.5 meters.
Step 3, unlatching feed mechanism 1, deliver to the carbide slag in hopper 2 in cement slurry preparing barrel 4 by feeding belt, controls liquid level to 4.2 meters, closes feed mechanism 1;
Step 4, the gas valve opened on exhaustor, by air compressor 6 to aeration in cement slurry preparing barrel 4;Aeration time is 30min, and stirring and aeration carry out simultaneously, and the method that also can adopt intermittent aeration is determined with specific reference to use.
Step 5, detection carbide slag slurries ammonia nitrogen index, recording ammonia-nitrogen content is 61.4mg/L.
Ammonia nitrogen in carbide slag slurries is generally with ammonium ion (NH4+) and free ammonia (NH3) state keep balance to exist, common processing method be in carbide slag and acid waste water and after again ammonia nitrogen is processed, due to wastewater flow rate relatively greatly, this mode can increase operation easier and construction cost undoubtedly, and additive easily causes secondary pollution.The present embodiment just removes ammonia nitrogen in pulping process, and carbide slag slurries content waste water total amount relatively to be dealt with is less, it is easy to operation controls.
This utility model is efficiently removed the principle of ammonia nitrogen and is in that, when alkalescence, and ammonium ion (NH4+) comparatively active, and the transition that suitable temperature (being not less than 50 DEG C) is electronics provides enough activation energy, by stirring the mode of aeration, by the free ammonia (NH of gas phase3) take out of, thus breaking balance, promote ammonium ion (NH4+) to free ammonia (NH3) change, thus reaching to remove the effect of ammonia nitrogen.Experiments show that, temperature, pH and three conditions of aeration are most important to this utility model, indispensable.
In concrete pulping process, utilize remaining hot water to carry out slurrying on the one hand, control water temperature and be not less than 50 DEG C, it is provided that higher reaction temperature;Control on the other hand to add the mass ratio of carbide slag and remaining hot water in cement slurry preparing barrel 4, it is ensured that carbide slag slurries concentration suitable for producing, and alkaline environment is provided, be conducive to ammonia nitrogen to separate from liquid phase;Additionally, utilize ring type aeration tube 5 to carry out a large amount of aeration, utilize the difference between actual concentrations and the equilibrium concentration of component in water, make ammonia nitrogen be transferred to gas phase and remove.
Comparative example 1
Step 1, utilize bucket 8 in carbide slag pulping device to collect sand leaching water, detect water temperature 25 DEG C by thermometer;
Step 2, it is pumped in cement slurry preparing barrel 4 by the sand leaching water in 7 buckets 8 of water pump to liquid level 3.5 meters;
Step 3, unlatching feed mechanism 1, deliver to the carbide slag in hopper 2 in cement slurry preparing barrel 4 by feeding belt, controls liquid level to 4.2 meters, closes feed mechanism 1;
Step 4, the gas valve opened on exhaustor, by air compressor 6 to aeration in cement slurry preparing barrel 4;Aeration time is 30min, and stirring and aeration carry out simultaneously.
Step 5, detection carbide slag slurries ammonia nitrogen index, recording ammonia-nitrogen content is 132.6mg/L.
Embodiment 4 is compared with comparative example 1, produces remaining hot water carbide slag slurries relatively sand leaching water carbide slag slurries ammonia nitrogen removal frank and is:
(61.4-132.6) ÷ 132.6=53.7%,
According to this result it can be seen that the obtained serosity of pulping process of the present utility model for ammonia-nitrogen content in treatment of acidic wastewater gained water far below ammonia-nitrogen content in the slurrying processing method of normal sands drainage, ammonia nitrogen removal frank improves more than 50%.
What deserves to be explained is, the slurrying that the carbide slag pulping device that above-mentioned comparative example 1 is based in this utility model carries out, if in common pulping device, lack ring type aeration tube, its ammonia-nitrogen content will be above detected 132.6mg/L, embodies the carbide slag pulping device of the present utility model superior function in removing ammonia-nitrogen content further.
In conjunction with actual production process, the displacement of pulping process of the present utility model is analyzed:
1, certain titanium dioxide sewage treatment process processes sewage 8000m day by day3, wherein H2SO4Content about 4%, FeSO4 content about 0.5%, supply dry carbide slag Ca (OH)2Content is about 50%;
2, the course of reaction of carbide slag and acid waste water is:
H2SO4+Ca(OH)2——CaSO4+2H2OFeSO4+Ca(OH)2——CaSO4+Fe(OH)2
987415274
According to above-mentioned formula, the odd-numbered day processes 8000m3Sewage need to consume the dry carbide quantity of slag:
8000 × 0.04 × 74 ÷ 98 ÷ 0.5+8000 × 0.005 × 74 ÷ 152 ÷ 0.5=522t;
3, carbide slag need to be made Ca (OH) by sewage disposal2Content is about the carbide slag slurries of 10% needs the water consumption to be:
522 × 0.5 ÷ 0.1-522=2088m3
4, can obtain drawing a conclusion according to above result of calculation:
With sand leaching water carbide slag slurries total displacement every day for 8000+2088=10088m3
To produce remaining hot water carbide slag slurries total displacement every day for 8000-2088=5912m3
Odd-numbered day water consumption, produces remaining hot water carbide slag slurries relatively sand leaching water carbide slag slurries and uses sand leaching water 2088m less3
Odd-numbered day total displacement, produces remaining hot water carbide slag slurries relatively sand leaching water carbide slag slurries and discharges less:
(5912-10088) ÷ 10088=41.4%, by relative analysis it can be seen that pulping process of the present utility model need not provide sand leaching water when slurrying, decreases total displacement.
This utility model utilizes temperature, pH, the aeration combined influence to material NH_3-N treating, recycle heat energy and water resource, improved energy utilization rate, and reduce total water discharge capacity, reduce the TAN being brought into neutralized system by carbide slag, greatly alleviate Environmental Inputs and ambient pressure.
Schematically this utility model and embodiment thereof being described above, this description does not have restricted, and shown in accompanying drawing is also one of embodiment of the present utility model, and actual structure is not limited thereto.So, if those of ordinary skill in the art is enlightened by it, when creating objective without departing from this utility model, design the frame mode similar to this technical scheme and embodiment without creationary, protection domain of the present utility model all should be belonged to.

Claims (9)

1. a carbide slag pulping device, including pay-off, slurrying agitating device and water supply installation, it is characterised in that:
Described pay-off is auger pay-off or belt type feeding device, for carrying carbide slag to agitating device;
Described slurrying agitating device includes rabbling mechanism (3) and cement slurry preparing barrel (4), pulls an oar for carbide slag;
Described cement slurry preparing barrel (4), built with ring type aeration tube (5), compresses air by ring type aeration tube (5) to supply in cement slurry preparing barrel (4);
Described water supply installation includes bucket (8), is used for storing slurrying water.
2. a kind of carbide slag pulping device according to claim 1, it is characterized in that: described belt type feeding device includes feed mechanism (1) and hopper (2), feed mechanism (1) is mainly made up of drive motor, bracing frame and feeding belt, described feeding belt one end is arranged on the lower section of hopper (2), and the other end is suspended on the top of cement slurry preparing barrel (4).
3. a kind of carbide slag pulping device according to claim 1, it is characterized in that: described rabbling mechanism (3) includes stirring motor and stirring paddle, the blade-carrying one end of described stirring paddle is arranged in cement slurry preparing barrel (4), and stirring motor is used for driving stirring paddle to rotate.
4. a kind of carbide slag pulping device according to claim 1, it is characterized in that: described ring type aeration tube (5) is connected by the exhaustor of two symmetrically arranged air hoses with air compressor (6), is provided with gas valve on exhaustor.
5. a kind of carbide slag pulping device according to claim 1 or 4, it is characterised in that: described ring type aeration tube (5) is provided with at least 5 solarization air caps.
6. a kind of carbide slag pulping device according to claim 5, it is characterised in that: the aperture of described solarization air cap is 10~30mm.
7. a kind of carbide slag pulping device according to claim 4, it is characterised in that: described ring type aeration tube (5) has an at least two, and ring type aeration tube (5) is along the upper and lower arrangement of inwall of cement slurry preparing barrel (4).
8. a kind of carbide slag pulping device according to claim 6, it is characterised in that: described ring type aeration tube (5) has an at least two, and ring type aeration tube (5) is along the upper and lower arrangement of inwall of cement slurry preparing barrel (4).
9. a kind of carbide slag pulping device according to claim 1, it is characterized in that: the reaction treatment aqueous phase that the water inlet pipe of described bucket (8) and band have surplus heat leads to, the drain pipe of bucket (8) is connected with cement slurry preparing barrel (4), is provided with water pump (7) on drain pipe;The thermometer for detecting water temperature it is provided with in described bucket (8).
CN201620114265.9U 2016-02-02 2016-02-02 Carbide slag slurrying device Active CN205361215U (en)

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