CN205288021U - Ammonia absorption device - Google Patents

Ammonia absorption device Download PDF

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Publication number
CN205288021U
CN205288021U CN201521041765.6U CN201521041765U CN205288021U CN 205288021 U CN205288021 U CN 205288021U CN 201521041765 U CN201521041765 U CN 201521041765U CN 205288021 U CN205288021 U CN 205288021U
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CN
China
Prior art keywords
tank
grades
tourie
touries
ammonia
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Expired - Fee Related
Application number
CN201521041765.6U
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Chinese (zh)
Inventor
王立峰
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TIANJIN HANDEWEI PHARMACEUTICAL CO Ltd
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TIANJIN HANDEWEI PHARMACEUTICAL CO Ltd
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Application filed by TIANJIN HANDEWEI PHARMACEUTICAL CO Ltd filed Critical TIANJIN HANDEWEI PHARMACEUTICAL CO Ltd
Priority to CN201521041765.6U priority Critical patent/CN205288021U/en
Application granted granted Critical
Publication of CN205288021U publication Critical patent/CN205288021U/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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  • Treating Waste Gases (AREA)

Abstract

The utility model provides an ammonia absorption device, including condenser, buffer tank, one -level tourie, second grade tourie, tertiary tourie and the tower of absorb the remnant air, it is consecutive through gas transmission pipeline between condenser, buffer tank, one -level tourie, second grade tourie, tertiary tourie and the the tower of absorb the remnant air, it has the heat preservation all to wrap up on one -level tourie and the external lateral wall of second grade tourie jar, all there is the heat sink in the internal portion of one -level tourie and second grade tourie jar. The utility model discloses having at the internal cloth of tourie and leading to a coil pipe and jar heat preservation of external portion that has the cooling water, make the temperature maintain below 25 DEG C, only through the water uptake, the absorption rate of ammonia can reach more than 99%, easy operation, running cost are very low, two one, , the circulation of tertiary tourie absorbs, makes the aqueous ammonia reutilization that generates, the yield can reach more than 99%, has both eliminated the influence to the environment, has very big social again.

Description

A kind of ammonia absorption device
Technical field
This utility model belongs to field of chemical equipment, especially relates to a kind of ammonia absorption device.
Background technology
Being hydrolyzed in industry in tobacco curing acid and .gamma.-pyridinecarboxylic acid technique by raw water solution a large amount of ammonias out, directly discharge meeting is to environment; Processing through wastewater treatment equipment, or process with acidic materials adjustment, treated wastewater flow rate is big, need to pass through purification reprocessing and just can bring benefits, and cost recovery is high, and process is complicated. Existing in ammonia process or retracting device, mostly adopt the mode of absorption tower ejecting liquid, ammonia is made to be dissolved in the fog-like liquid of ejection, the multistage tourie being provided with cooling device is adopted to be circulated absorption, in container, flow regime it is in yet with gas, the droplet of ejection is difficult to fill with whole container, and namely container is at the unapproachable dead angle of droplet, have impact on the dissolving of ammonia and recovery.
Utility model content
Problem to be solved in the utility model is to provide a kind of ammonia absorption device, it is possible to improving the response rate of ammonia, simple to operate, operating cost is low.
For solving above-mentioned technical problem, the technical solution adopted in the utility model is: a kind of ammonia absorption device, including condenser, surge tank, first order absorption tank, two grades of touries, three grades of touries and tail gas absorber; Condenser, surge tank, first order absorption tank, two grades of touries, three grades be sequentially connected by gas pipeline between tourie and tail gas absorber; Described first order absorption tank and two grades of tourie tank body lateral walls are all enclosed with heat-insulation layer, described first order absorption tank and two grades of tourie tank interior and all have heat sink. Heat-insulation layer plays the effect of isolation ambient temperature.
Further, described first order absorption tank, two grades of touries and three grades of touries are respectively arranged with air inlet and air vent, and air inlet and air vent are respectively positioned on more than tank body liquid level, and air inlet pipe inserts tank base respectively, being positioned under liquid level, the tube wall of the air inlet pipe below liquid level is provided with hole. Ammonia becomes tiny bubble through hole, is fully absorbed in water, generates ammonia.
Further, it is sequentially arranged with water between described first order absorption tank and two grades of touries and rushes pump and water pump, water rushes pump one end and is connected with first order absorption tank, and additionally two ends are connected with the air inlet of two grades of touries, water pump respectively, and the water pump other end connects the tank bottoms of two grades of touries. Under the effect of water pump, water body in two grades of touries rushes pump through water pump and water and forms a water ring, constantly the ammonia that first order absorption tank overflows is absorbed to two grades of tourie liquid, and make to be formed in first order absorption tank negative pressure, the ammonia that hydrolytic decomposition pot used in production is discharged is brought into first order absorption tank.
Further, described heat sink is coil pipe, is connected with cooling water in coil pipe. Due to ammonia is dissolved in water can be highly exothermic, ammonia spirit temperature rise after Ammonia solubility diminish, gained ammonia concn is relatively low. Coil pipe and heat-insulation layer coordinate makes the temperature in tank maintain less than 25 DEG C, to ensure the absorbance of ammonia.
Further, described tail gas absorber is built with water pump and spray equipment, and its air inlet is positioned at bottom tower body, and inlet end is equipped with blower fan. Make the continuous Sprayer Circulation of the water body in tower by water pump, absorb tail gas.
Further, described surge tank and first order absorption pot bottom are respectively equipped with the first discharging opening and the second discharging opening. Make pot liquid overflow to prevent the too much water yield from entering first order absorption tank, cause the systemic ammonia of tank to be unable to reach the concentration of needs, be mixed with the ammonia of steam, condenser is entered through pipeline, condensed cooling, steam coagulation Cheng Shui, accumulate in surge tank. Surge tank every batch puts a water by the first drain hole. In first order absorption tank, when ammonia concn reaches after more than 25%, namely reaching sale standard, collected by the second drain hole, notice specialty enterprise visits recovery. After ammonia water emptying in first order absorption tank, weak ammonia in two grades of touries can be proceeded to first order absorption tank, continue to absorb ammonia. After water body in two grades of touries proceeds to first order absorption tank, the water body of three grades of touries will be transferred into two grades of touries. After water body in three grades of touries proceeds to two grades of touries, tap water will be used directly to supplement three grades of tourie water bodys, extremely simple.
Further, described first order absorption pot sidewall is provided with ammonia concn detector and visual liquidometer. Ammonia concn in first order absorption tank can be measured, monitor liquid level.
Relative to prior art, ammonia absorption device described in the utility model has the advantage that
Ammonia absorption device described in the utility model: being furnished with the heat-insulation layer outside coil pipe and tank body being connected with cooling water in tourie body, make temperature maintain less than 25 DEG C, only by the absorption of water, the absorbance of ammonia is up to more than 99%; Simple to operate, operating cost is very low; The cyclic absorption of one, two, three tourie, the ammonia of its generation can utilize by secondary again further, and yield can reach more than 99%, reaches significantly high effects of energy saving and emission reduction, has both eliminated the impact on environment, has again great social benefit.
Accompanying drawing explanation
The accompanying drawing constituting a part of the present utility model is further appreciated by of the present utility model for providing, and schematic description and description of the present utility model is used for explaining this utility model, is not intended that improper restriction of the present utility model. In the accompanying drawings:
Fig. 1 is the structural representation of the ammonia absorption device described in this utility model embodiment.
Description of reference numerals:
1-condenser;2-surge tank; 3-first order absorption tank; Bis-grades of touries of 4-; Tri-grades of touries of 5-; 6-water pump; 7-water rushes pump; 8-tail gas absorber; 9-the first drain hole; 10-the second drain hole.
Detailed description of the invention
It should be noted that when not conflicting, the embodiment in this utility model and the feature in embodiment can be mutually combined.
Below in conjunction with accompanying drawing, specific embodiment of the utility model is elaborated.
As it is shown in figure 1, a kind of ammonia absorption device, including condenser 1, surge tank 2, first order absorption tank 4, three grades of touries 5 of 3, two grades of touries and tail gas absorber 8; Condenser 1, surge tank 2,3, two grades of touries of first order absorption tank 4, three grades are sequentially connected by gas pipeline between tourie 5 and tail gas absorber 8; Described first order absorption tank 3 and two grades of tourie 4 tank body lateral walls are all enclosed with heat-insulation layer, described first order absorption tank 3 and two grades of tourie 4 tank interior and all have heat sink.
3, two grades of touries 4 of above-mentioned first order absorption tank and three grades of touries 5 are respectively arranged with air inlet and air vent, and air inlet and air vent are respectively positioned on more than tank body liquid level, air inlet pipe inserts tank base respectively, is positioned under liquid level, and the tube wall of the air inlet pipe below liquid level is provided with hole.
It is sequentially arranged with water between above-mentioned first order absorption tank 3 and two grades of touries 4 and rushes pump 7 and water pump 6, water rushes pump 7 one end and is connected with first order absorption tank 3, additionally two ends are connected with the air inlet of two grades of touries 4, water pump 6 respectively, and water pump 6 other end connects the tank bottoms of two grades of touries 4.
Above-mentioned heat sink is coil pipe, is connected with cooling water in coil pipe.
Above-mentioned tail gas absorber 8 is built with water pump and spray equipment, and its air inlet is positioned at bottom tower body, and inlet end is equipped with blower fan.
The first discharging opening 9 and the second discharging opening 10 it is respectively equipped with bottom above-mentioned surge tank 2 and first order absorption tank 3.
Above-mentioned first order absorption tank 3 sidewall is provided with ammonia concn detector and visual liquidometer.
Discharging substantial amounts of ammonia in .gamma.-pyridinecarboxylic acid and nicotinic acid hydrolysis, enter condenser 1, condensed cooling, steam coagulation Cheng Shui by appendix, accumulate in surge tank 2, ammonia then continues to move forward into first order absorption tank 3. The air inlet of first order absorption tank 3 is positioned at more than tank level, and air inlet pipe is deep into tank base, and the air inlet tube wall below liquid level is equipped with pore, and ammonia becomes tiny bubble through pore, is fully absorbed in water, generates ammonia. Being furnished with the coil pipe of cooling in first order absorption tank 3, be connected with cooling water, have heat-insulation layer outside tank body in dish tank, both cooperations make the temperature in tank maintain less than 25 DEG C, to ensure the absorbance of ammonia. Unabsorbed ammonia enters two grades of touries 4 through exhaustor, and the air inlet of exhaustor is positioned at more than two grades of tourie 4 liquid levels. Two grades of touries 4 are identical with the structure of first order absorption tank 3. Pump 7 is rushed equipped with water between first order absorption tank 3 and two touries 4, under the effect of water pump 6, water body in two grades of touries 4 rushes pump 7 through water pump 6 and water and forms a water ring, the ammonia constantly overflowed by first order absorption tank 3 absorbs to two grades of tourie 4 tank liquid, and make to be formed in first order absorption tank 3 negative pressure, the ammonia that hydrolytic decomposition pot is discharged is brought into first order absorption tank 3. The minute quantity ammonia overflowed in two grades of touries 4, enters three grades of touries 5 by exhaustor. Three grades of tourie 5 only air inlet pipe are covered with hole below liquid level, and in tank, water body is room temperature. The ammonia amount overflowed because of two grades of touries 4 is very little, and therefore these ammonias substantially also can fully absorb with this understanding in three grades of touries 5.Three grades of tourie 5 exhaustors access tail gas absorber 8, eliminate the ammonia release risk to air further. In tail gas absorber 8, inlet end is equipped with blower fan, and tower body, built with water pump and spray equipment, makes the continuous Sprayer Circulation of the water body in tower by water pump, absorbs tail gas. The gas entering tail gas absorber 8 mainly has three parts: Part I originates from the gas of three grades of touries 5, and the ammonia wherein contained is extremely small; Part II originates from the remaining ammonia of workshop bleacher, owing to still having a small amount of ammonia to be dissolved in feed liquid in hydrolytic decomposition pot, enters in bleacher and also can discharge further, and it will directly be brought into absorption tower 8; Part III is the hydrochloric acid of volatilization in workshop and in crystallizer. This three part through spray-absorption, reaches acid-base neutralization in tail gas absorber 8, forms salt ammonium chloride, and environment is harmless. When the ammonia concn of first order absorption tank 3 reaches after more than 25%, namely reach sale standard, can notify that specialty enterprise visits recovery ammonia. After the ammonia water emptying of first order absorption tank 3, weak ammonia in two grades of touries 4 can be proceeded to first order absorption tank 3, continue to absorb ammonia. After water body in two grades of touries 4 proceeds to first order absorption tank 3, the water body of three grades of touries 5 will be transferred into two grades of touries 4. After water body in three grades of touries 5 proceeds to two grades of absorption 4 tanks, tap water will be used directly to supplement three grades of tourie 5 water bodys.
The foregoing is only preferred embodiment of the present utility model; not in order to limit this utility model; all within spirit of the present utility model and principle, any amendment of making, equivalent replacement, improvement etc., should be included within protection domain of the present utility model.

Claims (7)

1. an ammonia absorption device, it is characterised in that: include condenser (1), surge tank (2), first order absorption tank (3), two grades of touries (4), three grades of touries (5) and tail gas absorber (8); Condenser (1), surge tank (2), first order absorption tank (3), two grades of touries (4), it is sequentially connected by gas pipeline between three grades of touries (5) and tail gas absorber (8); Described first order absorption tank (3) and two grades of tourie (4) tank body lateral walls are all enclosed with heat-insulation layer, described first order absorption tank (3) and two grades of tourie (4) tank interior and all have heat sink.
2. ammonia absorption device according to claim 1, it is characterized in that: described first order absorption tank (3), two grades of touries (4) and three grades of touries (5) are respectively arranged with air inlet and air vent, and air inlet and air vent are respectively positioned on more than tank body liquid level, air inlet pipe inserts tank base respectively, being positioned under liquid level, the tube wall of the air inlet pipe below liquid level is provided with hole.
3. ammonia absorption device according to claim 2, it is characterized in that: be sequentially arranged with water between described first order absorption tank (3) and two grades of touries (4) and rush pump (7) and water pump (6), water rushes pump (7) one end and is connected with first order absorption tank (3), additionally two ends are connected with the air inlet of two grades of touries (4), water pump (6) respectively, and water pump (6) other end connects the tank bottoms of two grades of touries (4).
4. ammonia absorption device according to claim 1, it is characterised in that: described heat sink is coil pipe, is connected with cooling water in coil pipe.
5. ammonia absorption device according to claim 1, it is characterised in that: described tail gas absorber (8) is built with water pump and spray equipment, and its air inlet is positioned at bottom tower body, and inlet end is equipped with blower fan.
6. ammonia absorption device according to claim 1, it is characterised in that: described surge tank (2) and first order absorption tank (3) bottom are respectively equipped with the first discharging opening (9) and the second discharging opening (10).
7. ammonia absorption device according to claim 1, it is characterised in that: described first order absorption tank (3) sidewall is provided with ammonia concn detector and visual liquidometer.
CN201521041765.6U 2015-12-14 2015-12-14 Ammonia absorption device Expired - Fee Related CN205288021U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201521041765.6U CN205288021U (en) 2015-12-14 2015-12-14 Ammonia absorption device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201521041765.6U CN205288021U (en) 2015-12-14 2015-12-14 Ammonia absorption device

Publications (1)

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CN205288021U true CN205288021U (en) 2016-06-08

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CN201521041765.6U Expired - Fee Related CN205288021U (en) 2015-12-14 2015-12-14 Ammonia absorption device

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108117091A (en) * 2018-01-10 2018-06-05 南通大学 Aluminium clinker water solution denitrogenates apparatus control method

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108117091A (en) * 2018-01-10 2018-06-05 南通大学 Aluminium clinker water solution denitrogenates apparatus control method

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CF01 Termination of patent right due to non-payment of annual fee
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Granted publication date: 20160608

Termination date: 20201214