CN205191613U - Thermal power plant's chimney is discharged fume inner tube or inside lining and is used corrosion -resistant brick - Google Patents

Thermal power plant's chimney is discharged fume inner tube or inside lining and is used corrosion -resistant brick Download PDF

Info

Publication number
CN205191613U
CN205191613U CN201520873314.2U CN201520873314U CN205191613U CN 205191613 U CN205191613 U CN 205191613U CN 201520873314 U CN201520873314 U CN 201520873314U CN 205191613 U CN205191613 U CN 205191613U
Authority
CN
China
Prior art keywords
brick
coating
power plant
thermal power
chimney
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201520873314.2U
Other languages
Chinese (zh)
Inventor
李晓东
史杰智
张立新
李京
高英
赵海涛
郭旭
李变群
马越
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Institute of Metal Research of CAS
Original Assignee
Institute of Metal Research of CAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Institute of Metal Research of CAS filed Critical Institute of Metal Research of CAS
Priority to CN201520873314.2U priority Critical patent/CN205191613U/en
Application granted granted Critical
Publication of CN205191613U publication Critical patent/CN205191613U/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Landscapes

  • Chimneys And Flues (AREA)

Abstract

The utility model provides a thermal power plant's chimney is discharged fume inner tube or inside lining and is used corrosion -resistant brick which characterized in that: physically be provided with compact anticorrosive wear -resistant coating (2) in substrate (1) surface at the brick, the section porosity of anticorrosive wear -resistant coating (2) is 1~2 grade, coating curing degree >= 98 percent, anticorrosive wear -resistant coating specifically combines the coating of epoxy powder coating or the preparation of solvent -free epoxy liquid coating for the melting, the coating thickness is 0.2~6mm. The corrosion effects of corrosion -resistant brick is good, and it has, and relative light in weight, structural strength are high, the non -corrosibility can reach advantages such as economical and practical well.

Description

A kind of thermal power plant's chimney emission inner core or liner corrosion resistant brick
Technical field
The utility model relates to the structural design of corrosion resistant brick, preparation technology and applied technical field thereof, specifically proposes a kind of thermal power plant chimney emission inner core or liner corrosion resistant brick.
Background technology
Heat-engine plant wet flue gas desulfurization green technology is because of features such as its desulfuration efficiency is high, ature of coal is widely applicable, mature technology, the steady running cycle are long, load change impact is little, gas treatment ability is large, be widely used in each large and medium-sized thermal power plant, become the leading technology of domestic and international flue gas desulphurization.This technique be utilize flue gas by during desulfurizer and alkaline detergent meet, make acidic materials generation chemical reaction, generate salt, remove SO in flue gas 2deng material.Finally, the flue gas after wet desulfurizing process process discharges through chimney.In early days mainly for promoting the rising height of flue gas, flue gas heat-exchange unit GGH being installed, the neat stress about 50 DEG C that absorption tube is discharged being heated to about 80 DEG C and being beneficial to discharge.But in order to reduce the side effect that adds heat smoke and energy-conservation aspect is considered, all cancelling GGH at the desulfurizer built afterwards, making the wet steam of about 50 DEG C and flue gas directly in smoke stack emission like this, making the corrosion of the wet flue gas at this temperature to chimney even more serious.
When wet desulfurization system is out of service for some reason, the flue gas of now smoke stack emission can reach 180 DEG C, to the destruction of chimney protective materials also very greatly, meanwhile, powerful wet flue gas exhaust jet stream also has certain wear-out failure to chimney wall for flue gas alternation of wetting and drying and temperature alternate run.
Insoluble technical problem is there is: because the neat stress temperature after desulfurization is lower in prior art, humidity is comparatively large, flue gas in chimney along with the increase of height, when flue-gas temperature is lower than dew point, steam in flue gas condenses at inner wall of stack, the SO simultaneously in flue gas 3, HCl, HF, HNO 3etc. being condensed in condensate water, generate and have extremely strong corrosive acid solution, usual pH value is 1.5 ~ 2.5.Owing to generating corrosive acid solution to chimney lining corrosion failure containing wet larger smoke condensation, flue gas can penetrate into chimney internal cylinder surface by liner crack, causes chimney wall corrosion failure, affects chimney structure intensity time serious.
At present both at home and abroad chimney data, the structural material of thermal power plant's chimney emission inner core generally has two kinds: steel inner cylinder type structure and brick inner core or inside bearing strip structure.Wherein: steel inner cylinder structure adopts protective coating to carry out anticorrosion, namely as glass flake, fiberglass, polyurea protection etc., but there is large area hollowing and obscission in application soon.In addition also have and adopt titanium lined plate, but cost is extremely expensive.Corrosion resistant brick is adopted for brick inner core or inner lining structure, as materials such as foam glass brick, foamed ceramic brick, acidproof bricks, but in use affects by dry wet alternation and temperature alternating the phenomenon often finding that there is cracking and peel off.
People urgently wish to obtain a kind of economical and practical, thermal power plant's chimney emission inner core corrosion resistant brick that technique effect is excellent.
Utility model content
The purpose of this utility model is to provide a kind of economical and practical, thermal power plant's chimney emission inner core that technique effect is excellent or liner corrosion resistant brick.
A kind of thermal power plant's chimney emission inner core of the utility model or liner corrosion resistant brick, is characterized in that:
Be provided with fine and close antiseptic wearable coat 2 on brick body base material 1 surface, the section porosity of antiseptic wearable coat 2 is 1 ~ 2 grade, curing of coatings degree >=98 ﹪; Antiseptic wearable coat is specially the coating of smelting combined epoxy powdery paints or the making of non-solvent epoxy liquid coating; Coating layer thickness is 0.2 ~ 6 ㎜.
Corrosion resistant brick key property index request is as follows: compression strength >=2MPa; Resistance to 160 DEG C of temperature difference acute degenerations circulation >=30 times in air; Resistance to 75 DEG C of temperature difference acute degenerations circulation >=40 times in water; Resistance to 80 DEG C, the sulfuric acid of 20% soaks 7d: compression strength retention rate >=95%; Wearability: Cs10,1Kg, 1000r≤50mg.See table 1:
Table 1 corrosion resistant brick key property index request
Described thermal power plant chimney emission inner core corrosion resistant brick, is characterized in that: brick body base material is specifically following one of several: foamed brick, fired brick, cement brick or composite brick.
The utility model also relates to aforementioned by the preparation method of utility model content closely-related a kind of thermal power plant chimney emission inner core or liner corrosion resistant brick in technology application practice, automatic continuous production and the mode of production hand-manipulated can be adopted to carry out, it is characterized in that: at the high-performance epoxy anticorrosion wear-resistant coating that the preparation of brick body substrate surface is fine and close; Two kinds of preparation method's specific requirements of described thermal power plant chimney internal cylinder or liner corrosion resistant brick are as follows:
(1) with the preparation of smelting combined epoxy powdery paints:
First the preheating of brick body is carried out: treating that application brick body inserts preheating in baking oven, preheat temperature controls, at 220 ± 40 DEG C, to be then incubated 20 ~ 60 minutes;
Carry out application afterwards: preheating brick is immersed and fills in the fluid bed of powdery paints, regulate the fluidisation time according to actual conditions and immerse number of times, to reach required thickness 0.2 ~ 6 ㎜; Fluidisation time requirement is 1 ~ 10 second, and immersing number of times is 1 ~ 10 time;
And then carrying out curing of coatings: the brick applied is sent in baking oven and solidifies further, reach coating optimum performance, solidification temperature is 200 ± 40 DEG C;
(2) with the antiseptic wearable coat of non-solvent epoxy liquid coating in brick body substrate surface preparation densification: adopt high pressure airless spraying apparatus directly to carry out spray-on coating operation to brick body, coating layer thickness is 0.2 ~ 6mm as required.
The preparation method of described thermal power plant chimney emission inner core corrosion resistant brick, is characterized in that: when carrying out the preheating of brick body, preheat temperature controls, at 220 ± 40 DEG C, to be then incubated 20 ~ 60 minutes to assigned temperature; When carrying out curing of coatings, solidification temperature is 200 ± 40 DEG C.
Before the application of brick body, preferred operations will carry out surface pretreatment to brick body base material, specific requirement is as follows: matrix brick needs fully dry, adopt the mode texturing brick body of sandblasting to treat coating surface, depth of abrasion pattern, between 50 ~ 200 microns, purges surface clean with pressure-air afterwards.
For ensureing technique effect further, the matrix brick choice requirement surfacing of coating to be prepared, the nothing obviously rough and uneven in surface and open defect such as crack, cavity.
Adopt smelting combined epoxy powdery paints in fluidized bed painting mode, or (the similar preparation manipulation technique of liquid coating is similar with using in prior art in airless spraying mode to adopt solvent-free liquid epoxy coating, do not repeat them here), fine and close antiseptic wearable coat is formed in brick surface, to reach anticorrosion effect after solidification.
The good resistance to chemical corrosion that the utility model has based on high-performance epoxy coating and mechanical performance, described thermal power plant chimney emission inner core or liner corrosion resistant brick can resist the corrosive conditions environment of wet-method desulfurized fume condensation acidic liquid completely, if make this type coating of one deck on common brick surface, this composite brick matrix can be ensured under the corrosive conditions environmental condition of smoke condensation acidic liquid from corrosion.
Based on structural material and the Problems existing of thermal power plant's chimney emission inner core or liner employing both at home and abroad at present, the utility model proposes a kind of corrosion protection can better the corrosion resistant brick (essence is a kind of composite brick) of surface coating high-performance epoxy coating, it can substitute the material such as foam glass brick, foamed ceramic brick, acidproof brick used at present, has the advantages such as relative weight is light, structural strength is high, antiseptic property is good and economical and practical.
Accompanying drawing explanation
Below in conjunction with drawings and the embodiments, the utility model is described in further detail:
Fig. 1 is thermal power plant's chimney emission inner core corrosion resistant brick structural representation sketch sectional view.
Detailed description of the invention
The implication that in Fig. 1, Reference numeral 1 represents is brick body base material, Reference numeral 2 implication is that (smelting combined epoxy powdery paints or non-solvent epoxy liquid coating make face coat, in Fig. 1, Reference numeral 2 indication place is section, and hatching omits and do not draw---hereby illustrate).
Embodiment 1
A kind of thermal power plant's chimney emission inner core or liner corrosion resistant brick, be provided with fine and close antiseptic wearable coat 2 on brick body base material 1 surface, the section porosity of antiseptic wearable coat 2 is 1 ~ 2 grade, curing of coatings degree >=98 ﹪; Antiseptic wearable coat is specially the coating of smelting combined epoxy powdery paints or the making of non-solvent epoxy liquid coating; Coating layer thickness is 0.2 ~ 6 ㎜.
Corrosion resistant brick key property index request is as follows: compression strength >=2MPa; Resistance to 160 DEG C of temperature difference acute degenerations circulation >=30 times in air; Resistance to 75 DEG C of temperature difference acute degenerations circulation >=40 times in water; Resistance to 80 DEG C, the sulfuric acid of 20% soaks 7d: compression strength retention rate >=95%; Wearability: Cs10,1Kg, 1000r≤50mg.Specific targets can see table 1:
Table 1 corrosion resistant brick key property index request
In described thermal power plant chimney emission inner core corrosion resistant brick, brick body base material is specifically following one of several: foamed brick, fired brick, cement brick or composite brick.
With the preparation method of foregoing teachings closely-related thermal power plant chimney emission inner core or liner corrosion resistant brick: automatic continuous production and the mode of production hand-manipulated can be adopted to carry out, and its important requirement is:
At the high-performance epoxy anticorrosion wear-resistant coating that the preparation of brick body substrate surface is fine and close; Two kinds of preparation method's specific requirements of described thermal power plant chimney internal cylinder or liner corrosion resistant brick are as follows:
(1) with the preparation of smelting combined epoxy powdery paints:
First the preheating of brick body is carried out: treating that application brick body inserts preheating in baking oven, preheat temperature controls, at 220 ± 40 DEG C, to be then incubated 20 ~ 60 minutes;
Carry out application afterwards: preheating brick is immersed and fills in the fluid bed of powdery paints, regulate the fluidisation time according to actual conditions and immerse number of times, to reach required thickness 0.2 ~ 6 ㎜; Fluidisation time requirement is 1 ~ 10 second, and immersing number of times is 1 ~ 10 time;
And then carrying out curing of coatings: the brick applied is sent in baking oven and solidifies further, reach coating optimum performance, solidification temperature is 200 ± 40 DEG C;
(2) with the antiseptic wearable coat of non-solvent epoxy liquid coating in brick body substrate surface preparation densification: adopt high pressure airless spraying apparatus directly to carry out spray-on coating operation to brick body, coating layer thickness is 0.2 ~ 6mm as required.
The preparation method of described thermal power plant chimney emission inner core corrosion resistant brick, requires: when carrying out the preheating of brick body, preheat temperature controls, at 220 ± 40 DEG C, to be then incubated 20 ~ 60 minutes to assigned temperature; When carrying out curing of coatings, solidification temperature is 200 ± 40 DEG C.
Before the application of brick body, preferred operations will carry out surface pretreatment to brick body base material, specific requirement is as follows: matrix brick needs fully dry, adopt the mode texturing brick body of sandblasting to treat coating surface, depth of abrasion pattern, between 50 ~ 200 microns, purges surface clean with pressure-air afterwards.
For ensureing technique effect further, the matrix brick choice requirement surfacing of coating to be prepared, the nothing obviously rough and uneven in surface and open defect such as crack, cavity.
Adopt smelting combined epoxy powdery paints in fluidized bed painting mode, or (the similar preparation manipulation technique of liquid coating is similar with using in prior art in airless spraying mode to adopt solvent-free liquid epoxy coating, do not repeat them here), fine and close antiseptic wearable coat is formed in brick surface, to reach anticorrosion effect after solidification.
The good resistance to chemical corrosion that the present embodiment has based on high-performance epoxy coating and mechanical performance, described thermal power plant chimney emission inner core or liner corrosion resistant brick can resist the corrosive conditions environment of wet-method desulfurized fume condensation acidic liquid completely, if make this type coating of one deck on common brick surface, this composite brick matrix can be ensured under the corrosive conditions environmental condition of smoke condensation acidic liquid from corrosion.
Based on structural material and the Problems existing of thermal power plant's chimney emission inner core or liner employing both at home and abroad at present, the present embodiment proposes a kind of corrosion protection can better the corrosion resistant brick (essence is a kind of composite brick) of surface coating high-performance epoxy coating, it can substitute the material such as foam glass brick, foamed ceramic brick, acidproof brick used at present, has the advantages such as relative weight is light, structural strength is high, antiseptic property is good and economical and practical.
Embodiment 2
A kind of thermal power plant chimney emission inner core corrosion resistant brick, has fine and close antiseptic wearable coat at brick body substrate surface; Antiseptic wearable coat is specially the coating of smelting combined epoxy powdery paints or the making of non-solvent epoxy liquid coating; Coating layer thickness is 0.2 ~ 6 ㎜.
Described thermal power plant chimney emission inner core or liner corrosion resistant brick, is characterized in that: brick body base material is specifically following one of several: foamed brick, fired brick, cement brick or composite brick.
For ensureing technique effect further, treat the matrix brick choice requirement surfacing of application high-performance epoxy coating, the nothing obviously rough and uneven in surface and open defect such as crack, cavity.
Adopt smelting combined epoxy powdery paints with fluidized bed painting mode or with non-solvent epoxy liquid coating in the mode of airless spraying, after solidification, form the antiseptic wearable coat of densification in brick surface, to reach the wear-resistant effect of anticorrosion.
The good resistance to chemical corrosion that the present embodiment has based on high-performance epoxy coating and mechanical performance, described thermal power plant chimney emission inner core or liner corrosion resistant brick can resist the corrosive conditions environment of wet-method desulfurized fume condensation acidic liquid completely, if make one deck high-performance epoxy coating on common brick surface, this composite brick matrix can be ensured under the corrosive conditions environmental condition of smoke condensation acidic liquid from corrosion.
Based on structural material and the Problems existing of thermal power plant's chimney emission inner core employing both at home and abroad at present, the present embodiment proposes a kind of corrosion protection can better the corrosion resistant brick (essence is a kind of composite brick) of surface coating high-performance epoxy coating, it can substitute the material such as foam glass brick, foamed ceramic brick, acidproof brick used at present, has the advantages such as relative weight is light, structural strength is high, antiseptic property is good and economical and practical.
Embodiment 2
The preparation method of thermal power plant's chimney emission inner core or liner corrosion resistant brick described in embodiment 1: have fine and close high-performance epoxy anticorrosion wear-resistant coating at brick body substrate surface; The method that described thermal power plant chimney emission inner core corrosion resistant brick adopts clinkery epoxy powder coating to prepare is as follows:
First the preheating of brick body is carried out: treating that application brick body inserts preheating in baking oven, preheat temperature controls, at 220 ± 40 DEG C, to be then incubated 20 ~ 60 minutes to assigned temperature;
Carry out application afterwards: preheating brick is immersed and fills in the fluid bed of powdery paints, regulate the fluidisation time according to actual conditions and immerse number of times, to reach required thickness 0.2 ~ 6 ㎜;
And then carrying out curing of coatings: the brick applied is sent in baking oven and solidifies further, reach coating optimum performance, solidification temperature is 200 ± 40 DEG C.
Optimized parameter requires: when carrying out the preheating of brick body, preheat temperature controls, at 220 ± 40 DEG C, to be then incubated 20 ~ 60 minutes to assigned temperature; When carrying out curing of coatings, solidification temperature is about 200 ± 40 DEG C.
Preferably surface pretreatment can also be carried out to brick body base material before the application of brick body, specific requirement is as follows: matrix brick needs fully dry, adopt the mode texturing brick body of sandblasting to treat coating surface, depth of abrasion pattern, between 50 ~ 200 microns, purges surface clean with pressure-air afterwards.
For ensureing technique effect further, treat the matrix brick choice requirement surfacing of application high-performance epoxy coating, the nothing obviously rough and uneven in surface and open defect such as crack, cavity.
Adopt smelting combined epoxy powdery paints with fluidized bed painting mode or with non-solvent epoxy liquid coating in the mode of airless spraying, after solidification, form the high-performance epoxy anticorrosion wear-resistant coating of densification in brick surface, to reach anticorrosion effect.
The good resistance to chemical corrosion that the present embodiment has based on high-performance epoxy coating and mechanical performance, described thermal power plant chimney emission inner core corrosion resistant brick can resist the corrosive conditions environment of wet-method desulfurized fume condensation acidic liquid completely, if make one deck high-performance epoxy coating on common brick surface, this composite brick matrix can be ensured under the corrosive conditions environmental condition of smoke condensation acidic liquid from corrosion.
Based on structural material and the Problems existing of thermal power plant's chimney emission inner core employing both at home and abroad at present, the present embodiment proposes a kind of corrosion protection can better the corrosion resistant brick (essence is a kind of composite brick) of surface coating high-performance epoxy coating, it can substitute the material such as foam glass brick, foamed ceramic brick, acidproof brick used at present, has the advantages such as relative weight is light, structural strength is high, antiseptic property is good and economical and practical.

Claims (2)

1. thermal power plant's chimney emission inner core or liner corrosion resistant brick, it is characterized in that: be provided with fine and close antiseptic wearable coat (2) on brick body base material (1) surface, the section porosity of antiseptic wearable coat (2) is 1 ~ 2 grade, curing of coatings degree >=98 ﹪; Antiseptic wearable coat is specially the coating of smelting combined epoxy powdery paints or the making of non-solvent epoxy liquid coating; Coating layer thickness is 0.2 ~ 6mm.
2. according to thermal power plant's chimney emission inner core described in claim 1 or liner corrosion resistant brick, it is characterized in that: brick body base material is specifically following one of several: foamed brick, fired brick, cement brick or composite brick.
CN201520873314.2U 2015-11-04 2015-11-04 Thermal power plant's chimney is discharged fume inner tube or inside lining and is used corrosion -resistant brick Active CN205191613U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201520873314.2U CN205191613U (en) 2015-11-04 2015-11-04 Thermal power plant's chimney is discharged fume inner tube or inside lining and is used corrosion -resistant brick

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201520873314.2U CN205191613U (en) 2015-11-04 2015-11-04 Thermal power plant's chimney is discharged fume inner tube or inside lining and is used corrosion -resistant brick

Publications (1)

Publication Number Publication Date
CN205191613U true CN205191613U (en) 2016-04-27

Family

ID=55784596

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201520873314.2U Active CN205191613U (en) 2015-11-04 2015-11-04 Thermal power plant's chimney is discharged fume inner tube or inside lining and is used corrosion -resistant brick

Country Status (1)

Country Link
CN (1) CN205191613U (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106017114A (en) * 2016-06-18 2016-10-12 湖南众鑫新材料科技股份有限公司 Vanadium nitride kiln smoke discharge system modification process

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106017114A (en) * 2016-06-18 2016-10-12 湖南众鑫新材料科技股份有限公司 Vanadium nitride kiln smoke discharge system modification process
CN106017114B (en) * 2016-06-18 2017-12-12 湖南众鑫新材料科技股份有限公司 A kind of vanadium nitride stores stove Modification of Waste Gas Exhausting System technique

Similar Documents

Publication Publication Date Title
CN201437084U (en) Composite corrosion-resistant lining
CN201206948Y (en) Corrosion preventive ceramic fiber composite liner structure
CN114752278A (en) Solvent-free high-temperature-resistant heavy-duty anticorrosive paint and preparation method thereof
CN101168976B (en) Antisepsis method for fire coal tail gas funnel
CN205191613U (en) Thermal power plant's chimney is discharged fume inner tube or inside lining and is used corrosion -resistant brick
CN105951098B (en) A kind of preparation method of thermal power plant flue enamel plate
CN201593795U (en) Sealed lining antiseptic structure of wet chimney
CN202485016U (en) Wet-desulphurization anticorrosion system of inner-steel-cylinder chimney of thermal power plant
CN102191450A (en) Ceramic coating of boiler mucking machine, and preparation method thereof
CN102634784A (en) Surface treatment method of nuclear bridge
CN100402458C (en) Antiseptic acidproof heat-proof concrete and its uses
JP2006297883A (en) Heat-resistant, corrosion-resistant composite lining
CN102585655B (en) A kind of impregnating material for stack desulfurization chimney
CN211420051U (en) Energy-saving coke oven top
CN105823064A (en) Incinerator used for treating waste sulfuric acid with high salt content
CN202274497U (en) Corrosion-resistant structure for chimney liner
CN106642174A (en) Corrosion resistant brick for thermal power plant chimney inner cylinder or lining and preparation method thereof
CN205332248U (en) Corrosion control system behind single chimney wet flue gas desulfurization of reinforced concrete
CN211799874U (en) Corrosion-resistant high-strength desulfurization and denitrification spray tower
US20110017395A1 (en) Composite resin tile system
CN2928214Y (en) Spray washing tower for burning exhaust gas
CN205332249U (en) Corrosion control system that inside lining was demolishd behind single chimney wet flue gas desulfurization of tradition
CN212901568U (en) Corrosion-proof chimney
CN111036523A (en) Compound corrosion prevention process for desulfurizing tower
CN204962812U (en) Anticorrosive mechanism of chimney

Legal Events

Date Code Title Description
C14 Grant of patent or utility model
GR01 Patent grant