CN205164504U - Denitration of coke oven flue gas desulfurization and waste heat utilization system - Google Patents

Denitration of coke oven flue gas desulfurization and waste heat utilization system Download PDF

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CN205164504U
CN205164504U CN201521028664.5U CN201521028664U CN205164504U CN 205164504 U CN205164504 U CN 205164504U CN 201521028664 U CN201521028664 U CN 201521028664U CN 205164504 U CN205164504 U CN 205164504U
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coke oven
flue gas
heat
denitration
oven flue
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张亚志
张宇鑫
周向
朱繁
张传波
任乐
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MCC Capital Engineering and Research Incorporation Ltd
Zhongye Jingcheng Engineering Technology Co Ltd
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Zhongye Jingcheng Engineering Technology Co Ltd
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Abstract

The utility model provides a denitration of coke oven flue gas desulfurization and waste heat utilization system, this system includes at least: the unit is discharged to denitration of coke oven flue gas desulfurization and waste heat utilization unit and coke oven flue gas safety, denitration of coke oven flue gas desulfurization and waste heat utilization unit include SCR denitrification facility, SCR denitrification facility is the SCR denitrification facility 200 DEG C ~350 DEG C of uses, coke oven flue gas safety is discharged the unit and is included safe flue and chimney, the fume emission mouth of coke oven through pipeline and three -way switch valve connect respectively in the entry of denitration of coke oven flue gas desulfurization and waste heat utilization unit reaches the one end of safe flue, the other end of safe flue connect in the bottom of chimney, the bottom of chimney sets up and makes it make the heat supply unit that is in heat and is equipped with the state. Denitration of coke oven flue gas desulfurization and waste heat recovery system can ensure SOx/NOx control efficiency, and be safe feasible.

Description

Coke oven flue gas desulphurization denitration and bootstrap system
Technical field
The utility model relates to a kind of tail gas desulfurization denitration and bootstrap system, particularly relates to coke oven flue gas desulphurization denitration and bootstrap system.
Background technology
Along with the development of China's economy, every economic establishments are all flourish, but due to the weakness of environmental protection consciousness in development in the early stage and the not in place of environmental protection technology, exert a certain influence to environment especially atmospheric environment.The domestic even international extensive concern that causes especially of many ground, north severe haze weather that especially Beijing area occurs in recent years.
At present, the desulphurization denitration process of domestic coke oven flue gas is still in the starting stage, and the coke oven flue gas of most coke-oven plant, steel mill is still not treated to be directly discharged in air.Such way has had a strong impact on local atmospheric environment, also brings very large hidden danger to the health of people.Along with the appearance of stricter coke oven flue gas discharge standard GB16171-2012, the desulphurization and denitration of coke oven flue gas will become the indispensable technique of domestic all coking production factories.Can predict, the discharge standard of following flue gas can be drawn close to stricter International Environmental Protection standard, to adapt to international energy-conserving and environment-protective trend.So, a kind of reliable system and technique must be had to the object of the desulphurization denitration and waste heat recovery that realize coke oven flue gas.
CN104548900A discloses a kind of coke oven flue gas denitration desulfurization and reheat system process unit, and it is connected is formed by SCR denitration reactor, GGH smoke re-heater, desulfurizing tower, ammoniacal liquor evaporimeter, ammonia empty blender, dilution air, ammoniacal liquor thinning tank, aqua ammonia pump, booster fan, flue gas transfer valve, chimney and pipeline.First flue gas from coke oven enters SCR denitration reactor and carries out denitration, wet flue gas after heat smoke enters GGH smoke re-heater and desulfurizing tower desulfurization after denitration carries out heat exchange, by entering desulfurizing tower desulfurization after booster fan supercharging after after heat exchange, heat smoke is down to 150 ~ 160 DEG C by 280 ~ 350 DEG C, desulfurizing tower outlet wet flue gas enters GGH smoke re-heater and becomes about 160 DEG C flue gases to enter smoke stack emission by 70 ~ 80 DEG C of heat exchange; Whole system flue gas is switched by flue gas transfer valve, and namely when the situations such as desulfurization maintenance or fault outage occur, after denitration, flue gas is opened by transfer valve and directly entered smoke stack emission; Online regenerative ratio is switched by flue gas transfer valve after SCR denitration reactor internal cause tarry matters in smoke etc. are poisoning.This technology, owing to have employed GGH smoke heat replacing device, causes the flue-gas temperature entering air to reach 160 DEG C, waste completely in coke oven flue gas with heat.High-temperature flue gas directly enters the waste that air causes the energy, cannot recycle this part energy and must cause other energy resource consumptions.
CN104923046A discloses a kind of coke oven flue gas desulphurization and denitration and waste heat recovery integral method, and the system that the method adopts comprises heating furnace, denitrification apparatus, waste-heat recovery device, supplies ammonia system, desulfurizer, thiamine recovery device etc.First flue gas from coke oven enters heating furnace and is heated to 300 ~ 400 DEG C, then enters denitrification apparatus, utilizes denitrification reducing agent and denitrating catalyst to remove nitrogen oxide in flue gas; Denitrification reducing agent is ammonia; Denitrification apparatus flue gas out reclaims heat be cooled to 100 ~ 150 DEG C through waste-heat recovery device, then enters ammonia desulfuration equipment and remove sulfur dioxide in flue gas.The heating furnace that this technology must use needs a large amount of energy resource consumptions, increases extra fuel consumption and environmental pressure.The denitrification apparatus that this system adopts cannot carry out middle low-temperature denitration, can only rely on heating furnace and carry out flue gas; Whole system does not arrange fail-safe exhaust system, cannot ensure coke oven safety in the state of accident, easily causes coke oven to block up cigarette blast.
For a long time, what restriction coke oven flue gas desulfurizing and denitrifying process developed mainly contains two problems: one is the feature that existing desulphurization denitration and waste heat reclaiming process can not adapt to coke oven production, after installing desulphurization denitration facility additional, because flue gas passage resistance strengthens, production security is had an impact.Two is that coke oven flue gas temperature is lower, and existing technique cannot reach good denitration efficiency, and the effect of whole technique cannot be guaranteed.Due to the existence of this two problems, in reality, not yet there is a kind of can either ensure system and technique that coke oven production safety efficiently can complete again desulphurization denitration and waste heat recovery.Therefore, developing a kind of system that can either ensure that coke oven production safety efficiently can complete again desulphurization denitration and waste heat recovery is one of those skilled in the art's technical problem needing solution badly.
Utility model content
Main purpose of the present utility model is to provide coke oven flue gas desulphurization denitration and bootstrap system, and this system can efficiently complete desulphurization denitration and waste heat recovery in the production safety of effective guarantee denitration sulfur removal technology simultaneously.
For achieving the above object, the utility model provides a kind of coke oven flue gas desulphurization denitration and bootstrap system, and wherein, this system at least comprises: coke oven flue gas desulphurization denitration and UTILIZATION OF VESIDUAL HEAT IN unit and coke oven flue gas safety dumping unit;
Described coke oven flue gas desulphurization denitration and UTILIZATION OF VESIDUAL HEAT IN unit comprise SCR denitration device;
Described SCR denitration device is 200 DEG C ~ 350 DEG C SCR denitration device used;
Described coke oven flue gas safety dumping unit comprises safe flue and chimney;
The fume emission mouth of coke oven is connected to the entrance of described coke oven flue gas desulphurization denitration and UTILIZATION OF VESIDUAL HEAT IN unit and one end of described safe flue by pipeline and three-way switch valve, the other end of described safe flue is connected to the bottom of described chimney, and the bottom of described chimney arranges and makes it make to be in the heating unit of hot standby state.
System described in the utility model is by scientific and reasonable design, coke oven flue gas desulphurization denitration and UTILIZATION OF VESIDUAL HEAT IN unit and coke oven flue gas safety dumping unit are be arranged in parallel, enable whole system in the state of accident by the instant switching of three-way switch valve, make coke oven flue gas drain into safe flue and enter air, because chimney is in hot standby state, it will produce nature suction to safe flue, this suction can ensure that coke oven smoke evacuation normally stifled cigarette explosion accident does not occur, thus ensure coke oven safety in production, solve the problem that desulfurizing and denitrifying process under existence conditions cannot ensure coke oven production safety.
In addition, low temperature SCR denitration device during the SCR denitration device used at 200 DEG C ~ 350 DEG C in the utility model system belongs to, because coke oven flue gas temperature is low, for the denitration desulfuration efficiency of not influential system, the denitrification apparatus that prior art adopts needs heating coke oven flue gas could ensure denitration desulfuration efficiency usually, and low temperature SCR denitration device in the utility model use, it can make when not heating coke oven flue gas, ensure the efficiency of denitration desulfurization, effectively solve current coke oven flue gas desulphurization denitration and to consume energy serious problem.The catalyst used in 200 DEG C ~ 350 DEG C SCR denitration device used described in the utility model is the existing catalyst used in this temperature range.SCR denitration device described in the utility model comprises supporting denitrfying agent (ammoniacal liquor or urea etc.) supply system.
According to specific embodiments of the present utility model, wherein, described heating unit comprise the bottom being connected to described chimney or be connected to the pipeline for carrying hot-air on the safe flue of chimney bottom.
According to specific embodiments of the present utility model, wherein, described coke oven flue gas desulphurization denitration and UTILIZATION OF VESIDUAL HEAT IN unit also comprise waste-heat recovery device and desulfurizer.
According to specific embodiments of the present utility model, wherein, described waste-heat recovery device comprise connect successively take air as the air heat-exchanging device of heat transferring medium and take water as the boiler heat-exchanging device of heat transferring medium.Air heat-exchanging device described in the utility model is that the heat smoke after adopting denitration realizes heat exchange as heat source air; Boiler heat-exchanging device described in the utility model adopts the heat smoke after the preliminary heat exchange of air heat-exchanging device to realize heat exchange as heat source water.Adopt the air heat-exchanging device that connects successively and boiler heat-exchanging device effectively can reclaim the heat of heat smoke after denitration, the energy is effectively utilized, and the denitration flue gas after reclaiming can be made to be content with very little the requirement of sulfur removal technology.
The utility model is not construed as limiting described air heat-exchanging device type, as long as can realize heat exchange function, it is tubular type or board-like heat exchanger usually.The temperature of the flue gas after denitration, usually at about 250 DEG C, uses air heat-exchanging device that this flue gas can be utilized cold air to be heated to more than 100 DEG C for thermal source.
The particular type of the utility model to described boiler heat-exchanging device is not construed as limiting, as long as can heat exchange function be realized, usually it is a kind of pipe heat exchanger, uses boiler heat-exchanging device that about 230 DEG C flue gases can be utilized after denitration heat exchange medium cool water heating to be produced saturated vapor for thermal source.Preferably, this medium cold water can be industrial soft water.
According to specific embodiments of the present utility model, wherein, the entrance of described coke oven flue gas desulphurization denitration and UTILIZATION OF VESIDUAL HEAT IN unit is described SCR denitration device entrance, the outlet of described SCR denitration device is connected by the entrance of pipeline with described air heat-exchanging device, and the outlet of described air heat-exchanging device is connected by the entrance of pipeline with described boiler heat-exchanging device; The outlet of described boiler heat-exchanging device is connected with the entrance of described desulfurizer.
SCR denitration device is arranged on the front end of system, its beneficial effect is that coke oven flue gas directly can carry out denitration, without the need to flue gas reheat equipment, without the need to a large amount of flue gas reheat energy resource consumption.By air heat-exchanging device and boiler heat-exchanging device between SCR denitration device and desulfurizer, it is advantageous that:
(1) can heat energy to greatest extent in recovered flue gas, avoid the waste that high temperature discharge causes;
(2) can make flue gas reach wet desulphurization the reaction temperature that is suitable for, the water resources consumption eliminating flue gas cool-down equipment and cause;
According to specific embodiments of the present utility model, wherein, described for carrying the pipeline of hot-air to be connected with the hot air outlet of described air heat-exchanging device.Adopt this set can directly make the hot-air after being heated by described air heat-exchanging device not need as hot standby chimney thermal source to consume additional energy source, effectively save energy resource consumption.
According to specific embodiments of the present utility model, wherein, described desulfurizer is wet desulphurization device.The desulfurizing agent used in wet desulphurization device described in the utility model is the existing desulfurizing agent for wet desulphurization device.
System described in the utility model can conveniently be applied existing outfit in the coke oven factory of coke oven flue gas desulphurization denitration and UTILIZATION OF VESIDUAL HEAT IN unit, after having installed the novel described coke oven flue gas desulphurization denitration of this enforcement and UTILIZATION OF VESIDUAL HEAT IN unit additional, can using the former safe flue of original directly discharge coke oven flue gas and former chimney as the safe flue in system described in the utility model and chimney.
In specific implementation process, when coke oven flue gas desulphurization denitration UTILIZATION OF VESIDUAL HEAT IN unit is in normal condition, coke oven flue gas realizes desulphurization and denitration and waste heat recovery by this unit, and the flue gas after desulfurization directly can discharge through the chimney be above connected on desulfurizer.When coke oven flue gas desulphurization denitration UTILIZATION OF VESIDUAL HEAT IN unit is in accident condition, by three-way switch valve, coke oven flue gas is switched to escape way and carry out dump.Preferably, in concrete system of the present utility model, first coke oven flue gas enters middling temperature DeNOx device or low temperature SCR denitration device, and the heat smoke after denitration enters air heat-exchanging device, enters boiler heat-exchanging device after heat smoke heating environment air; Flue gas enters desulfurizer after heating process soft water in boiler heat-exchanging device, connects chimney and directly discharge after desulfurization on desulfurization module.It is standby that air heat-exchanging device utilizes heat smoke heat exchange the temperature of surrounding air to be risen to send into after more than 100 DEG C chimney bottom to carry out safe heating; Technique soft water is heated into saturated vapor and delivers to plant area's pipe network by boiler heat-exchanging device.Under accident condition, close coke oven flue gas by three-way switch valve and lead to SCR denitration device pipeline, coke oven flue gas causes chimney through safe flue and carries out dump.Adopt system of the present utility model, denitration efficiency reaches more than 95%, and desulfuration efficiency reaches more than 98%, realizes coke oven flue gas qualified discharge.
Accompanying drawing explanation
Fig. 1 is the coke oven flue gas desulphurization denitration described in embodiment 1 and bootstrap system schematic diagram; Label in Fig. 1 has following meaning:
1: coke oven; 2: three-way switch valve; 3: the SCR denitration device used at 200 DEG C ~ 350 DEG C; 4: air heat-exchanging device; 41: cool air inlet; 42: hot air outlet; 5: boiler heat-exchanging device; 51: technique soft water entrance; 52: steam outlet; 6: desulfurizer; 7: ammoniacal liquor supply system; 8: safe flue; 9: chimney.
Detailed description of the invention
In order to there be understanding clearly to technical characteristic of the present utility model, object and beneficial effect, now in conjunction with instantiation and accompanying drawing, following detailed description is carried out to the technical solution of the utility model, these examples should be understood and be only not used in restriction scope of the present utility model for illustration of the utility model.
Embodiment 1
Fig. 1 is described coke oven flue gas desulphurization denitration and the bootstrap system schematic diagram of the present embodiment, and this system comprises coke oven flue gas desulphurization denitration and UTILIZATION OF VESIDUAL HEAT IN unit and coke oven flue gas safety dumping unit;
Described coke oven flue gas safety dumping unit comprises safe flue 8 and chimney 9;
Described coke oven flue gas desulphurization denitration and UTILIZATION OF VESIDUAL HEAT IN unit comprise SCR denitration device;
Described SCR denitration device is the SCR denitration device 3 used at 200 DEG C ~ 350 DEG C; The catalyst used in this device is middle low temperature sulfur resistant catalyst;
Described coke oven flue gas desulphurization denitration and UTILIZATION OF VESIDUAL HEAT IN unit also comprise connect successively take air as the air heat-exchanging device 4 of heat transferring medium and take water as boiler heat-exchanging device 5 and the desulfurizer 6 of heat transferring medium; Described air heat-exchanging device 4 comprises cool air inlet 41 and hot air outlet 42; Described boiler heat-exchanging device 5 comprises technique soft water entrance 51 and steam outlet 52;
The fume emission mouth of coke oven 1 is connected to one end of described SCR denitration device 3 entrance and described safe flue 8 by pipeline and three-way switch valve 2, the other end of described safe flue 8 is connected to the bottom of described chimney 9, and the bottom of described chimney 9 arranges and makes it make it be in the heating unit of hot standby state; Described heating unit comprises the pipeline for carrying hot-air on the safe flue 8 that is connected to bottom the described chimney 9, also this can be used for carrying the pipeline of hot-air to be connected directly between bottom described chimney 9;
The outlet of described SCR denitration device 3 is connected by the entrance of pipeline with described air heat-exchanging device 4, and the outlet of described air heat-exchanging device 4 is connected by the entrance of pipeline with described boiler heat-exchanging device 5; The outlet of described boiler heat-exchanging device 5 is connected with the entrance of described desulfurizer 6;
Desulfurizer 6 described in the present embodiment is wet desulphurization device; The desulfurizing agent used in this device is Ca (OH) 2, MgO or ammoniacal liquor etc.
For carrying the pipeline of hot-air to be connected with the hot air outlet 42 of described air heat-exchanging device 4 described in the present embodiment;
System described in the present embodiment also comprises the ammoniacal liquor supply system 7 for providing reducing agent to SCR denitration device.
When the system of embody rule the present embodiment, from the flue gas of coke oven 1, (mean concentration of this nitrogen oxides in effluent is 2500mg/Nm 3, the mean concentration of sulfide is 500mg/Nm 3temperature is 250 DEG C) first enter SCR denitration device 3 and carry out denitrating flue gas process, flue-gas temperature after denitration is 230 DEG C, flue gas after this denitration enters in air heat-exchanging device 4 and carries out heat exchange with surrounding air, the cold air entering air heat-exchanging device 4 is heated to be the hot-air of 100 DEG C, this hot-air, by carrying out standby heat for carrying the pipeline of hot-air to send into bottom chimney 9 to it, keeps negative pressure in the safe flue of bypass; Flue gas after heat exchange enters into residual heat boiler for exchanging heat device 5, technique soft water is heated into the saturated steam of constant pressure quality, saturated vapor input user side or plant area's steam pipe system; Coke oven flue gas temperature through twice heat exchange is down to 100 ~ 120 DEG C, enters in desulfurizer 6 and carries out wet desulphurization, and the neat stress after desulfurization is directly disposed in air by chimney above desulfurizing tower, and in this neat stress, the mean concentration of nitrogen oxide is≤150mg/Nm 3, the mean concentration of sulfide is≤30mg/Nm 3.
Under accident condition, the valve of coke oven flue gas towards SCR denitration device 3 is closed by three-way switch valve 2, open the valve that coke oven flue gas leads to safe flue 8, coke oven flue gas directly discharges through safe flue 8 to chimney 9, ensure that coke oven smoke evacuation normally stifled cigarette explosion accident does not occur.
In summary, coke oven flue gas desulphurization denitration described in the utility model and residual neat recovering system can ensure denitrification efficiency, safe and feasible, can reduce the huge SO of total amount every year in engineering practice for coking industry 2, NO xdischarge.The heat energy simultaneously reclaimed is utilized effectively, and can save a large amount of electric energy and other fuel.The production safety of coke oven can be ensured fully, and coke oven can not be caused danger because of situations such as the fault of desulphurization denitration facility or power-off.
Finally illustrate: above embodiment is only for illustration of implementation process of the present utility model and feature; and unrestricted the technical solution of the utility model; although be described in detail the utility model with reference to above-described embodiment; those of ordinary skill in the art is to be understood that: still can modify to the utility model or equivalent replacement; and do not depart from any modification or partial replacement of spirit and scope of the present utility model, all should be encompassed in the middle of protection domain of the present utility model.

Claims (7)

1. coke oven flue gas desulphurization denitration and a bootstrap system, is characterized in that: this system at least comprises coke oven flue gas desulphurization denitration and UTILIZATION OF VESIDUAL HEAT IN unit and coke oven flue gas safety dumping unit;
Described coke oven flue gas desulphurization denitration and UTILIZATION OF VESIDUAL HEAT IN unit comprise SCR denitration device;
Described SCR denitration device is the SCR denitration device used at 200 DEG C ~ 350 DEG C;
Described coke oven flue gas safety dumping unit comprises safe flue and chimney;
The fume emission mouth of coke oven is connected to the entrance of described coke oven flue gas desulphurization denitration and UTILIZATION OF VESIDUAL HEAT IN unit and one end of described safe flue by pipeline and three-way switch valve, the other end of described safe flue is connected to the bottom of described chimney, and the bottom of described chimney arranges and makes it make to be in the heating unit of hot standby state.
2. system according to claim 1, is characterized in that: the pipeline for carrying hot-air on safe flue that is that described heating unit comprises the bottom being connected to described chimney or that be connected to close chimney bottom.
3. system according to claim 2, is characterized in that: described coke oven flue gas desulphurization denitration and UTILIZATION OF VESIDUAL HEAT IN unit also comprise waste-heat recovery device and desulfurizer.
4. system according to claim 3, is characterized in that: described waste-heat recovery device comprise connect successively take air as the air heat-exchanging device of heat transferring medium and take water as the boiler heat-exchanging device of heat transferring medium.
5. system according to claim 4, it is characterized in that: the entrance of described coke oven flue gas desulphurization denitration and UTILIZATION OF VESIDUAL HEAT IN unit is described SCR denitration device entrance, the outlet of described SCR denitration device is connected by the entrance of pipeline with described air heat-exchanging device, and the outlet of described air heat-exchanging device is connected by the entrance of pipeline with described boiler heat-exchanging device; The outlet of described boiler heat-exchanging device is connected with the entrance of described desulfurizer.
6. system according to claim 5, is characterized in that: described for carrying the pipeline of hot-air to be connected with the hot air outlet of described air heat-exchanging device.
7. the system according to any one of claim 2 ~ 6, is characterized in that: described desulfurizer is wet desulphurization device.
CN201521028664.5U 2015-12-10 2015-12-10 Denitration of coke oven flue gas desulfurization and waste heat utilization system Active CN205164504U (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105797581A (en) * 2016-06-03 2016-07-27 中冶京诚工程技术有限公司 System and process for utilizing coke oven flue gas desulfurization and denitrification waste heat
CN105879674A (en) * 2016-05-31 2016-08-24 武汉钢铁股份有限公司 Waste heat utilization and denitration combination technology for coke oven smoke
CN106178877A (en) * 2016-08-31 2016-12-07 大连华锐重工集团股份有限公司 A kind of coke oven flue waste gas purification waste heat recovery apparatus and technique
CN106352314A (en) * 2016-10-19 2017-01-25 北京京诚科林环保科技有限公司 Remained energy utilization system for coke oven flue gas
CN108362134A (en) * 2018-04-03 2018-08-03 中冶京诚工程技术有限公司 Coke oven chimney Unpowered thermal is for system and method
CN108387112A (en) * 2018-04-12 2018-08-10 深圳市凯盛科技工程有限公司 Glass furnace cooling horizontal type waste heat boiler system
CN108744918A (en) * 2018-06-14 2018-11-06 鞍钢股份有限公司 The system and technique of coke oven flue gas NO_x Reduction by Effective are realized using raw coke oven gas waste heat
CN110038414A (en) * 2019-03-25 2019-07-23 华电电力科学研究院有限公司 A kind of gas turbine flue gas denitrating system and method for denitration

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105879674A (en) * 2016-05-31 2016-08-24 武汉钢铁股份有限公司 Waste heat utilization and denitration combination technology for coke oven smoke
CN105797581A (en) * 2016-06-03 2016-07-27 中冶京诚工程技术有限公司 System and process for utilizing coke oven flue gas desulfurization and denitrification waste heat
CN106178877A (en) * 2016-08-31 2016-12-07 大连华锐重工集团股份有限公司 A kind of coke oven flue waste gas purification waste heat recovery apparatus and technique
CN106352314A (en) * 2016-10-19 2017-01-25 北京京诚科林环保科技有限公司 Remained energy utilization system for coke oven flue gas
CN108362134A (en) * 2018-04-03 2018-08-03 中冶京诚工程技术有限公司 Coke oven chimney Unpowered thermal is for system and method
CN108387112A (en) * 2018-04-12 2018-08-10 深圳市凯盛科技工程有限公司 Glass furnace cooling horizontal type waste heat boiler system
CN108744918A (en) * 2018-06-14 2018-11-06 鞍钢股份有限公司 The system and technique of coke oven flue gas NO_x Reduction by Effective are realized using raw coke oven gas waste heat
CN110038414A (en) * 2019-03-25 2019-07-23 华电电力科学研究院有限公司 A kind of gas turbine flue gas denitrating system and method for denitration
CN110038414B (en) * 2019-03-25 2023-05-09 华电电力科学研究院有限公司 Gas turbine flue gas denitration system and denitration method

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