CN205155984U - Handle heat accumulation formula catalysis direct combustion system of VOCs waste gas - Google Patents
Handle heat accumulation formula catalysis direct combustion system of VOCs waste gas Download PDFInfo
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- CN205155984U CN205155984U CN201521008466.2U CN201521008466U CN205155984U CN 205155984 U CN205155984 U CN 205155984U CN 201521008466 U CN201521008466 U CN 201521008466U CN 205155984 U CN205155984 U CN 205155984U
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Abstract
The utility model relates to a handle heat accumulation formula catalysis direct combustion system of VOCs waste gas, it includes waste gas inlet piping, catalysis direct combustion room, flue gas export pipeline, air inlet piping, air export pipeline, draught fan, aiutage, catalysis direct combustion roof portion installation explosion vent, catalysis direct combustion room one end installation main burner, the combustion -supporting combustor of other end installation, air intlet pipeline and the reverse installation of waste gas inlet piping, a thermocouple and a catalyst layer are respectively installed to the indoor both sides of catalysis direct combustion, install two -layer heat accumulator layer at least between the catalyst layer. The utility model discloses constitution, rational in infrastructure, energy -conserving effectual, investment and working costs are low, and the VOCs treatment effeciency is high. Can extensively be used for the VOCs exhaust -gas treatment field.
Description
Technical field
The utility model belongs to VOCs exhaust-gas treatment field, particularly a kind of heat accumulating type catalysis direct combustion system processing VOCs waste gas.
Background technology
Volatile organic matter (VOCs, VolatileOrganicCompounds) and oxysulfide, nitrogen oxide and dust are all the major pollutants causing atmosphere pollution.VOCs complicated component, source exhaust gas containing VOCs is numerous (as VOCS production industries such as petroleum refining, organic chemical industry, medicine, food, commodity, Tire production, and the manufacturing that is raw material with VOCS product such as packages printing, machine-building, Electronic products manufacturing, transit equipment manufacture, wood-based plate and Furniture manufacture), therefore the processing method of VOCs is more.For the waste gas containing VOCs, treatment effect can stablize reach more than 95% be combustion method.Whether combustion method is divided into direct-fired oxidation furnace (TO) and heat accumulating type oxidation furnace (RTO) according to accumulation of heat; If add catalyst in these two kinds of oxidation furnaces, just become now conventional
there is no heat accumulation functioncatalysis direct-combustion furnace and heat accumulating type Catalytic oxidation furnace.Catalysis direct-combustion furnace structure is simple, and the temperature of decomposing VOCs needs is low, and its fuel consumption is lower than direct-fired oxidation furnace, and therefore this catalysis direct-combustion furnace is more in the exhaust-gas treatment field application containing VOCs.The catalysis direct combustion indoor of catalysis direct-combustion furnace only have catalyst layer, advantage when processing VOCs waste gas is that treatment effeciency is high and invest low, but the gas flow temperature that this device flows out stove is very high, even if the additional heat exchanger of stove, heat recovery efficiency also only has about 60%, therefore the fuel consumption of this catalysis direct-combustion furnace is comparatively large, and energy-saving effect is poor, and operating cost is high.Heat accumulating type Catalytic oxidation furnace, by the switching of regenerator, has the heat recovery efficiency of more than 90%, but this device has numerous valve.In order to the heat recovery efficiency reached, numerous valve will switch once within 3 minutes, and this just proposes very high requirement to valve mass and control system.Heat accumulating type Catalytic oxidation furnace has two regenerator at least to complete the periodic accumulation of heat of heat storage and heat release, need a large amount of heat storages, therefore this apparatus structure is complicated, and volume is much larger than catalysis direct-combustion furnace, and this also makes its investment cost also far above catalysis direct-combustion furnace.
Summary of the invention
Technical problem to be solved in the utility model overcomes above-mentioned the deficiencies in the prior art, proposes a kind of composition, rational in infrastructure, good energy-conserving effect, investment and operating cost low, the heat accumulating type catalysis direct combustion system that VOCs treatment effeciency is high.
The technical scheme in the invention for solving the above technical problem is: a kind of heat accumulating type catalysis direct combustion system processing VOCs waste gas, it comprises exhaust gas inlet pipeline, catalysis direct combustion room, exhanst gas outlet pipeline, air inlet duct, air outlet duct, air-introduced machine, aiutage, it is characterized in that: explosion proof door is installed at top, described catalysis direct combustion room, main burner is installed in one end, catalysis direct combustion room, and the other end installs auxiliary burner; Described exhaust gas inlet pipeline enters catalysis direct combustion room from the one end of installing main burner, waste gas after process is discharged through air-introduced machine by exhanst gas outlet pipeline and exhanst gas outlet valve, described air inlet duct and the reverse installation of exhaust gas inlet pipeline, enter catalysis direct combustion room from the one end of installing booster burners, discharged through air-introduced machine by air outlet duct; A thermocouple and a catalyst layer are respectively installed in the both sides of described catalysis direct combustion indoor, are provided with at least two-layer heat storage layer between catalyst layer.
Further, the utility model is also provided with bypass line and bypass valve, and described bypass duct is arranged on exhaust gas inlet pipeline and catalysis direct combustion outside side by side, and waste gas directly can enter air-introduced machine by bypass duct and bypass valve.
Further, the utility model is also provided with a flue gas recirculation pipeline, the gas that described air-introduced machine is discharged, by flue gas recirculation pipeline access exhaust gas inlet pipeline, is together introduced catalysis direct combustion room with waste gas, is controlled the flow of flue gas recirculation pipeline by flue gas recirculation valve.
Further, described exhaust gas inlet pipeline is provided with filter, exhaust gas inlet valve, spark arrester, surge tank.
Further, the through hole of described heat storage floor is along catalysis direct combustion room length direction, every layer of heat storage floor fills up the cross section vertical with catalysis direct combustion room length direction, doubly, the gross thickness of heat storage floor is the 10%-40% of catalysis direct combustion room length to the 1-3 being spaced apart single heat storage thickness between adjacent heat storage layer.
The utility model adopts above-mentioned composition structure, is installed to by heat storage layer in catalysis direct-combustion furnace, forms heat accumulating type VOCs catalysis direct combustion system.The air quantity of catalytic combustion indoor is entered by bypass flue increase, thus the adaptedness that improvement catalysis direct combustion room reduces exhausted air quantity.Improve heat recovery rate by heat storage accumulation of heat, reduce the fuel consumption of burner by heat storage heat release, when there being very high VOCs treatment effeciency, energy-conservation and operating cost is lower than catalysis direct-combustion furnace; Valve does not need frequent opening and closing, to the requirement of valve mass and control system lower than heat accumulating type Catalytic oxidation furnace; Catalysis direct combustion room of the present utility model volume is a bit larger tham the catalysis direct-combustion furnace not having heat storage, but is less than heat accumulating type Catalytic oxidation furnace, and therefore investment cost is far below heat accumulating type Catalytic oxidation furnace.As can be seen here, against existing technologies, the utility model composition is rational in infrastructure, good energy-conserving effect, and VOCs exhaust treatment efficiency is high, and control easily, cost is low, and operating cost is also low.
Accompanying drawing explanation
Below in conjunction with accompanying drawing, the utility model is described further.
Fig. 1 is composition structural representation of the present utility model.
Label in figure is: 1. exhaust gas inlet pipeline, 2. bypass duct, 3. flue gas recirculation pipeline, 4. air inlet duct, 5. air outlet duct, 6. catalysis direct combustion room, 7. exhanst gas outlet pipeline, 8. air-introduced machine, 9. aiutage.11. filters, 12. exhaust gas inlet valves, 13. spark arresters, 14. surge tanks, 21. bypass valves, 31. flue gas recirculation valves, 41. air inlet valves, 51. air outlet valves, 61. main burners, 62. explosion proof doors, 63. auxiliary heat galvanic couples, 64. main thermocouples, 65. auxiliary burners, 66. main catalytic oxidant layer, 67. heat storage layers, 68. auxiliary catalysis oxidant layer, 71. exhanst gas outlet valves.
Detailed description of the invention
As can be seen from Figure 1, process a heat accumulating type catalysis direct combustion system for VOCs waste gas, it comprises exhaust gas inlet pipeline 1, bypass duct 2, flue gas recirculation pipeline 3, catalysis direct combustion room 6, air inlet duct 4, air outlet duct 5, exhanst gas outlet pipeline 7, air-introduced machine 8, aiutage 9 etc.Described exhaust gas inlet pipeline 1 is provided with filter 11, exhaust gas inlet valve 12, spark arrester 13 and surge tank 14; Bypass duct 2 is provided with bypass valve 21; Flue gas recirculation pipeline 3 is provided with flue gas recirculation valve 31; Air inlet duct 4 is provided with air inlet valve 41; Air outlet duct 5 is provided with air outlet valve 51; Exhanst gas outlet pipeline 7 is provided with exhanst gas outlet valve 71.
Explosion proof door 62 is installed at top, described catalysis direct combustion room 6, timely pressure release when the effect of explosion proof door 62 is room 6 implodes of catalysis direct combustion.Main burner 61 is installed in one end, catalysis direct combustion room, and the other end installs auxiliary burner 65; Described exhaust gas inlet pipeline 1 enters catalysis direct combustion room 6 from the one end of installing main burner 61, waste gas after process is discharged through air-introduced machine 8 by exhanst gas outlet pipeline 7 and exhanst gas outlet valve 71, described air inlet duct 4 and the reverse installation of exhaust gas inlet pipeline 1, enter catalysis direct combustion room from the one end of installing auxiliary burner 65, discharged through air-introduced machine 8 by air outlet duct 5.
Auxiliary heat galvanic couple 63 and auxiliary catalysis oxidant layer 68 are installed in main burner 61 side in described catalysis direct combustion room 6, and main thermocouple 64 and main catalytic oxidant layer 66 are installed in auxiliary burner 65 side.At least two-layer heat storage layer 67 is installed between auxiliary catalysis oxidant layer 68 and main catalytic oxidant layer 64.
Further, bypass duct 2 described in the utility model is arranged on outside exhaust gas inlet pipeline 1 and catalysis direct combustion room 6 side by side.Specifically, on the entrance of the described bypass duct 2 exhaust gas inlet pipeline 1 between filter 11 and exhaust gas inlet valve 12, export on the exhanst gas outlet pipeline 7 between exhanst gas outlet valve 71 and air-introduced machine 8.
Further, flue gas recirculation pipeline 3 described in the utility model be connected to air-introduced machine 8 export exhanst gas outlet pipeline 7 and surge tank 14 after exhaust gas inlet pipeline 1 between.The gas that described air-introduced machine 8 is discharged is divided into two-way, lead up to aiutage discharged to air, flue gas recirculation pipeline of leading up to access exhaust gas inlet pipeline 1, is together introduced catalysis direct combustion room 6 with waste gas, is controlled the flow of flue gas recirculation pipeline 3 by flue gas recirculation valve 31.
Further, the through hole level of described heat storage layer 67, namely along the length direction of catalysis direct combustion room 6, every layer of heat storage floor 67 all fills up the longitudinal cross-section of catalysis direct combustion room 6, and air-flow can only flow in through-holes.More than one times that is spaced apart single heat storage thickness between adjacent heat storage layer 67, preferably 1-3 doubly.Object be make air flow energy evenly the longitudinal cross-section being distributed in catalysis direct combustion room 6.The gross thickness of heat storage floor 67 is the 10%-40% of catalysis direct combustion room 6 length.
The course of work of the present utility model comprises purging, heats up, the four-stages such as operation and shutdown.First carry out purge stages: air inlet valve 41 and air outlet valve 51 are opened, and air-introduced machine 8 is opened, exhaust gas inlet valve 12, exhanst gas outlet valve 71 and flue gas recirculation valve 31 are closed, and bypass valve 21 is according to or without VOCs toxic emission opening and closing.VOCs residual in main catalytic oxidant layer 66, heat storage floor 67 and auxiliary catalysis oxidant layer 68 is blown out catalysis direct combustion room 6 by the air that air-introduced machine 8 is introduced.
After purge stages, enter the temperature rise period: auxiliary burner 65 is lighted a fire, by the air heat in catalysis direct combustion room 6, along with the flowing of air in catalysis direct combustion room 6, main catalytic oxidant layer 66, heat storage layer 67 and auxiliary catalysis oxidant layer 68 heat up successively; After the temperature of auxiliary heat galvanic couple 63 detection reaches setting value, the temperature rise period terminates, and the operation phase starts.
In operation phase, exhaust gas inlet valve 12 and exhanst gas outlet valve 71 are opened, and air inlet valve 41, air outlet valve 51 and bypass valve 21 are closed, and VOCs waste gas enters catalysis direct combustion room 6, and main burner 61 is lighted a fire, and auxiliary burner 65 stops working.VOCs waste gas is heated by main burner 61, and by there is catalytic reaction during auxiliary catalysis oxidant layer 68, VOCs is decomposed into carbon dioxide and water and heat release, and waste gas becomes free of contamination heat smoke; Heat smoke flows through heat storage layer 67 and main catalytic oxidant layer 66, and they is heated; Flue gas flows out catalysis direct combustion room 6, enters air through air-introduced machine 8 and aiutage 9; When main thermocouple 64 detect temperature be elevated to setting value time, main burner 61 stops working, and now auxiliary catalysis oxidant layer 68 and heat storage layer 67 still have higher temperature, can continue heat exhaust gases, and the VOCs after heating is decomposed by during main catalytic oxidant layer 66; Along with auxiliary catalysis oxidant layer 68 and heat storage layer 67 are cooled by waste gas, prescribe a time limit close to the lower of main catalytic oxidant layer 66 decomposition temperature when main thermocouple 64 detects EGT, main burner 61 is lighted a fire again, starts next circulation.When the best air quantity scope that exhausted air quantity works lower than catalysis direct combustion room 6, flue gas recirculation valve 31 is opened, and the flue gas that part flows out air-introduced machine 8 enters catalysis direct combustion room 6, remains in optimum range to make its air quantity and temperature.The exhaust gas volumn of recirculation is regulated by flue gas recirculation valve 31.When breaking down in catalysis direct combustion room 6, bypass valve 21 is opened, and exhaust gas inlet valve 12, flue gas recirculation valve 31, air inlet valve 41, air outlet valve 51 and exhanst gas outlet valve 71 are closed, and waste gas directly enters air by air-introduced machine 8 and aiutage 9.
The last shutdown stage: main burner 61 and auxiliary burner 65 stop working, and air inlet valve 41, air outlet valve 51 and bypass valve 21 are opened, and exhaust gas inlet valve 12, exhanst gas outlet valve 71 and flue gas recirculation valve 31 are closed.Air enters catalysis direct combustion room 6, VOCs residual for main catalytic oxidant layer 66, heat storage floor 67 and auxiliary catalysis oxidant layer 68 is blown out catalysis direct combustion room 6, and lowers the temperature.When auxiliary heat galvanic couple 63 detect temperature drop to setting value time, close air-introduced machine 8; Except flue gas recirculation valve 31, other valve is all closed, system shutdown.
By the accumulation of heat of the indoor heat storage layer of catalysis direct combustion, substantially increase the heat recovery rate of catalysis direct combustion method; By the heat release of heat storage layer, as long as within the scope of the catalytic temperature of catalyst layer, burner just need not be opened, thus energy-conservation and reduce operating cost; Valve cost and catalysis direct combustion room volume are all less than heat accumulating type Catalytic oxidation furnace.In addition, the heat accumulating type catalysis direct combustion system architecture of process VOCs waste gas is simple, can transform, thus make the utility model have wide practical value on the basis of existing catalysis direct-combustion furnace.
Claims (5)
1. one kind processes the heat accumulating type catalysis direct combustion system of VOCs waste gas, it comprises exhaust gas inlet pipeline, catalysis direct combustion room, exhanst gas outlet pipeline, air inlet duct, air outlet duct, air-introduced machine, aiutage, it is characterized in that: explosion proof door is installed at top, described catalysis direct combustion room, main burner is installed in one end, catalysis direct combustion room, and the other end installs booster burners; Described exhaust gas inlet pipeline enters catalysis direct combustion room from the one end of installing main burner, waste gas after process is discharged through air-introduced machine by exhanst gas outlet pipeline and exhanst gas outlet valve, described air inlet duct and the reverse installation of exhaust gas inlet pipeline, enter catalysis direct combustion room from the one end of installing booster burners, discharged through air-introduced machine by air outlet duct; A thermocouple and a catalyst layer are respectively installed in the both sides of described catalysis direct combustion indoor, are provided with at least two-layer heat storage layer between catalyst layer.
2. the heat accumulating type catalysis direct combustion system of process VOCs waste gas according to claim 1, it is characterized in that: it is also provided with bypass line and bypass valve, described bypass duct is arranged on exhaust gas inlet pipeline and catalysis direct combustion outside side by side, and waste gas directly can enter air-introduced machine by bypass duct and bypass valve.
3. the heat accumulating type catalysis direct combustion system of process VOCs waste gas according to claim 1, it is characterized in that: it is also provided with a flue gas recirculation pipeline, the gas that described air-introduced machine is discharged is by flue gas recirculation pipeline access exhaust gas inlet pipeline, together introduce catalysis direct combustion room with waste gas, controlled the flow of flue gas recirculation pipeline by flue gas recirculation valve.
4. the heat accumulating type catalysis direct combustion system of process VOCs waste gas according to claim 1, is characterized in that: described exhaust gas inlet pipeline is provided with filter, exhaust gas inlet valve, spark arrester, surge tank.
5. the heat accumulating type catalysis direct combustion system of process VOCs waste gas according to claim 1, it is characterized in that: the through hole of described heat storage floor is along catalysis direct combustion room length direction, every layer of heat storage floor fills up the cross section vertical with catalysis direct combustion room length direction, doubly, the gross thickness of heat storage floor is the 10%-40% of catalysis direct combustion room length to the 1-3 being spaced apart single heat storage thickness between adjacent heat storage layer.
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