CN205145995U - Ferrous sulfate filtration system - Google Patents
Ferrous sulfate filtration system Download PDFInfo
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- CN205145995U CN205145995U CN201520909628.3U CN201520909628U CN205145995U CN 205145995 U CN205145995 U CN 205145995U CN 201520909628 U CN201520909628 U CN 201520909628U CN 205145995 U CN205145995 U CN 205145995U
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Abstract
The utility model relates to a ferrous sulfate filtration system, its innovation point lies in: loop filter system in one, including four the two liang parallelly connected ceramic membrane subassemblies in back of establishing ties, interior loop filter headtotail has charge -in system and dope discharge system, still includes a ceramic membrane pickling system, and this ceramic membrane pickling system includes pickling jar, pickle back flow, pickle feed liquor pipe, washes back liquid back flow. The utility model has the advantages of: the utility model discloses in, four ceramic membrane subassemblies adopt two liang of parallelly connected modes in back of establishing ties to the cooperation circulating pump constitutes two interior loop filter return circuits, makes the ferrous sulfate suspension of continuous thickened constantly circulate in this return circuit, makes it move along the pipe wall orientation and constantly washes away the ceramic membrane inside pipe wall, reduces titanium dioxide granule and other impurity attached to the probability of inside pipe wall, and avoiding the membrane flux to descend fast, the influence is normal filters the extension life cycle.
Description
Technical field
The utility model relates to a kind of ferrous sulfate production equipment, particularly a kind of ferrous sulfate filtration system.
Background technology
Ferrous sulfate can be used for molysite processed, iron oxide pigment, mordant, water purification agent, anticorrisive agent, disinfectant etc., with in the process of method for producing gtitanium dioxide with sulphuric acid, byproduct dilute sulfuric acid can be produced, the concentration of dilute sulfuric acid is about 20 ~ 25%, reacted by dilute sulfuric acid and iron filings, iron powder again and generate ferrous sulfate, both can consume dilute sulfuric acid, ferrous sulfate product can be produced again, reach the bumper harvests of environmental protection and economy benefit.But containing certain titanium ion in ferrous sulfate product, its actual concentrations is about 90%, and it needs to be removed to obtain more highly purified ferrous sulfate.
Traditional method is removed by natural sedimentation method or filter press technique, natural sedimentation method is by the pond storing this ferrous sulfate suspension, by insert copper billet displacement and natural sedimentation realize, the method cycle is long, have impact on production efficiency greatly.And press filtration rule carries out pressure filtration by the filter cloth on sheet frame, utilize that titanium dioxide is water insoluble to be removed, but its defect existed is: in pressure-filtering process, titanium dioxide granule is constantly blocked by filter cloth under pressure, and be adsorbed on filter cloth, with regard to needing, the titanium dioxide granule be blocked on filter cloth is cleaned out after press filtration a period of time, otherwise reduce efficiency of press filtering greatly, therefore need cleaning work frequently.
Utility model content
The technical problems to be solved in the utility model is to provide a kind ofly can remove titanium dioxide granule and ferrous sulfate filtration system without the need to frequently clearing up fast.
For solving the problems of the technologies described above, the technical solution of the utility model is: a kind of ferrous sulfate filtration system, its innovative point is: comprise an internal circulation filtering system, comprises the first ceramic film component, the second ceramic film component, the 3rd ceramic film component, the 4th ceramic film component, the first surge tank, the second surge tank, circulating pump; Described first ceramic film component, the second ceramic film component, the 3rd ceramic film component, the 4th ceramic film component structure are identical, all there is a ceramic periosteum, and one to export with the interior dope be communicated with of ceramic-film tube with the import is communicated with in ceramic-film tube, a purified liquor outlet be communicated with outward with ceramic-film tube; The import of first and second ceramic film component described is communicated with the first surge tank, the dope outlet of the first ceramic film component is communicated with by internal recycle pipeline A with the import of the 4th ceramic film component, the dope outlet of the second ceramic film component is communicated with by internal recycle pipeline B with the import of the 3rd ceramic film component, the dope outlet of third and fourth ceramic film component is communicated with the second surge tank, described first surge tank is communicated with by internal recycle pipeline C with the second surge tank, and installs circulating pump on internal recycle pipeline C; One feed system, comprises stoste feed pipe, feed pump, the internal recycle pipeline C of this stoste feed pipe access internal circulation filtering system, and installs feed pump on stoste feed pipe; One clear liquid gathering system, comprises the 3rd surge tank, the 4th surge tank, the first clear liquid arm, the second clear liquid arm, the 3rd clear liquid arm, the 4th clear liquid arm, clear liquid house steward; The purified liquor outlet of described first, fourth ceramic film component is communicated with the 3rd surge tank respectively by the first clear liquid arm, the 4th clear liquid arm, the purified liquor outlet of second and third ceramic film component described is communicated with the 4th surge tank respectively by the second clear liquid arm, the 3rd clear liquid arm, third and fourth surge tank described is also communicated with clear liquid house steward, and installs clear liquid by-pass valve control on clear liquid house steward; One dope discharges system, and comprise dope discharge pipe, dope by-pass valve control, described dope discharge pipe is communicated with the second surge tank, and installs dope by-pass valve control on dope discharge pipe; One ceramic membrane pickling system, comprises pickling tank, pickle return duct, pickle feed tube, washes rear liquid return duct; Pickling tank top there is a clean pickle refluxing opening and one wash rear liquid refluxing opening, there is bottom pickling tank a pickle liquor outlet; Described pickle liquor outlet is communicated with the stoste feed pipe of feed system by pickle feed tube, and arranges pickling liquid flowing valve on pickle feed tube; Described pickle refluxing opening is communicated with clear liquid house steward by pickle return duct, and installs pickle return valve on pickle return duct; Describedly wash rear liquid refluxing opening and be communicated with the second surge tank of internal circulation filtering system by washing rear liquid return duct.
Preferably, described first ceramic film component, the second ceramic film component, the 3rd ceramic film component, the 4th ceramic film component all also have a sewage draining exit be communicated with ceramic-film tube outward.
Preferably, described ferrous sulfate filtration system also comprises a gas backwash system, and this gas backwash system comprises recoil inlet manifold, recoil air inlet first arm and recoil air inlet second arm; Recoil inlet manifold is communicated with the 3rd surge tank, the 4th surge tank respectively by recoil air inlet first arm, recoil air inlet second arm, and installs recoil air inlet first valve and recoil air inlet second valve on recoil air inlet first arm, recoil air inlet second arm.
The utility model has the advantage of:
Filtered by ceramic membrane in the utility model, ferrous sulfate suspension is at ceramic membrane Bottomhole pressure, and the titanium dioxide granule and other impurity that are greater than tube wall membrane aperture are intercepted at inside film, forms dope in pipe; Be less than the sulfate ion of tube wall membrane aperture, ferrous ion and water and then ooze out along the vertical direction of tube wall tangent line that pipe is outer enters clear liquid side, form pure ferrous sulfate clear liquid; The filter type of slipstream pattern can delay the formation of polluting filter cake, permeant flux is kept for a long time, if system long-play causes flux depression, then be filled with clear water by backwash mechanism again and carry out timing automatic cleaning ceramic-film tube inwall, greatly extend the cycle of disassembly, cleaning.
In the utility model, mode in parallel after four ceramic film components adopt series connection between two, and coordinate circulating pump to form two internal circulation filtering loops, the ferrous sulfate suspension constantly thickened constantly is circulated in this loop, make it move along tube wall direction and constantly wash away ceramic-film tube inwall, reduction titanium dioxide granule and other impurity are attached to the probability of inside pipe wall, and avoiding membrane flux to decline fast affects normal filtration, extend life cycle.Owing to being equipped with ceramic membrane pickling system in the utility model, it dissolves by acid and is adsorbed on a small quantity on ceramic-film tube inwall and the titanium dioxide granule be not easily washed, and avoids frequently dismantling ceramic film component and clears up.
Also can be equipped with a gas backwash system in the utility model, before pickling prerequisite, purge ceramic film component inside pipe wall, the titanium dioxide granule be adsorbed on inwall is purged, then by pickling system dissolved particles, dual cleaning, improves the cleaning performance of ceramic membrane.
Accompanying drawing explanation
Fig. 1 is the utility model ferrous sulfate filtration system structural representation.
First ceramic film component 1, second ceramic film component 2, 3rd ceramic film component 3, 4th ceramic film component 4, first surge tank 5, second surge tank 6, circulating pump 7, internal recycle pipeline A8, internal recycle pipeline B9, internal recycle pipeline C10, stoste feed pipe 11, feed pump 12, 3rd surge tank 13, 4th surge tank 14, first clear liquid arm 15, second clear liquid arm 16, 3rd clear liquid arm 17, 4th clear liquid arm 18, clear liquid house steward 19, clear liquid by-pass valve control 20, pickling tank 23, pickle return duct 24, pickle feed tube 25, wash rear liquid return duct 26, pickling liquid flowing valve 27, pickle return valve 28, wash rear liquid return valve 29, recoil inlet manifold 30, recoil air inlet first arm 31 and recoil air inlet second arm 32, recoil air inlet first valve 33 and recoil air inlet second valve 34.
Detailed description of the invention
As shown in Figure 1, comprise internal circulation filtering system, feed system, clear liquid gathering system, dope discharge system, ceramic membrane pickling system and gas backpurge system, concrete structure is as follows:
Internal circulation filtering system, comprises the first ceramic film component 1, second ceramic film component 2, the 3rd ceramic film component 3, the 4th ceramic film component 4, first surge tank 5, second surge tank 6, circulating pump 7.
First ceramic film component 1, second ceramic film component 2, the 3rd ceramic film component 3, the 4th ceramic film component 4 structure are identical, all there is a ceramic periosteum, and one exports b, a purified liquor outlet c be communicated with ceramic-film tube with the import a be communicated with in ceramic-film tube, outward with the dope be communicated with in ceramic-film tube.First ceramic film component 1, second ceramic film component 2, the 3rd ceramic film component 3, the 4th ceramic film component 4 all also have a sewage draining exit g be communicated with ceramic-film tube outward.
Wherein, the import a of the first ceramic film component 1, second ceramic film component 2 is communicated with the first surge tank 5, the dope outlet b of the first ceramic film component 1 is communicated with by internal recycle pipeline A8 with the import a of the 4th ceramic film component 4, the dope outlet b of the second ceramic film component 2 is communicated with by internal recycle pipeline B9 with the import a of the 3rd ceramic film component 3, the dope outlet b of the 3rd ceramic film component 3, the 4th ceramic film component 4 is communicated with the second surge tank 6, first surge tank 5 is communicated with by internal recycle pipeline C10 with the second surge tank 6, and installs circulating pump 7 on internal recycle pipeline C10.
Feed system, comprises stoste feed pipe 11, feed pump 12 and inlet control valve 35, and this stoste feed pipe 11 accesses the internal recycle pipeline C10 of internal circulation filtering system, and installs feed pump 12 on stoste feed pipe 11.
Clear liquid gathering system, comprises the 3rd surge tank 13, the 4th surge tank 14, first clear liquid arm 15, second clear liquid arm 16, the 3rd clear liquid arm 17, the 4th clear liquid arm 18, clear liquid house steward 19; The purified liquor outlet c of the first ceramic film component 1, the 4th ceramic film component 4 is communicated with the 3rd surge tank 13 respectively by the first clear liquid arm 15, the 4th clear liquid arm 18, the purified liquor outlet c of the second ceramic film component 2, the 3rd ceramic film component 3 is communicated with the 4th surge tank 14 respectively by the second clear liquid arm 16, the 3rd clear liquid arm 17,3rd surge tank 13, the 4th surge tank 14 are also communicated with clear liquid house steward 19, and install clear liquid by-pass valve control 20 on clear liquid house stewards 19.
Dope discharges system, and comprise dope discharge pipe 21, dope by-pass valve control 22, dope discharge pipe 21 is communicated with the second surge tank 6, and installs dope by-pass valve control 22 on dope discharge pipe 21.
Ceramic membrane pickling system, comprises pickling tank 23, pickle return duct 24, pickle feed tube 25, washes rear liquid return duct 26, pickling liquid flowing valve 27, pickle return valve 28; Pickling tank 23 top has a clean pickle refluxing opening d and and washes rear liquid refluxing opening e, has a pickle liquor outlet f bottom pickling tank; Wherein, pickle liquor outlet f is communicated with the stoste feed pipe 11 of feed system by pickle feed tube 25, and arranges pickling liquid flowing valve 27 on pickle feed tube 25; Pickle refluxing opening d is communicated with clear liquid house steward 19 by pickle return duct 24, and installs pickle return valve 28 on pickle return duct 24; Wash rear liquid refluxing opening e to be communicated with the second surge tank 6 of internal circulation filtering system by washing rear liquid return duct 26, and after washing on liquid return duct 26 install wash after liquid return valve 29.
In the utility model, ferrous sulfate filtration system also comprises a gas backwash system, and this gas backwash system comprises recoil inlet manifold 30, recoil air inlet first arm 31 and recoil air inlet second arm 32; Recoil inlet manifold 30 is communicated with the 3rd surge tank 13, the 4th surge tank 14 respectively by recoil air inlet first arm 31, recoil air inlet second arm 32, and installs recoil air inlet first valve 33 and recoil air inlet second valve 34 on recoil air inlet first arm 31, recoil air inlet second arm 32.
Operation principle:
filtration condition:ferrous sulfate suspension solid content containing titanium dioxide is about 0.2%, and it, after preheater preheats to 50 degree Celsius, passes into stoste feed pipe, pump into internal recycle pipeline C under the effect of feed pump, closedown feed pump and inlet control valve after charging completes; Then the Inner eycle in two loops is carried out by circulating pump,
First loop is: ferrous sulfate suspension enters the first surge tank by circulating pump, then the first ceramic film component is entered, be less than the sulfate ion of tube wall membrane aperture, ferrous ion and water in suspension and then ooze out along the vertical direction of tube wall tangent line that pipe is outer enters purified liquor outlet, and be greater than the titanium dioxide granule of tube wall membrane aperture and other impurity is intercepted at inside film; Enter again in the 4th ceramic film component through the ferrous sulfate suspension well internal recycle pipeline A of the first ceramic film component dope outlet discharge and carry out secondary filter, the ferrous sulfate suspension that content of titanium dioxide after filtration constantly promotes gets back to the first surge tank by the second surge tank and internal recycle pipeline C again, so constantly clear liquid is discharged in circulation, leaves the dope containing more titanium dioxide granule;
Second servo loop is: ferrous sulfate suspension enters the first surge tank by circulating pump, then the second ceramic film component is entered, be less than the sulfate ion of tube wall membrane aperture, ferrous ion and water in suspension and then ooze out along the vertical direction of tube wall tangent line that pipe is outer enters purified liquor outlet, and be greater than the titanium dioxide granule of tube wall membrane aperture and other impurity is intercepted at inside film; Enter again in the 3rd ceramic film component through the ferrous sulfate suspension well internal recycle pipeline B of the second ceramic film component dope outlet discharge and carry out secondary filter, the ferrous sulfate suspension that content of titanium dioxide after filtration constantly promotes gets back to the first surge tank by internal recycle pipeline C again, so constantly clear liquid is discharged in circulation, leaves the dope containing more titanium dioxide granule.
The ferrous sulfate clear liquid that the solid content that filtration obtains is very low enters clear liquid house steward by the 3rd surge tank, the 4th surge tank, after filtering a period of time, closes circulating pump, is discharged by dope by dope discharge pipe.
Cleaning state:
Open pickling liquid flowing valve, the pickle in pickling tank is made to pump in internal circulation filtering system by feed pump, utilize circulating pump that pickle is constantly circulated in internal circulation filtering system, the titanium dioxide granule of pickle solution ceramic membrane module inside pipe wall gradually, in cyclic process, part pickle is discharged from purified liquor outlet through ceramic membrane, flow in pickling tank through third and fourth surge tank and pickle return duct again, the pickle being dissolved with titanium dioxide granule then by the second surge tank, wash rear liquid return duct and flow back to pickling tank.
Before pickling, can first air inlet recoil purge, to be blown off by the particle be adsorbed on inside pipe wall: open recoil air inlet first valve and recoil air inlet second valve, back flushing air enters the 3rd surge tank, the 4th surge tank by recoil air inlet first arm and recoil air inlet second arm; The clear liquid side of the first ceramic film component, the second ceramic film component, the 3rd ceramic film component, the 4th ceramic film component is entered again through the first clear liquid arm, the second clear liquid arm, the 3rd clear liquid arm, the 4th clear liquid arm, sweep Compressed Gas by punching in pipe extroversion pipe, the particle be adsorbed on inside pipe wall is blown off.
More than show and describe general principle of the present utility model and principal character and advantage of the present utility model.The technical staff of the industry should understand; the utility model is not restricted to the described embodiments; what describe in above-described embodiment and description just illustrates principle of the present utility model; under the prerequisite not departing from the utility model spirit and scope; the utility model also has various changes and modifications, and these changes and improvements all fall within the scope of claimed the utility model.The claimed scope of the utility model is defined by appending claims and equivalent thereof.
Claims (3)
1. a ferrous sulfate filtration system, is characterized in that: comprise
One internal circulation filtering system, comprises the first ceramic film component, the second ceramic film component, the 3rd ceramic film component, the 4th ceramic film component, the first surge tank, the second surge tank, circulating pump; Described first ceramic film component, the second ceramic film component, the 3rd ceramic film component, the 4th ceramic film component structure are identical, all there is a ceramic periosteum, and one to export with the interior dope be communicated with of ceramic-film tube with the import is communicated with in ceramic-film tube, a purified liquor outlet be communicated with outward with ceramic-film tube; The import of first and second ceramic film component described is communicated with the first surge tank, the dope outlet of the first ceramic film component is communicated with by internal recycle pipeline A with the import of the 4th ceramic film component, the dope outlet of the second ceramic film component is communicated with by internal recycle pipeline B with the import of the 3rd ceramic film component, the dope outlet of third and fourth ceramic film component is communicated with the second surge tank, described first surge tank is communicated with by internal recycle pipeline C with the second surge tank, and installs circulating pump on internal recycle pipeline C;
One feed system, comprises stoste feed pipe, feed pump, the internal recycle pipeline C of this stoste feed pipe access internal circulation filtering system, and installs feed pump on stoste feed pipe;
One clear liquid gathering system, comprises the 3rd surge tank, the 4th surge tank, the first clear liquid arm, the second clear liquid arm, the 3rd clear liquid arm, the 4th clear liquid arm, clear liquid house steward; The purified liquor outlet of described first, fourth ceramic film component is communicated with the 3rd surge tank respectively by the first clear liquid arm, the 4th clear liquid arm, the purified liquor outlet of second and third ceramic film component described is communicated with the 4th surge tank respectively by the second clear liquid arm, the 3rd clear liquid arm, third and fourth surge tank described is also communicated with clear liquid house steward, and installs clear liquid by-pass valve control on clear liquid house steward;
One dope discharges system, and comprise dope discharge pipe, dope by-pass valve control, described dope discharge pipe is communicated with the second surge tank, and installs dope by-pass valve control on dope discharge pipe;
One ceramic membrane pickling system, comprises pickling tank, pickle return duct, pickle feed tube, washes rear liquid return duct; Pickling tank top there is a clean pickle refluxing opening and one wash rear liquid refluxing opening, there is bottom pickling tank a pickle liquor outlet; Described pickle liquor outlet is communicated with the stoste feed pipe of feed system by pickle feed tube, and arranges pickling liquid flowing valve on pickle feed tube; Described pickle refluxing opening is communicated with clear liquid house steward by pickle return duct, and installs pickle return valve on pickle return duct; Describedly wash rear liquid refluxing opening and be communicated with the second surge tank of internal circulation filtering system by washing rear liquid return duct.
2. ferrous sulfate filtration system according to claim 1, is characterized in that: described first ceramic film component, the second ceramic film component, the 3rd ceramic film component, the 4th ceramic film component all also have a sewage draining exit be communicated with ceramic-film tube outward.
3. ferrous sulfate filtration system according to claim 1, is characterized in that: described ferrous sulfate filtration system also comprises a gas backwash system, and this gas backwash system comprises recoil inlet manifold, recoil air inlet first arm and recoil air inlet second arm; Recoil inlet manifold is communicated with the 3rd surge tank, the 4th surge tank respectively by recoil air inlet first arm, recoil air inlet second arm, and installs recoil air inlet first valve and recoil air inlet second valve on recoil air inlet first arm, recoil air inlet second arm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201520909628.3U CN205145995U (en) | 2015-11-16 | 2015-11-16 | Ferrous sulfate filtration system |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201520909628.3U CN205145995U (en) | 2015-11-16 | 2015-11-16 | Ferrous sulfate filtration system |
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| Publication Number | Publication Date |
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| CN205145995U true CN205145995U (en) | 2016-04-13 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201520909628.3U Expired - Fee Related CN205145995U (en) | 2015-11-16 | 2015-11-16 | Ferrous sulfate filtration system |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105233698A (en) * | 2015-11-16 | 2016-01-13 | 南通宝聚颜料有限公司 | Ferrous sulfate filtering system |
| CN110813098A (en) * | 2019-11-18 | 2020-02-21 | 上海安赐环保科技股份有限公司 | Sulfuric acid method titanium dioxide production method and cleaning method of membrane equipment |
-
2015
- 2015-11-16 CN CN201520909628.3U patent/CN205145995U/en not_active Expired - Fee Related
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105233698A (en) * | 2015-11-16 | 2016-01-13 | 南通宝聚颜料有限公司 | Ferrous sulfate filtering system |
| CN110813098A (en) * | 2019-11-18 | 2020-02-21 | 上海安赐环保科技股份有限公司 | Sulfuric acid method titanium dioxide production method and cleaning method of membrane equipment |
| CN110813098B (en) * | 2019-11-18 | 2022-03-08 | 上海安赐环保科技股份有限公司 | Sulfuric acid method titanium dioxide production method and cleaning method of membrane equipment |
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160413 Termination date: 20201116 |
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| CF01 | Termination of patent right due to non-payment of annual fee |