CN205024023U - Cyanide wastewater advanced oxidation treatment reactor - Google Patents
Cyanide wastewater advanced oxidation treatment reactor Download PDFInfo
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- CN205024023U CN205024023U CN201520742557.2U CN201520742557U CN205024023U CN 205024023 U CN205024023 U CN 205024023U CN 201520742557 U CN201520742557 U CN 201520742557U CN 205024023 U CN205024023 U CN 205024023U
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Abstract
The utility model discloses a cyanide wastewater advanced oxidation treatment reactor, it is by reactor shell, ozone aeration pipe, the ultraviolet fluorescent tube, the ultrasonic wave takes place the system and ozone generator constitutes, wherein reactor shell leans to one side to be equipped with feed liquor pipe and drain pipe, ozone aeration pipe is terminal to link to each other with ozone generator, the front end stretches into inside the reactor shell lower extreme, link to each other with ozone aeration main pipe and microporous aerator, the ultraviolet fluorescent tube is the cylinder long tube, ultraviolet lamp outside of tubes face is equipped with the quartz glass sleeve pipe, fix on the lamp stand, the system takes place and becomes width of cloth pole probe by the ultrasonic wave for the ultrasonic wave, ultrasonic transducer and supersonic generator constitute. The utility model discloses combine ozone oxidation, ultraviolet ray catalytic oxidation and ultrasonic treatment be in the same place, realize in coordination that multiple advanced oxidation reacts, can realize effectively getting rid of of cyanide, complex compound and other difficult degradation organic matters, have area little, integrate advantages such as degree height, treatment effect are good.
Description
Technical field
The utility model relates to industrial waste water treatment, particularly a kind of Oxidation Treatment of Cyanide Containing Wastewater reactor.
Background technology
At present, most domestic gold mine still uses cyaniding and leaching process, this makes produce a large amount of cyaniding tailing slurries in production process, cyaniding tailing slurry can produce a large amount of containing cyanogen percolate and leaching liquor in the banking process of Tailings Dam, this part cyanide wastewater, due to lower containing cyanogen concentration, recycles cost higher, once select factory to satisfy after water, if do not processed, will be the environmental protection hidden danger of gold mine enterprise all the time.At present, gold mine Treatment of cyanogen-contained wastewater comprises Pomolio-Celdecor process, Yin Kefa, hydrogen peroxide oxidation method, By Ozone, biological process etc., the process that these methods have is not thorough, there is a processing efficiency low, some meetings produce the reasons such as secondary pollution, them are made in cyanide wastewater process, to there is certain defect and affect its application, and advanced oxidation processes is by producing active extremely strong free radical in the reaction, can effectively by the free Cyanide in cyanide wastewater, complexing cyanogen, the pollutent fast degradations such as thiocyanate-are removed, there is reaction efficiency high, speed of response is fast, contaminant degradation is thorough, the advantages such as wide accommodation, have broad prospects in cyanide wastewater process field.But the problems such as existing advanced oxidation treatment facility ubiquity integrated level is low, floor space is large, ozone utilization rate is low, make high-level oxidation technology be restricted applying in process.
Summary of the invention
The purpose of this utility model is exactly for the problems referred to above, and provides a kind of advanced oxidation reactor for Oxidation Treatment of Cyanide Containing Wastewater.
The utility model is made up of shell of reactor, ozonation aerated pipe, ultraviolet lamp tube, ultrasonic wave generation systems and ozonizer, wherein shell of reactor is cylindric, upper and lower closed at both ends, shell of reactor bottom of leaning to one side is provided with liquid-inlet pipe, shell of reactor top of leaning to one side is provided with drain pipe, and shell of reactor inwall scribbles nano-titania photocatalyst coating; Ozonation aerated pipe end is connected with ozonizer, and it is inner that front end extend into shell of reactor lower end, is connected with micro-hole aerator with ozonation aerated arm; Ultraviolet lamp tube is round shape long tube, is evenly erected at the inside of shell of reactor, and ultraviolet lamp tube is fixed on the lamp socket on shell of reactor top, and ultraviolet lamp tube skin is provided with quartz glass sleeve; Ultrasonic wave generation systems is made up of ultrasonic variable amplitude bar probe, ultrasonic transducer and ultrasonic generator, ultrasonic variable amplitude bar probe uniform vertical is arranged on the upper area of shell of reactor inside, ultrasonic variable amplitude bar probe top is connected with ultrasonic transducer, is connected above ultrasonic transducer with ultrasonic generator.
The both sides, front end of described ozonation aerated pipe are equidistantly vertically provided with each ozonation aerated arm, and each ozonation aerated arm is equidistantly provided with micro-hole aerator.
The circular array of described ultraviolet lamp tube is in the inside of shell of reactor, and the overall length of each vertical direction ultraviolet lamp tube is 1/2 ~ 1 of shell of reactor height, and ultraviolet lamp tube wavelength is between 180 ~ 750nm.
The diameter of described ultrasonic variable amplitude bar probe is adjustable, and the quantity of ultrasonic variable amplitude bar probe is more than or equal to one, is evenly distributed on waste water below liquid level 30mm and locates.
The material of described ozone micro-hole aerator is 316L stainless steel, titanium alloy or pottery, and shell of reactor, ozonation aerated pipe, ozonation aerated arm and ultrasonic variable amplitude bar probe is stainless steel.
The beneficial effects of the utility model:
Ozone oxidation, ultraviolet catalytic oxidation and ultrasonication combine by the utility model, the multiple advanced oxidation reaction of cooperative achievement, effective removal of prussiate, complex compound and other hardly degraded organic substances can be realized, have that floor space is little, integration degree is high, high treating effect, there is good application prospect.
Accompanying drawing explanation
Fig. 1 is structural representation of the present utility model.
Fig. 2 is the ozonation aerated pipe of the utility model, ozonation aerated arm and micro-hole aerator vertical view.
Fig. 3 is the ultraviolet lamp tube vertical view of the utility model.
Wherein, 1-shell of reactor; 11-liquid-inlet pipe; 12-drain pipe; 13-nano-titania photocatalyst coating; 2-ozonation aerated pipe; 21-ozonation aerated arm; 22-micro-hole aerator; 3-ultraviolet lamp tube; 31-quartz glass sleeve; 32-lamp socket; 4-ultrasonic wave generation systems; 41-ultrasonic variable amplitude bar is popped one's head in; 42-ultrasonic transducer; 43-ultrasonic generator; 5-ozonizer.
Embodiment
Refer to shown in Fig. 1, the present embodiment is made up of shell of reactor 1, ozonation aerated pipe 2, ultraviolet lamp tube 3, ultrasonic wave generation systems 4 and ozonizer 5, wherein shell of reactor 1 is cylindric, upper and lower closed at both ends, shell of reactor 1 bottom of leaning to one side is provided with liquid-inlet pipe 11, shell of reactor 1 top of leaning to one side is provided with drain pipe 12, and shell of reactor 1 inwall scribbles nano-titania photocatalyst coating 13; Ozonation aerated pipe 2 end is connected with ozonizer 5, and the lower end that front end extend into shell of reactor 1 is inner, is connected with micro-hole aerator 22 with ozonation aerated arm 21; Ultraviolet lamp tube 3 is round shape long tube, is evenly erected at the inside of shell of reactor 1, and ultraviolet lamp tube 3 is fixed on the lamp socket 32 on shell of reactor 1 top, and ultraviolet lamp tube 3 skin is provided with quartz glass sleeve 31; Ultrasonic wave generation systems 4 is made up of ultrasonic variable amplitude bar probe 41, ultrasonic transducer 42 and ultrasonic generator 43, ultrasonic variable amplitude bar 41 uniform vertical of popping one's head in are arranged on the upper area of shell of reactor 1 inside, be connected with ultrasonic transducer 42 above ultrasonic variable amplitude bar probe 41, be connected with ultrasonic generator 43 above ultrasonic transducer 42.
As shown in Figure 2, the both sides, front end of ozonation aerated pipe 2 are equidistantly vertically provided with each ozonation aerated arm 21, and each ozonation aerated arm 21 is equidistantly provided with micro-hole aerator 22.
As shown in Figure 3, the circular array of ultraviolet lamp tube 3 is in the inside of shell of reactor 1, and the overall length of each vertical direction ultraviolet lamp tube 3 is 1/2 ~ 1 of shell of reactor 1 height, and the wavelength of ultraviolet lamp tube 3 is between 180 ~ 750nm.
The diameter of described ultrasonic variable amplitude bar probe 41 is adjustable, and the quantity of ultrasonic variable amplitude bar probe 41 is more than or equal to one, is evenly distributed on waste water below liquid level 30mm and locates.
The material of described micro-hole aerator 22 is 316L stainless steel, titanium alloy or pottery, and shell of reactor 1, ozonation aerated pipe 2, ozonation aerated arm 21 and ultrasonic variable amplitude bar probe 41 is stainless steel.
The utility model in Treatment of Cyanide-containing Wastewater time, waste water enters into this reactor from liquid-inlet pipe 11, open ozonizer 5, ozone is passed into from micro-hole aerator 22, open ultraviolet lamp tube 3 and ultrasonic generator 43, carry out advanced oxidation process by ozone oxidation, ultraviolet lamp catalysis and ultrasonic synergistic to cyanide wastewater, the waste water after process flows out from drain pipe 12.
Claims (5)
1. a cyanide wastewater advanced oxidation treatment reactor, it is characterized in that: be made up of shell of reactor (1), ozonation aerated pipe (2), ultraviolet lamp tube (3), ultrasonic wave generation systems (4) and ozonizer (5), wherein shell of reactor (1) is cylindric, upper and lower closed at both ends, shell of reactor (1) bottom of leaning to one side is provided with liquid-inlet pipe (11), shell of reactor (1) top of leaning to one side is provided with drain pipe (12), and shell of reactor (1) inwall scribbles nano-titania photocatalyst coating (13); Ozonation aerated pipe (2) end is connected with ozonizer (5), and the lower end that front end extend into shell of reactor (1) is inner, is connected with micro-hole aerator (22) with ozonation aerated arm (21); Ultraviolet lamp tube (3) is round shape long tube, evenly be erected at the inside of shell of reactor (1), ultraviolet lamp tube (3) is fixed on the lamp socket (32) on shell of reactor (1) top, and ultraviolet lamp tube (3) skin is provided with quartz glass sleeve (31); Ultrasonic wave generation systems (4) is made up of ultrasonic variable amplitude bar probe (41), ultrasonic transducer (42) and ultrasonic generator (43), ultrasonic variable amplitude bar probe (41) uniform vertical is arranged on the inner upper area of shell of reactor (1), ultrasonic variable amplitude bar probe (41) top is connected with ultrasonic transducer (42), and ultrasonic transducer (42) top is connected with ultrasonic generator (43).
2. a kind of cyanide wastewater advanced oxidation treatment reactor according to claim 1, it is characterized in that: the both sides, front end of described ozonation aerated pipe (2) are equidistantly vertically provided with ozonation aerated arm (21), each ozonation aerated arm (21) is equidistantly provided with micro-hole aerator (22).
3. a kind of cyanide wastewater advanced oxidation treatment reactor according to claim 1, it is characterized in that: described ultraviolet lamp tube (3) circular array is in the inside of shell of reactor (1), the overall length of each vertical direction ultraviolet lamp tube (3) is 1/2 ~ 1 of shell of reactor (1) height, and the wavelength of ultraviolet lamp tube (3) is between 180 ~ 750nm.
4. a kind of cyanide wastewater advanced oxidation treatment reactor according to claim 1, it is characterized in that: the diameter of described ultrasonic variable amplitude bar probe (41) is adjustable, the quantity of ultrasonic variable amplitude bar probe (41) is more than or equal to one, is evenly distributed on waste water below liquid level 30mm and locates.
5. a kind of cyanide wastewater advanced oxidation treatment reactor according to claim 1, it is characterized in that: the material of described micro-hole aerator (22) is 316L stainless steel, titanium alloy or pottery, shell of reactor (1), ozonation aerated pipe (2), ozonation aerated arm (21) and ultrasonic variable amplitude bar probe (41) are stainless steel.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201520742557.2U CN205024023U (en) | 2015-09-24 | 2015-09-24 | Cyanide wastewater advanced oxidation treatment reactor |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201520742557.2U CN205024023U (en) | 2015-09-24 | 2015-09-24 | Cyanide wastewater advanced oxidation treatment reactor |
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| CN205024023U true CN205024023U (en) | 2016-02-10 |
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| CN201520742557.2U Active CN205024023U (en) | 2015-09-24 | 2015-09-24 | Cyanide wastewater advanced oxidation treatment reactor |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106517619A (en) * | 2017-01-03 | 2017-03-22 | 吉林师范大学 | Device and method for treating organic wastewater by sound, light and ozone coupling |
| CN108483563A (en) * | 2018-06-04 | 2018-09-04 | 大连鑫恒环保科技有限公司 | Efficient ultrasonic wastewater by photocatalysis system |
| CN108911023A (en) * | 2018-07-10 | 2018-11-30 | 北京高能时代环境技术股份有限公司 | A kind of circulating out-phase Treatment by Photocatalysis Oxidation system and processing method |
| CN109368765A (en) * | 2018-11-20 | 2019-02-22 | 萍乡亨厚新材科技有限公司 | A method of utilizing air-treatment cyanide wastewater |
-
2015
- 2015-09-24 CN CN201520742557.2U patent/CN205024023U/en active Active
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106517619A (en) * | 2017-01-03 | 2017-03-22 | 吉林师范大学 | Device and method for treating organic wastewater by sound, light and ozone coupling |
| CN108483563A (en) * | 2018-06-04 | 2018-09-04 | 大连鑫恒环保科技有限公司 | Efficient ultrasonic wastewater by photocatalysis system |
| CN108911023A (en) * | 2018-07-10 | 2018-11-30 | 北京高能时代环境技术股份有限公司 | A kind of circulating out-phase Treatment by Photocatalysis Oxidation system and processing method |
| CN108911023B (en) * | 2018-07-10 | 2023-05-30 | 北京高能时代环境技术股份有限公司 | Circulation type heterogeneous photocatalytic oxidation treatment system and treatment method |
| CN109368765A (en) * | 2018-11-20 | 2019-02-22 | 萍乡亨厚新材科技有限公司 | A method of utilizing air-treatment cyanide wastewater |
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Legal Events
| Date | Code | Title | Description |
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CP01 | Change in the name or title of a patent holder |
Address after: 130012 No. 6760 nanhu road, Jilin City, Changchun Province Patentee after: Changchun Gold Research Institute Co., Ltd. Address before: 130012 No. 6760 nanhu road, Jilin City, Changchun Province Patentee before: Changchun Gold Research Institute |
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| CP01 | Change in the name or title of a patent holder | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20180613 Address after: 562299 Jianshe Road 43, min Gu Town, Zhenfeng County, Southwest Guizhou Province, Buyei and Miao Autonomous Prefecture, Guizhou Patentee after: Guizhou Jinfeng Mining Limited Address before: 130012 No. 6760 nanhu road, Jilin City, Changchun Province Patentee before: Changchun Gold Research Institute Co., Ltd. |
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| TR01 | Transfer of patent right |