CN204999859U

CN204999859U - Device of disulphide is retrieved in condensate removal of mercaptans and alkali lye regeneration

Info

Publication number: CN204999859U
Application number: CN201520641107.4U
Authority: CN
Inventors: 喻武钢; 聂通元; 王铭; 蔡喜洋
Original assignee: NINGBO ZHONGYI PETROCHEMICAL TECHNOLOGY Co Ltd
Current assignee: NINGBO ZHONGYI PETROCHEMICAL TECHNOLOGY Co Ltd
Priority date: 2015-08-24
Filing date: 2015-08-24
Publication date: 2016-01-27
Anticipated expiration: 2025-08-24

Abstract

The utility model relates to a device of disulphide is retrieved in condensate removal of mercaptans and alkali lye regeneration, including removal of mercaptans processing unit, the export of removal of mercaptans processing unit bottom is linked together with alkali lye oxidation and sulfur dioxide separating element bottom entry, alkali lye oxidation and the export of sulfur dioxide separating element bottom are linked together with alkali lye stripping tower side entry, alkali lye oxidation and the export of sulfur dioxide separating element top, the export of alkali lye stripping tower top all are linked together with tail gas washing dealkalize jar side entry, alkali lye oxidation and the export of sulfur dioxide separating element side, the export of tail gas washing dealkalize tank bottom end all are linked together with disulphide tank deck end entrance, the export of alkali lye stripping tower bottom is linked together with removal of mercaptans processing unit side entry to and with the aforesaid one or more a plurality of filters of being connected, a plurality of circulating pump, a plurality of pipeline, a plurality of inlet and a plurality of liquid outlet in each part.

Description

A kind of condensate oil mercaptan removal and alkali liquid regeneration reclaim the device of disulphide

Technical field

The utility model relates to a kind of condensate oil treatment facility, is specifically related to the device of a kind of condensate oil mercaptan removal and alkali liquid regeneration recovery disulphide.

Background technology

Boiling range generally all contains the H of trace in the condensate oil of 30 DEG C of-210 DEG C of scopes ₂s, and the hundreds of even thioether of several thousand ppm, mercaptan, thiophene sulfides, wherein mercaptans content accounts for more than 70% of total sulfur, and carbon three and following mercaptan account for more than 80% of mercaptan total amount, and there is stronger toxicity, volatility, corrodibility and nauseating bad odor due to mercaptan, comparatively serious to the corrosion of condensate oil processing unit (plant), environmental pollution impact is simultaneously very large.

Processing at present to condensate oil, part refinery adopts the way of straight-forward fractional distillation to obtain each fraction product, then desulfurization process is carried out to reach quality product requirement to each fraction product, but condensate oil fractionation plant etching problem is more serious, Maintenance and Repair cost is high, and is unfavorable for that device long-term stability is run.There is following shortcoming in existing device and treatment process: raw material water entrainment dilution mercaptan removal alkali lye cause alkaline residue consumption and alkaline residue quantity discharged large, still there is part severe toxicity, corrodibility Stenchy sulfides in material after treatment, carry alkali lye secretly to problems such as the seriously corrodeds of downstream condensate oil processing unit (plant).Part refinery adopts the way of first condensate oil raw material being carried out to hydrogenating desulfurization, although solve the problem of fractionation plant seriously corroded, the investment of hydrogenation unit is huge, improves desulphurization cost.

Therefore, need the device of a kind of novel condensate oil mercaptan removal of design and alkali liquid regeneration recovery disulphide badly, to solve the problems referred to above that prior art exists.

Utility model content

The purpose of this utility model is to provide the device of a kind of condensate oil mercaptan removal and alkali liquid regeneration recovery disulphide, to overcome currently available technology above shortcomings.

The purpose of this utility model is achieved through the following technical solutions:

A kind of condensate oil mercaptan removal and alkali liquid regeneration reclaim the device of disulphide, comprise mercaptan removal processing unit, described mercaptan removal processing unit bottom end outlet is connected with alkali liquor oxidized and sulfurous gas separating unit bottom entrance, described alkali liquor oxidized and sulfurous gas separating unit bottom end outlet is connected with alkali lye gas stripping column side entrance, described alkali liquor oxidized and sulfurous gas separating unit top outlet, alkali lye stripper overhead brings out mouth and all washes dealkalize tank side entrance with tail gas and be connected, described alkali liquor oxidized and sulfurous gas separating unit side outlet, tail gas washing dealkalize tank bottom end outlet is all connected with disulphide upper end entrance, described alkali lye gas stripping column bottom end outlet is connected with mercaptan removal processing unit side entrance, and with one or more some strainers be connected in above-mentioned each parts, some recycle pumps, some pipelines, some fluid inlets and some liquid outlets.

Further, coalescent processed unit and/or condensate oil washing dealkalize unit is also comprised; Described coalescent processed cell side brings out mouth and is connected with mercaptan removal processing unit top inlet; Described condensate oil washing dealkalize unit top inlet exports with mercaptan removal processing unit top and is connected.

Further, described strainer comprises condensate oil strainer, air filter, alkali lye strainer, described condensate oil filter outlet is connected with coalescent processed unit top inlet, described air filter is connected with alkali liquor oxidized and sulfurous gas separating unit side entrance, described alkali lye filter inlet is connected with alkali lye gas stripping column bottom entrance, therebetween be provided with regenerating alkali liquid pump, described alkali lye filter outlet is connected with mercaptan removal processing unit side entrance.

Further, described pipeline comprises the condensate oil feed-pipe be connected with condensate oil strainer, mouth is brought out respectively with coalescent processed cell side, the condensate oil pipe connecting that mercaptan removal processing unit top inlet is connected, wash dealkalize cell side with condensate oil to bring out the condensate oil that mouth is connected and go out device pipe, the oily(waste)water pipe be connected with coalescent processed unit bottom end outlet, respectively with mercaptan removal processing unit bottom end outlet, the rich alkali liquor pipe of the mercaptan removal that alkali liquor oxidized and sulfurous gas separating unit bottom entrance is connected, the alkaline residue pipe be connected with the rich alkali liquor pipe of mercaptan removal, the non-purifying wind pipe be connected with air filter, export with sulfurous gas separating unit top respectively, the offgas duct that tail gas washing dealkalize tank side entrance is connected, wash dealkalize upper end with tail gas to export the tail gas be connected and go out device pipe, export with mercaptan removal processing unit side respectively, the disulphide pipe connecting that disulphide upper end entrance is connected, disulphide tank bottom end outlet is communicated with disulphide and goes out device pipe, condensate oil washing dealkalize unit bottom end outlet is communicated with alkaline waste water pipe, alkali lye gas stripping column lower side end entrance is communicated with nitrogen tube.

Further, described mercaptan removal processing unit is device one, device two or device three;

Described device one comprises one-level liquid membrane contactor and coupled logical first grade desulfurizing alcohol separating tank, described one-level liquid membrane contactor top inlet brings out mouth with coalescent processed cell side and is connected, described alkali lye gas stripping column bottom end outlet, fresh alkali liquor pipe all with one-level liquid membrane contactor side entrance be connected, described first grade desulfurizing alcohol separating tank bottom end outlet is connected with sulfurous gas separating unit bottom entrance, and the outlet of described first grade desulfurizing alcohol separating tank top is washed dealkalize unit top inlet with condensate oil and is connected;

Described device two comprises one-level liquid membrane contactor and coupled logical first grade desulfurizing alcohol separating tank, secondary liquid membrane contactor and coupled logical two-grade desulfurizing alcohol separating tank;

Described one-level liquid membrane contactor top inlet brings out mouth with coalescent processed cell side and is connected, described one-level liquid membrane contactor side entrance is connected with two-grade desulfurizing alcohol separating tank bottom end outlet by NaOH solution circulating pump, described NaOH solution circulating pump is arranged on circulation alkali liquor pipe, described first grade desulfurizing alcohol separating tank bottom end outlet is connected with sulfurous gas separating unit bottom entrance, the outlet of described first grade desulfurizing alcohol separating tank top is connected with secondary liquid membrane contactor top inlet, described alkali lye gas stripping column bottom end outlet, fresh alkali liquor pipe all with secondary liquid membrane contactor side entrance be connected, the outlet of described two-grade desulfurizing alcohol separating tank top is washed dealkalize unit top inlet with condensate oil and is connected, or

Described one-level liquid membrane contactor top inlet brings out mouth with coalescent processed cell side and is connected, described one-level liquid membrane contactor side entrance and secondary liquid membrane contactor side entrance all with alkali lye gas stripping column bottom end outlet, fresh alkali liquor pipe is connected, described first grade desulfurizing alcohol separating tank bottom end outlet is all connected with sulfurous gas separating unit bottom entrance with two-grade desulfurizing alcohol separation tank bottom end entrance, the outlet of described first grade desulfurizing alcohol separating tank top is connected with secondary liquid membrane contactor top inlet, the outlet of described two-grade desulfurizing alcohol separating tank top is washed dealkalize unit top inlet with condensate oil and is connected,

Described device three comprises the coupled logical first grade desulfurizing alcohol separating tank of one-level liquid membrane contactor, the coupled logical two-grade desulfurizing alcohol separating tank of secondary liquid membrane contactor, three grades of coupled three grades of logical mercaptan removal separating tanks of liquid membrane contactor;

Described one-level liquid membrane contactor top inlet brings out mouth with coalescent processed cell side and is connected, described one-level liquid membrane contactor side entrance is connected with two-grade desulfurizing alcohol separating tank bottom end outlet by NaOH solution circulating pump, described first grade desulfurizing alcohol separating tank bottom end outlet is connected with sulfurous gas separating unit bottom entrance, the outlet of described first grade desulfurizing alcohol separating tank top is connected with secondary liquid membrane contactor top inlet, described secondary liquid membrane contactor side entrance is connected with three grades of mercaptan removal separating tank bottom end outlet by NaOH solution circulating pump, the outlet of described two-grade desulfurizing alcohol separating tank top is connected with three grades of liquid membrane contactor top inlet, described alkali lye gas stripping column bottom end outlet, fresh alkali liquor pipe is all connected with three grades of liquid membrane contactor side entrances, the outlet of described three grades of mercaptan removal separating tank tops is washed dealkalize unit top inlet with condensate oil and is connected, or

Described one-level liquid membrane contactor top inlet brings out mouth with coalescent processed cell side and is connected, the outlet of described first grade desulfurizing alcohol separating tank top is connected with secondary liquid membrane contactor top inlet, described secondary liquid membrane contactor is all connected with three grades of mercaptan removal separating tank bottom end outlet by NaOH solution circulating pump with the side entrance of three grades of liquid membrane contactors, described first grade desulfurizing alcohol separating tank is all connected with sulfurous gas separating unit bottom entrance with the bottom end outlet of two-grade desulfurizing alcohol separating tank, the outlet of described two-grade desulfurizing alcohol separating tank top is connected with three grades of liquid membrane contactor top inlet, described alkali lye gas stripping column bottom end outlet, fresh alkali liquor pipe is all connected with three grades of liquid membrane contactor side entrances, the outlet of described three grades of mercaptan removal separating tank tops is washed dealkalize unit top inlet with condensate oil and is connected.

Further, described sulfurous gas separating unit is device four or device five;

Described device four comprises alkali liquor oxidized tower, the inner position, middle and lower part of described alkali liquor oxidized tower is provided with gas distributor one, described alkali liquor oxidized tower side outlet to be exported with disulphide knockout tower side by regeneration alkali liquor pipe and is connected, described alkali liquor oxidized tower side entrance, the position of gas distributor one is communicated with non-purifying wind pipe, described alkali liquor oxidized tower bottom entrance is connected with mercaptan removal processing unit bottom end outlet, alkali lye interchanger and catalyst injector is disposed with between described mercaptan removal processing unit and alkali liquor oxidized tower, upperly in described disulphide knockout tower inside install disulphide coalescent pack, described disulphide knockout tower bottom end outlet is connected with alkali lye gas stripping column side entrance, described disulphide knockout tower side outlet is connected with disulphide upper end entrance, described alkali liquor oxidized tower, the outlet of disulphide knockout tower top is all washed dealkalize tank side entrance and is connected with tail gas, in described tail gas washing dealkalize tank inside, upper/lower positions is provided with gas distributor three,

Described device five comprises alkali liquor oxidized knockout tower, described alkali liquor oxidized knockout tower bottom entrance is connected with mercaptan removal processing unit bottom end outlet, described alkali liquor oxidized knockout tower inner route clapboard is separated into two regions, middle upper/lower positions in one region is provided with gas distributor one, upperly in another region install disulphide coalescent pack, alkali lye interchanger and catalyst injector is provided with successively between described alkali liquor oxidized knockout tower and mercaptan removal processing unit, described alkali liquor oxidized knockout tower lower end outlet is connected with alkali lye gas stripping column side entrance, described alkali liquor oxidized knockout tower side outlet is connected with disulphide upper end entrance, described alkali liquor oxidized knockout tower top outlet is washed dealkalize tank side entrance with tail gas and is connected, in described tail gas washing dealkalize tank inside, upper/lower positions is provided with gas distributor three.

Further, described coalescent processed unit comprises coalescent water trap, described coalescent water trap top inlet is connected with condensate oil feed-pipe, and described coalescent water trap bottom end outlet is connected with oily(waste)water pipe, and described coalescent water trap side is connected with condensate oil pipe connecting;

Described condensate oil washing dealkalize unit is device six or device seven;

Described device six comprises coalescent dealkalize device, described coalescent dealkalize device top inlet exports with the top of mercaptan removal processing unit and is connected, described coalescent dealkalize device bottom end outlet is connected with alkaline waste water pipe, and described coalescent dealkalize device side outlet goes out device pipe with condensate oil and is connected;

Described device seven comprises liquid film washing contactor, described liquid film washing contact top end entrance exports with the top of mercaptan removal processing unit and is connected, described liquid film washing contactor is connected with washing separating tank, the outlet of described washing separating tank lower end is washed contactor side entrance by water washing cycles pump and liquid film and is connected, and described washing separating tank top is communicated with condensate oil and goes out device pipe.

Further, exit, described first grade desulfurizing alcohol separating tank top is provided with first grade desulfurizing alcohol separating tank condensate oil outlet damper, exit, described two-grade desulfurizing alcohol separating tank top is provided with two-grade desulfurizing alcohol separating tank condensate oil outlet damper, and exit, described three grades of mercaptan removal separating tank tops is provided with three grades of mercaptan removal separating tank condensate oil outlet dampers.

A kind of device utilizing described condensate oil mercaptan removal and alkali liquid regeneration to reclaim disulphide carries out the method for condensate oil process, it is characterized in that, comprise elementary mercaptan removal and/or two-grade desulfurizing alcohol and/or three grades of mercaptan removal steps, described elementary mercaptan removal step is as follows: utilize condensate oil strainer to filter the condensate oil after dehydration, the condensate oil of described filtration and circulation alkali liquor enter one-level liquid membrane contactor from condensate oil import and alkali lye import respectively; Described two-grade desulfurizing alcohol step is as follows: after abovementioned steps process, condensate oil and alkali lye settlement separate in first grade desulfurizing alcohol separating tank, condensate oil after separation is derived from first grade desulfurizing alcohol separating tank top, then enters secondary liquid membrane contactor from condensate oil import and alkali lye import respectively with regeneration alkali lye; Described three grades of mercaptan removal steps are as follows: after abovementioned steps process, condensate oil and alkali lye settlement separate at two-grade desulfurizing alcohol separating tank, the condensate oil after separation is derived from two-grade desulfurizing alcohol separating tank top;

A small amount of free alkali lye is entrained with for condensate oil after caustic wash desulfuration alcohol, coalescent water trap is adopted to be separated to reduce to alkali lye and to carry the infection of alkali lye to downstream condensate oil processing unit (plant) secretly, one-level liquid membrane contactor water elution is adopted to remove, washing process is: after alkali cleaning, condensate oil enters from liquid membrane contactor top with the de-mineralized water come by circulating water wash pumping, and washing dealkalize is completed in liquid film washing contactor, after dealkalize, condensate oil and de-mineralized water are separated washing separating tank, refining condensate oil goes out device, de-mineralized water is cycled to used in dealkalize, according to product condensate oil sodium ions content rising situation periodic replacement de-mineralized water, fresh de-mineralized water is come by fresh de-mineralized water pumping,

The alkali lye being rich in sodium mercaptides that condensate oil caustic wash desulfuration alcohol produces, enter alkali liquid regeneration part, alkali liquor oxidized tower and disulphide knockout tower or alkali liquor oxidized knockout tower is utilized to carry out being separated of alkali liquor oxidized and disulphide respectively, 50-300ppm titanium cyanines cobalt class catalyzer is added in the rich alkali lye after mercaptan removal, catalyst injector is utilized titanium cyanines cobalt class catalyzer to be injected into the oxidation zone of alkali liquor oxidized tower or alkali liquor oxidized knockout tower from the import of tower bottom alkali lye, pressurized air after air filter filters imports via the oxidation wind import bottom the oxidation zone of alkali liquor oxidized tower or alkali liquor oxidized knockout tower, gas distributor a pair pressurized air be arranged in tower processes, obtain the microvesicle of diameter 0.1-5mm and be dispersed in the alkali lye of the oxidation zone of alkali liquor oxidized tower or alkali liquor oxidized knockout tower, alkali lye and air fully contact and complete mercaptan oxidation and transform,

Be separated alkali lye after disulphide to derive bottom the disengaging zone of alkali liquor oxidized tower or alkali liquor oxidized knockout tower, enter from the import of alkali lye gas stripping column alkali lye, air after being filtered or nitrogen gas distributor two or two kind of gas in alkali lye gas stripping column are scattered in alkali lye from the rill of different gas distributor formation diameter 10-100mm respectively, in alkali lye, the disulphide of trace to be dissolved in air and to be brought in tail gas, tail gas is from alkali lye gas stripping column) top derivation, alkali lye is derived after standing separation gas bottom alkali lye gas stripping column bottom alkali lye gas stripping column, alkali lye is sent to mercaptan removal processing unit by regenerating alkali liquid pump,

Tail gas washing dealkalize tank carries out washing dealkalize to the tail gas after oxidation and air lift, gas distributor three pairs of tail gas process, it is made to be scattered in the water in tail gas washing dealkalize tank with the bubble form of diameter 1-5cm, thus the micro-alkali lye water elution carried secretly in alkali liquor oxidized regeneration and air lift tail gas is removed, the tail gas guide after dealkalize is delivered to burning, desulfurization equipment process or is utilized and reclaims disulphide, desulfurization equipment and process it.

Further, utilize coalescent water trap to carry out processed to the condensate oil raw material being entrained with free-water, thus make the free-water in condensate oil be down to below 10ppm.

The beneficial effects of the utility model are:

(1) Mercaptan removal rate, mercaptan removal alkali liquid regeneration efficiency are high:

Condensate oil mercaptan removal adopts fiber film contactor efficient mass transfer equipment, by being designed to single-stage, two-stage or multistage, the modes such as serial or parallel connection, make Mercaptan removal rate in condensate oil reach more than 90%, and wherein carbon three and following Mercaptan removal rate reach more than 99%;

Alkali liquor oxidized employing contacts oxidation technology entirely, and regeneration alkali lye quality is good, and alkali liquid regeneration rate reaches more than 90%;

(2) technique is simple, and energy consumption is low:

The method Separation and Recovery disulphide such as adopt efficient oxidation, low disturbance, air supporting coalescent, and can be used as chemical resource and utilize, turn waste into wealth, alkali liquid regeneration does not need the hydrotreatment of solvent extraction and sulfur-bearing solvent;

Alkali liquor oxidizedly carry out under about 40 DEG C conditions, more conventional or similar technique energy consumption reduces more than 50%;

(3) three waste discharge is low, and environmental benefit is good:

More conventional or the similar technique of alkaline residue quantity discharged reduces more than 50-80%: adopt coalescer to remove the water carried secretly in raw material, discharge from Sources controlling alkaline residue; Mercaptan removal alkali liquid regeneration rate reaches more than 90%.

In raw material condensate oil, the mercaptan of more than 80% finally with liquid disulfide isolated in form out, utilizes as industrial chemicals, meets national circular economy policy guiding.

(4) plant running cost is low:

It is low that cost refined by condensate oil, is 1/4-1/2 that is conventional or similar technique cost.

Accompanying drawing explanation

Below in order to be illustrated more clearly in the utility model embodiment or technical scheme of the prior art, be briefly described to the accompanying drawing used required in embodiment below, apparently, accompanying drawing in the following describes is only some embodiments of the application, for those of ordinary skill in the art, under the prerequisite not paying creative work, other accompanying drawing can also be obtained according to these accompanying drawings.

Fig. 1 is the apparatus structure schematic diagram one that condensate oil mercaptan removal described in the utility model embodiment and alkali liquid regeneration reclaim disulphide;

Fig. 2 is the apparatus structure schematic diagram two that condensate oil mercaptan removal described in the utility model embodiment and alkali liquid regeneration reclaim disulphide;

Fig. 3 is the apparatus structure schematic diagram three that condensate oil mercaptan removal described in the utility model embodiment and alkali liquid regeneration reclaim disulphide;

Fig. 4 is the apparatus structure schematic diagram four that condensate oil mercaptan removal described in the utility model embodiment and alkali liquid regeneration reclaim disulphide;

Fig. 5 is the apparatus structure schematic diagram five that condensate oil mercaptan removal described in the utility model embodiment and alkali liquid regeneration reclaim disulphide;

Fig. 6 is the apparatus structure schematic diagram six that condensate oil mercaptan removal described in the utility model embodiment and alkali liquid regeneration reclaim disulphide;

Fig. 7 is the apparatus structure schematic diagram seven that condensate oil mercaptan removal described in the utility model embodiment and alkali liquid regeneration reclaim disulphide;

Fig. 8 is the apparatus structure schematic diagram eight that condensate oil mercaptan removal described in the utility model embodiment and alkali liquid regeneration reclaim disulphide;

Fig. 9 is the apparatus structure schematic diagram nine that condensate oil mercaptan removal described in the utility model embodiment and alkali liquid regeneration reclaim disulphide.

In figure:

1, condensate oil strainer; 2, coalescent water trap; 3, one-level liquid membrane contactor; 4, first grade desulfurizing alcohol separating tank; 5, first grade desulfurizing alcohol separating tank condensate oil outlet damper; 6, secondary liquid membrane contactor; 7, two-grade desulfurizing alcohol separating tank; 8, two-grade desulfurizing alcohol separating tank condensate oil outlet damper; 9, coalescent dealkalize device; 10, NaOH solution circulating pump; 11, air filter; 12, alkali lye interchanger; 13, catalyst injector; 14, alkali liquor oxidized tower; 15, gas distributor one; 16, disulphide knockout tower; 17, disulphide coalescent pack; 18, alkali lye gas stripping column; 19, gas distributor two; 20, regenerating alkali liquid pump; 21, alkali lye strainer; 22, tail gas washing dealkalize tank; 23, gas distributor three; 24, disulphide tank; 25, condensate oil feed-pipe; 26, condensate oil pipe connecting; 27, condensate oil goes out device pipe; 28, oily(waste)water pipe; 29, the rich alkali liquor pipe of mercaptan removal; 30, alkali liquor pipe is regenerated; 31, circulation alkali liquor pipe; 32, fresh alkali liquor pipe; 33, alkaline residue pipe; 34, non-purifying wind pipe; 35, offgas duct; 36, tail gas goes out device pipe; 37, disulphide pipe connecting; 38, disulphide goes out device pipe; 39, alkaline waste water pipe; 40, nitrogen tube; 41, mercaptan removal processing unit; 42, alkali liquor oxidized and sulfurous gas separating unit; 43, coalescent processed unit; 44 condensate oil washing dealkalize unit; 45, alkali liquor oxidized knockout tower; 46, liquid film washing contactor; 47, separating tank is washed; 48, separating tank baffle plate is washed; 49, water washing cycles pump; 50, desalination water pipe; 51, fresh desalination water pipe.

Embodiment

Below in conjunction with the accompanying drawing in the utility model embodiment, be clearly and completely described the technical scheme in the utility model embodiment, obviously, described embodiment is only the utility model part embodiment, instead of whole embodiments.Based on the embodiment in the utility model, the every other embodiment that those of ordinary skill in the art obtain, all belongs to the scope of the utility model protection.

A kind of condensate oil mercaptan removal as shown in figs 1-9 and alkali liquid regeneration reclaim the device of disulphide, comprise mercaptan removal processing unit 41, described mercaptan removal processing unit 41 bottom end outlet is connected with alkali liquor oxidized and sulfurous gas separating unit 42 bottom entrance, described alkali liquor oxidized and sulfurous gas separating unit 42 bottom end outlet is connected with alkali lye gas stripping column 18 side entrance, described alkali liquor oxidized and sulfurous gas separating unit 42 top outlet, the outlet of alkali lye gas stripping column 18 top is all washed dealkalize tank 22 side entrance and is connected with tail gas, described alkali liquor oxidized and sulfurous gas separating unit 42 side outlet, tail gas washing dealkalize tank 22 bottom end outlet is all connected with disulphide tank 24 top inlet, described alkali lye gas stripping column 18 bottom end outlet is connected with mercaptan removal processing unit 41 side entrance, and with one or more some strainers be connected in above-mentioned each parts, some recycle pumps, some pipelines, some fluid inlets and some liquid outlets.

In one embodiment, coalescent processed unit 43 and/or condensate oil washing dealkalize unit 44 is also comprised; Described coalescent processed unit 43 side outlet is connected with mercaptan removal processing unit 41 top inlet; Described condensate oil washing dealkalize unit 44 top inlet exports with mercaptan removal processing unit 41 top and is connected.

In another embodiment, described strainer comprises condensate oil strainer 1, air filter 11, alkali lye strainer 21, described condensate oil strainer 1 outlet is connected with coalescent processed unit 43 top inlet, described air filter 11 is connected with alkali liquor oxidized and sulfurous gas separating unit 42 side entrance, described alkali lye strainer 21 entrance is connected with alkali lye gas stripping column 18 bottom entrance, therebetween be provided with regenerating alkali liquid pump 20, described alkali lye strainer 21 outlet is connected with mercaptan removal processing unit 41 side entrance.

In another embodiment, described pipeline comprises the condensate oil feed-pipe 25 be connected with condensate oil strainer 1, export with coalescent processed unit 43 side respectively, the condensate oil pipe connecting 26 that mercaptan removal processing unit 41 top inlet is connected, wash dealkalize unit 44 side with condensate oil to export the condensate oil be connected and go out device pipe 27, the oily(waste)water pipe 28 be connected with coalescent processed unit 43 bottom end outlet, respectively with mercaptan removal processing unit 41 bottom end outlet, the rich alkali liquor pipe 29 of the mercaptan removal that alkali liquor oxidized and sulfurous gas separating unit 42 bottom entrance is connected, the alkaline residue pipe 33 be connected with the rich alkali liquor pipe 29 of mercaptan removal, the non-purifying wind pipe 34 be connected with air filter 11, export with sulfurous gas separating unit 42 top respectively, the offgas duct 35 that tail gas washing dealkalize tank 22 side entrance is connected, wash dealkalize tank 22 top with tail gas to export the tail gas be connected and go out device pipe 36, export with mercaptan removal processing unit 41 side respectively, the disulphide pipe connecting 37 that disulphide tank 24 top inlet is connected, disulphide tank 24 bottom end outlet is communicated with disulphide and goes out device pipe 38, condensate oil washing dealkalize unit 44 bottom end outlet is communicated with alkaline waste water pipe 39, alkali lye gas stripping column 18 lower side end entrance is communicated with nitrogen tube 40.

In another embodiment, described mercaptan removal processing unit 41 is device one, device two or device three;

Described device one comprises one-level liquid membrane contactor 3 and coupled logical first grade desulfurizing alcohol separating tank 4, described one-level liquid membrane contactor 3 top inlet exports with coalescent processed unit 43 side and is connected, described alkali lye gas stripping column 18 bottom end outlet, fresh alkali liquor pipe 32 all with one-level liquid membrane contactor 3 side entrance be connected, described first grade desulfurizing alcohol separating tank 4 bottom end outlet is connected with sulfurous gas separating unit 42 bottom entrance, and the outlet of described first grade desulfurizing alcohol separating tank 4 top is washed dealkalize unit 44 top inlet with condensate oil and is connected;

Described device two comprises one-level liquid membrane contactor 3 and coupled logical first grade desulfurizing alcohol separating tank 4, secondary liquid membrane contactor 6 and coupled logical two-grade desulfurizing alcohol separating tank 7;

Described one-level liquid membrane contactor 3 top inlet exports with coalescent processed unit 43 side and is connected, described one-level liquid membrane contactor 3 side entrance is connected with two-grade desulfurizing alcohol separating tank 7 bottom end outlet by NaOH solution circulating pump 10, described NaOH solution circulating pump 10 is arranged on circulation alkali liquor pipe 31, described first grade desulfurizing alcohol separating tank 4 bottom end outlet is connected with sulfurous gas separating unit 42 bottom entrance, the outlet of described first grade desulfurizing alcohol separating tank 4 top is connected with secondary liquid membrane contactor 6 top inlet, described alkali lye gas stripping column 18 bottom end outlet, fresh alkali liquor pipe 32 all with secondary liquid membrane contactor 6 side entrance be connected, the outlet of described two-grade desulfurizing alcohol separating tank 7 top is washed dealkalize unit 44 top inlet with condensate oil and is connected, or

Described one-level liquid membrane contactor 3 top inlet exports with coalescent processed unit 43 side and is connected, described one-level liquid membrane contactor 3 side entrance and secondary liquid membrane contactor 6 side entrance all with alkali lye gas stripping column 18 bottom end outlet, fresh alkali liquor pipe 32 is connected, described first grade desulfurizing alcohol separating tank 4 bottom end outlet is all connected with sulfurous gas separating unit 42 bottom entrance with two-grade desulfurizing alcohol separating tank 7 bottom entrance, the outlet of described first grade desulfurizing alcohol separating tank 4 top is connected with secondary liquid membrane contactor 6 top inlet, the outlet of described two-grade desulfurizing alcohol separating tank 7 top is washed dealkalize unit 44 top inlet with condensate oil and is connected,

Described device three comprises the coupled logical first grade desulfurizing alcohol separating tank 4 of one-level liquid membrane contactor 3, the coupled logical coupled three grades of logical mercaptan removal separating tanks of two-grade desulfurizing alcohol separating tank 7, three grades of liquid membrane contactors of secondary liquid membrane contactor 6;

Described one-level liquid membrane contactor 3 top inlet exports with coalescent processed unit 43 side and is connected, described one-level liquid membrane contactor 3 side entrance is connected with two-grade desulfurizing alcohol separating tank 7 bottom end outlet by NaOH solution circulating pump 10, described first grade desulfurizing alcohol separating tank 4 bottom end outlet is connected with sulfurous gas separating unit 42 bottom entrance, the outlet of described first grade desulfurizing alcohol separating tank 4 top is connected with secondary liquid membrane contactor 6 top inlet, described secondary liquid membrane contactor 6 side entrance is connected with three grades of mercaptan removal separating tank bottom end outlet by NaOH solution circulating pump 10, the outlet of described two-grade desulfurizing alcohol separating tank 7 top is connected with three grades of liquid membrane contactor top inlet, described alkali lye gas stripping column 18 bottom end outlet, fresh alkali liquor pipe 32 is all connected with three grades of liquid membrane contactor side entrances, the outlet of described three grades of mercaptan removal separating tank tops is washed dealkalize unit 44 top inlet with condensate oil and is connected, or

Described one-level liquid membrane contactor 3 top inlet exports with coalescent processed unit 43 side and is connected, the outlet of described first grade desulfurizing alcohol separating tank 4 top is connected with secondary liquid membrane contactor 6 top inlet, described secondary liquid membrane contactor 6 is all connected with three grades of mercaptan removal separating tank bottom end outlet by NaOH solution circulating pump 10 with the side entrance of three grades of liquid membrane contactors, described first grade desulfurizing alcohol separating tank 4 is all connected with sulfurous gas separating unit 42 bottom entrance with the bottom end outlet of two-grade desulfurizing alcohol separating tank 7, the outlet of described two-grade desulfurizing alcohol separating tank 7 top is connected with three grades of liquid membrane contactor top inlet, described alkali lye gas stripping column 18 bottom end outlet, fresh alkali liquor pipe 32 is all connected with three grades of liquid membrane contactor side entrances, the outlet of described three grades of mercaptan removal separating tank tops is washed dealkalize unit 44 top inlet with condensate oil and is connected.

In another embodiment, described sulfurous gas separating unit 42 is device four or device five;

Described device four comprises alkali liquor oxidized tower 14, position, described alkali liquor oxidized tower 14 inner middle and lower part is provided with gas distributor 1, the outlet of described alkali liquor oxidized tower 14 side to be exported with disulphide knockout tower 16 side by regeneration alkali liquor pipe 30 and is connected, described alkali liquor oxidized tower 14 side entrance, the position of gas distributor 1 is communicated with non-purifying wind pipe 34, described alkali liquor oxidized tower 14 bottom entrance is connected with mercaptan removal processing unit 41 bottom end outlet, alkali lye interchanger 12 and catalyst injector 13 is disposed with between described mercaptan removal processing unit 41 and alkali liquor oxidized tower 14, upperly in described disulphide knockout tower 16 inside install disulphide coalescent pack 17, described disulphide knockout tower 16 bottom end outlet is connected with alkali lye gas stripping column 18 side entrance, described disulphide knockout tower 16 side outlet is connected with disulphide tank 24 top inlet, described alkali liquor oxidized tower 14, the outlet of disulphide knockout tower 16 top is all washed dealkalize tank 22 side entrance and is connected with tail gas, in described tail gas washing dealkalize tank 22 inside, upper/lower positions is provided with gas distributor 3 23,

Described device five comprises alkali liquor oxidized knockout tower 45, described alkali liquor oxidized knockout tower 45 bottom entrance is connected with mercaptan removal processing unit 41 bottom end outlet, described alkali liquor oxidized knockout tower 45 inner route clapboard is separated into two regions, middle upper/lower positions in one region is provided with gas distributor 1, upperly in another region install disulphide coalescent pack 17, alkali lye interchanger 12 and catalyst injector 13 is provided with successively between described alkali liquor oxidized knockout tower 45 and mercaptan removal processing unit 41, the outlet of described alkali liquor oxidized knockout tower 45 lower end is connected with alkali lye gas stripping column 18 side entrance, described alkali liquor oxidized knockout tower 45 side outlet is connected with disulphide tank 24 top inlet, the outlet of described alkali liquor oxidized knockout tower 45 top is washed dealkalize tank 22 side entrance with tail gas and is connected, in described tail gas washing dealkalize tank 22 inside, upper/lower positions is provided with gas distributor 3 23.

In another embodiment, described coalescent processed unit 43 comprises coalescent water trap 2, described coalescent water trap 2 top inlet is connected with condensate oil feed-pipe 25, described coalescent water trap 2 bottom end outlet is connected with oily(waste)water pipe 28, and described coalescent water trap 2 side is connected with condensate oil pipe connecting 26;

Described condensate oil washing dealkalize unit 44 is device six or device seven;

Described device six comprises coalescent dealkalize device 9, described coalescent dealkalize device 9 top inlet exports with the top of mercaptan removal processing unit 41 and is connected, described coalescent dealkalize device 9 bottom end outlet is connected with alkaline waste water pipe 39, and described coalescent dealkalize device 9 side outlet goes out device pipe 27 with condensate oil and is connected;

Described device seven comprises liquid film washing contactor 46, described liquid film washing contactor 46 top inlet exports with the top of mercaptan removal processing unit 41 and is connected, described liquid film washing contactor 46 is connected with washing separating tank 47, the outlet of described washing separating tank 47 lower end is washed contactor 46 side entrance by water washing cycles pump 49 and liquid film and is connected, and described washing separating tank 47 top is communicated with condensate oil and goes out device pipe 27.

In another embodiment, exit, described first grade desulfurizing alcohol separating tank 4 top is provided with first grade desulfurizing alcohol separating tank condensate oil outlet damper 5, exit, described two-grade desulfurizing alcohol separating tank 7 top is provided with two-grade desulfurizing alcohol separating tank condensate oil outlet damper 8, and exit, described three grades of mercaptan removal separating tank tops is provided with three grades of mercaptan removal separating tank condensate oil outlet dampers.

During concrete use, utilize coalescent water trap 2 to carry out processed to the condensate oil raw material being entrained with free-water, thus make the free-water in condensate oil be down to below 10ppm, if not containing free-water in raw material condensate oil, coalescent water trap 2 can be omitted;

As shown in accompanying drawing 1-8, adopt fiber film contactor alkali washing process, liquid membrane contactor inner core is made up of special hydrophilic fibers silk, alkali lye extends at filament surface and forms the ultra-thin alkali lye liquid film of very big area, condensate oil passes through between alkali lye liquid film, alkali lye and condensate oil contact area significantly increase, interphase mass transfer distance shortens greatly, two contact fully and are swift in response, thus the reaction depth of sodium hydroxide in mercaptan and alkali lye in raising condensate oil, for different mercaptans content, the condensate oil raw material of different treatment scale and operating mode, user is to the specification of quality of product, the alkali cleaning of single-stage liquid membrane contactor can be selected, two-stage or multistage liquid membrane contactor series connection alkali cleaning, two or the alkali cleaning in parallel of multiple stage liquid membrane contactor, or the combination process of aforesaid way, washing process is: after alkali cleaning, condensate oil enters from liquid membrane contactor top with the de-mineralized water come by circulating water wash pumping, and washing dealkalize is completed in liquid film washing contactor 46, after dealkalize, condensate oil and de-mineralized water are separated washing separating tank 47, refining condensate oil goes out device, de-mineralized water is cycled to used in dealkalize, according to product condensate oil sodium ions content rising situation periodic replacement de-mineralized water, fresh de-mineralized water is come by fresh de-mineralized water pumping,

The alkali lye being rich in sodium mercaptides that condensate oil caustic wash desulfuration alcohol produces, enter alkali liquid regeneration part, alkali liquor oxidized tower 14 and disulphide knockout tower 16 or alkali liquor oxidized knockout tower 45 is utilized to carry out being separated of alkali liquor oxidized and disulphide respectively, 50-300ppm titanium cyanines cobalt class catalyzer is added in the rich alkali lye after mercaptan removal, described titanium cyanines cobalt class catalyzer comprises sulfonation titanium cyanines cobalt, poly-titanium cyanines cobalt, titanium cyanines cobalt ammonium sulphonate, catalyst injector 13 or volume pump is utilized titanium cyanines cobalt class catalyzer to be injected into the oxidation zone of alkali liquor oxidized tower 14 or alkali liquor oxidized knockout tower 45 from the import of tower bottom alkali lye, pressurized air after air filter 11 filters imports via the oxidation wind import bottom the oxidation zone of alkali liquor oxidized tower 14 or alkali liquor oxidized knockout tower 45, owing to being provided with gas distributor 1 bottom the oxidation zone of alkali liquor oxidized tower 14 or alkali liquor oxidized knockout tower 45, described gas distributor one 15 pairs of oxidation airs process, it is made to be dispersed in alkali lye with the microvesicle form of diameter 0.1-5mm, oxidation air becomes the order of magnitude to increase with alkali lye contact area, alkali liquor oxidized efficiency comparatively traditional technology improves 2-3 doubly, after oxidation, in alkali lye, sodium mercaptides concentration can be stabilized in below 1000ppm, minimumly reach below 100ppm, simultaneously, in the oxidation zone of alkali liquor oxidized tower 14 or alkali liquor oxidized knockout tower 45, because in air and alkaline reaction process, disturbance is little, sodium mercaptides oxidation conversion speed is fast, the disulphide of the disulphide larger drop of coalescent formation under microvesicle air supporting effect generated, thus avoid the emulsification of disulphide in regeneration alkali lye, described disulphide mean drop diameter is 30-100 times of the disulphide drop that conventional filler tower oxidizing process obtains, therefore the utility model is very beneficial for being separated of disulphide and alkali lye, meanwhile, coalescent pack in disulphide knockout tower 16 or alkali liquor oxidized knockout tower 45 disengaging zone makes the alkali lye being entrained with a small amount of disulphide form liquid film thereon, it is made fully to contact with the disulphide of layering, thus a small amount of disulphide carried secretly in alkali lye is extracted in the disulphide of layering, finally realize the Separation and Recovery of the disulphide of more than 80%,

Mercaptan removal alkali lye is after peroxidation and Separation and Recovery disulphide, utilization is provided with micro-disulphide still residual in alkali lye gas stripping column alkali 18 pairs of alkali lye of gas distributor 2 19 and processes, described gas distributor 2 19 processes the nitrogen imported or air, make its rill forming diameter 10-100mm and be dispersed in alkali lye, residual disulphide to be dissolved in bubble and to be pulled away along with tail gas volatilization, tail gas is derived from alkali lye gas stripping column 18 top, alkali lye is derived after standing separation gas bottom alkali lye gas stripping column 18 bottom alkali lye gas stripping column 18, alkali lye is sent to mercaptan removal processing unit 41 by regenerating alkali liquid pump 20, in regeneration alkali lye, disulphide content can drop to below 500ppm, minimumly be reduced to below 10ppm, when this alkali lye can be cycled to used in condensate oil mercaptan removal, the process of trace disulphide is stripped in product condensate oil to prevent it, owing to not needing frequently to change alkali lye, alkali lye consumes and alkaline residue discharge comparatively other technique minimizing more than 80%,

The temperature of mercaptan removal alkali lye in alkali liquor oxidized tower 14 or alkali liquor oxidized knockout tower 45 oxidation zone need maintain within the scope of 30-70 DEG C, if enter the alkali liquid temperature of alkali liquor oxidized tower 14 lower than 30 DEG C, need be heated it by alkali lye interchanger 12, be heated to temperature and reach 30-40 DEG C, in alkali lye, sodium mercaptides oxidation heat liberation can make alkali lye have certain temperature rise, if the alkali liquid temperature entering alkali liquor oxidized tower 14 is higher than 30 DEG C, then without the need to using alkali lye interchanger 12, with energy efficient;

Tail gas washing dealkalize tank 22 carries out washing dealkalize to the tail gas after oxidation and air lift, gas distributor 3 23 pairs of tail gas process, it is made to be scattered in the water in tail gas washing dealkalize tank 22 with the bubble form of diameter 1-5cm, thus the micro-alkali lye water elution carried secretly in alkali liquor oxidized regeneration and air lift tail gas is removed, the tail gas guide after dealkalize is delivered to burning, desulfurization equipment process or is utilized and reclaims disulphide, desulfurization equipment and process it.

Embodiment one

As shown in Figure 1, condensate oil is by feed-pipe 25 access to plant, condensate oil feed-pipe 25 connects condensate oil strainer 1 and coalescent water trap 2, condensate oil is crossed through condensate oil strainer 1 and is filtered mechanical impurity, the water carried secretly is removed through coalescent water trap 2, oily(waste)water pipe 28 is connected with bottom coalescent water trap 2, coalescent water trap 2 connects one-level liquid membrane contactor 3 by condensate oil pipe connecting 26, one-level liquid membrane contactor 3 is arranged on first grade desulfurizing alcohol separating tank 4 by flange, first grade desulfurizing alcohol separating tank 4 top has condensate oil to export, condensate oil outlet is provided with first grade desulfurizing alcohol separating tank condensate oil outlet damper 5 in tank, condensate oil outlet connects secondary liquid membrane contactor 6 by condensate oil pipe connecting 26, secondary liquid membrane contactor 6 is arranged on two-grade desulfurizing alcohol separating tank 7 by flange, two-grade desulfurizing alcohol separating tank 7 top has condensate oil to export, condensate oil outlet is provided with two-grade desulfurizing alcohol separating tank condensate oil outlet damper 8 in tank, condensate oil successively removes through one-level liquid membrane contactor 3 and secondary liquid membrane contactor 6 alkali cleaning the mercaptan carried secretly, after alkali cleaning, condensate oil and alkali lye are settlement separate in first grade desulfurizing alcohol separating tank 4 and two-grade desulfurizing alcohol separating tank 7 respectively, after alkali cleaning, condensate oil is connected coalescent dealkalize device 9 through outlet with condensate oil pipe connecting 26, the alkali lye carried secretly is removed through coalescent dealkalize device 9, coalescent dealkalize device 9 top connects condensate oil and goes out device pipe 27, bottom connects alkaline waste water pipe 39, alkali lye is had to export bottom two-grade desulfurizing alcohol separating tank 7, alkali lye outlet delivers to one-level liquid membrane contactor 3 by circulation alkali liquor pipe 31 through NaOH solution circulating pump 10, alkali lye is had to export bottom first grade desulfurizing alcohol separating tank 4, alkali lye outlet is by the rich alkali liquor pipe 29 of mercaptan removal and alkali lye interchanger 12, catalyst injector 13, alkali liquor oxidized tower 14 connects, rich alkali lye heats through alkali lye interchanger 12, by the alkali liquor oxidized catalyzer of catalyst injector 13 regular replenishment, in alkali liquor oxidized tower 14, gas distributor 1 is installed, gas distributor 1 is connected with air filter 11 by non-purifying wind pipe 34, oxidation air is dispersed into small bubble through gas distributor 1, alkali lye and bubble fully contact and react oxidizing reaction in alkali liquor oxidized tower 14, sodium mercaptides in alkali lye is oxidized to sodium hydroxide and disulphide, sodium hydroxide is dissolved in alkali lye and alkali lye is regenerated, disulphide is undertaken being separated and reclaiming by follow-up equipment, an offgas outlet and alkali lye outlet are respectively arranged at alkali liquor oxidized tower 14 top, offgas outlet is by offgas duct 35 and disulphide knockout tower 16 offgas outlet, alkali lye gas stripping column 18 offgas outlet, tail gas washing dealkalize tank 22 inlet exhaust gas connects, alkali lye outlet is connected with the import of disulphide knockout tower 16 alkali lye by regeneration alkali liquor pipe 30, disulphide knockout tower 16 top is provided with disulphide coalescent pack 17, under disulphide coalescent pack 17 acts on, after oxidation, alkali lye is separated with disulphide, and periodic exhaustion goes out equipment reclaims, disulphide knockout tower 16 top has offgas outlet to connect offgas duct 35, upper lateral part respectively has an alkali lye outlet and disulphide outlet, bottom has alkali lye to export, disulphide outlet is connected with the import of disulphide tank 24 disulphide by disulphide pipe connecting 37, alkali lye outlet is connected with the import of alkali lye gas stripping column 18 alkali lye by regeneration alkali liquor pipe 30, the import of alkali lye gas stripping column 18 alkali lye is in middle and upper part, top has offgas outlet to connect offgas duct 35, gas distributor 2 19 is installed in alkali lye gas stripping column 18, gas distributor 2 19 connects nitrogen tube 40, nitrogen is dispersed into tiny bubble by gas distributor 2 19, alkali lye after Separation and Recovery disulphide still can carry a small amount of disulphide secretly, this alkali lye dissolves disulphide by nitrogen bubble and takes away disulphide with tail gas, alkali lye is had to export bottom alkali lye gas stripping column 18, alkali lye outlet connects regenerating alkali liquid pump 20 by regeneration alkali liquor pipe 30, alkali lye strainer 21 and secondary liquid membrane contactor 6, regenerating alkali liquid pump 20 import is connected with fresh alkali liquor pipe 32, the rich alkali liquor pipe 29 of one-level liquid film mercaptan removal separating tank outlet mercaptan removal is connected with alkaline residue pipe 33, tail gas washing dealkalize tank 22 portion on the lower side connects offgas duct 35, in tail gas washing dealkalize tank 22, gas distributor 3 23 is installed, gas distributor 3 23 connects inlet exhaust gas, tail gas is dispersed into tiny bubble through gas distributor 3 23 and fully contacts with the water in tank, wash away the alkali lye carried secretly, tail gas washing dealkalize tank 22 top is offgas outlet, connect tail gas and go out device pipe 36, be disulphide outlet bottom tail gas washing dealkalize tank 22, connect disulphide pipe connecting 37, disulphide tank 24 top is disulphide import, connect disulphide pipe connecting 37, it is disulphide outlet bottom disulphide tank 24, connect disulphide and go out device pipe 38.

Embodiment two

As shown in Figure 2, condensate oil is by condensate oil feed-pipe 25 access to plant, condensate oil feed-pipe 25 connects condensate oil strainer 1 and coalescent water trap 2, condensate oil is crossed through condensate oil strainer 1 and is filtered mechanical impurity, the water carried secretly is removed through coalescent water trap 2, oily(waste)water pipe 28 is connected with bottom coalescent water trap 2, coalescent water trap 2 connects one-level liquid membrane contactor 3 by condensate oil pipe connecting 26, one-level liquid membrane contactor 3 is arranged on first grade desulfurizing alcohol separating tank 4 by flange, first grade desulfurizing alcohol separating tank 4 top has condensate oil to export, condensate oil outlet is provided with baffle plate 5 in tank, condensate oil outlet connects secondary liquid membrane contactor 6 by condensate oil pipe connecting 26, secondary liquid membrane contactor 6 is arranged on two-grade desulfurizing alcohol separating tank 7 by flange, two-grade desulfurizing alcohol separating tank 7 top has condensate oil to export, condensate oil outlet is provided with two-grade desulfurizing alcohol separating tank condensate oil outlet damper 8 in tank, condensate oil successively removes through one-level liquid membrane contactor 3 and secondary liquid membrane contactor 6 alkali cleaning the mercaptan carried secretly, after alkali cleaning, condensate oil and alkali lye are settlement separate in first grade desulfurizing alcohol separating tank 4 and two-grade desulfurizing alcohol separating tank 7 respectively, after alkali cleaning, condensate oil is connected coalescent dealkalize device 9 through outlet with condensate oil pipe connecting 26, the alkali lye carried secretly is removed through coalescent dealkalize device 9, coalescent dealkalize device 9 top connects condensate oil and goes out device pipe 27, bottom connects alkaline waste water pipe 39, alkali lye is had to export bottom two-grade desulfurizing alcohol separating tank 7, alkali lye outlet delivers to one-level liquid membrane contactor 3 by circulation alkali liquor pipe 31 through NaOH solution circulating pump 10, alkali lye is had to export bottom first grade desulfurizing alcohol separating tank 4, alkali lye outlet is by the rich alkali liquor pipe 29 of mercaptan removal and alkali lye interchanger 12, catalyst injector 13, alkali liquor oxidized knockout tower 45 connects, rich alkali lye heats through alkali lye interchanger 12, by the alkali liquor oxidized catalyzer of catalyst injector 13 regular replenishment, alkali liquor oxidized knockout tower 45 dividing plate is divided into Liang Ge district, one district is alkali liquor oxidized district, another district is disulphide disengaging zone, gas distributor 1 is installed bottom alkali liquor oxidized district, gas distributor 1 is connected with air filter 11 by non-purifying wind pipe 34, oxidation air is dispersed into small bubble through gas distributor 1, alkali lye and bubble fully contact and react oxidizing reaction in alkali liquor oxidized district, sodium mercaptides in alkali lye is oxidized to sodium hydroxide and disulphide, sodium hydroxide is dissolved in alkali lye and alkali lye is regenerated, after oxidation, alkali lye overflows across dividing plate and flows to disulphide disengaging zone, top, disulphide disengaging zone is provided with coalescent pack 17, under coalescent pack 17 acts on, after oxidation, alkali lye is separated with disulphide, and periodic exhaustion reclaims to disulphide tank 24, disengaging zone upper lateral part also has an alkali lye outlet and disulphide outlet, alkali lye is had to export bottom disengaging zone, disulphide outlet is connected with the import of disulphide tank 24 disulphide by disulphide pipe connecting 37, an offgas outlet is arranged at alkali liquor oxidized knockout tower 45 top, offgas outlet is by offgas duct 35 and alkali lye gas stripping column 18 offgas outlet, tail gas washing dealkalize tank 22 inlet exhaust gas connects, alkali lye outlet is connected with the import of alkali lye gas stripping column 18 alkali lye by regeneration alkali liquor pipe 30, the import of alkali lye gas stripping column 18 alkali lye is in middle and upper part, top has offgas outlet to connect offgas duct 35, gas distributor 2 19 is installed in alkali lye gas stripping column 18, gas distributor 2 19 connects nitrogen tube 40, nitrogen is dispersed into tiny bubble by gas distributor 2 19, alkali lye after Separation and Recovery disulphide still can carry a small amount of disulphide secretly, this alkali lye dissolves disulphide by nitrogen bubble and takes away disulphide with tail gas, alkali lye is had to export bottom alkali lye gas stripping column 18, alkali lye outlet connects regenerating alkali liquid pump 20 by alkali liquor pipe 30, alkali lye strainer 21 and secondary liquid membrane contactor 6, regenerating alkali liquid pump 20 import is connected with fresh alkali liquor pipe 32, the rich alkali liquor pipe 29 of one-level liquid film mercaptan removal separating tank outlet mercaptan removal is connected with alkaline residue pipe 33, tail gas washing dealkalize tank 22 portion on the lower side connects offgas duct 35, in tail gas washing dealkalize tank 22, gas distributor 3 23 is installed, gas distributor 3 23 connects inlet exhaust gas, tail gas is dispersed into tiny bubble through gas distributor 3 23 and fully contacts with the water in tank, wash away the alkali lye carried secretly, tail gas washing dealkalize tank 22 top is offgas outlet, connect tail gas and go out device pipe 36, be disulphide outlet bottom tail gas washing dealkalize tank 22, connect disulphide pipe connecting 37, disulphide tank 24 top is disulphide import, connect disulphide pipe connecting 37, it is disulphide outlet bottom disulphide tank 24, connect disulphide and go out device pipe 38.

Embodiment three

As shown in Figure 9, condensate oil is by feed-pipe 25 access to plant, condensate oil feed-pipe 25 connects condensate oil strainer 1 and coalescent water trap 2, condensate oil is crossed through condensate oil strainer 1 and is filtered mechanical impurity, the water carried secretly is removed through coalescent water trap 2, oily(waste)water pipe 28 is connected with bottom coalescent water trap 2, coalescent water trap 2 connects one-level liquid membrane contactor 3 by condensate oil pipe connecting 26, one-level liquid membrane contactor 3 is arranged on first grade desulfurizing alcohol separating tank 4 by flange, first grade desulfurizing alcohol separating tank 4 top has condensate oil to export, condensate oil outlet is provided with baffle plate 5 in tank, condensate oil outlet connects secondary liquid membrane contactor 6 by condensate oil pipe connecting 26, secondary liquid membrane contactor 6 is arranged on two-grade desulfurizing alcohol separating tank 7 by flange, two-grade desulfurizing alcohol separating tank 7 top has condensate oil to export, condensate oil outlet is provided with baffle plate 8 in tank, condensate oil successively removes through one-level liquid membrane contactor 3 and secondary liquid membrane contactor 6 alkali cleaning the mercaptan carried secretly, after alkali cleaning, condensate oil and alkali lye are settlement separate in first grade desulfurizing alcohol separating tank 4 and two-grade desulfurizing alcohol separating tank 7 respectively, after alkali cleaning, condensate oil washes contactor 46 through outlet and condensate oil pipe connecting 26 connecting fluid film water, after alkali cleaning, condensate oil removes the alkali lye of deentrainment through liquid film washing contactor 46 and de-mineralized water washing, liquid film washing contactor 46 is arranged on washing separating tank 47 by flange, washing separating tank 47 top has condensate oil to export, condensate oil outlet is provided with washing separating tank baffle plate 48 in tank, condensate oil outlet connects condensate oil and goes out device pipe 27, de-mineralized water is had to export bottom washing separating tank 47, de-mineralized water outlet is washed contactor 46 by desalination water pipe 50 with water washing cycles pump 49 and liquid film and is connected, desalination water pipe 50 is connected with alkaline waste water pipe 39 and fresh desalination water pipe 51, alkali lye is had to export bottom two-grade desulfurizing alcohol separating tank 7, alkali lye outlet delivers to one-level liquid membrane contactor 3 by circulation alkali liquor pipe 31 through NaOH solution circulating pump 10, alkali lye is had to export bottom first grade desulfurizing alcohol separating tank 4, alkali lye outlet is by the rich alkali liquor pipe 29 of mercaptan removal and alkali lye interchanger 12, catalyst injector 13, alkali liquor oxidized tower 14 connects, rich alkali lye heats through alkali lye interchanger 12, by the alkali liquor oxidized catalyzer of catalyst injector 13 regular replenishment, in alkali liquor oxidized tower 14, gas distributor 1 is installed, gas distributor 1 is connected with air filter 11 by non-purifying wind pipe 34, oxidation air is dispersed into small bubble through gas distributor 1, alkali lye and bubble fully contact and react oxidizing reaction in alkali liquor oxidized tower 14, sodium mercaptides in alkali lye is oxidized to sodium hydroxide and disulphide, sodium hydroxide is dissolved in alkali lye and alkali lye is regenerated, disulphide is undertaken being separated and reclaiming by follow-up equipment, an offgas outlet and alkali lye outlet are respectively arranged at alkali liquor oxidized tower 14 top, offgas outlet is by offgas duct 35 and disulphide knockout tower 16 offgas outlet, alkali lye gas stripping column 18 offgas outlet, tail gas washing dealkalize tank 22 inlet exhaust gas connects, alkali lye outlet is connected with the import of disulphide knockout tower 16 alkali lye by regeneration alkali liquor pipe 30, disulphide knockout tower 16 top is provided with coalescent pack 17, under coalescent pack 17 acts on, after oxidation, alkali lye is separated with disulphide, and periodic exhaustion goes out equipment reclaims, disulphide knockout tower 16 top has offgas outlet to connect offgas duct 35, upper lateral part respectively has an alkali lye outlet and disulphide outlet, bottom has alkali lye to export, disulphide outlet is connected with the import of disulphide tank 24 disulphide by disulphide pipe connecting 37, alkali lye outlet is connected with the import of alkali lye gas stripping column 18 alkali lye by regeneration alkali liquor pipe 30, the import of alkali lye gas stripping column 18 alkali lye is in middle and upper part, top has offgas outlet to connect offgas duct 35, gas distributor 2 19 is installed in alkali lye gas stripping column 18, gas distributor 2 19 connects nitrogen tube 40, nitrogen is dispersed into tiny bubble by gas distributor 2 19, alkali lye after Separation and Recovery disulphide still can carry a small amount of disulphide secretly, this alkali lye dissolves disulphide by nitrogen bubble and takes away disulphide with tail gas, alkali lye is had to export bottom alkali lye gas stripping column 18, alkali lye outlet connects regenerating alkali liquid pump 20 by alkali liquor pipe 30, alkali lye strainer 21 and secondary liquid membrane contactor 6, regenerating alkali liquid pump 20 import is connected with fresh alkali liquor pipe 32, the rich alkali liquor pipe 29 of one-level liquid film mercaptan removal separating tank outlet mercaptan removal is connected with alkaline residue pipe 33, tail gas washing dealkalize tank 22 portion on the lower side connects offgas duct 35, in tail gas washing dealkalize tank 22, gas distributor 3 23 is installed, gas distributor 3 23 connects inlet exhaust gas, tail gas is dispersed into tiny bubble through gas distributor three (23) and fully contacts with the water in tank, wash away the alkali lye carried secretly, tail gas washing dealkalize tank 22 top is offgas outlet, connect tail gas and go out device pipe 36, be disulphide outlet bottom tail gas washing dealkalize tank 22, connect disulphide pipe connecting 37, disulphide tank 24 top is disulphide import, connect disulphide pipe connecting 37, it is disulphide outlet bottom disulphide tank 24, connect disulphide and go out device pipe 38.

Application example one

With reference to the accompanying drawings shown in 1, certain petrochemical corporation (complex) utilized this technique to build a set of condensate oil liquid film mercaptan removal and alkali liquor oxidized regenerating unit, condensate oil processing power 200 tons/hour, the average 2930ppm of raw material total sulfur content, the average 2570ppm of mercaptan sulfur content, free water content is about 500ppm, after the process of the utility model full scale plant, product condensate oil total sulfur≤700ppm, mercaptan sulfur content≤240ppm, carbon three and following mercaptans content≤20ppm, plant running 6 months, discharge alkaline residue 760 tons, monthly reclaim disulphide about 300 tons, disulphide is reclaimed by technology suppliers, use as industrial chemicals after processing, cost about 7.8 yuan/ton is refined by condensate oil unit.

The utility model is not limited to above-mentioned preferred forms; anyone can draw other various forms of products under enlightenment of the present utility model; no matter but any change is done in its shape or structure; every have identical with the application or akin technical scheme, all drops within protection domain of the present utility model.

Claims

1. a condensate oil mercaptan removal and alkali liquid regeneration reclaim the device of disulphide, it is characterized in that, comprise mercaptan removal processing unit (41), described mercaptan removal processing unit (41) bottom end outlet is connected with alkali liquor oxidized and sulfurous gas separating unit (42) bottom entrance, described alkali liquor oxidized and sulfurous gas separating unit (42) bottom end outlet is connected with alkali lye gas stripping column (18) side entrance, described alkali liquor oxidized and sulfurous gas separating unit (42) top outlet, the outlet of alkali lye gas stripping column (18) top is all washed dealkalize tank (22) side entrance and is connected with tail gas, described alkali liquor oxidized and sulfurous gas separating unit (42) side outlet, tail gas washing dealkalize tank (22) bottom end outlet is all connected with disulphide tank (24) top inlet, described alkali lye gas stripping column (18) bottom end outlet is connected with mercaptan removal processing unit (41) side entrance, and with one or more some strainers be connected in above-mentioned each parts, some recycle pumps, some pipelines, some fluid inlets and some liquid outlets.

2. condensate oil mercaptan removal according to claim 1 and alkali liquid regeneration reclaim the device of disulphide, it is characterized in that, also comprise coalescent processed unit (43) and/or condensate oil washing dealkalize unit (44); Described coalescent processed unit (43) side outlet is connected with mercaptan removal processing unit (41) top inlet; Described condensate oil washing dealkalize unit (44) top inlet exports with mercaptan removal processing unit (41) top and is connected.

3. condensate oil mercaptan removal according to claim 1 and 2 and alkali liquid regeneration reclaim the device of disulphide, it is characterized in that, described strainer comprises condensate oil strainer (1), air filter (11), alkali lye strainer (21), described condensate oil strainer (1) outlet is connected with coalescent processed unit (43) top inlet, described air filter (11) is connected with alkali liquor oxidized and sulfurous gas separating unit (42) side entrance, described alkali lye strainer (21) entrance is connected with alkali lye gas stripping column (18) bottom entrance, therebetween regenerating alkali liquid pump (20) is provided with, described alkali lye strainer (21) outlet is connected with mercaptan removal processing unit (41) side entrance.

4. condensate oil mercaptan removal according to claim 3 and alkali liquid regeneration reclaim the device of disulphide, it is characterized in that, described pipeline comprises the condensate oil feed-pipe (25) be connected with condensate oil strainer (1), export with coalescent processed unit (43) side respectively, the condensate oil pipe connecting (26) that mercaptan removal processing unit (41) top inlet is connected, wash dealkalize unit (44) side with condensate oil to export the condensate oil be connected and go out device pipe (27), the oily(waste)water pipe (28) be connected with coalescent processed unit (43) bottom end outlet, respectively with mercaptan removal processing unit (41) bottom end outlet, the rich alkali liquor pipe (29) of the mercaptan removal that alkali liquor oxidized and sulfurous gas separating unit (42) bottom entrance is connected, the alkaline residue pipe (33) be connected with the rich alkali liquor pipe (29) of mercaptan removal, the non-purifying wind pipe (34) be connected with air filter (11), export with sulfurous gas separating unit (42) top respectively, the offgas duct (35) that tail gas washing dealkalize tank (22) side entrance is connected, wash dealkalize tank (22) top with tail gas to export the tail gas be connected and go out device pipe (36), export with mercaptan removal processing unit (41) side respectively, the disulphide pipe connecting (37) that disulphide tank (24) top inlet is connected, disulphide tank (24) bottom end outlet is communicated with disulphide and goes out device pipe (38), condensate oil washing dealkalize unit (44) bottom end outlet is communicated with alkaline waste water pipe (39), alkali lye gas stripping column (18) lower side end entrance is communicated with nitrogen tube (40).

5. condensate oil mercaptan removal according to claim 2 and alkali liquid regeneration reclaim the device of disulphide, it is characterized in that, described mercaptan removal processing unit (41) is device one, device two or device three;

Described device one comprises one-level liquid membrane contactor (3) and coupled logical first grade desulfurizing alcohol separating tank (4), described one-level liquid membrane contactor (3) top inlet exports with coalescent processed unit (43) side and is connected, described alkali lye gas stripping column (18) bottom end outlet, fresh alkali liquor pipe (32) all with one-level liquid membrane contactor (3) side entrance be connected, described first grade desulfurizing alcohol separating tank (4) bottom end outlet is connected with sulfurous gas separating unit (42) bottom entrance, the outlet of described first grade desulfurizing alcohol separating tank (4) top is washed dealkalize unit (44) top inlet with condensate oil and is connected,

Described device two comprises one-level liquid membrane contactor (3) and coupled logical first grade desulfurizing alcohol separating tank (4), secondary liquid membrane contactor (6) and coupled logical two-grade desulfurizing alcohol separating tank (7);

Described one-level liquid membrane contactor (3) top inlet exports with coalescent processed unit (43) side and is connected, described one-level liquid membrane contactor (3) side entrance is connected with two-grade desulfurizing alcohol separating tank (7) bottom end outlet by NaOH solution circulating pump (10), described NaOH solution circulating pump (10) is arranged on circulation alkali liquor pipe (31), described first grade desulfurizing alcohol separating tank (4) bottom end outlet is connected with sulfurous gas separating unit (42) bottom entrance, the outlet of described first grade desulfurizing alcohol separating tank (4) top is connected with secondary liquid membrane contactor (6) top inlet, described alkali lye gas stripping column (18) bottom end outlet, fresh alkali liquor pipe (32) all with secondary liquid membrane contactor (6) side entrance be connected, the outlet of described two-grade desulfurizing alcohol separating tank (7) top is washed dealkalize unit (44) top inlet with condensate oil and is connected, or

Described one-level liquid membrane contactor (3) top inlet exports with coalescent processed unit (43) side and is connected, described one-level liquid membrane contactor (3) side entrance and secondary liquid membrane contactor (6) side entrance all with alkali lye gas stripping column (18) bottom end outlet, fresh alkali liquor pipe (32) is connected, described first grade desulfurizing alcohol separating tank (4) bottom end outlet is all connected with sulfurous gas separating unit (42) bottom entrance with two-grade desulfurizing alcohol separating tank (7) bottom entrance, the outlet of described first grade desulfurizing alcohol separating tank (4) top is connected with secondary liquid membrane contactor (6) top inlet, the outlet of described two-grade desulfurizing alcohol separating tank (7) top is washed dealkalize unit (44) top inlet with condensate oil and is connected,

Described device three comprises the coupled logical first grade desulfurizing alcohol separating tank (4) of one-level liquid membrane contactor (3), the coupled logical two-grade desulfurizing alcohol separating tank (7) of secondary liquid membrane contactor (6), three grades of coupled three grades of logical mercaptan removal separating tanks of liquid membrane contactor;

Described one-level liquid membrane contactor (3) top inlet exports with coalescent processed unit (43) side and is connected, described one-level liquid membrane contactor (3) side entrance is connected with two-grade desulfurizing alcohol separating tank (7) bottom end outlet by NaOH solution circulating pump (10), described first grade desulfurizing alcohol separating tank (4) bottom end outlet is connected with sulfurous gas separating unit (42) bottom entrance, the outlet of described first grade desulfurizing alcohol separating tank (4) top is connected with secondary liquid membrane contactor (6) top inlet, described secondary liquid membrane contactor (6) side entrance is connected with three grades of mercaptan removal separating tank bottom end outlet by NaOH solution circulating pump (10), the outlet of described two-grade desulfurizing alcohol separating tank (7) top is connected with three grades of liquid membrane contactor top inlet, described alkali lye gas stripping column (18) bottom end outlet, fresh alkali liquor pipe (32) is all connected with three grades of liquid membrane contactor side entrances, the outlet of described three grades of mercaptan removal separating tank tops is washed dealkalize unit (44) top inlet with condensate oil and is connected, or

Described one-level liquid membrane contactor (3) top inlet exports with coalescent processed unit (43) side and is connected, the outlet of described first grade desulfurizing alcohol separating tank (4) top is connected with secondary liquid membrane contactor (6) top inlet, described secondary liquid membrane contactor (6) is all connected with three grades of mercaptan removal separating tank bottom end outlet by NaOH solution circulating pump (10) with the side entrance of three grades of liquid membrane contactors, described first grade desulfurizing alcohol separating tank (4) is all connected with sulfurous gas separating unit (42) bottom entrance with the bottom end outlet of two-grade desulfurizing alcohol separating tank (7), the outlet of described two-grade desulfurizing alcohol separating tank (7) top is connected with three grades of liquid membrane contactor top inlet, described alkali lye gas stripping column (18) bottom end outlet, fresh alkali liquor pipe (32) is all connected with three grades of liquid membrane contactor side entrances, the outlet of described three grades of mercaptan removal separating tank tops is washed dealkalize unit (44) top inlet with condensate oil and is connected.

6. condensate oil mercaptan removal according to claim 2 and alkali liquid regeneration reclaim the device of disulphide, and it is characterized in that, described sulfurous gas separating unit (42) is device four or device five;

Described device four comprises alkali liquor oxidized tower (14), position, described alkali liquor oxidized tower (14) inner middle and lower part is provided with gas distributor one (15), the outlet of described alkali liquor oxidized tower (14) side to be exported with disulphide knockout tower (16) side by regeneration alkali liquor pipe (30) and is connected, described alkali liquor oxidized tower (14) side entrance, the position of gas distributor one (15) is communicated with non-purifying wind pipe (34), described alkali liquor oxidized tower (14) bottom entrance is connected with mercaptan removal processing unit (41) bottom end outlet, alkali lye interchanger (12) and catalyst injector (13) is disposed with between described mercaptan removal processing unit (41) and alkali liquor oxidized tower (14), upperly in described disulphide knockout tower (16) inside install disulphide coalescent pack (17), described disulphide knockout tower (16) bottom end outlet is connected with alkali lye gas stripping column (18) side entrance, described disulphide knockout tower (16) side outlet is connected with disulphide tank (24) top inlet, described alkali liquor oxidized tower (14), the outlet of disulphide knockout tower (16) top is all washed dealkalize tank (22) side entrance and is connected with tail gas, in described tail gas washing dealkalize tank (22) inside, upper/lower positions is provided with gas distributor three (23),

Described device five comprises alkali liquor oxidized knockout tower (45), described alkali liquor oxidized knockout tower (45) bottom entrance is connected with mercaptan removal processing unit (41) bottom end outlet, described alkali liquor oxidized knockout tower (45) inner route clapboard is separated into two regions, middle upper/lower positions in one region is provided with gas distributor one (15), upperly in another region install disulphide coalescent pack (17), alkali lye interchanger (12) and catalyst injector (13) is provided with successively between described alkali liquor oxidized knockout tower (45) and mercaptan removal processing unit (41), the outlet of described alkali liquor oxidized knockout tower (45) lower end is connected with alkali lye gas stripping column (18) side entrance, described alkali liquor oxidized knockout tower (45) side outlet is connected with disulphide tank (24) top inlet, the outlet of described alkali liquor oxidized knockout tower (45) top is washed dealkalize tank (22) side entrance with tail gas and is connected, in described tail gas washing dealkalize tank (22) inside, upper/lower positions is provided with gas distributor three (23).

7. condensate oil mercaptan removal according to claim 2 and alkali liquid regeneration reclaim the device of disulphide, it is characterized in that, described coalescent processed unit (43) comprises coalescent water trap (2), described coalescent water trap (2) top inlet is connected with condensate oil feed-pipe (25), described coalescent water trap (2) bottom end outlet is connected with oily(waste)water pipe (28), and described coalescent water trap (2) side is connected with condensate oil pipe connecting (26);

Described condensate oil washing dealkalize unit (44) is device six or device seven;

Described device six comprises coalescent dealkalize device (9), described coalescent dealkalize device (9) top inlet exports with the top of mercaptan removal processing unit (41) and is connected, described coalescent dealkalize device (9) bottom end outlet is connected with alkaline waste water pipe (39), and described coalescent dealkalize device (9) side outlet goes out device pipe (27) with condensate oil and is connected;

Described device seven comprises liquid film washing contactor (46), described liquid film washing contactor (46) top inlet exports with the top of mercaptan removal processing unit (41) and is connected, described liquid film washing contactor (46) is connected with washing separating tank (47), the outlet of described washing separating tank (47) lower end is washed contactor (46) side entrance by water washing cycles pump (49) and liquid film and is connected, and described washing separating tank (47) top is communicated with condensate oil and goes out device pipe (27).

8. condensate oil mercaptan removal according to claim 5 and alkali liquid regeneration reclaim the device of disulphide, it is characterized in that, described first grade desulfurizing alcohol separating tank (4) exit, top is provided with first grade desulfurizing alcohol separating tank condensate oil outlet damper (5), described two-grade desulfurizing alcohol separating tank (7) exit, top is provided with two-grade desulfurizing alcohol separating tank condensate oil outlet damper (8), and exit, described three grades of mercaptan removal separating tank tops is provided with three grades of mercaptan removal separating tank condensate oil outlet dampers.