CN204897650U - Chemistry pharmacy effluent disposal system - Google Patents
Chemistry pharmacy effluent disposal system Download PDFInfo
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- CN204897650U CN204897650U CN201520576927.XU CN201520576927U CN204897650U CN 204897650 U CN204897650 U CN 204897650U CN 201520576927 U CN201520576927 U CN 201520576927U CN 204897650 U CN204897650 U CN 204897650U
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- 239000002351 wastewater Substances 0.000 claims abstract description 170
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 109
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- 238000007254 oxidation reaction Methods 0.000 claims abstract description 16
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- 238000004065 wastewater treatment Methods 0.000 claims description 13
- 238000006460 hydrolysis reaction Methods 0.000 claims description 11
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- 238000000034 method Methods 0.000 description 15
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- 238000010521 absorption reaction Methods 0.000 description 4
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 239000010815 organic waste Substances 0.000 description 4
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 4
- 230000002829 reduced Effects 0.000 description 4
- 229960001701 Chloroform Drugs 0.000 description 3
- 230000037250 Clearance Effects 0.000 description 3
- CVTZKFWZDBJAHE-UHFFFAOYSA-N [N].N Chemical compound [N].N CVTZKFWZDBJAHE-UHFFFAOYSA-N 0.000 description 3
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- 239000002585 base Substances 0.000 description 3
- 230000015556 catabolic process Effects 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- HEDRZPFGACZZDS-UHFFFAOYSA-N chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 3
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- 239000006228 supernatant Substances 0.000 description 3
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- 238000005406 washing Methods 0.000 description 3
- KDSNLYIMUZNERS-UHFFFAOYSA-N Isobutylamine Chemical compound CC(C)CN KDSNLYIMUZNERS-UHFFFAOYSA-N 0.000 description 2
- LYGJENNIWJXYER-UHFFFAOYSA-N Nitromethane Chemical compound C[N+]([O-])=O LYGJENNIWJXYER-UHFFFAOYSA-N 0.000 description 2
- 231100000614 Poison Toxicity 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- GVXIVWJIJSNCJO-UHFFFAOYSA-L aluminum;calcium;sulfate Chemical compound [Al+3].[Ca+2].[O-]S([O-])(=O)=O GVXIVWJIJSNCJO-UHFFFAOYSA-L 0.000 description 2
- 238000004176 ammonification Methods 0.000 description 2
- 235000012970 cakes Nutrition 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 230000001112 coagulant Effects 0.000 description 2
- 230000000875 corresponding Effects 0.000 description 2
- 238000005189 flocculation Methods 0.000 description 2
- 230000016615 flocculation Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000006396 nitration reaction Methods 0.000 description 2
- 239000011368 organic material Substances 0.000 description 2
- 239000002957 persistent organic pollutant Substances 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 238000006479 redox reaction Methods 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 230000000452 restraining Effects 0.000 description 2
- 235000019600 saltiness Nutrition 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 239000002028 Biomass Substances 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K Iron(III) chloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- 230000036740 Metabolism Effects 0.000 description 1
- 235000015450 Tilia cordata Nutrition 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 229940035295 Ting Drugs 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000005804 alkylation reaction Methods 0.000 description 1
- 230000003851 biochemical process Effects 0.000 description 1
- 238000005842 biochemical reaction Methods 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 230000024881 catalytic activity Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000003640 drug residue Substances 0.000 description 1
- 229940079593 drugs Drugs 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000005658 halogenation reaction Methods 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
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- 239000004571 lime Substances 0.000 description 1
- 230000005389 magnetism Effects 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
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- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 239000000693 micelle Substances 0.000 description 1
- 230000000813 microbial Effects 0.000 description 1
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- 239000012452 mother liquor Substances 0.000 description 1
- 239000010413 mother solution Substances 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L na2so4 Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 230000001473 noxious Effects 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
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- 239000004576 sand Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
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- 239000007858 starting material Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
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- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- ZNRSXPDDVNZGEN-UHFFFAOYSA-K trisodium;chloride;sulfate Chemical compound [Na+].[Na+].[Na+].[Cl-].[O-]S([O-])(=O)=O ZNRSXPDDVNZGEN-UHFFFAOYSA-K 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Abstract
The utility model discloses a processing system is synthesized to the chemistry pharmacy waste water, its characterized in that: superelevation concentration wastewater collection cell -out mouth links to each other with the MVR evaporimeter, evaporates water and gets into evaporation water collecting pit, and evaporation water collecting pit links to each other with comprehensive waste water equalizing basin with the buffer pool, the front portion in high concentration wastewater collection pond is equipped with the oil removal district, and the delivery port in high concentration wastewater collection pond links to each other with first high enriched water sedimentation pond, and the waste water in first high enriched water sedimentation pond gets into the buffer pool, buffer pool and multidimension electricity catalytic converter link to each other, and multidimension electricity catalytic converter's delivery port links to each other with interior electrolysis trough, and the delivery port of interior electrolysis trough links to each other with the catalytic oxidation groove, and the delivery port in catalytic oxidation groove links to each other with the pH regulating pondage, and the delivery port of pH regulating pondage links to each other with second high enriched water sedimentation pond, and the export in the high enriched water sedimentation pond of second links to each other with the transfer pond, and the transfer pond links to each other with the combined governing pond, low concentration wastewater collection pond and sedimentation tank link to each other, and the oil removal sedimentation tank links to each other with the combined governing pond. And the physiochemical property of the waste water is improved.
Description
Technical field
The utility model relates to a kind of method of wastewater treatment, particularly a kind of chemical pharmaceutical factory Waste Water Treatment.
Background technology
The waste water of chemical pharmaceutical factory mainly comes from medical intermediate production waste water, equipment washing waste water, the Cleaning Wastewater of facility floor, sanitary sewage, and wherein sanitary sewage is mainly derived from again the draining at the places such as plant area dining room, lavatory, bath room.
Medical intermediate production waste water main source has:
1. processing wastewater, as various crystalline mother solution, phase inversion mother liquor, absorption raffinate etc.;
2. flushing waste water, comprises the washing waste water etc. of the washing water of the equipment such as reactor, filter, support of the catalyst, resin and parts and ground, apparatus;
3. reclaim raffinate, comprise solvent recuperation raffinate, byproduct reclaims raffinate etc.;
4. supporting process waste water, as sealing water, overflows water etc.
The feature of medical intermediate production waste water roughly can be summarized as follows:
1. the pollutent of waste water not only has Conventional pollution (as COD, SS, ammonia nitrogen etc.), also has characteristic contamination (as trichloromethane, tetrahydrofuran (THF), acetonitrile etc.); The pollutant load of waste water is high, and the COD concentration of some waste water is up to 300000 ~ 400000mg/L.
2. waste water comprises unreacted starting material, solvent, with a large amount of compound, and compound different with the difference of chemical reaction (such as: nitrated, ammonification, halogenation, sulfonation, alkylation reaction).Chemosynthesis waste water and biological treatment system are incompatible, because in biochemical treatment system, too high or toxicity is too large to the concentration of unit volume biomass for compound, therefore generally needs to carry out Chemical Pretreatment to chemosynthesis waste water before biological treatment.
3. waste component is complicated, be difficult to degrade containing microorganism and even microorganism had to the material of high inhibition effect, organic or inorganic salt, midbody product, residual solvent, drug residue and the degradation production etc. that add as reaction process have certain density existence in waste water, can microbial growth be suppressed when low dose, make biochemical system start domestication and extend, reduce anaerobic gas generation amount and biochemical treatment efficiency.
4. because waste water contains drug component, have bio-toxicity, the biodegradability of waste water is poor.
5. the pH value change of waste water is frequent, and fluctuation range is large; Waste water ph or in acid, or in alkalescence.
6. effluent part SO42-, Cl-concentration is higher, such as: SO42-and the Cl-concentration in waste water 3 is up to 40000mg/L, and high salinity has a certain impact to biochemical reaction efficiency.
7. the nutrition source deficiency (being mainly C, N, P out of proportion) of waste water.
8. drainage point is many, effluent part intermittently discharged, acid-basicity and temperature variation are comparatively large, needs larger collection setting device.
In sum, chemical pharmacy terminal waste water belongs to water quality complexity, unmanageable organic waste water, wastewater treatment is mainly main process route based on the biochemical treatment of relatively economical, meanwhile need take the pre-treatment measure of some necessity for waste water characteristic, to guarantee Biochemical Treatment.
Utility model content
For existing problem, the purpose of this utility model is the total system providing a kind of chemical pharmacy waste water, the waste water energy qualified discharge after this treatment system process.
To achieve these goals, the technical solution of the utility model is: a kind of chemical pharmacy Waste Water Treatment, comprise pretreatment system and biochemical treatment system, it is characterized in that: described pretreatment system: comprise low concentration wastewater collecting tank, high-concentration waste water collecting tank and ultrahigh concentration wastewater collection pond;
The outlet of described ultrahigh concentration wastewater collection pond is connected with MVR vaporizer, and vaporize water enters vaporize water collecting tank, and described vaporize water collecting tank is connected with comprehensive wastewater equalizing tank with Buffer Pool;
The front portion of described high-concentration waste water collecting tank is provided with oil removal district, and the water outlet of high-concentration waste water collecting tank is connected with the first high dense water precipitation pond, and the waste water in described first high dense water precipitation pond enters described Buffer Pool;
Described Buffer Pool is connected with multi-dimensional electro-catalytic reactor, the water outlet of described multi-dimensional electro-catalytic reactor is connected with Inner electrolysis groove, the water outlet of Inner electrolysis groove is connected with catalyzed oxidation groove, water outlet and the pH of described catalyzed oxidation groove adjust pond and are connected, the water outlet that described pH adjusts pond is connected with the second high dense water precipitation pond, the outlet in described second high dense water precipitation pond is connected with transfer pond, and described transfer pond is connected with comprehensive adjustment pond;
Described low concentration wastewater collecting tank is connected with settling tank, and described oil partiting precipitation pool is connected with comprehensive adjustment pond;
Described biochemical treatment system comprises the hydrolysis acidification pool be connected successively, micro-oxygen pond, desulfurization settling tank, UASB anaerobic reation pool, anaerobic precipitation pond, anoxic pond, Aerobic Pond, second pond, ABFT pond, final deposition pool and clean water basin, wherein hydrolysis acidification pool is connected with comprehensive adjustment pond, and the mixed solution in Aerobic Pond and the partial sludge in second pond are back to anoxic pond.
Grille well is provided with before described low concentration wastewater collecting tank.
Adopt such scheme, plant area's terminal waste water is divided three classes by we, and one is that ultrahigh concentration waste water COD is greater than 80,000 mg/L (average COD: 80,000 ~ 400,000 mg/L); Two is high-concentration waste water (2000mg/L≤COD≤80,000 mg/L); Three is that low concentration wastewater COD is less than or equal to 2,000 mg/L (the average 2000mg/L of COD).
Ultrahigh concentration waste water is mainly factory effluent and has high COD content, containing organic solvent, and saltiness (on average about 13%) or poisonous, the feature such as biochemical is poor.Enter ultrahigh concentration wastewater collection pond.
Also be factory effluent in high-concentration waste water, mainly containing organic solvent (methyl alcohol, acetone, trichloromethane, methylene dichloride, tetrahydrofuran (THF), isobutylamine, Nitromethane 99Min., DMF, acetonitrile etc.), medicine intermediate and about 2% ~ 8% salinity (sodium-chlor, sodium sulfate); PH value 3 ~ 9.Enter high-concentration waste water collecting tank.
Low concentration wastewater water quality situation: comprise equipment and terrace wash-down water, experimental analysis detects waste water, sanitary wastewater etc.Low concentration wastewater collecting tank is entered through grille well.
Ultrahigh concentration waste water is after MVR evaporation, if vaporize water COD > 30000mg/L or B/C < 0.25, vaporize water enters pretreatment of High Concentration Wastewater system (i.e. multi-dimensional electro-catalytic, Inner electrolysis, catalytic oxidizing equipment).If vaporize water COD≤30000mg/L or B/C >=0.25, waste water can directly enter comprehensive wastewater equalizing tank, enters biochemical treatment system.
High-concentration waste water enters high-concentration waste water collecting tank by plant area, first after oil removal district, removal oil slick.By aeration agitation, regulate the waste water quality water yield, then enter to flow to the first high dense water precipitation pond by lift pump, add coagulating agent and flocculation agent entering between the first high density settling tank.At the first high dense water precipitation pond precipitation slag thing, after reducing concentration of suspension, enter Buffer Pool, enter multi-dimensional electro-catalytic reactive system through lift pump.
Add hydrochloric acid at Buffer Pool lift pump rising pipe, by line mixer, pH value is controlled in acid (pH3 ~ 4).In electrocatalytic reaction system, waste water is under multi-dimensional electric field and pole plate, the effect of granule electrode catalytic activity, and the organism generation electrochemical oxidation-reduction reaction of difficult degradation, COD is degraded.Waste water enters Inner electrolysis groove.
Organism in waste water Inner electrolysis groove waste water is partially removed, and COD is reduced, and the biodegradability of waste water is improved.
The water outlet of Inner electrolysis groove is to catalyzed oxidation groove, catalytic oxidation belongs to high-level oxidation technology, under certain pH value, temperature condition and catalyst action, and the organism of degraded multiple types, thus alleviate its restraining effect to microorganism, for the effective degradable organic pollutant of biochemical system creates conditions.PH value is acid, and temperature is generally 70-80 DEG C.
The water outlet of catalyzed oxidation groove flows into pH and adjusts pond, through adding mixed in hydrochloric acid, pH value is controlled, 8 ~ 8.5, then to add PAC, PAM, due to the calcium sulfate containing generation in waste water, and the aluminum ion absorption calcium sulfate in PAC, and then generate aluminium calcium sulfate throw out.
PH adjusts pond water outlet and flows automatically to the second high dense water precipitation pond, and vertical sedimentation tank selected by this settling tank, and supernatant water flows automatically to transfer pond, more all amount enters comprehensive adjustment pond.Then biochemical treatment system is entered, final qualified discharge.
Also comprise accident pool, described accident pool is connected with ultrahigh concentration wastewater collection pond with low concentration wastewater collecting tank, high-concentration waste water collecting tank respectively.
After accident pool has an accident, factory effluent collects accident pool temporarily, after the measurement of COD, then enter corresponding ultrahigh concentration wastewater collection pond and high-concentration waste water collecting tank respectively.
In such scheme: also comprise materialized mud pond, the mud in described first high dense water precipitation pond and the second high dense water precipitation pond enters materialized mud pond, then obtain mud cake through Chamber Type Diaphragm Filter Press press filtration, the filtrate outlet of described Chamber Type Diaphragm Filter Press press filtration is connected to high-concentration waste water collecting tank.
In such scheme: be equipped with aerating apparatus in described ultrahigh concentration wastewater collection pond and high-concentration waste water collecting tank.Aerating apparatus is set and carries out aeration, make not produce precipitation, even water quality and the water yield, biodegradability of increasing water quality.
In such scheme: also comprise biochemical sludge pond, the mud of the pretreated settling tank of described low concentration wastewater enters described biochemical sludge pond; In biochemical system, the mud of described hydrolysis acidification pool, desulfurization settling tank, UASB anaerobic reation pool, anaerobic precipitation pond, second pond, ABFT pond, final deposition pool enters biochemical sludge pond.
In such scheme, the bottom in described comprehensive adjustment pond is provided with aerating apparatus.Intermittent aeration, plays regulating water quality, improves the effect of biochemical.
The beneficial effects of the utility model are: the utility model technical process is simple, construction cost is low, Technology is advanced, after pre-treatment, the clearance of COD can reach 60%, the clearance of sulfate radical can reach 50%, improves the ratio of BOD/COD, namely improves the biodegradability of waste water, achieve the pretreated object of high concentration hard-degraded organic waste water, finally make discharged wastewater met the national standard through biochemical treatment.
Accompanying drawing explanation
Fig. 1 is the process flow sheet of the utility model pretreatment system;
Fig. 2 is the process flow sheet of biochemical stage.
Embodiment
Below in conjunction with the drawings and specific embodiments, the utility model is further described:
Embodiment 1
One, pretreatment system,
Low concentration wastewater collecting tank 1, high-concentration waste water collecting tank 2, ultrahigh concentration wastewater collection pond 3 and accident pool 4, accident pool 4 is connected with ultrahigh concentration wastewater collection pond 3 with low concentration wastewater collecting tank 1, high-concentration waste water collecting tank 2 respectively.
Plant area's terminal waste water is divided three classes by we, and one is that ultrahigh concentration waste water COD is greater than 80,000 mg/L (COD:8 ten thousand ~ 400,000 mg/L); Two is high-concentration waste water (2000mg/L≤COD≤80,000 mg/L); Three is that low concentration wastewater COD is less than 2,000 mg/L (the average 2000mg/L of COD).
Ultrahigh concentration waste water and high-concentration waste water are from factory effluent, and ultrahigh concentration waste water is mainly factory effluent and has high COD content, containing organic solvent, and saltiness (on average about 13%) or poisonous, the feature such as biochemical is poor.Enter ultrahigh concentration wastewater collection pond 3.
Also be factory effluent in high-concentration waste water, mainly containing organic solvent (methyl alcohol, acetone, trichloromethane, methylene dichloride, tetrahydrofuran (THF), isobutylamine, Nitromethane 99Min., DMF, acetonitrile etc.), medicine intermediate and about 2% ~ 8% salinity (sodium-chlor about 3.5%, sodium sulfate about 2%); PH value 3 ~ 9.Enter high-concentration waste water collecting tank 2.
Low concentration wastewater water quality situation: comprise equipment and terrace wash-down water, experimental analysis detects waste water, sanitary wastewater etc.Enter low concentration wastewater collecting tank 1.
After having an accident, factory effluent collects accident pool 4 temporarily, after the measurement of COD, then enter corresponding ultrahigh concentration wastewater collection pond 3 and high-concentration waste water collecting tank 2 or low concentration wastewater collecting tank 1 respectively.
Ultrahigh concentration wastewater collection pond 3 is equalizing tank again, bottom it, be provided with aerating apparatus, carries out aeration by aerating apparatus, makes not produce precipitation, even water quality and the water yield, biodegradability of increasing water quality.Then ultrahigh concentration waste water enters MVR vaporizer 5, MVR vaporizer is prior art, does not repeat at this.Vaporize water collecting tank 6 is entered from MVR vaporizer 5 waste water out, ultrahigh concentration waste water is after MVR evaporation, if vaporize water COD > 30000mg/L or B/C < 0.25, vaporize water enters the Buffer Pool 7 of pretreatment of High Concentration Wastewater system.If vaporize water COD≤30000mg/L or B/C >=0.25, waste water can directly enter comprehensive wastewater equalizing tank 15, enters biochemical treatment system.Vaporize water collecting tank 6 is connected with comprehensive wastewater equalizing tank 15 with Buffer Pool 7.Ultrahigh concentration waste water obviously can reduce the content of COD after MVR evaporation.
The front portion of high-concentration waste water collecting tank 2 is provided with oil removal district, and this is prior art, oil removal district not shown in FIG..Bottom in high-concentration waste water collecting tank 2 is also provided with aerating apparatus, this is prior art, do not repeat at this, the water outlet of high-concentration waste water collecting tank 2 is connected with the first high dense water precipitation pond 8, the waste water in the first high dense water precipitation pond 8 enters described Buffer Pool 7, high-concentration waste water is removed after oil slick through oil removal district 2a and is entered high-concentration waste water collecting tank 2, through aeration agitation, regulate the waste water water yield, then the first high dense water precipitation pond 8 is pumped into by lift pump, at rising pipe dosing coagulant and the flocculation agent of lift pump, PAM and PAC.Waste water and the coagulating agent added first through coagulating, then enter the first high dense water precipitation pond 8, precipitation slag thing, reduce concentration of suspension, then enter Buffer Pool 7, pump into multi-dimensional electro-catalytic reactor 9 through lift pump.Hydrochloric acid is added at the rising pipe of this lift pump, pass through line mixer, make pH value control at acid (pH3-4), waste water in multi-dimensional electro-catalytic reactor 9, the organism generation electrochemical oxidation-reduction reaction of difficult degradation, COD is degraded, waste water enters Inner electrolysis groove 10, is provided with the recycle system, aerating apparatus in Inner electrolysis groove 10, this is prior art, does not repeat at this.In Inner electrolysis groove 10, the organism in waste water is partially removed, and COD is reduced, and the biodegradability of waste water is improved.The water outlet of Inner electrolysis groove is to catalyzed oxidation groove 11, catalytic oxidation belongs to high-level oxidation technology, at certain pH value (pH12, add lime adjust), temperature (room temperature) condition and catalyzer (molysite) effect under, the organism of degraded multiple types, thus alleviate its restraining effect to microorganism, for the effective degradable organic pollutant of biochemical system creates conditions.
Catalyzed oxidation groove 11 water outlet flows into pH and adjusts pond 12, through adding mixed in hydrochloric acid, pH value is controlled, 8 ~ 8.5, then to add PAC, PAM, due to the calcium sulfate containing generation in waste water, and the aluminum ion absorption calcium sulfate in PAC, and then generate aluminium calcium sulfate throw out.
It is vertical sedimentation tank that pH adjustment pond 11 water outlet flows automatically to the second high dense water precipitation pond 13, high dense water precipitation pond 13, second, and supernatant water flows automatically to transfer pond 14, more all amount enters comprehensive adjustment pond 15.
Low concentration wastewater COD concentration is lower, containing suspended substance and petroleum hydrocarbons.
First enter grille well 31, after grid debris retaining thing, enter low concentration wastewater collecting tank 1 namely equalizing tank, adopt aeration agitation, after regulating water quality, the water yield, adopt lifting to pump into settling tank 18.Waste water is through precipitation sand grains and suspended substance, after removal oil slick, enter comprehensive adjustment pond 15.
The mud in the first high dense water precipitation pond 8 and the second high dense water precipitation pond 13 pumps into materialized mud pond 16, and then obtain mud cake through Chamber Type Diaphragm Filter Press 17 press filtration, the filtrate outlet of described Chamber Type Diaphragm Filter Press 17 press filtration is connected to high-concentration waste water collecting tank 2.
Table 1 is each step effect data of pre-treatment.
Table 1
As can be seen from the table after pre-treatment, COD is significantly reduced, and the sulfate radical clearance of high-concentration waste water can reach 5%, and biodegradability is improved.
Application multi-dimensional electro-catalytic+Inner electrolysis+catalytic oxidation, the removal ability of its COD is relatively low, but can improve the ratio of BOD/COD, namely improves the biodegradability of waste water, achieves the pretreated object of high concentration hard-degraded organic waste water.Organic waste water effect for pre-treating difficultly-degradable and containing hazardous and noxious substances is better, as used water difficult to degradate such as heterocyclic.
Two, the biochemical treatment stage
After pre-treatment, all kinds of waste water introduces comprehensive adjustment pond 15 (also claiming main regulation pond), because some waste water salt content is higher, in all kinds of waste water combined process in main regulation pond, salinity and some bio-toxicity materials are diluted, and are conducive to the efficiency improving subsequent biochemical process.For strengthening main regulation pond is to the homogenizing of water quality, the bottom in comprehensive adjustment pond 15 arranges aerating apparatus preaeration blower fan, to main regulation pond waste water intermittent aeration.The on-line checkingi such as liquidometer, pH value can be established in main regulation pond, all kinds of waste water main regulation pond nature in and, when pH runaways (6 ~ 9), pH on-line computing model is reported to the police, and automatically drops into hydrochloric acid (or alkali lye) adjust ph by volume pump.In order to ensure the phosphorus element that microorganism growth is required, being provided with and adjusting medicine groove preparation phosphorus containing agent to be added to comprehensive adjustment pond 15.
Main body biochemical treatment unit is followed successively by hydrolysis acidification pool 19, micro-oxygen pond 20, desulfurization settling tank 21, UASB anaerobic reation pool 22, anaerobic precipitation pond 23, anoxic pond 24, Aerobic Pond 25, second pond 26, ABFT pond 27, final deposition pool 28 and clean water basin 29.
The waste water in comprehensive adjustment pond 15 enters hydrolysis acidification pool 19, organic acidication is mainly there is at hydrolysis acidification pool, simultaneously due to the metabolism of hydrolysed ferment bacterium, larger molecular organics is made to be degraded to small organic molecule, improve the biodegradability of water outlet, the COD of sewage obtains removal to a certain extent simultaneously, and under anaerobic, most sulfate radical is reduced into H by sulphate reducing bacteria (SRB) in acidication
2s.
The waste water of hydrolysis acidification pool 19 enters micro-oxygen pond 20, due to the H generated
2s major part is dissolved in water, is oxidized into simple substance S after entering micro-oxygen pond 10, then to add after coagulating agent PAC precipitate and separate in desulfurization settling tank 21.
The water outlet of desulfurization settling tank 21 to UASB anaerobic reation pool 22, removes in waste water most of organism by the anaerobic treatment of high loading by lift pump.UASB anaerobic reation pool 22 is stirred by pulse water distribution, waterpower internal recycle and promotes fully mixing of sewage and mud, and is provided with multiple thief hole and carrys out the indexs such as sampling analysis sludge concentration, VFA, pH value (basicity) to the operation of control UASB anaerobic reaction.Biogas enters water-sealed tank after being collected by gas skirt, then discharges (also can be back to boiler).This is prior art, does not repeat at this.
UASB anaerobic reation pool 22 water outlet is to anaerobic precipitation pond 23.
In anaerobic precipitation pond 23, waste water is through precipitation, and clear water enters A/O system.
A/O system establishes anoxic pond 24, Aerobic Pond 25.Anoxic pond 24 water outlet flows automatically to Aerobic Pond 25.In A/O unit, the mixed solution in Aerobic Pond 25 is partly refluxed to anoxic pond 24, and this circulation is called internal recycle.NO in backflow mixed liquor
3-N utilizes the carbonaceous organic material in raw waste water in anoxic pond 24, to carry out anti-nitration reaction as carbon source material under the effect of denitrifying bacteria.Anoxic pond 24 water outlet enters Aerobic Pond 25, and the nitrification of the oxidation of carbonaceous organic material, the ammonification of itrogenous organic substance and ammonia nitrogen occurs in Aerobic Pond 25.The mixed solution of Aerobic Pond 25 flows automatically to second pond 26, and the dense sludge part produced after mud-water separation at second pond 26 is back to anoxic pond 24, and this circulation is called outer circulation.
The O pond of the present invention in A/O system adds powdered carbon (being also PACT flow process), synergy.Namely in Aerobic Pond 25, add Powdered Activated Carbon, the add-on of Powdered Activated Carbon is 50-100g/L water, similar to active sludge performance, and PACT flow process is also that suspension, collagenous and soluble solid are converted to can the biological micelle of powdered activated carbon of sedimentation.PACT has had many advantages compared with traditional active sludge, is summarized as follows:
1), in PACT system, MLSS will be significantly increased, reduce the value of F/M, also reduce SVI (sludge volume index), the synergy of gac and active sludge can make PACT have than independent activated carbon adsorption (no matter being powdery or granular) or the better treatment effect of activated sludge process, synergy also makes process more quick, makes that PACT system specific activity mud is timid can have larger sludge loading.
2), the high absorption capacity of gac is cushioned the impact that toxicant and load impact bring microorganism.Than the traditional sludge method ecosystem, PACT can provide more stable environment to microorganism, and the pollution substance of more difficult decomposition simultaneously also can be kept to process with quite long hydraulic detention time in systems in which.
3), the existence of powdered carbon makes aerobic environment be improved.This is because gac has great magnetism to gaseous oxygen, and makes in PACT system, and oxygen utilization rate is improved.
4), PACT technique, the refractory organic in the adsorbable waste water of dust active carbon, can adsorpting characteristic pollution factor: methylene dichloride, therefore adopts PACT technique can make methylene dichloride qualified discharge.
The backflow of second pond 26 mud and Aerobic Pond 25 mixed solution ensure that anoxic pond 24 has the denitrifying bacteria of sufficient amount, and takes the nitric nitrogen of nitrated for Aerobic Pond 25 generation to anoxic pond 24.Anaerobic precipitation pond water out enters anoxic pond and mixes with the mixed solution that Aerobic Pond 25 refluxes, for anoxic pond 24 denitrification provides sufficient carbon source.Anoxic pond 24 also makes organism obtain the removal of respective degrees while denitrogenation, and this pond can make to enter the NO in this pond waste water
3the complete denitrification of-N, its water outlet flows automatically to downstream Aerobic Pond, and the organism in waste water is degraded further, and the ammonia nitrogen in waste water changes nitric nitrogen into because of nitration reaction, Aerobic Pond 25 can make can be nitrated in waste water TN completely nitrated.In Aerobic Pond 25, add Powdered Activated Carbon, the amount adding Powdered Activated Carbon in Aerobic Pond is 50-100g/L.
A/O unit establishes pH value, dissolved oxygen instrument and sludge concentration meter respectively, by dissolved oxygen, the inside and outside quantity of reflux of sludge concentration signal control and adjustment wind supply quantity.
Second pond 26 is vertical sedimentation tank, and after precipitation, supernatant liquor is pooled to the overflow groove of pond periphery, then from flowing out pond.Base sludge external reflux pump is transported to anoxic pond 24 import, and excess sludge is discharged to UASB anaerobic reation pool or biochemical sludge pond 30.
Second pond 26 water outlet enters ABFT pond 27 (aerated biological fludized bed), and ABFT pond 27 water outlet enters final deposition pool 28, clean water basin 29, through monitoring discharge.
Biochemical treatment flow process produces mud point to be had: the point such as low concentration wastewater pre-treatment settling tank 18 (belong to physics mud, belong to biochemical sludge), hydrolysis acidification pool 19, desulfurization settling tank 21, UASB anaerobic reation pool 22, anaerobic precipitation pond 23, second pond 26, ABFT pond 27, final deposition pool 28.More than producing mud point adopts pump spoil disposal to biochemical sludge pond 30 respectively.
In biochemical sludge pond 30, mud forms upper clear supernate and base sludge by gravity compressed, upper clear supernate guides to high-concentration waste water collecting tank 2 or comprehensive adjustment pond 15 with pipeline after peripheral overflow groove collects, and base sludge sludge delivery pump delivers to Chamber Type Diaphragm Filter Press 17 mud inlet end.The press filtration also rear dry filter cake (comprising the grid slag that mechanical grille produces) produced of squeezing is transferred to the saving of dewatered sludge pond, and as ready sets off and disposes, and Chamber Type Diaphragm Filter Press filtrate flows automatically to high-concentration waste water collecting tank 2 or comprehensive adjustment pond 15.
Table 2 is each stage effectiveness data sheet of biochemical treatment
Table 2
Illustrate: 1), intake and design by maximum concentration; 2), ultrahigh concentration vaporize water fixes tentatively COD30000mg/L, by directly entering comprehensive adjustment pond accounting (if COD exceedes set(ting)value 30000mg/L, being then introduced into high-concentration waste water physico-chemical pretreatment system).
Continually through continuous two months detect discharge outlet waste water, water outlet can stably reaching standard discharge.The process of this system to pharmacy waste water is effective system.
Table 3 is for receiving sewage drainage standard.
Table 3
The utility model is not limited to above-described embodiment, should be appreciated that those of ordinary skill in the art just can make many modifications and variations according to design of the present utility model without the need to creative work.Therefore, all technician in the art according to design of the present utility model on the basis of existing technology by the available technical scheme of logical analysis, reasoning, or a limited experiment, all should by the determined protection domain of claims.
Claims (8)
1. a chemical pharmacy Waste Water Treatment, comprises pretreatment system and biochemical treatment system, it is characterized in that: described pretreatment system: comprise low concentration wastewater collecting tank, high-concentration waste water collecting tank and ultrahigh concentration wastewater collection pond;
The outlet of described ultrahigh concentration wastewater collection pond is connected with MVR vaporizer, and vaporize water enters vaporize water collecting tank, and described vaporize water collecting tank is connected with comprehensive wastewater equalizing tank with Buffer Pool;
The front portion of described high-concentration waste water collecting tank is provided with oil removal district, and the water outlet of high-concentration waste water collecting tank is connected with the first high dense water precipitation pond, and the waste water in described first high dense water precipitation pond enters described Buffer Pool;
Described Buffer Pool is connected with multi-dimensional electro-catalytic reactor, the water outlet of described multi-dimensional electro-catalytic reactor is connected with Inner electrolysis groove, the water outlet of Inner electrolysis groove is connected with catalyzed oxidation groove, water outlet and the pH of described catalyzed oxidation groove adjust pond and are connected, the water outlet that described pH adjusts pond is connected with the second high dense water precipitation pond, the outlet in described second high dense water precipitation pond is connected with transfer pond, and described transfer pond is connected with comprehensive adjustment pond;
Described low concentration wastewater collecting tank is connected with settling tank, and described oil partiting precipitation pool is connected with comprehensive adjustment pond;
Described biochemical treatment system comprises the hydrolysis acidification pool be connected successively, micro-oxygen pond, desulfurization settling tank, UASB anaerobic reation pool, anaerobic precipitation pond, anoxic pond, Aerobic Pond, second pond, ABFT pond, final deposition pool and clean water basin, wherein hydrolysis acidification pool is connected with comprehensive adjustment pond, and the mixed solution in Aerobic Pond and the partial sludge in second pond are back to anoxic pond.
2. chemical pharmacy Waste Water Treatment according to claim 1, it is characterized in that: also comprise materialized mud pond, the mud in described first high dense water precipitation pond and the second high dense water precipitation pond enters materialized mud pond, then through Chamber Type Diaphragm Filter Press press filtration, the filtrate outlet of described Chamber Type Diaphragm Filter Press press filtration is connected to high-concentration waste water collecting tank.
3. chemical pharmacy Waste Water Treatment according to claim 1, is characterized in that: be equipped with aerating apparatus in described ultrahigh concentration wastewater collection pond and high-concentration waste water collecting tank.
4. chemical pharmacy Waste Water Treatment according to claim 1, is characterized in that: described second high dense water precipitation pond is vertical sedimentation tank.
5. chemical pharmacy Waste Water Treatment according to claim 1, it is characterized in that: also comprise accident pool, described accident pool is connected with ultrahigh concentration wastewater collection pond with low concentration wastewater collecting tank, high-concentration waste water collecting tank respectively.
6. chemical pharmacy Waste Water Treatment according to any one of claim 1-5, is characterized in that: be provided with grille well before described low concentration wastewater collecting tank.
7. chemical pharmacy Waste Water Treatment according to claim 1, its spy is characterised in that: also comprise biochemical sludge pond, and the mud of the pretreated settling tank of described low concentration wastewater enters described biochemical sludge pond; In biochemical system, the mud of described hydrolysis acidification pool, desulfurization settling tank, UASB anaerobic reation pool, anaerobic precipitation pond, second pond, ABFT pond, final deposition pool enters biochemical sludge pond.
8. chemical pharmacy Waste Water Treatment according to claim 1, is characterized in that: the bottom in described comprehensive adjustment pond is provided with aerating apparatus.
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105060627A (en) * | 2015-08-04 | 2015-11-18 | 重庆杰润科技有限公司 | Chemical pharmacy wastewater comprehensive treatment system |
| CN106145404A (en) * | 2016-08-11 | 2016-11-23 | 陕西昕宇表面工程有限公司 | A kind of Industrial Wastewater Treatment recovery system and process technique |
| CN108658376A (en) * | 2018-05-21 | 2018-10-16 | 湖北创力药业有限公司 | A kind of sewage disposal system and its processing method for pharmaceuticals industry waste water |
| CN110526517A (en) * | 2019-09-20 | 2019-12-03 | 重庆杰润科技有限公司 | A kind of medical intermediate production waste water treatment process |
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| CN112499842A (en) * | 2021-02-05 | 2021-03-16 | 华夏碧水环保科技有限公司北京分公司 | Pretreatment system and pretreatment method for chemical synthesis pharmaceutical high-salt high-concentration wastewater |
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2015
- 2015-08-04 CN CN201520576927.XU patent/CN204897650U/en active Active
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105060627A (en) * | 2015-08-04 | 2015-11-18 | 重庆杰润科技有限公司 | Chemical pharmacy wastewater comprehensive treatment system |
| CN106145404A (en) * | 2016-08-11 | 2016-11-23 | 陕西昕宇表面工程有限公司 | A kind of Industrial Wastewater Treatment recovery system and process technique |
| CN108658376A (en) * | 2018-05-21 | 2018-10-16 | 湖北创力药业有限公司 | A kind of sewage disposal system and its processing method for pharmaceuticals industry waste water |
| CN110526517A (en) * | 2019-09-20 | 2019-12-03 | 重庆杰润科技有限公司 | A kind of medical intermediate production waste water treatment process |
| CN111453880A (en) * | 2020-04-09 | 2020-07-28 | 安徽浩悦环境科技有限责任公司 | Method for removing waste liquid containing various heavy metals by combined precipitation method |
| CN112499842A (en) * | 2021-02-05 | 2021-03-16 | 华夏碧水环保科技有限公司北京分公司 | Pretreatment system and pretreatment method for chemical synthesis pharmaceutical high-salt high-concentration wastewater |
| CN112499842B (en) * | 2021-02-05 | 2021-05-07 | 华夏碧水环保科技有限公司北京分公司 | Pretreatment system and pretreatment method for chemical synthesis pharmaceutical high-salt high-concentration wastewater |
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