CN204891590U - Energy -efficient deNOx systems of domestic waste power plant - Google Patents

Energy -efficient deNOx systems of domestic waste power plant Download PDF

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CN204891590U
CN204891590U CN201520665629.8U CN201520665629U CN204891590U CN 204891590 U CN204891590 U CN 204891590U CN 201520665629 U CN201520665629 U CN 201520665629U CN 204891590 U CN204891590 U CN 204891590U
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伍长青
陈竹
李军
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Nantong Tianlan Environmental Protection and Energy Equipment Co Ltd
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Abstract

一种生活垃圾电厂高效节能的脱硝系统,涉及生活垃圾脱硝系统的设计技术领域。本实用新型包括炉排炉、余热锅炉、脱酸反应塔、布袋除尘器、灰仓、低温SCR反应器、引风机、烟囱、SNCR喷枪、第一空压机、软水箱、SNCR氨水缓冲罐、第一氨水输送泵、氨水储存罐、第二氨水输送泵、SCR氨水缓冲罐、氨蒸发器、混合器、第二空压机;本实用新型采用“SNCR+低温SCR”组合脱销,节约投资成本,节省了电厂的热能,延长了催化剂的使用寿命,具有一定的经济性;满足排放标准,具有高效性。

A high-efficiency and energy-saving denitrification system for a domestic waste power plant relates to the technical field of design of the domestic waste denitrification system. The utility model includes grate furnace, waste heat boiler, deacidification reaction tower, bag dust collector, ash bin, low temperature SCR reactor, induced draft fan, chimney, SNCR spray gun, first air compressor, soft water tank, SNCR ammonia water buffer tank, The first ammonia water delivery pump, the ammonia water storage tank, the second ammonia water delivery pump, the SCR ammonia water buffer tank, the ammonia evaporator, the mixer, and the second air compressor; the utility model adopts the "SNCR+low temperature SCR" combination out of stock, saving investment costs, It saves the heat energy of the power plant, prolongs the service life of the catalyst, and has certain economic efficiency; it meets the emission standard and has high efficiency.

Description

一种生活垃圾电厂高效节能的脱硝系统A high-efficiency and energy-saving denitrification system for domestic waste power plants

技术领域 technical field

本实用新型涉及生活垃圾脱硝系统的设计技术领域。 The utility model relates to the technical field of design of a domestic garbage denitrification system.

背景技术 Background technique

我国新建的垃圾焚烧发电厂数量逐年增加,焚烧法在生活垃圾处理方式中所占的比例也逐年上升。生活垃圾焚烧厂同燃煤发电厂一样,在焚烧过程中会产生大量含有颗粒物、HCl、SO2、NOX、二噁英等大气污染物。目前,生活垃圾电厂烟气处理方式是“半干法/干法脱酸+布袋除尘器”,有效控制了烟尘、颗粒物和易溶性酸性气体。但烟气中的NOX不易溶于水,脱酸反应塔无法有效去除。国内已建成运营的生活垃圾焚烧厂烟气排放均执行《生活垃圾焚烧污染控制标准》(GB18485-2014),NOX排放限值为250mg/Nm3,因此生活垃圾焚烧电厂必须实施切实可行的NOX控制措施。 The number of new waste incineration power plants in my country is increasing year by year, and the proportion of incineration in domestic waste disposal is also increasing year by year. Domestic waste incineration plants, like coal-fired power plants, will produce a large amount of air pollutants such as particulate matter, HCl, SO2, NOX, and dioxins during the incineration process. At present, the flue gas treatment method of domestic waste power plants is "semi-dry method/dry method deacidification + bag filter", which effectively controls smoke dust, particulate matter and soluble acid gas. However, NOX in the flue gas is not easily soluble in water, and the deacidification reaction tower cannot effectively remove it. Domestic waste incineration plants that have been built and operated in China implement the "Standards for Pollution Control of Domestic Waste Incineration" (GB18485-2014), and the NOX emission limit is 250mg/Nm3. Therefore, domestic waste incineration plants must implement feasible NOX control measures .

在生活垃圾电厂的脱硝工艺中,SNCR和SCR为常规处理工艺。单独使用SNCR系统已经很难达到环保所要求的大气污染物排放标准,此外SNCR具有一定的缺点:反应温度一般在850~1100℃,当反应温度过高时,由于氨的分解会使NOX还原率降低,当反应温度过低时,氨的逃逸增加,也会使NOX还原率降低。NH3是高挥发性和有毒物质,氨的逃逸会造成新的环境污染;单独使用SCR系统,可以使NOX排放达标。SCR技术的反应原理是在催化剂作用下,温度在250~450℃区间,含有氨基的还原剂将焚烧炉内烟气中的NOX选择性地还原为N2。SCR布置方式通常分为高温高尘、高温低尘和低温低尘三种布置方式。采用高温高尘布置,SCR反应器布置在省煤器与空预器之间,燃煤电厂多为此种布置方式;高温低尘布置方式,SCR反应器布置在除尘器后,由于除尘器需采用高温除尘器,造价较高,因此工程上应用极少;低温低尘布置方式,SCR反应器布置在脱硫除尘装置之后。生活垃圾焚烧炉产生的烟气重金属含量较高、灰尘较大型,相对于火力电厂更易引起催化剂中毒,大大削弱催化剂活性,增加运营成本。生活垃圾电厂工程上切实可行的多为低温低尘方式,但通常采用热源对烟气进行再加热运行费用十分昂贵。 In the denitrification process of domestic waste power plants, SNCR and SCR are conventional treatment processes. Using the SNCR system alone has been difficult to meet the air pollutant emission standards required by environmental protection. In addition, SNCR has certain disadvantages: the reaction temperature is generally 850-1100°C. When the reaction temperature is too high, the decomposition of ammonia will reduce the NOX reduction rate. When the reaction temperature is too low, the escape of ammonia will increase, which will also reduce the NOX reduction rate. NH3 is a highly volatile and toxic substance, and the escape of ammonia will cause new environmental pollution; using the SCR system alone can make the NOX emission meet the standard. The reaction principle of SCR technology is that under the action of a catalyst, the reducing agent containing amino groups will selectively reduce NOX in the flue gas in the incinerator to N2 at a temperature between 250 and 450 °C. SCR layouts are generally divided into three layouts: high temperature and high dust, high temperature and low dust, and low temperature and low dust. The high-temperature and high-dust layout is adopted, and the SCR reactor is arranged between the economizer and the air preheater, which is mostly used in coal-fired power plants; the high-temperature and low-dust layout, the SCR reactor is arranged after the dust collector, because the dust collector needs The high-temperature dust collector is used, which is expensive, so it is rarely used in engineering; the low-temperature and low-dust arrangement, the SCR reactor is arranged after the desulfurization and dust removal device. The flue gas produced by domestic waste incinerators has higher heavy metal content and larger dust, which is more likely to cause catalyst poisoning than thermal power plants, greatly weakening catalyst activity and increasing operating costs. Low-temperature and low-dust methods are mostly feasible in domestic waste power plant engineering, but usually using a heat source to reheat the flue gas is very expensive to operate.

实用新型内容 Utility model content

本实用新型目的在于针对以上问题,提供一种节约成本、具有高效性的生活垃圾电厂高效节能的脱硝系统。 The purpose of the utility model is to solve the above problems and provide a cost-saving and high-efficiency denitrification system for domestic waste power plants with high efficiency and energy saving.

本实用新型包括炉排炉、余热锅炉、脱酸反应塔、布袋除尘器、灰仓、低温SCR反应器、引风机、烟囱、SNCR喷枪、第一空压机、软水箱、SNCR氨水缓冲罐、第一氨水输送泵、氨水储存罐、第二氨水输送泵、SCR氨水缓冲罐、氨蒸发器、混合器、第二空压机; The utility model includes grate furnace, waste heat boiler, deacidification reaction tower, bag dust collector, ash bin, low temperature SCR reactor, induced draft fan, chimney, SNCR spray gun, first air compressor, soft water tank, SNCR ammonia water buffer tank, First ammonia delivery pump, ammonia storage tank, second ammonia delivery pump, SCR ammonia buffer tank, ammonia evaporator, mixer, second air compressor;

所述炉排炉的排烟口与余热锅炉的输入端连接,所述余热锅炉的输出端与脱酸反应塔的输入端连接,所述脱酸反应塔的输出端与布袋除尘器的输入端连接,所述布袋除尘器的输出端与低温SCR反应器的输入端连接,所述低温SCR反应器的输出端与引风机的输入端连接,所述引风机的输出端与烟囱的输入端连接;在所述余热锅炉、脱酸反应塔、布袋除尘器的下部分别设置与灰仓连接的管道; The exhaust port of the grate furnace is connected to the input end of the waste heat boiler, the output end of the waste heat boiler is connected to the input end of the deacidification reaction tower, the output end of the deacidification reaction tower is connected to the input end of the bag filter connected, the output end of the bag filter is connected to the input end of the low-temperature SCR reactor, the output end of the low-temperature SCR reactor is connected to the input end of the induced draft fan, and the output end of the induced draft fan is connected to the input end of the chimney ; Pipelines connected to the ash bin are respectively arranged at the lower part of the waste heat boiler, the deacidification reaction tower, and the bag filter;

在所述炉排炉排烟口的上部设置SNCR喷枪,所述SNCR喷枪的输入端分别连接SNCR氨水缓冲罐、软水箱和第一空压机的输出端,所述SNCR氨水缓冲罐的输入端与第一氨水输送泵的输出端连接;所述氨水储存罐设有两个输出端,分别为第一输出端和第二输出端,所述氨水储存罐的第一输出端与第一氨水输送泵的输入端连接; An SNCR spray gun is arranged on the top of the smoke outlet of the fire grate, and the input end of the SNCR spray gun is respectively connected to the output end of the SNCR ammonia buffer tank, the soft water tank and the first air compressor, and the input end of the SNCR ammonia buffer tank It is connected with the output end of the first ammonia water delivery pump; the ammonia water storage tank is provided with two output ends, which are respectively the first output end and the second output end, and the first output end of the ammonia water storage tank is connected with the first ammonia water delivery pump input connection;

所述氨水储存罐的第二输出端与第二氨水输送泵的输入端连接,所述第二氨水输送泵的输出端与SCR氨水缓冲罐的输入端连接,所述SCR氨水缓冲罐的输出端与氨蒸发器的输入端连接,所述氨蒸发器的输出端与混合器的氨气输入端连接,所述第二空压机的输出端与混合器的空气输入端连接,所述混合器的输出端与低温SCR反应器的输入端连接。 The second output end of the ammonia water storage tank is connected to the input end of the second ammonia water delivery pump, the output end of the second ammonia water delivery pump is connected to the input end of the SCR ammonia water buffer tank, and the output end of the SCR ammonia water buffer tank It is connected with the input end of the ammonia evaporator, the output end of the ammonia evaporator is connected with the ammonia gas input end of the mixer, the output end of the second air compressor is connected with the air input end of the mixer, and the mixer The output end of is connected with the input end of the low-temperature SCR reactor.

本实用新型采用“SNCR+低温SCR”组合脱销,氨水储存罐为SNCR系统和低温SCR系统公用设备,为两者的还原剂储存单元。第一氨水输送泵将氨水储存罐中的还原剂输送至SNCR氨水缓冲罐,再通过NOX排放反馈值实现与软水箱的软水定量混合,在适当的温度窗分配至喷枪,在喷枪内,经过空压机提供的压缩空气对氨水混合溶液进行雾化,最终喷入燃烧炉膛的烟道中,达到初步去除NOX的目的。低温SCR单元中第二氨水输送泵将氨水储存罐中的还原剂输送至SCR氨水缓冲罐,还原剂经过氨蒸发器的作用,与来自空压机中的压缩空气进入混合器进行还原剂充分稀释后,进入低温SCR反应器,此时烟气的温度为140~160℃,烟气经过低温SCR反应器中的喷氨格栅、混合单元在低温催化剂的作用下,实现对NOX的脱除。 The utility model adopts the "SNCR+low temperature SCR" combination out of stock, and the ammonia water storage tank is the common equipment of the SNCR system and the low temperature SCR system, and is the reducing agent storage unit of both. The first ammonia water delivery pump transports the reducing agent in the ammonia water storage tank to the SNCR ammonia water buffer tank, and then quantitatively mixes with the soft water in the soft water tank through the NOX emission feedback value, and distributes it to the spray gun in an appropriate temperature window. In the spray gun, it passes through the air The compressed air provided by the compressor atomizes the mixed solution of ammonia and water, and finally sprays it into the flue of the combustion furnace to achieve the purpose of preliminary removal of NOX. The second ammonia delivery pump in the low-temperature SCR unit delivers the reducing agent in the ammonia storage tank to the SCR ammonia buffer tank. The reducing agent passes through the ammonia evaporator and enters the mixer with the compressed air from the air compressor to fully dilute the reducing agent. Finally, it enters the low-temperature SCR reactor. At this time, the temperature of the flue gas is 140-160°C. The flue gas passes through the ammonia injection grid and the mixing unit in the low-temperature SCR reactor. Under the action of the low-temperature catalyst, the removal of NOX is realized.

本实用新型的优点是(1)同步建成SNCR+低温SCR,NOX排放要求提升后不需要改造;(2)大量设备可以共用,如氨水储罐、输送模块、控制模块,节约投资成本;(3)排放要求低时使用SNCR,SCR反应器不装催化剂;(4)排放要求高后安装催化剂,投运SCR;(5)经过布袋除尘之后的烟气温度在140~160℃,传统的SCR工艺需要对空气进行再次换热,才可以进入SCR反应器,本发明可以直接在此温度下进行脱硝反应,节省了电厂的热能;(6)经过处理后的烟气分别进入脱硫装置和布袋除尘器进行脱硫和除尘处理,出去烟气中的SO2和灰尘,避免对后续低温SCR催化剂的损害,延长了催化剂的使用寿命,具有一定的经济性;(7)经过本发明工艺处理后的烟气NOX浓度将会小于100mg/Nm3,满足排放标准,具有高效性。 The utility model has the advantages of (1) synchronously building SNCR+low temperature SCR, no modification is required after the NOX emission requirements are raised; (2) a large number of equipment can be shared, such as ammonia storage tanks, delivery modules, and control modules, saving investment costs; (3) SNCR is used when the emission requirements are low, and the SCR reactor is not equipped with a catalyst; (4) When the emission requirements are high, a catalyst is installed and the SCR is put into operation; The air can be heated again before entering the SCR reactor. The present invention can directly carry out the denitrification reaction at this temperature, saving the heat energy of the power plant; (6) The treated flue gas enters the desulfurization device and the bag filter respectively for Desulfurization and dust removal treatment, remove SO2 and dust in the flue gas, avoid damage to the subsequent low-temperature SCR catalyst, prolong the service life of the catalyst, and have certain economical efficiency; (7) NOX concentration of the flue gas after the process of the present invention It will be less than 100mg/Nm3, which meets the emission standard and has high efficiency.

附图说明 Description of drawings

图1为本实用新型的系统原理框图。 Fig. 1 is a system block diagram of the utility model.

具体实施方式 Detailed ways

如图1所示,本实用新型包括炉排炉1、余热锅炉2、脱酸反应塔3、布袋除尘器4、灰仓5、低温SCR反应器6、引风机7、烟囱8、SNCR喷枪9、第一空压机10、软水箱11、SNCR氨水缓冲罐12、第一氨水输送泵13、氨水储存罐14、第二氨水输送泵15、SCR氨水缓冲罐16、氨蒸发器17、混合器18、第二空压机19。 As shown in Figure 1, the utility model includes grate furnace 1, waste heat boiler 2, deacidification reaction tower 3, bag filter 4, ash bin 5, low temperature SCR reactor 6, induced draft fan 7, chimney 8, SNCR spray gun 9 , the first air compressor 10, the soft water tank 11, the SNCR ammonia water buffer tank 12, the first ammonia water delivery pump 13, the ammonia water storage tank 14, the second ammonia water delivery pump 15, the SCR ammonia water buffer tank 16, the ammonia evaporator 17, the mixer 18. The second air compressor 19.

所述炉排炉1的排烟口与余热锅炉2的输入端连接,所述余热锅炉2的输出端与脱酸反应塔3的输入端连接,所述脱酸反应塔3的输出端与布袋除尘器4的输入端连接,所述布袋除尘器4的输出端与低温SCR反应器6的输入端连接,所述低温SCR反应器6的输出端与引风机7的输入端连接,所述引风机7的输出端与烟囱8的输入端连接;在所述余热锅炉2、脱酸反应塔3、布袋除尘器4的下部分别设置与灰仓5连接的管道20。 The exhaust port of the grate furnace 1 is connected to the input end of the waste heat boiler 2, the output end of the waste heat boiler 2 is connected to the input end of the deacidification reaction tower 3, and the output end of the deacidification reaction tower 3 is connected to the cloth bag The input end of the dust collector 4 is connected, the output end of the bag filter 4 is connected with the input end of the low-temperature SCR reactor 6, the output end of the low-temperature SCR reactor 6 is connected with the input end of the induced draft fan 7, and the input end of the induced draft fan 7 is connected. The output end of the blower fan 7 is connected to the input end of the chimney 8; the pipes 20 connected with the ash bin 5 are respectively arranged at the lower part of the waste heat boiler 2, the deacidification reaction tower 3, and the bag filter 4.

在所述炉排炉1排烟口的上部设置SNCR喷枪9,所述SNCR喷枪9的输入端分别连接SNCR氨水缓冲罐12、软水箱11和第一空压机10的输出端,所述SNCR氨水缓冲罐12的输入端与第一氨水输送泵13的输出端连接;所述氨水储存罐14设有两个输出端,分别为第一输出端和第二输出端,所述氨水储存罐14的第一输出端与第一氨水输送泵13的输入端连接。 An SNCR spray gun 9 is arranged on the top of the exhaust port of the grate furnace 1, and the input end of the SNCR spray gun 9 is respectively connected to the output end of the SNCR ammonia buffer tank 12, the soft water tank 11 and the first air compressor 10, and the SNCR spray gun 9 is connected to the output end of the first air compressor 10. The input end of the ammonia water buffer tank 12 is connected with the output end of the first ammonia water delivery pump 13; The ammonia water storage tank 14 is provided with two output ends, is respectively the first output end and the second output end, and the ammonia water storage tank 14 The first output end of is connected with the input end of the first ammonia water delivery pump 13.

所述氨水储存罐14的第二输出端与第二氨水输送泵15的输入端连接,所述第二氨水输送泵15的输出端与SCR氨水缓冲罐16的输入端连接,所述SCR氨水缓冲罐16的输出端与氨蒸发器17的输入端连接,所述氨蒸发器17的输出端与混合器18的氨气输入端连接,所述第二空压机19的输出端与混合器18的空气输入端连接,所述混合器18的输出端与低温SCR反应器6的输入端连接。 The second output end of the ammonia water storage tank 14 is connected with the input end of the second ammonia water delivery pump 15, and the output end of the second ammonia water delivery pump 15 is connected with the input end of the SCR ammonia water buffer tank 16, and the SCR ammonia water buffer The output end of tank 16 is connected with the input end of ammonia evaporator 17, the output end of described ammonia evaporator 17 is connected with the ammonia gas input end of mixer 18, the output end of described second air compressor 19 is connected with mixer 18 The air input end of the mixer 18 is connected to the input end of the low-temperature SCR reactor 6 .

Claims (1)

1. the denitrating system that one way of life garbage power plant is energy-efficient, is characterized in that: comprise grate furnace, waste heat boiler, depickling reaction tower, sack cleaner, ash silo, low-temperature SCR reactor, air-introduced machine, chimney, SNCR spray gun, the first air compressor machine, softened water tank, SNCR ammonia water surge tank, the first ammonium hydroxide delivery pump, ammoniacal liquor holding vessel, the second ammonium hydroxide delivery pump, SCR ammoniacal liquor surge tank, ammonia evaporator, blender, the second air compressor machine;
The exhaust opening of described grate furnace is connected with the input of waste heat boiler, the output of described waste heat boiler is connected with the input of depickling reaction tower, the described output of depickling reaction tower is connected with the input of sack cleaner, the output of described sack cleaner is connected with the input of low-temperature SCR reactor, the described output of low-temperature SCR reactor is connected with the input of air-introduced machine, and the output of described air-introduced machine is connected with the input of chimney; In the bottom of described waste heat boiler, depickling reaction tower, sack cleaner, the pipeline be connected with ash silo is set respectively;
On the top of described grate furnace exhaust opening, SNCR spray gun is set, the input of described SNCR spray gun connects the output of SNCR ammonia water surge tank, softened water tank and the first air compressor machine respectively, and the input of described SNCR ammonia water surge tank is connected with the output of the first ammonium hydroxide delivery pump; Described ammoniacal liquor holding vessel is provided with two outputs, is respectively the first output and the second output, and the first output of described ammoniacal liquor holding vessel is connected with the input of the first ammonium hydroxide delivery pump;
Second output of described ammoniacal liquor holding vessel is connected with the input of the second ammonium hydroxide delivery pump, the output of described second ammonium hydroxide delivery pump is connected with the input of SCR ammoniacal liquor surge tank, the output of described SCR ammoniacal liquor surge tank is connected with the input of ammonia evaporator, the output of described ammonia evaporator is connected with the ammonia input of blender, the described output of the second air compressor machine is connected with the air input of blender, and the output of described blender is connected with the input of low-temperature SCR reactor.
CN201520665629.8U 2015-08-31 2015-08-31 Energy -efficient deNOx systems of domestic waste power plant Expired - Lifetime CN204891590U (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106215563A (en) * 2016-09-21 2016-12-14 光大环保技术研究院(深圳)有限公司 Garbage-incineration smoke purifying processing system
CN106994302A (en) * 2017-05-03 2017-08-01 江苏天楹环保能源成套设备有限公司 A kind of new and effective SCR denitration system
CN107376639A (en) * 2017-09-20 2017-11-24 山东大学 A kind of dangerous waste incineration flue gas purifying method

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106215563A (en) * 2016-09-21 2016-12-14 光大环保技术研究院(深圳)有限公司 Garbage-incineration smoke purifying processing system
CN106994302A (en) * 2017-05-03 2017-08-01 江苏天楹环保能源成套设备有限公司 A kind of new and effective SCR denitration system
CN107376639A (en) * 2017-09-20 2017-11-24 山东大学 A kind of dangerous waste incineration flue gas purifying method
CN107376639B (en) * 2017-09-20 2020-07-24 山东大学 Hazardous waste incineration flue gas purification method

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