CN204824148U - Adopt device of membrane separation hydrogen - Google Patents
Adopt device of membrane separation hydrogen Download PDFInfo
- Publication number
- CN204824148U CN204824148U CN201520629400.9U CN201520629400U CN204824148U CN 204824148 U CN204824148 U CN 204824148U CN 201520629400 U CN201520629400 U CN 201520629400U CN 204824148 U CN204824148 U CN 204824148U
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- hydrogen
- shell
- separation film
- pipe
- hydrogen separation
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Abstract
The utility model discloses an adopt device of membrane separation hydrogen, hydrogen separator include tubulose hydrogen diffusion barrier, shell, embedment, mist intake pipe, strain back gas outgoing pipe, hydrogen discharge pipe, the shell bottom is installed the mist intake pipe and is strained back gas outgoing pipe, the mist intake pipe directly extends to inside the shell, the hydrogen discharge pipe is installed at the shell top, the inside hydrogen diffusion barrier that is provided with of shell, hydrogen diffusion barrier upper end and shrouding, bottom plate sealing connection for the lower extreme, hydrogen diffusion barrier and shell between the interval be 15mm -25mm, the hydrogen diffusion barrier adopt the preparation of copper palldium alloy to form, be provided with between bottom plate and the mist intake pipe and strain back gas outgoing way, strain back gas outgoing way and strain back gas outgoing pipe and link up.
Description
Technical field
The utility model relates to a kind of hydrogen separation membrane device, and described a kind of device of membrane sepn hydrogen that adopts can make hydrogen separate from containing the mixed gas of hydrogen.
Background technology
Along with the environmental problems such as Global warming in the last few years receive much concern, the product research little to environment negatively influencing and exploitation are also more and more taken seriously.These start to be used as hydrogen and hydrogen fuel cell equal energy source.Described hereafter is the technology be separated from the gas body of hydrogen by hydrogen, more particularly, is a kind of hydrogen purification device with tubulose palladium alloy membrane.Hydrogen generates by reacting (see formula (1)) in water vapor as methane, also can produce hydrogen (see formula (2)) when carbon monoxide and water vapour react.
（1）CH4+H2O→CO+3H2
（2）CO+H2O→CO2+H2
But by finding out in the method for above-mentioned generation hydrogen, the hydrogen after generation is in mixed gas, and these mixed gass comprise carbonic acid gas, methane and water vapour.Although different with the type of reaction conditions according to raw material composition, in mixed gas, the large appointment of hydrogen accounts for cumulative volume 70%, and carbonic acid gas concentration wherein accounts for 30% of cumulative volume.
The utility model object is the problem solving hydrogen purification in mixed gas, adopts a kind of device of membrane sepn hydrogen that adopts to be separated from mixed gas by hydrogen.
Utility model content
The purpose of this utility model is to overcome in prior art not enough, provide a kind of Hydrogen Separation equipment, according to a kind of device adopting membrane sepn hydrogen of the present utility model, user can isolate high-purity hydrogen and have containing good hydrogen production efficiency from pending gas.For achieving the above object, the utility model have employed following technical scheme:
A kind of device adopting membrane sepn hydrogen, described hydrogen separation device comprises tubulose Hydrogen Separation film, shell, insert, mixed gas inlet pipe, gas outlet pipe after filter, hydrogen discharge pipe, described outer casing bottom is provided with mixed gas inlet pipe and the rear gas outlet pipe of filter, described mixed gas inlet pipe directly extends to enclosure, described cover top portion is provided with hydrogen discharge pipe, described enclosure is provided with Hydrogen Separation film, described Hydrogen Separation film upper end and shrouding, lower end base plate is tightly connected, between described Hydrogen Separation film and shell, spacing is 15mm-25mm, described Hydrogen Separation film adopts copper palldium alloy to be made, gas outlet duct after filtering is provided with between described base plate and mixed gas inlet pipe, after described filter, gas outlet duct is through with the rear gas outlet pipe of filter.
Preferably, described Hydrogen Separation film thickness is 3 μm.
Preferably, described insert, shell, base plate and shrouding all adopt Inconel(nickel alloys) to make.
The utility model has following advantage: according to a kind of device adopting membrane sepn hydrogen of the present utility model, and user can isolate high-purity hydrogen and have containing good hydrogen production efficiency from pending gas.
Accompanying drawing explanation
Fig. 1 is the structural representation of this hydrogen separation device.
Wherein, 1, Hydrogen Separation film; 1a, Hydrogen Separation film internal surface; 1b, Hydrogen Separation film outer surface; 2, shrouding; 3, base plate; 4, hydrogen discharge pipe; 5, shell; 6, mixed-gas channel; 7, gas outlet duct after filter; 8, insert; 8a, insert inwall; 8b, insert outer wall; 8c, insert roof; 8d, insert diapire; 8e, through hole; 9, gas outlet pipe after filter; 10, mixed gas inlet pipe.
Embodiment
With the drawings and specific embodiments, the utility model is described in further detail below.
A kind of device adopting membrane sepn hydrogen shown in Fig. 1, described hydrogen separation device comprises tubulose Hydrogen Separation film 1, shell 5, insert 8, mixed gas inlet pipe 10, gas outlet pipe 9 after filter, hydrogen discharge pipe 4, mixed gas inlet pipe 10 and the rear gas outlet pipe 9 of filter are installed bottom described shell 5, it is inner that described mixed gas inlet pipe 10 directly extends to shell 5, described shell 5 top is provided with hydrogen discharge pipe 4, described shell 5 inside is provided with Hydrogen Separation film 1, described Hydrogen Separation film 1 upper end and shrouding 2, lower end base plate 3 is tightly connected, between described Hydrogen Separation film and shell, spacing is 15mm-25mm, described Hydrogen Separation film 1 adopts copper palldium alloy to be made, gas outlet duct 7 after filtering is provided with between described base plate 3 and mixed gas inlet pipe 10, after described filter, gas outlet duct 7 is through with the rear gas outlet pipe 9 of filter.
Preferably, described Hydrogen Separation film 1 thickness is 3 μm.
Preferably, described insert 8, shell 5, base plate 3 and shrouding 2 all adopt Inconel(nickel alloys) to make.
Hydrogen Separation film 1 has the performance of selectivity through hydrogen molecule.This Hydrogen Separation film can selective permeability be because the hydrogen molecule of the internal surface 1a of Hydrogen Separation film arrives at 2000 DEG C
Hydrogen atom has been dispersed at the temperature of 6000 DEG C, hydrogen atom is subject to the motivating force produced at Hydrogen Separation film outer surface 1b due to Hydrogen Separation film 1 surfaces externally and internally pressure difference when moving to Hydrogen Separation film outer surface 1b, hydrogen atom and other hydrogen atoms are tied at the outside surface 1b of Hydrogen Separation film 1 outside surface being incorporated in Hydrogen Separation film and generated hydrogen.
In shell 5, Hydrogen Separation film 1 is dense film, and makes pending mixed gas isolate hydrogen by described film.
During use, mixed gas is entered by mixed gas inlet pipe 10, mixed gas is in Hydrogen Separation film 1 internal flow, because hydrogen at high temperature forms hydrogen atom, and between Hydrogen Separation film surfaces externally and internally, have pressure difference to impel hydrogen to enter in the cavity between shell and Hydrogen Separation film by Hydrogen Separation film, due to the selectivity of Hydrogen Separation film, gas outlet duct after causing other gas to enter into filter through through hole along passage, discharged by gas outlet pipe after filter, the hydrogen after filtering then is discharged by hydrogen discharge pipe again.
Claims (3)
1. one kind adopts the device of membrane sepn hydrogen, it is characterized in that: described hydrogen separation device comprises tubulose Hydrogen Separation film, shell, insert, mixed gas inlet pipe, gas outlet pipe after filter, hydrogen discharge pipe, described outer casing bottom is provided with mixed gas inlet pipe and the rear gas outlet pipe of filter, described mixed gas inlet pipe directly extends to enclosure, described cover top portion is provided with hydrogen discharge pipe, described enclosure is provided with Hydrogen Separation film, described Hydrogen Separation film upper end and shrouding, lower end base plate is tightly connected, between described Hydrogen Separation film and shell, spacing is 15mm-25mm, described Hydrogen Separation film adopts copper palldium alloy to be made, gas outlet duct after filtering is provided with between described base plate and mixed gas inlet pipe, after described filter, gas outlet duct is through with the rear gas outlet pipe of filter.
2. a kind of device adopting membrane sepn hydrogen according to claim 1, is characterized in that, described Hydrogen Separation film thickness is 3 μm.
3. a kind of device adopting membrane sepn hydrogen according to claim 1, is characterized in that, described insert, shell, base plate and shrouding all adopt Inconel(nickel alloys) to make.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201520629400.9U CN204824148U (en) | 2015-08-20 | 2015-08-20 | Adopt device of membrane separation hydrogen |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201520629400.9U CN204824148U (en) | 2015-08-20 | 2015-08-20 | Adopt device of membrane separation hydrogen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN204824148U true CN204824148U (en) | 2015-12-02 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201520629400.9U Expired - Fee Related CN204824148U (en) | 2015-08-20 | 2015-08-20 | Adopt device of membrane separation hydrogen |
Country Status (1)
| Country | Link |
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| CN (1) | CN204824148U (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107029559A (en) * | 2016-02-04 | 2017-08-11 | 中国科学院大连化学物理研究所 | A kind of palladium membrane component for integrating electrical heating and Hydrogen Separation |
-
2015
- 2015-08-20 CN CN201520629400.9U patent/CN204824148U/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107029559A (en) * | 2016-02-04 | 2017-08-11 | 中国科学院大连化学物理研究所 | A kind of palladium membrane component for integrating electrical heating and Hydrogen Separation |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| CB03 | Change of inventor or designer information |
Inventor after: Liu Cao Inventor before: Wu Dong |
|
| COR | Change of bibliographic data | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20160811 Address after: 100000 No. 5 building, No. seven, Toyohashi Road, Beijing, Fengtai District Patentee after: Liu Cao Address before: 232200 Fengzhen, Anhui Province, Shouxian County Jing Tong Village Yao Ying group Patentee before: Wu Dong |
|
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20151202 Termination date: 20160820 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |