CN204799088U - Sulphuric acid tail gas desulfurization device - Google Patents
Sulphuric acid tail gas desulfurization device Download PDFInfo
- Publication number
- CN204799088U CN204799088U CN201520183894.2U CN201520183894U CN204799088U CN 204799088 U CN204799088 U CN 204799088U CN 201520183894 U CN201520183894 U CN 201520183894U CN 204799088 U CN204799088 U CN 204799088U
- Authority
- CN
- China
- Prior art keywords
- desulfurizing tower
- tail gas
- tower
- pipeline
- pump
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
Abstract
The utility model relates to a sulphuric acid tail gas desulfurization device, the multilayer sprays the washing defogging in the desulfurizing tower, secondary oxidation unit designs with preventing blockking up, with the desulfurization, wash, three function collection of defogging are in a tower, the desulfurizing tower bottom is inserted the drain pipe and is inserted the circulating pump, the circulating pump passes through the pipeline connected blender, connect the ammonia pump and inserted aqueous ammonia groove through the pipeline on the blender, tower inner loop solution is ammonium sulfite and ammonium bisulfite, can reach higher desulfurization efficiency, the blender passes through pipeline connected one -level oxidation groove and inserts second grade oxidation groove, the outer secondary hydrogen peroxide solution oxidation of desulfurizing tower, the stirring that makes ammonium sulfite solution and hydrogen peroxide solution pass through the air is fully reacted, the oxygenation efficiency of ammonium sulfite can reach more than 98%, conscientiously, the quality of by -product ammonium sulfate solution has been ensured, sulphuric acid tail gas is through absorbing, adjust, the oxidation, generate ammonium sulfate, the utility model discloses operation equipment is few, and the power consumption is low energy -conserving.
Description
Technical field
The utility model belongs to industrial waste gas process field, relates to vent gas treatment qualified discharge in sulphuric acid process, or Appropriate application accessory substance non-pollutant discharge, relates to a kind of sulfuric acid tail gas desulfurizer particularly.
Background technology
At present, the industrial desulfur technology generally used has the technology of the multiple tail gas desulfurization such as semidry method and dry method, Gypsum Wet (FGD), Dual alkali, Sea water respiratory distress syndrome, but above-mentioned some problems of desulfur technology ubiquity, as system complex, catalyst attrition is high, equipment cost is high, investment is large, system cloud gray model maintenance cost is high, desulfuration efficiency is low, accessory substance cannot process.
Ammonia-process desulfurization technique development and application is in recent years very fast, ammonia-process desulfurization technique is a kind of liquid desulfuration technology, ammonia-process desulfurization technique has the advantage of by-product 30% ammonium sulfate or ammonium sulfate solids, therefore be with a wide range of applications for the sulfur dioxide removed in tail gas, the raw material that byproduct of ammonium sulfate can be used as composite heat transfer directly uses, save the production cost of composite fertilizer, meet again the ecological requirements of enterprise.
The ammonium sulfite ammonia process of desulfurization produced produces more than 30% ammonium sulfate by air oxidation, and equipment investment is relatively large, and stability is inadequate, still ammonium sulfite is there is in product, raw material as composite heat transfer can produce sulfur dioxide (SO2) emissions, affects the production of composite fertilizer, unfavorable to environment.The invention of hydrogen peroxide-ammonia-process desulfurization technique thoroughly solves the problem of complex utilization of sulfuric acid tail gas discharge and accessory substance.
Summary of the invention
The purpose of this utility model is to provide a kind of sulfuric acid tail gas desulfurizer, clean demist and secondary oxidation apparatus and anti-clogging by Multi-layer sprinkling in tower to design, desulfurization, cleaning, demist three functions are combined in a tower, running device is few, power consumption is low energy-conservation, tower Inner eycle solution is ammonium sulfite and ammonium bisulfite, higher desulfuration efficiency can be reached, stop the generation of desulfurizing tower clogging, reduce the power consumption of circulating pump, ensure lower exhaust emissions temperature, sulfuric-acid production tail gas desulfurization qualified discharge and byproduct comprehensive process are utilized.
The technical solution adopted in the utility model: a kind of sulfuric acid tail gas desulfurizer, mainly bottom desulfurizing tower, be connected to engine manifold, engine manifold is connected to feed tube and water inlet pipe, desulfurizing tower is connected to water inlet pipe, access drain pipe bottom desulfurizing tower and access circulating pump, circulating pump accesses blender by pipeline, and blender accesses stair oxidation groove by pipeline and accesses secondary oxidation groove;
In described desulfurizing tower, it is first that desulfurizing tower bottom is provided with spray, and middle part arranges and rises gas cap, and rise above gas cap and be provided with spray head two, desulfurizing tower top is provided with Multi-layer sprinkling head, and desulfurizing tower top is provided with demister, is provided with cleaning shower nozzle above described demister;
Described blender is connected to aqua ammonia pump by pipeline and accesses ammonia vessel, bottom described aqua ammonia pump access desulfurizing tower;
Described stair oxidation groove and secondary oxidation groove are connected with hydrogen peroxide pump by pipeline and are accessed dioxygen tank.
Described liter in gas cap is provided with cap bar, and cap bar is fixed on bottom desulfurizing tower, rises gas cap diameter and is less than desulfurizing tower internal diameter.
Described stair oxidation groove and secondary oxidation groove are connected to primary cycle pump and secondary cycle pump respectively by pipeline.
Described water inlet pipe accesses that spray in desulfurizing tower is first, spray head two, Multi-layer sprinkling head, demister respectively.
The beneficial effect of technical solutions of the utility model is:
1, the utility model sulfuric acid tail gas desulfurizer adopts the method high-efficiency desulfurization of tower inner exhaust gas three layers of cleaning showers and one deck demist, the sulfur dioxide of desulfurizing tower bottom tail gas reacts with the ammonium sulfite solution sprayed into, ground floor tail gas enter desulfurization in spraying layer backward on; Second layer tail gas enters rapid ball cleaning layer by rising gas cap, remove a small amount of micron order ammonium bisulfite, ammonium sulfate and minute solid particles and free ammonia in tail gas, third layer tail gas enter cleaning layer cleaning backward on, last tail gas enters demist layer, the droplet carried secretly in the cleaning shower nozzle removing tail gas that demister top is arranged, and clean demister and the ammonia carried secretly in tail gas and sulfur dioxide are absorbed again, gas-liquid two-phase contact area is large, desulfuration efficiency is high, and operating flexibility is large.
2, the utility model sulfuric acid tail gas desulfurizer adopts high-efficiency desulfurization and anti-clogging design, remains that in desulfurizing tower, solution pH value is in suitable scope, is conducive to the cyclic absorption to sulfur dioxide, improve the desulfuration efficiency of device; Avoid the formation of ammonium sulfate in tower, tower Inner eycle solution is ammonium sulfite and ammonium bisulfite, and the effective absorption composition in circulation fluid increases greatly, is conducive to improving absorption efficiency, reduces solution circulation amount and system power consumption; The concentration of conservative control circulation solution sulfite ammonium is about 20%, fundamentally stop the formation of crystallization inside tower, avoid crystallization inside tower and block up tower and blocking pipe, shower nozzle, to also reduce in circulation solution containing the wearing and tearing of crystallization to pipeline and equipment, substantially increase the stable operation cycle of equipment.
3, the utility model sulfuric acid tail gas desulfurizer adopts twin-stage jet regeneration oxidizing process, sulfur dioxide in the tail gas of desulfurizing tower bottom and the ammonium sulfite solution sprayed into react, the negative pressure that in injector, liquid at high speed flowing is formed passes through air agitation oxidative ammonium by after air intake, improve the probability that sulfite oxidation becomes ammonium sulfate, oxygenation efficiency >=98% of ammonium sulfite, ensure that the quality of byproduct of ammonium sulfate solution, be better than the air aeration oxidation in tower, ammonium sulfate product sulfite ammonium component content after oxidation is very low, the ammonium sulfate product rate of recovery is high and quality is pure, stop the generation of desulfurizing tower clogging, ensure lower exhaust emissions temperature, , the gas ammonia solving the ammonia process of desulfurization is preferably escaped and tail gas trailing whites problem.
4, the utility model sulfuric acid tail gas desulfurizer adopts the method for the outer secondary hydrogen peroxide oxidation of tower, one-level, secondary oxidation groove are set separately, ammonium sulfite solution certain density in tower is sent to tower external oxidation and becomes ammonium sulfate, this technique desulfurizing tower internal solution is the mixed solution of ammonium sulfite, ammonium bisulfite and ammoniacal liquor, substantially not liquid containing ammonium sulfate, does not affect the absorption to sulfur dioxide in tail gas.
5, the utility model sulfuric acid tail gas desulfurizer adopts tower external oxidation flow process, avoid the liquid-gas ratio that the requirements of process of tower internal oxidition is larger, larger circulation solution amount, the power consumption of circulating pump is also higher, the oxidation fan of relatively high power is set, tower external oxidation technical scheme greatly reduces the internal circulating load of doctor solution, without the need to oxidation fan, desulfurization, cleaning, demist three functions are combined in a tower, running device is few, power consumption is low energy-conservation, and in desulfurizer tower, solution is all the active ingredient of sulfur dioxide absorption, can reach higher desulfuration efficiency.
6, the utility model sulfuric acid tail gas desulfurizer adopts Optimum Operation control method, the pH value of mixed solution is regulated by controlling to add the addition of ammoniacal liquor in static mixer, ammoniacal liquor flow is controlled with pH value, with Liquid level engine manifold shower water flow, with final products density domination product ammonium sulfate flow; Simultaneously ammoniacal liquor directly adds bottom desulfurizing tower, react on the one hand generate ammonium sulfite with the ammonium bisulfite in desulfurizing tower Inner eycle liquid, the pH value of another aspect mainly controlled circulation liquid; Every data acquisition scene and the instruction of DCS dual system, Con trolling index all accesses DCS control system, has good stability and security, can realize automatic operating completely, simple to operate.
Accompanying drawing explanation
Fig. 1 is a kind of sulfuric acid tail gas desulfurizer of the utility model process chart.
Engine manifold 101, desulfurizing tower 102, feed tube 103, water inlet pipe 104, water inlet pipe 105, drain pipe 106, circulating pump 107, spray first 108, rise gas cap 109, spray head 2 110, Multi-layer sprinkling head 111, demister 112, cleaning shower nozzle 113, cap bar 114, blender 201, aqua ammonia pump 202, ammonia vessel 203, stair oxidation groove 301, secondary oxidation groove 302, dioxygen water pump 303, dioxygen tank 304, primary cycle pump 305, secondary cycle pump 306.
Detailed description of the invention
Below in conjunction with embodiment, the utility model is further illustrated.
The technological process of a kind of sulfuric acid tail gas sulfur method, sulfuric acid tail gas house steward 101 is connected to ammonium sulfite solution feed tube 103 and water inlet pipe 104, sulfuric acid tail gas house steward 101 is connected to bottom desulfurizing tower 102, desulfurizing tower 102 is connected to water inlet pipe 105, access drain pipe 106 bottom desulfurizing tower 102 and access circulating pump 107, circulating pump 107 is by pipeline access blender 201, and blender 201 is connected to aqua ammonia pump 202 by pipeline and accesses ammonia vessel 203, aqua ammonia pump 201 accesses bottom desulfurizing tower 102 simultaneously; Blender 201 is by pipeline access stair oxidation groove 301 and access secondary oxidation groove 302, and stair oxidation groove 301 and secondary oxidation groove 302 are connected with hydrogen peroxide pump 303 by pipeline and are accessed dioxygen tank 304.
1, Structure of Flue Gas Desulfuration Absorbing and material, in desulfurizing tower 102, desulfurizing tower 102 bottom is provided with spray first 108, middle part arranges and rises gas cap 109, rise in gas cap 109 and be provided with cap bar 114, cap bar 114 is fixed on bottom desulfurizing tower 102, rises gas cap 109 diameter and is less than desulfurizing tower 102 internal diameter; Rise above gas cap 109 and be provided with spray head 2 110, desulfurizing tower 102 top is provided with Multi-layer sprinkling head 111, and desulfurizing tower 102 top is provided with demister 112, is provided with cleaning shower nozzle 113 above described demister 112.
Desulfurizing tower 102 shell adopts whole glass steel material, material vinyl base resin also partly have employed special high temperature-resistant resin, desulfurizing tower is furnished with No leakage manhole and peep hole, and manhole being equipped with handle Yi Kaiyi pass size is at least DN500, and peephole is easy to change and internal washing measure.
Gas feed employing and horizontal sextant angle 30 ° of directions of desulfurizing tower enter, and gas and the bisulfite ammonium salt solution carried secretly are ejected on the liquid level at the bottom of tower, avoid and are directly injected to tower wall and cause wash away infringement.
2, desulfurizing tower 102 bottom is provided with spray first 108, spray first 108 times distribution washing sections, the distribution grid being 32% by percent opening forms, distribution grid to make in desulfurizing tower tail gas upwards be uniformly distributed, the gas-liquid mass transfer of this section is increased, impurity capture in tail gas is got off, strengthens sulfur dioxide absorption.
3, the inner ammonium sulfite solution spray equipment of desulfurizing tower 102, by rising gas cap 109 and spray head 2 110 absorber portion forms, the spray flux of the distribution reasonable in design of spray equipment, carries out simulation by utilizing computer and makes flue gas flow direction even, and guarantee that ammonium sulfite solution and flue gas fully contact and react.Shower material selection corrosion resistant, wear-resisting composite, be made up of vinylite, glass fibre and 316L stainless steel.
In main absorber portion and the spray-absorption section of desulfurizing tower 102, the tail gas be evenly distributed, be atomized the ammonium sulfite solution counter current contacting under spraying with the even Multi-layer sprinkling head 111 of desulfurizing tower spraying layer, the sour gas such as the sulfur dioxide in tail gas and ammonium sulfite solution reaction generate ammonium bisulfite and fall at the bottom of tower; Ammonia of carrying secretly simultaneously in tail gas is also got off by spray washing.
4, desulfurizing tower gas-liquid separation device
Gas-liquid separation device, namely demister 112 is arranged on desulfurizing tower 102 top, is provided with the droplet that cleaning shower nozzle 113 is carried secretly in order to be separated neat stress above demister 112, and demister outlet tail gas droplet is not more than 75mg/Nm
3(butt), demister material adopts and strengthens polypropylene, can bear high-velocity flow and wash away.
5, blender 201 be connected to aqua ammonia pump 202 by pipeline and access ammonia vessel 203, aqua ammonia pump 201 accesses bottom desulfurizing tower 102 simultaneously; Stair oxidation groove 301 and secondary oxidation groove 302 are connected with hydrogen peroxide pump 303 by pipeline and are accessed dioxygen tank 304.
Sulfuric acid tail gas is delivered to desulfurizing tower 102 through engine manifold 101, the tail gas entering desulfurizing tower 102 bottom runs from bottom to top in tower, sulfur dioxide in desulfurizing tower inner exhaust gas and the ammonium sulfite solution sprayed into react, generate bisulfite ammonium salt solution, have sulfur trioxide, acid mist and ammoniacal liquor to generate ammonium sulfate etc.; With entering desulfurizing tower 102 bottom together with the ammonium bisulfite mixed solution that unreacted ammonium sulfite solution and reaction generate, tail gas is on the first 108 spray desulfurization of ground floor spray are backward.
Tail gas is in spraying layer after desulfurization, by rising gas cap 109, to enter the desulfurizing tower second layer be rapid ball cleaning layer, through spray head 2 110 cleaning showers, remove a small amount of micron order ammonium bisulfite, ammonium sulfate and minute solid particles and free ammonia in tail gas, solve aerosol, the escaping of ammonia and tail gas trailing whites.
It is demist layer that tail gas enters third layer, tail gas enters demister 112 through Multi-layer sprinkling head 111 cleaning showers, demister 112 removes the droplet carried secretly in tail gas, demister 112 top is provided with cleaning shower nozzle 113, not only can clean demister, pre-anti-clogging, and again can absorb the ammonia carried secretly in tail gas and sulfur dioxide, reduce the content in the discharge of its tail gas, the exhaust temperature after cleaning and demist drops to about 30 DEG C through smoke stack emission to air.Through desulfurization, washing, demist, sulfuric acid tail gas outlet sulfur dioxide concentration is less than 200mg/Nm
3, ammonia content is less than 10mg/Nm
3, misty liquid droplets is less than 75mg/Nm
3.
At the bottom of desulfurizing tower 102 tower, solution is after circulating pump 107 iterative cycles, generate the mixed solution of certain density ammonium bisulfite and ammonium sulfite, when ammonium sulfite solution concentration reaches about 25-35%, part mixed solution delivers to blender 201 through circulating pump 107.In blender 201, regulate the pH value of mixed solution by controlling the addition of ammoniacal liquor, the invalid component ammonium bisulfite in solution be all converted into ammonium sulfite, after continue to be fed into, stair oxidation groove 301 and secondary oxidation groove 302 carry out two-stage oxidation.Stair oxidation groove 301 adds hydrogen peroxide neutralization, makes ammonium sulfite be generated ammonium sulfate by Quick Oxidation, and secondary oxidation groove 302 adds excessive in a subtle way hydrogen peroxide makes it standing stable.
Claims (4)
1. a sulfuric acid tail gas desulfurizer, it is characterized in that: desulfurizing tower (102) bottom is connected to engine manifold (101), engine manifold (101) is connected to feed tube (103) and water inlet pipe (104), desulfurizing tower (102) is connected to water inlet pipe (105), desulfurizing tower (102) bottom access drain pipe (106) also accesses circulating pump (107), circulating pump (107) accesses blender (201) by pipeline, and blender (201) accesses stair oxidation groove (301) by pipeline and accesses secondary oxidation groove (302);
In described desulfurizing tower (102), desulfurizing tower (102) bottom is provided with spray first (108), middle part arranges and rises gas cap (109), rise gas cap (109) top and be provided with spray head two (110), desulfurizing tower (102) top is provided with Multi-layer sprinkling head (111), desulfurizing tower (102) top is provided with demister (112), and described demister (112) top is provided with cleaning shower nozzle (113);
Described blender (201) is connected to aqua ammonia pump (202) by pipeline and accesses ammonia vessel (203), described aqua ammonia pump (202) access desulfurizing tower (102) bottom;
Described stair oxidation groove (301) and secondary oxidation groove (302) are connected with hydrogen peroxide pump (303) by pipeline and are accessed dioxygen tank (304).
2. a kind of sulfuric acid tail gas desulfurizer according to claim 1, it is characterized in that: described liter in gas cap (109) is provided with cap bar (114), cap bar (114) is fixed on desulfurizing tower (102) bottom, rises gas cap (109) diameter and is less than desulfurizing tower (102) internal diameter.
3. a kind of sulfuric acid tail gas desulfurizer according to claim 1, is characterized in that: described stair oxidation groove (301) and secondary oxidation groove (302) are connected to primary cycle pump (305) and secondary cycle pump (306) respectively by pipeline.
4. a kind of sulfuric acid tail gas desulfurizer according to claim 1, is characterized in that: described water inlet pipe (105) accesses spray first (108), spray head two (110), Multi-layer sprinkling head (111), demister (112) in desulfurizing tower (102) respectively.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201520183894.2U CN204799088U (en) | 2015-03-31 | 2015-03-31 | Sulphuric acid tail gas desulfurization device |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201520183894.2U CN204799088U (en) | 2015-03-31 | 2015-03-31 | Sulphuric acid tail gas desulfurization device |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN204799088U true CN204799088U (en) | 2015-11-25 |
Family
ID=54583981
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201520183894.2U Expired - Fee Related CN204799088U (en) | 2015-03-31 | 2015-03-31 | Sulphuric acid tail gas desulfurization device |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN204799088U (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104998530A (en) * | 2015-03-31 | 2015-10-28 | 武汉宇青环保科技有限公司 | Sulfuric acid tail gas desulphurization device and method |
-
2015
- 2015-03-31 CN CN201520183894.2U patent/CN204799088U/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104998530A (en) * | 2015-03-31 | 2015-10-28 | 武汉宇青环保科技有限公司 | Sulfuric acid tail gas desulphurization device and method |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103223292B (en) | Ammonia process flue gas treatment method for acidic tail gas and device | |
| CN201880482U (en) | Stepped spray tower for desulfurization by ammonia method | |
| CN103252158B (en) | Desulfurization system and desulfurization process thereof | |
| WO2014172860A1 (en) | Method and apparatus for treating acidic tail gas by using ammonia process flue gas | |
| EP2762221B1 (en) | Dual-chamber multi-absorption wet flue desulfurization device | |
| CN206652377U (en) | Ammonia fertilizer method desulphurization system | |
| CN104998530A (en) | Sulfuric acid tail gas desulphurization device and method | |
| CN106139850A (en) | A kind of energy-efficient gas-liquid coupling oxidation sweetening denitrification apparatus | |
| CN101428196A (en) | In-hollow column intercrystalline ammonia process of desulfurization, recovery system and method thereof | |
| CN103349902B (en) | Flue gas processing method | |
| CN106345288B (en) | A kind of method and system using phosphate ore pulp processing sulfur-containing smoke gas | |
| CN215249581U (en) | Smelting flue gas acid making dry absorption device | |
| CN105749704A (en) | Ammonium sulphite desulphurization system and process | |
| CN209501361U (en) | Novel energy-conserving Complexing Iron desulphurization plant | |
| CN204799088U (en) | Sulphuric acid tail gas desulfurization device | |
| CN204193780U (en) | A kind of high-efficiency desulfurization absorption tower | |
| CN107158918A (en) | A kind of nitrate method phosphoric acid tail gas defluorinate denitration process system and processing method | |
| CN203408621U (en) | Acidic flue gas treatment system | |
| CN201669053U (en) | Desulfurizing device with gas fume washing component | |
| CN206935095U (en) | A kind of nitrate method phosphoric acid tail gas defluorinate denitration process system | |
| CN201609626U (en) | Device applied in ammonia flue gas desulfurization by using technology of hydrochloric acid production through flue gas dechlorination | |
| CN103272471B (en) | Desulphurization system and sulfur removal technology thereof | |
| CN207941383U (en) | Chloracetyl chloride tail gas by-product sulfuric acid apparatus | |
| CN216825595U (en) | Internal circulation flue gas dust removal and desulfurization device | |
| CN109381988A (en) | A kind of device preventing ammonia process desulfuration tower Crystallization Plugging |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20151125 Termination date: 20190331 |