CN204689900U - Be applicable to the whipping device of cement-based material two benches stirring technique - Google Patents

Be applicable to the whipping device of cement-based material two benches stirring technique Download PDF

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CN204689900U
CN204689900U CN201520378966.9U CN201520378966U CN204689900U CN 204689900 U CN204689900 U CN 204689900U CN 201520378966 U CN201520378966 U CN 201520378966U CN 204689900 U CN204689900 U CN 204689900U
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agitation vat
cement
agitator
benches
applicable
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杜玉兵
唐拥政
支正东
杨建明
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Yangcheng Institute of Technology
Yancheng Institute of Technology
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Yangcheng Institute of Technology
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Abstract

The utility model discloses a kind of whipping device being applicable to cement-based material two benches stirring technique, comprise: frame, be located at the first agitation vat in this frame and the second agitation vat, with the first agitator that described first agitation vat is supporting, and second agitator supporting with described second agitation vat; Described first agitation vat is arranged in described frame turningly, when the upset of this first agitation vat is toppled over can by it in the material deposited pour in described second agitation vat.Use this whipping device can fully dissolve and disperse compound retarder and the acid constituents of magnesium phosphate cement, be conducive to the acid-base reaction process of promotion magnesium phosphate cement sill, the degree of reaction and the homogeneity of strength development; And gelling material and aggregate, fiber interface can also be made fully to infiltrate and bond, reduce the air bubble of mixture simultaneously.

Description

Be applicable to the whipping device of cement-based material two benches stirring technique
Technical field
The utility model relates to a kind of whipping device, and particularly a kind of whipping device being applicable to cement-based material two benches stirring technique, belongs to civil material technical field of processing equipment.
Background technology
Magnesium phosphate cement (MPC) is a kind of novel gelled material of early-strong-fast-hard, have cryogenic temperature condensation fast, with concrete structure cohesive strength is high, drying shrinkage is little, adhesivity is strong, wear resistance and the advantage such as frost resistance is good, there is good application prospect.Magnesium phosphate cement sill forms intensity based on Components of Acid-Base reaction, compared with silicate cement, it is for subsequent use that the alkaline constituents (dead roasting magnesia powder) in its gelling material and acid constituents (phosphoric acid salt) should not mix rear prolonged storage because making moist reaction.In addition, existing experimental result shows, Components of Acid-Base ratio is one of key parameter affecting magnesium phosphate cement material performance.The research to MPC such as Weill is thought, alkaline constituents should be relatively excessive, and excessive MgO is as the skeleton of gelling system or heap buildup to the raising of hardenite intensity with stablize useful, but acid/base ratio should meet certain requirements.If MgO consumption very little in system, so the non-complete reaction of acidic components after material cured, leaves soluble salt in cured body, the strength of materials will be caused to decay too fast.If consumption is too many, speed of response will be caused too fast, and slurry is short for time of coagulation, is not easy to use, and too fast hydration heat speed makes, and hydrated product crystal is unstable, defect is more, and material later strength is declined.And Related Experimental Study shows, the material forms that magnesium phosphate cement is starched only, mortar, concrete etc. are different, the magnesia powder of corresponding the best is different with phosphate ratio, is 1:2.5 ~ 1:3 and 1:1.5 ~ 1:2 (mass ratio) as MPC starches only with the best Components of Acid-Base of mortar.Thus, when magnesium phosphate cement uses, gelling material should adopt soda acid two chemical species, is not only beneficial to and guarantees the quality, the optimization design of matrix material of being more convenient for.
In addition, the reaction mechanism of magnesium phosphate cement is the acid-base reaction based on slightly soluble salt.The solubleness of the potassium primary phosphate that MPC adopts in 20 DEG C of 100g water is 22.6g, the solubleness of ammonium di-hydrogen phosphate in 20 DEG C of 100g water is 37.4g, and is about 1.8:1 ~ 1.9:1 according to the mass ratio that the best water-cement ratio experimental result of MPC calculates phosphoric acid salt and water; Borax is one of retardant used in MPC, and its solubleness in 20 DEG C of 100g water is 2.01g, and in the component of MPC, the mass ratio of borax and water is more than 0.07; As can be seen here, water in magnesium phosphate cement sill component is not enough to dissolving acid component and retardant, and alkaline constituents magnesia powder is water insoluble especially, how fully to disperse acid constituents and retardant, not only affect the homogeneity of MPC strength of materials development, also can affect the adequacy of acid-base reaction.
In sum, the mixing forming strength development uniform magnesium phosphate cement sill relates to the abundant dispersion of acid constituents, retardant, then with even mix two critical process of magnesia powder, therefore, be necessary to carry out design and development to the stirring technique of MPC material and relevant device.
The stirring technique of cement-based material is inquired into by SooPAT patent search system, mainly contain patent " secondary stirring technologyf or concrete " (CN1249232A) that following typical cement-based material stirring technique and method: Xu Huxian etc. apply for provide one first coarse aggregate is carried out rinsing, moistening, carry out powder again and wrap stirring, finally add the concrete secondary mixing methods of fine aggregate, admixture fusion stirring, because flushing process improves the quality of aggregate, effectively improve concrete quality.Patent " multi-step concrete stirring technology for fast grout preparation method " (CN1396048A) of the application such as Xu Huxian is quickly preparing cement paste multistep concrete stirring technology, it is characterized in that mixing cement in advance powder, again with aggregate mix, this patent can make the binder in concrete obtain sufficient aquation, contribute to improving concrete strength, can the binders such as cement be saved further, simultaneously, powder is stirred into slurry and enters concrete mixer, effectively reduces dust pollution.Patent " asphalt cement mortar stirring technique " (CN101234511A) of the application such as Liang Yi is for forming high-performance asphalt cement mortar, stirring technique is divided into high-speed stirring and two stages of stirring at low speed, high-speed stirring makes emulsified bitumen, liquid agent, dry-mixed mortar Quick uniform be scattered in stirring host liquid, avoids the formation of cohesion and even precipitates, improves mix working efficiency simultaneously; And add defoamer subsequently and stirring at low speed, avoid in finished asphalt sand-cement slurry, being mixed with air and form bubble, ensure mixture quality.First cement, water are added paste roller mill by required proportioning by the patent " cement concrete Secondary mixing " (CN103862570A) of Zhang Jiqing application, the power friction of paste roller mill and shearing is utilized to make the abundant aquation of cement, stir again in the forced mixer that the cement slurry made adds sand, stone aggregate again, make Cement Concrete compound.The whipping process that this patent provides can not form free moisture film on sandstone surface, contributes to the cohesive force improving gelling material and aggregate, improve concrete strength and also reach the object of saving cement, but this patent does not provide corresponding mixing equipment to design.
The stirring of compound is spread between each phase materials, shears and the process of convection current, and the cohesive force of material table central bay stirs the main source of resistance, and the agglomerate of material, precipitation and immiscible be the key factor affecting mixture uniformity.For many years, about scholar and slip-stick artist, the stirring technique to cement-based material proposes design and the experimental verification of novelty, vibration, shearing and traditional alr mode is combined.Wherein Vibratory Mixing technical study comparatively early, and think that vibrating device makes material particles be in chatter state, destroys cement agglomerates, reduce material movement resistance, improve stirring efficiency.Zhao Lijun etc. have carried out experimental study to the reasonable exciting mode of the Vibratory Mixing of cement concrete, rationally vibration parameters, and have designed and produced the vibration experimental prototype integrated with whipping appts; And patent " oscillating mixer " (CN203985794U) of the application such as Chen Biao arranges vibrating motor in agitation vat side, with the homogeneity of strength imparting material mixing.Shear agitation is used for Fine Chemical, also application is had in the modification preparation of pitch, and application in the stirring of cement-based material is less, gold is founded the state and is waited patent " Mobile high-speed cement slurry shear mixer " (CN201752904U) of application to stir disc rapid dispersion grout with three of high speed rotating justice, improves the homogeneity of grout.
By patent retrieval and Literature Consult, about exploitation and the research of magnesium phosphate cement sill stirring technique and equipment, there is not been reported.
Utility model content
The utility model object is: for the problems referred to above, a kind of whipping device being applicable to cement-based material two benches stirring technique is provided, use this equipment can fully dissolve and disperse compound retarder and the acid constituents of magnesium phosphate cement, be conducive to the acid-base reaction process of promotion magnesium phosphate cement sill, the degree of reaction and the homogeneity of strength development; And gelling material and aggregate, fiber interface can also be made fully to infiltrate and bond, reduce the air bubble of mixture simultaneously.
The technical solution of the utility model is: the described whipping device being applicable to cement-based material two benches stirring technique, comprising:
Frame,
Be located at the first agitation vat in this frame and the second agitation vat,
With the first agitator that described first agitation vat is supporting, and
With the second agitator that described second agitation vat is supporting;
Described first agitation vat is arranged in described frame turningly, when the upset of this first agitation vat is toppled over can by it in the material deposited pour in described second agitation vat.
The utility model, on the basis of technique scheme, also comprises following preferred version:
Described first agitator comprises the first agitator motor, the motor shaft of this first agitator motor is connected with the first agitating vane stretched in described first agitation vat.
Described first agitator also comprises high-speed shearing machine.
Described second agitator comprises the second agitator motor, the motor shaft of this second agitator motor is connected with the second agitating vane stretched in described second agitation vat.
Described second agitator also involving vibrations motor, this vibrating motor is provided with the exciting rod stretched in described second agitation vat.
Described frame is fixedly installed the first column of parallel distribution inside and outside two, described first agitation vat is connected on these two first columns by rotating shaft upset.
Described frame is also provided with the first chain to be connected with described rotating shaft transmission, to overturn motor for the first agitation vat driving described first agitation vat to make rotary movement.
Described frame is furnished with the dust-proof protective cover covered on outside described first agitation vat upset motor.
Described frame is provided with the second column of parallel distribution inside and outside two, and be arranged in the crossbeam on these two second column tops, the lower end being wherein positioned at that root second column of inner side is fixed in frame, and the lower end being positioned at that root second column in outside is connected in frame by unidirectional hinge upset, one end of described crossbeam is connected to the top of that root second column of inner side by hinge upset, the other end of crossbeam is supported on the top of that root second column of outside, and that root second column of outside is connected with the ripping bar be positioned at below described second agitation vat, described second agitator is fixed on described crossbeam.
That root second column of outside is connected with the first constraint steel band be enclosed within outside described second agitation vat, described ripping bar is connected with the second constraint steel band be enclosed within the second agitation vat.
The utility model has the advantages that: this whipping device of the utility model is applicable to the requirement of cement-based material two benches stirring technique, and the interspersed mix of multiple batches of compound can be realized, improve mix efficiency.When applying, compound retarder and the acid constituents of magnesium phosphate cement can fully be dissolved and disperse to the shear agitation of its first stage, is conducive to the acid-base reaction process of promotion magnesium phosphate cement sill, the degree of reaction and the homogeneity of strength development; The Vibratory Mixing of subordinate phase can reduce the resistance of motion of material mix, improves mix efficiency, makes gelling material and aggregate, fiber interface fully infiltrate and bond, reduce the air bubble of mixture simultaneously.
Accompanying drawing explanation
In order to be illustrated more clearly in the technical scheme of the utility model embodiment, below the accompanying drawing used required in describing embodiment is briefly described, accompanying drawing in the following describes is only embodiments more of the present utility model, for those of ordinary skill in the art, under the prerequisite not paying creative work, other accompanying drawing can also be obtained according to these accompanying drawings.
Fig. 1 is the vertical view of whipping device in the utility model embodiment;
Fig. 2 is that the A-A of Fig. 1 is to sectional view;
Fig. 3 is the side-view of whipping device in the utility model embodiment;
Fig. 4 is that the B-B of Fig. 3 is to sectional view;
Fig. 5 is step 4 in the utility model embodiment) operation demonstration graph;
Fig. 6 is step 7 in the utility model embodiment) operation demonstration graph;
Fig. 7 is step 8 in the utility model embodiment) operation demonstration graph;
Fig. 8 is the influence curve figure that in the utility model embodiment, alr mode starches hydration temperature only to MPC;
Fig. 9 is that the MPC of different larval instar in the utility model technique effect embodiment one starches anti-folding and ultimate compression strength curve only;
Figure 10 be in the utility model technique effect embodiment two different stirring means to the influence curve figure of MPC mortar Compressive Strength;
Wherein: 1-frame, 2-first agitation vat, 3-second agitation vat, 4-first agitator motor, 5-first agitating vane, 6-high-speed shearing machine, 7-second agitator motor, 8-second agitating vane, 9-vibrating motor, 10-exciting rod, 11-first column, 12-rotating shaft, 13-first chain, 14-first agitation vat upset motor, 15-second column, 16-crossbeam, the unidirectional hinge of 17-, 18-hinge, 19-dust-proof protective cover, 20-ripping bar, 21-first retrains steel band, 22-second retrains steel band, 23-road wheel, 24-push and pull bar, 25-leg, 26-device control unit, 27-bearing support, supporting seat at the bottom of 28-bucket, 29-gear, 30-worm screw wheel box, 31-second chain, 32-stirs drive-motor, 33-staving upset snap ring, 34-limited slip block.
Embodiment:
Below in conjunction with specific embodiment, such scheme is described further.Should be understood that these embodiments are for illustration of the utility model and unrestricted scope of the present utility model.The implementation condition adopted in embodiment can do further adjustment according to the condition of Specific construction unit, and not marked implementation condition is generally the condition in normal experiment.
Technical scheme embodiment:
Magnesium phosphate cement sill is generally divided into the types such as magnesium phosphate cement is starched only, magnesium phosphate cement mortar, magnesium phosphate cement concrete, fiber magnesium phosphate cement based composites.Applicant verifies by experiment, and feasible stirring feeding sequence is: (a) set retarder components dissolves (water and compound slow setting coagulate agent); (b) add magnesium phosphate cement sill acid constituents (be soluble phosphate, be generally potassium primary phosphate, ammonium di-hydrogen phosphate, etc.) dispersion; C () adds alkaline constituents (being generally magnesia powder), the adulterant mix of magnesium phosphate cement sill; D () adds the mixing such as aggregate, fiber compound.Wherein, (a) and (b) needs fully to dissolve and dispersion, and mixing thing is liquid; C the mixing thing of () should mix, form the clay of certain denseness according to the different water-binder ratios of design; And the mixing of (d) forms final mix product, need to make gelling material and aggregate, fiber interfacial layer well-bonded, infiltrate, to air bubble be reduced, to be conducive to the intensity of shaped component simultaneously.Therefore, magnesium phosphate cement sill is adopted two benches stirring technique by the present embodiment, first stage is that the compound retarder of magnesium phosphate cement sill and acid constituents dissolution dispersity stir, and subordinate phase is that the mixture of first stage and the compound mixing of basic component, adulterant, aggregate and fiber and other material form final compound.
According to above-mentioned analysis, this magnesium phosphate cement sill two benches stirring technique designed by the present embodiment specifically comprises following operation:
1) according to mix proportion design, quantitatively take the raw materials such as water, compound retarder, acid constituents, alkaline constituents, adulterant, be put in temporary containers for future use respectively.If mixing is magnesium phosphate cement mortar, magnesium phosphate cement concrete or fiber magnesium phosphate cement based composites, also need the aggregate taking certain component or/and fiber.
2) water and compound retarder are poured in agitation vat A, open agitator motor A and (circumference turn is mixed) 10 seconds are stirred to the water in bucket and compound retarder, open high-speed shearing machine mixing retarder solution 30 ~ 60 second (emulsification pretreatment is carried out to water and compound retarder), shears speed is 3000r/min ~ 4000r/min, closing high-speed shears, agitator motor A Keep agitation (circumference turn is mixed).
3) acid constituents (abbreviation acid constituents) of magnesium phosphate cement sill is also poured in above-mentioned agitation vat, offer agitator motor Keep agitation 10 second, open high shear agitation machine and fully disperse acid constituents 60 ~ 90 second, closing high-speed shears and agitator motor, obtain first stage mixture.
4) obtained first stage mixture is poured in another agitation vat B, open the agitator motor B supporting with this agitation vat B.
5) while pouring first stage mixture into agitation vat B, alkaline constituents and Additive is slowly added in agitation vat B, after first stage mixture, alkaline constituents and Additive are thrown in and are terminated, open dither, utilize agitator motor B and this dither to turn first stage mixture, alkaline constituents and the Additive circumference in agitation vat B and mix and stir vibration 60 seconds ~ 90 seconds, close agitator motor B and dither.
6) if mixing be magnesium phosphate cement mortar, magnesium phosphate cement concrete or fiber magnesium phosphate cement based composites, after above-mentioned alkaline constituents and adulterant Keep agitation 60 second, throw in aggregate or/and fiber and other material, and Keep agitation 60 seconds ~ 90 closes agitator motor B and dither after second, required magnesium phosphate cement sill finished product just can be obtained.
If mixing is that magnesium phosphate cement is starched only, so above-mentioned operation 5) terminate after, just can obtain that required magnesium phosphate cement sill finished product---magnesium phosphate cement is starched only, without the need to carrying out above-mentioned operation 6) operation.
With reference to shown in Fig. 1 ~ Fig. 7, for the ease of the enforcement of above-mentioned stirring technique, this example additionally provides a kind of whipping device of this technique of specially for carrying out, and this whipping device comprises:
Frame 1,
Be located at the first agitation vat 2 and the second agitation vat 3 in this frame 1,
With the first agitator that described first agitation vat 2 is supporting, and
With the second agitator that described second agitation vat 3 is supporting;
Described first agitation vat 2 is arranged in described frame 1 turningly, when the upset of this first agitation vat is toppled over can by it in the material deposited pour in described second agitation vat 3.
Said in the utility model " interior " and " outward " are all reference with Fig. 3, are inwardly " interior " in figure 3 perpendicular to paper, are outwards " outward " in figure 3 perpendicular to paper.
As shown in Figure 2, in the present embodiment, described first agitator comprises the first agitator motor 4, the motor shaft of this first agitator motor 4 is connected with the first agitating vane 5 stretched in described first agitation vat 2.In order to strengthen the mix ability of this first agitator, this first agitator also comprises a high-speed shearing machine 6, as shown in Fig. 3 and Fig. 2.
As shown in Figure 2, in the present embodiment, described second agitator comprises the second agitator motor 7, the motor shaft of this second agitator motor 7 is connected with the second agitating vane 8 stretched in described second agitation vat 3.In order to strengthen the mix ability of this second agitator, described second agitator also involving vibrations motor 9, this vibrating motor 9 is provided with the exciting rod 10 stretched in described second agitation vat 3.
In this example, described first agitation vat 2 can refer to shown in Fig. 2 with Fig. 2 with the concrete assembling mode between frame 1: the first column 11, first agitation vat 2 frame 1 being fixedly installed parallel distribution inside and outside two is overturn by rotating shaft 12 and is connected on these two first columns 11.For the ease of the upset of operator to the first agitation vat 2, this example is also provided with the first chain 13 and is in transmission connection with described rotating shaft 12, overturns motor 14 for the first agitation vat driving described first agitation vat 2 to make rotary movement in frame 1.
Because the first agitation vat upset motor 14 in this example is arranged in the lower position that personnel easily touch, in order to ensure personal security, avoid motor control of dust, this example is also furnished with the dust-proof protective cover 19 covered on outside described first agitation vat upset motor 14 in frame 1 simultaneously.
With reference to shown in Fig. 4, in order to operator can be poured out by the material in the second agitation vat 3 very easily, this example additionally uses following structure: frame 1 be provided with the second column 15 of parallel distribution inside and outside two and be arranged in the crossbeam 16 on these two second column 15 tops.The lower end being wherein positioned at that root second column 15 of inner side is fixed in frame 1, and the lower end being positioned at that root second column 15 in outside is connected in frame 1 by unidirectional hinge 17 upset.One end of described crossbeam 16 is connected to the top of that root second column 15 of inner side by hinge 18 upset, the other end of crossbeam 16 is supported on the top of that root second column 15 of outside.And that root second column 15 of outside is connected with the ripping bar 20 be positioned at below the second agitation vat 3.Described second agitator motor 7 and vibrating motor 9 are all fixedly installed on described crossbeam 16.
With reference to shown in Fig. 6 and Fig. 7, in practical application, after the stirring thing mix in the second agitation vat 3 completes, open crossbeam 16 in figure 6, thus make the second agitating vane 8 that the second agitator motor 7 connects remove outside the second agitation vat 3 with the exciting rod 10 that vibrating motor 9 is connected, then that root second column 15 in outside is opened downwards, under the effect of ripping bar 20, second agitation vat 3 is levered up and overturns and topple over, and then the material in the second agitation vat 3 is poured out, now the second agitation vat 3 to be supported on above the second column 15 (now the second column 15 laterally topples over layout) as Fig. 7.
After laterally toppling over to make the second column 15 can stable support on the ground, this example is provided with leg 25 in the upper end (taking Fig. 3 as reference) of the second column 15.
In addition, this example in frame 1, be provided with a bearing support 27, at the bottom of the bucket on this bearing support supporting seat 28 of being rotatably connected, to be fixed on barrel at the bottom of gear 29 on supporting seat and the stirring drive-motor 32 that is in transmission connection with described gear 29 by worm screw wheel box 30 and the second chain 31.On supporting seat 28 at the bottom of described second agitation vat 3 is supported on barrel, when stirring drive-motor 32 and running, it can drive the second agitation vat 3 to do and the rightabout rotary motion of described second agitating vane 8.In Fig. 1, arrow M represents the sense of rotation of the second agitation vat 3, and arrow N represents the sense of rotation of the second agitating vane 8.
And at the bottom of bucket at the bottom of supporting seat 28 and the second agitation vat bucket between be provided with staving upset snap ring 33, during to avoid work, the second agitation vat 3 departs from supporting seat 28 at the bottom of bucket.
As shown in Figure 6 and Figure 7, during in order to avoid opening that root second column 15 of outside downwards, second agitation vat 3 gets off from the second column 15 landing, this example is connected to the first constraint steel band 21 be enclosed within outside described second agitation vat 3 on that root second column 15 of outside, is connected with the second constraint steel band 22 be enclosed within the second agitation vat 3 on described ripping bar 20 simultaneously.
Refer again to shown in Fig. 2 and Fig. 3, conveniently operator are to the movement of this whipping device, and this example is also provided with several road wheels 23 in the bottom of frame 1, and wherein a part of road wheel 23 is universal wheel, and the road wheel 23 of rest part is one-way wheel.And push and pull bar 24 is provided with in frame 1.
For the ease of the Automated condtrol of operator to above-mentioned first agitator motor, the second agitator motor, high-speed shearing machine, vibrating motor and the first agitation vat upset motor, this example is also provided with the device control unit 26 overturning motor circuit with described first agitator motor, the second agitator motor, high-speed shearing machine, vibrating motor and the first agitation vat and be connected in frame 1, as shown in Figure 2.
This whipping device is used to implement the concrete steps of above-mentioned stirring technique as follows:
1) according to mix proportion design, quantitatively take the raw materials such as water, compound retarder, acid constituents, alkaline constituents, adulterant, be put in temporary containers for future use respectively.If mixing is magnesium phosphate cement mortar, magnesium phosphate cement concrete or fiber magnesium phosphate cement based composites, also need the aggregate taking certain component or/and fiber.
2) water and compound retarder are poured in the first agitation vat 2 shown in Fig. 2, open the first agitator motor 4 and stirred for 10 seconds, open high-speed shearing machine 6 mixing retarder solution 30 ~ 60 second, shears speed is 3000r/min ~ 4000r/min, closing high-speed shears, the first agitator motor 4 Keep agitation.
3) acid constituents is poured into first agitation vat 2, first agitator motor 4 Keep agitation 10 second, open high-speed shearing machine 6 fully dispersion acid constituents 60 ~ 90 second, closing high-speed shears 6 and the first agitator motor 4.
4) the stirring drive-motor 32 shown in Fig. 2 and the second agitator motor 7 is opened, open the first agitation vat upset motor 14 shown in Fig. 4 subsequently, first agitation vat 2 is toppled over to the second agitation vat 3 upset, thus by step 3) mixture that obtains pours the second agitation vat 3 into, after first agitation vat 2 topples over end, reversion first agitation vat overturns motor 14, recovers the position of the first agitation vat 2.
5) in step 4) in the second agitation vat, pour first stage mixture into while, alkaline constituents and adulterant is slowly added in the second agitation vat, throw in and terminate the vibrating motor 9 shown in rear unlatching Fig. 5, continue to stir and vibrated for 60 seconds ~ 90 seconds, close the second agitator motor and vibrating motor 9.
6) if mixing be magnesium phosphate cement mortar, magnesium phosphate cement concrete or fiber magnesium phosphate cement based composites, after above-mentioned alkaline constituents and adulterant Keep agitation 60 second, throw in aggregate or/and fiber and other material, and Keep agitation 60 seconds ~ 90 closes the second agitator motor and vibrating motor 9 after second, required magnesium phosphate cement sill finished product just can be obtained.
If mixing is that magnesium phosphate cement is starched only, so above-mentioned operation 5) terminate after, just can obtain that required magnesium phosphate cement sill finished product---magnesium phosphate cement is starched only, without the need to carrying out above-mentioned operation 6) operation.
7) as shown in Figure 6, upwards open crossbeam 16, thus the second agitating vane 8 that the second agitator motor 7 connects is removed outside the second agitation vat 3 with the exciting rod 10 that vibrating motor 9 is connected.
8) in figure 6, open that root second column 15 (this root second column is around unidirectional hinge rotary movement) in outside downwards, under the effect of ripping bar 20, second agitation vat 3 is levered up and overturns and topple over, and then the finished product materials in the second agitation vat 3 is poured out.Or directly this is followed leg 25 dischargings in material disc on the second column 15.
9) agitation vat and agitating vane is cleaned immediately.
The each link of above mixing, except discharging, all carries out sequencing setting and control by the device control unit 26 shown in Fig. 3.Step 4) in open the second agitator motor 7 be low rate mixing, too much air bubble can not be brought in the physics of follow-up stirring, and step 5) in the exciting rod of high-speed vibrator opened not only contribute to getting rid of the air bubble in mixture, more can liquefy MPC gelling material, improves MPC gelling material and aggregate, the wrapping of fiber interface, infiltration degree and cohesive strength.If multiple batches of compound continuously stirring, can in step 4) terminate water, the compound retarder of rear input next batch, by above-mentioned steps 4) ~ step 8) start repeatability stirring flow process, shorten the time of multiple batches of compound mixing thus, improve stirring efficiency.
This small-sized whipping device of this example is applicable to the compound of all employing two benches stirring techniques, but the mixture of first stage is preferably flow-like, to be suitable for using high shear agitation machine.
Technique effect checking embodiment one: MPC starches stirring only
This patent designer also uses equipment model machine of the present utility model, and mixing magnesium phosphate cement is starched only (being called for short MPC only to starch, is the one of magnesium phosphate cement sill), and the different alr mode of comparative analysis starches the impact of physical and mechanical properties only on MPC.
Table 1: the difference that magnesium phosphate cement is starched only stirs system
Wherein MPC only starches proportioning and is: (quality of compound retarder)/(quality of dead roasting magnesia powder)=11%, (quality of dead roasting magnesia powder)/(quality of PHOSPHORIC ACID TECH.GRADE potassium dihydrogen)=1:3, (quality of water)/(total mass of dead roasting magnesia powder and PHOSPHORIC ACID TECH.GRADE potassium dihydrogen)=0.12.
MPC adopts back taper method to test denseness immediately after only starching stirring, actual measurement consistometric value is as shown in table 1.According to the observation to whipping process, by the high speed shear emulsification to compound retarder, acid constituents potassium primary phosphate, improve the dissolution degree of potassium primary phosphate, thus increase liquid composition volume, and magnesia powder water insoluble, thus, the slurry actual measurement of emulsification pretreatment relative low rate mixing method gained is bored and is increased 83.3% times into the degree of depth, and the serviceability that MPC starches only is greatly improved.
Release with a large amount of heats in the acid-base neutralisation reaction process that MPC starches only, the process of its acid-base reaction can be understood by the change of temperature in test MPC hydration process.This experiment is under each stirring system listed by table 1, get 100g immediately after stirring MPC starches only to put into plastic cup, again plastic cup is put into thermos cup, plug rapidly previously prepd thermocouple thermometer, utilize automatic temp. recorder to record a temperature data every 1min, continuously tested 24h.By peak value size and the corresponding time point of the temperature curve of test, analyze different stirring system starches heat evolution velocity only impact on MPC.
Table 2: the clean pulp-water temperature curve eigenwert under different stirring system
Fig. 8 is the hydration temperature curve of MPC slurry, and owing to being mixed with the obvious compound retarder of retarding effect, the presetting period that MPC starches only is greater than 30min, and hydration temperature curve all has two temperature peaks and a resting stage, and initial temperature peak is lower than 30 DEG C.Rapid stirring and emulsification pretreatment improve dispersion and the dissolution degree of potassium primary phosphate component, make to produce more H in solution +, the equation of potassium primary phosphate hydrolysis is shown below:
MgO ionizes in an acidic solution, and equation is shown below:
MgO+H 2O→MgOH ++OH -(3-3)
MgOH ++2H 2O→Mg(OH) 2+H 3O +(3-4)
Mg(OH) 2→Mg 2++2OH -(3-5)
Obviously, the acidity of solution is larger, and the electrolysis Shaoxing opera of MgO can be impelled strong, and the heat of generation is more.Show according to observed temperature data calculating parameter in the temperature variation curve of Fig. 2 and table 2, to the emulsification pretreatment of potassium primary phosphate in advance, relatively common low rate mixing mode, facilitate the ionization of MgO, first temperature rise peak value and corresponding moment improve 2.5 DEG C and accelerate 0.11h respectively, and temperature rise rate improves 0.2 DEG C/min.Mg in the solution 2+when reaching certain value with phosphoric acid hydrogen radical ion concentration, just there is following reaction:
But due to a large amount of generation and the precipitation of the retards MgKPO46H20 of compound retarder, the resting stage on temperature development curve has been there is after MgO ionizes heat release in a large number, but it is more abundant that emulsification pretreatment makes potassium primary phosphate be hydrolyzed, more phosphate anion breaks through the constraint of retardant, accelerates and Mg (aq) 2+and K +reaction, the mixture relative low rate mixing mixture that emulsification is in advance sheared to shorten resting stage 0.27h, the temperature rise of second time aquation speed exceeds 0.23 DEG C/min, temperature rise curve peak value improves 4.3 DEG C.Aquation generates the ionization heat release of thermal discharge apparently higher than MgO of MgKPO46H20, and two temperature rise curve peak values of low rate mixing and acid constituents emulsification pretreatment two kinds of alr modes improve 12.5 DEG C and 14.3 DEG C respectively.With the carrying out of MPC hydration reaction, free water reduces rapidly, and the MgKPO46H20 gel pack produced is rolled in MgO surface, stops the hydrolysis of MgO and follow-up hydration reaction, MgKPO46H20 gel phase lap connects formation network structure, makes MPC slurry rapid curing one-tenth high strength hardenite.
Table 3: the intensity of clean slurry different larval instar
Only test specimen is starched, the folding strength of test different larval instar and ultimate compression strength, as shown in Table 3 and Figure 2 by stirring system shaping 25mm × 25mm × 280mm listed by table 1.Test result shows, to compound retarder and the existing emulsification pretreatment of MPC acid constituents, acid-base reaction can be made more abundant, and the mortar strength of the relative low rate mixing of intensity in each length of time all increases.For folding strength, emulsification pretreatment premixing makes early stage folding strength amplification relatively large, reaches about 16%; For ultimate compression strength, emulsification pretreatment makes the ultimate compression strength amplification in later stage relatively large, reaches about 20%.
Technique effect checking embodiment two: MPC mortar stirs
This patent designer uses above-mentioned whipping device model machine, mixing magnesium phosphate cement (MPC) mortar, the standard rubber sand test specimen of shaping 40mm × 40mm × 160mm, and the different alr mode of comparative analysis is on the impact of MPC mortar slurry mechanical property.MPC mortar mix ratio is: (quality of compound retarder)/(total mass of dead roasting magnesia powder and adulterant)=11%, (quality of dead roasting magnesia powder)/(quality of PHOSPHORIC ACID TECH.GRADE potassium dihydrogen)=1:2, (quality of water)/(total mass of dead roasting magnesia powder and PHOSPHORIC ACID TECH.GRADE potassium dihydrogen)=0.17, (quality of mixed sand)/(total mass of dead roasting magnesia powder and PHOSPHORIC ACID TECH.GRADE potassium dihydrogen)=1.5:1, wherein, mixed sand is mixed by the Machine-made Sand of particle diameter 1.18mm ~ 4.75mm and the yellow sand of 0.3mm ~ 2.36mm, (quality of Machine-made Sand)/(quality of yellow sand)=1:1.
For the different alr mode of comparative analysis is on the impact of MPC mortar strength, design four shown in table 4 kind stir system, with identical proportioning mixing MPC mortar, existing side by side is shaping standard rubber sand test specimen, under room temperature, natural curing is to different larval instar, test anti-folding and ultimate compression strength, observed strength is as shown in table 5 and Figure 10.
The difference of table 4:MPC sand-cement slurry stirs system
Table 5: different alr mode is on the impact of MPC mortar strength
MPC mortar observed strength is shown, emulsification pretreatment is carried out to compound retarder and MPC acid constituents, or use high-frequency vibration when mixing mortar, be all conducive to the abundant reaction of MPC Components of Acid-Base, thus promote the development of intensity.And emulsification pretreatment and high-frequency vibration use simultaneously, the early anti pressured intension of MPC mortar can be improved greatly, search to the bottom the dissolving of high degree of reason MPC acid constituents and dispersion, MPC gelling material to fully the wrapping of aggregate, moistening and bonding, and decrease air bubble, make shaping test specimen finer and close.
Certainly, above-described embodiment, only for technical conceive of the present utility model and feature are described, its object is to people can be understood content of the present utility model and implement according to this, can not limit protection domain of the present utility model with this.All equivalent transformations of doing according to the spirit of the utility model main technical schemes or modification, all should be encompassed within protection domain of the present utility model.

Claims (10)

1. be applicable to a whipping device for cement-based material two benches stirring technique, it is characterized in that this stirrer comprises:
Frame (1),
Be located at the first agitation vat (2) in this frame (1) and the second agitation vat (3),
With the first agitator that described first agitation vat (2) is supporting, and
With the second agitator that described second agitation vat (3) is supporting;
Described first agitation vat (2) is arranged in described frame (1) turningly, when the upset of this first agitation vat is toppled over can by it in the material deposited pour in described second agitation vat (3).
2. the whipping device being applicable to cement-based material two benches stirring technique according to claim 1, it is characterized in that: described first agitator comprises the first agitator motor (4), the motor shaft of this first agitator motor (4) is connected with the first agitating vane (5) stretched in described first agitation vat (2).
3. the whipping device being applicable to cement-based material two benches stirring technique according to claim 2, is characterized in that: described first agitator also comprises high-speed shearing machine (6).
4. the whipping device being applicable to cement-based material two benches stirring technique according to claim 1, it is characterized in that: described second agitator comprises the second agitator motor (7), the motor shaft of this second agitator motor (7) is connected with the second agitating vane (8) stretched in described second agitation vat (3).
5. the whipping device being applicable to cement-based material two benches stirring technique according to claim 1, it is characterized in that: described second agitator is involving vibrations motor (9) also, this vibrating motor (9) is provided with the exciting rod (10) stretched in described second agitation vat (3).
6. the whipping device being applicable to cement-based material two benches stirring technique according to claim 1, it is characterized in that: the first column (11) described frame (1) being fixedly installed parallel distribution inside and outside two, described first agitation vat (2) is connected on these two first columns (11) by rotating shaft (12) upset.
7. the whipping device being applicable to cement-based material two benches stirring technique according to claim 6, is characterized in that: described frame (1) is also provided with the first chain (13) and is in transmission connection with described rotating shaft (12), overturns motor (14) for the first agitation vat driving described first agitation vat (2) to make rotary movement.
8. the whipping device being applicable to cement-based material two benches stirring technique according to claim 6, is characterized in that: described frame (1) is furnished with and covers on described first agitation vat upset motor (14) dust-proof protective cover outward (19).
9. the whipping device being applicable to cement-based material two benches stirring technique according to claim 1, it is characterized in that: the second column (15) described frame (1) being provided with parallel distribution inside and outside two, and be arranged in the crossbeam (16) on these two second column (15) tops, the lower end being wherein positioned at that root second column (15) of inner side is fixed in frame (1), and the lower end being positioned at that root second column (15) in outside is connected in frame (1) by unidirectional hinge (17) upset, one end of described crossbeam (16) is connected to the top of that root second column (15) of inner side by hinge (18) upset, the other end of crossbeam (16) is supported on the top of that root second column (15) of outside, and that root second column (15) of outside is connected with the ripping bar (20) being positioned at described second agitation vat (3) below, described second agitator is fixed on described crossbeam (16).
10. the whipping device being applicable to cement-based material two benches stirring technique according to claim 9, it is characterized in that: that root second column (15) of outside is connected with and is enclosed within the first constraint steel band (21) outward of described second agitation vat (3), described ripping bar (20) is connected with the second constraint steel band (22) be enclosed within the second agitation vat (3).
CN201520378966.9U 2015-06-04 2015-06-04 Be applicable to the whipping device of cement-based material two benches stirring technique Expired - Fee Related CN204689900U (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109129918A (en) * 2018-09-05 2019-01-04 刘丽军 A kind of multifunction simple interior decoration cement blender
CN112171889A (en) * 2020-09-28 2021-01-05 杭州金知科技有限公司 A multicomponent stirring mixing arrangement for building material production
CN112549290A (en) * 2020-12-03 2021-03-26 贵州新中水工程有限公司 Mixing method and system for ensuring magnesium oxide distribution uniformity in concrete mixture

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109129918A (en) * 2018-09-05 2019-01-04 刘丽军 A kind of multifunction simple interior decoration cement blender
CN109129918B (en) * 2018-09-05 2020-09-18 山东淄建集团有限公司 Multi-functional simple and easy cement mixer for interior decoration
CN112171889A (en) * 2020-09-28 2021-01-05 杭州金知科技有限公司 A multicomponent stirring mixing arrangement for building material production
CN112549290A (en) * 2020-12-03 2021-03-26 贵州新中水工程有限公司 Mixing method and system for ensuring magnesium oxide distribution uniformity in concrete mixture

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