CN204672126U - A kind of multistage multiple spot efficient oxidation blast furnace or heating system fire coal absorb denitrification apparatus - Google Patents

A kind of multistage multiple spot efficient oxidation blast furnace or heating system fire coal absorb denitrification apparatus Download PDF

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Publication number
CN204672126U
CN204672126U CN201520339319.7U CN201520339319U CN204672126U CN 204672126 U CN204672126 U CN 204672126U CN 201520339319 U CN201520339319 U CN 201520339319U CN 204672126 U CN204672126 U CN 204672126U
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tower
oxidative absorption
absorption tower
denitrating
counter direction
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CN201520339319.7U
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武晓冬
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Abstract

The utility model is that a kind of multistage multiple spot efficient oxidation blast furnace or heating system fire coal absorb denitrification apparatus, described denitrification apparatus comprises oxidative absorption tower, denitrating tower, described oxidative absorption tower, denitrating tower is the cylindrical shell of hollow, the inside of described oxidative absorption tower is respectively arranged with cyclone mixer under upper, NaOH atomising device, counter direction jet trays, described denitrating tower inside is divided into upper and lower two parts, counter direction jet trays is set, NaOH atomising device, cyclone mixer, the top of described oxidative absorption tower, ozone generator is respectively arranged with between the top and the bottom of connecting pipe and described denitrating tower, fully nitrogen oxide is absorbed by the combination of counter direction jet trays, NaOH and cyclone mixer, is divided into three groups progressively to carry out once, secondary, three times absorb, finally reach denitration rate and reach more than 90%.Solve the pollution problem of nitrogen oxide.

Description

A kind of multistage multiple spot efficient oxidation blast furnace or heating system fire coal absorb denitrification apparatus
Technical field
The utility model relates to a kind of denitrification apparatus, refers in particular to a kind of multistage multiple spot efficient oxidation blast furnace or heating system fire coal absorption denitrification apparatus.
Background technology
At present, the ratio 78%, 21% of our known air is oxygen, 1% is other inert gas.Oxygen at normal temperatures, nitrogen does not react, so human body oxygen intake, nitrogen are safe from harm, and air produces a large amount of nitrogen oxide in high-temp combustion, NOx has toxicity after being sucked by human body, destroys serious, affect the blood oxygen carrying capacity of people to the respiratory system of people, cause multiple diseases simultaneously, people can be caused time serious and be poisoned to death.Although the NOx that nature is produced by soil, ocean, thunder and lightning, volcano eruption etc. is flood tide, because its distribution is wide, be inappreciable impact on human body.Create a large amount of NOx concentration large, but in the fume emission region of the coal-burning boilers such as industrial production, generating, heating, mostly be the compact district of people, so large to harm, effective method must be taked to administer.Need a kind of multistage multiple spot efficient oxidation blast furnace or heating system fire coal absorption denitrification apparatus badly, solve the pollution problem of nitrogen oxide.
Summary of the invention
The purpose of this utility model is to provide a kind of multistage multiple spot efficient oxidation blast furnace or heating system fire coal to absorb denitrification apparatus, solves the pollution problem of nitrogen oxide.
The utility model adopts following technical scheme:
A kind of multistage multiple spot efficient oxidation absorbs denitrification apparatus, comprising: desulfurizing tower (10), dewater unit (20), and described desulfurizing tower (10) bottom is provided with gas approach; Also comprise oxidative absorption tower (1), denitrating tower (2), described desulfurizing tower (10) top is provided with pipeline communication oxidative absorption tower (1) top, the bottom of described oxidative absorption tower (1) is communicated with by connecting pipe (3) with the bottom of described denitrating tower (2), and described denitrating tower (2) top is provided with pipeline communication dewater unit (20) top;
Described oxidative absorption tower (1), denitrating tower (2) is the cylindrical shell of hollow, the inside of described oxidative absorption tower (1) is respectively arranged with cyclone mixer (4) under upper, NaOH atomising device (5), counter direction jet trays (6), described denitrating tower (2) inside is divided into, lower two parts, on, lower part arranges counter direction jet trays (6) respectively from top to bottom, NaOH atomising device (5), cyclone mixer (4), top in described oxidative absorption tower (1), connecting pipe (3) neutralizes the upper of described denitrating tower (2), ozone generator (7) is respectively arranged with between bottom,
Described cyclone mixer (4) is the cylinder being furnished with flabellum (41) along inwall circumferential row, the arrangement center of described flabellum (41) is connected with the concentric cylinder (42) be socketed with described cylinder, and described counter direction jet trays (6) is for there being the cylinder of multiple upper and lower inclined hole (61).
By three the described ozone generators arranged in oxidative absorption tower (1) to denitrating tower (2), the ozone that order manufactures 50%, 30%, 20% successively is respectively set by above-mentioned.
Advantage of the present utility model is as follows:
1. fully nitrogen oxide is absorbed by the combination of counter direction jet trays, NaOH and cyclone mixer, is divided into three groups progressively to carry out once, secondary, three times absorb, finally reach denitration rate and reach more than 90%.
2. counter direction jet trays and cyclone mixer slow down course of reaction, add the reaction time, make reaction more abundant.
3. simple and reasonable for structure.
Accompanying drawing illustrates:
Fig. 1 is the utility model anatomical connectivity relation schematic diagram;
Fig. 2 is the structural representation of the utility model counter direction jet trays top view;
Fig. 3 is the structural representation of the utility model counter direction jet trays sectional view;
Fig. 4 is the structural representation of the utility model cyclone mixer;
Detailed description of the invention
Below in conjunction with accompanying drawing, detailed description of the invention of the present utility model is described further.
Following examples are only be clearly this example of utility model, and the restriction not to embodiment of the present utility model.For those of ordinary skill in the field; can also make other multi-form change or variations on the basis of the following description, and these belong to the utility model spirit apparent change of drawing or variation is still among protection domain of the present utility model.
A kind of multistage multiple spot efficient oxidation blast furnace or heating system fire coal absorb denitrification apparatus, comprising: desulfurizing tower 10, dewater unit 20, are provided with gas approach bottom described desulfurizing tower 10; Also comprise oxidative absorption tower 1, denitrating tower 2, described desulfurizing tower 10 top is provided with pipeline communication oxidative absorption tower 1 top, the bottom of described oxidative absorption tower 1 is communicated with by connecting pipe 3 with the bottom of described denitrating tower 2, and described denitrating tower 2 top is provided with pipeline communication dewater unit 20 top;
Described oxidative absorption tower 1, denitrating tower 2 are the cylindrical shell of hollow, the inside of described oxidative absorption tower 1 is respectively arranged with cyclone mixer 4 under upper, NaOH atomising device 5, counter direction jet trays 6, described denitrating tower 2 inside is divided into upper and lower two parts, upper and lower part arranges counter direction jet trays 6, NaOH atomising device 5, cyclone mixer 4 respectively from top to bottom, is respectively arranged with ozone generator 7 in the top in described oxidative absorption tower 1, connecting pipe 3 and between the upper and lower part of described denitrating tower 2;
Described cyclone mixer 4 is the cylinder being furnished with flabellum 41 along inwall circumferential row, and the arrangement center of described flabellum 41 is connected with the concentric cylinder 42 be socketed with described cylinder, and described counter direction jet trays 6 is for there being the cylinder of multiple upper and lower inclined hole 61.
By three the described ozone generators arranged in oxidative absorption tower 1 to denitrating tower 2, the ozone that order manufactures 50%, 30%, 20% successively is respectively set by above-mentioned.
In the middle of flue gas, NOx main component is NO (accounting for 95%).NO is insoluble in water, and high-valence state NO 2, N 2o 5deng water soluble.This device is after flue-gas dust-removing and desulfurization, and to a kind of method that NO administers, this method adopts oxidative absorption method, utilizes ozone, as strong oxidizer, NO is oxidized to high price NOx soluble in water, absorbs NOx adding NaOH as absorbent.
Absorption reaction equation is as follows:
2NaOH+2NO=NaNO 3+NaNO 2+H 2O
2NaOH+NO 2=2NaNO 3+H 2O
In actual use procedure, first the flue gas after dust-removal and desulfurizing is introduced oxidative absorption tower 1 by pipeline and carry out oxidation processes.Ozone generator 7 now discharge content be 50% ozone and described flue gas react, then mix by during described cyclone mixer 4, after ozone and the NO in described flue gas fully being contacted form high-valence state NOx, reactive absorption is carried out again by the NaOH of atomization, counter direction jet trays 6 makes flue gas secondary response more again by inclined hole, add the reaction time, make reaction more abundant.
Flue gas continues to enter denitrating tower 10 by pipeline, is reacted by identical ozone, and cyclone mixer 4 mixes, and NaOH absorbs again, and counter direction jet trays 6 continues to extend the reaction time.By the oxidative absorption of three times, make the denitration rate of NOx reach more than 90%, thus reach the requirement of national environmental protection method to NOx emission index.

Claims (2)

1. multistage multiple spot efficient oxidation blast furnace or heating system fire coal absorb a denitrification apparatus, comprising: desulfurizing tower (10), dewater unit (20), and described desulfurizing tower (10) bottom is provided with gas approach; It is characterized in that: also comprise oxidative absorption tower (1), denitrating tower (2), described desulfurizing tower (10) top is provided with pipeline communication oxidative absorption tower (1) top, the bottom of described oxidative absorption tower (1) is communicated with by connecting pipe (3) with the bottom of described denitrating tower (2), and described denitrating tower (2) top is provided with pipeline communication dewater unit (20) top;
Described oxidative absorption tower (1), denitrating tower (2) is the cylindrical shell of hollow, the inside of described oxidative absorption tower (1) is respectively arranged with cyclone mixer (4) under upper, NaOH atomising device (5), counter direction jet trays (6), described denitrating tower (2) inside is divided into, lower two parts, on, lower part arranges counter direction jet trays (6) respectively from top to bottom, NaOH atomising device (5), cyclone mixer (4), top in described oxidative absorption tower (1), connecting pipe (3) neutralizes the upper of described denitrating tower (2), ozone generator (7) is respectively arranged with between bottom,
Described cyclone mixer (4) is the cylinder being furnished with flabellum (41) along inwall circumferential row, the arrangement center of described flabellum (41) is connected with the concentric cylinder (42) be socketed with described cylinder, and described counter direction jet trays (6) is for there being the cylinder of multiple upper and lower inclined hole (61).
2. one according to claim 1 multistage multiple spot efficient oxidation blast furnace or heating system fire coal absorb denitrification apparatus, it is characterized in that: arrange by above-mentioned the ozone that order manufactures 50%, 30%, 20% successively respectively by three the described ozone generators arranged in oxidative absorption tower (1) to denitrating tower (2).
CN201520339319.7U 2015-05-22 2015-05-22 A kind of multistage multiple spot efficient oxidation blast furnace or heating system fire coal absorb denitrification apparatus Expired - Fee Related CN204672126U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106139852A (en) * 2016-08-29 2016-11-23 中国恩菲工程技术有限公司 Benitration reactor
CN107185398A (en) * 2017-03-22 2017-09-22 傅国琳 A kind of system and its method of work for administering boiler smoke

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106139852A (en) * 2016-08-29 2016-11-23 中国恩菲工程技术有限公司 Benitration reactor
CN107185398A (en) * 2017-03-22 2017-09-22 傅国琳 A kind of system and its method of work for administering boiler smoke

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CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20150930

Termination date: 20180522

CF01 Termination of patent right due to non-payment of annual fee