CN204550200U - Municipal effluent denitrogenation dephosphorizing treatment system - Google Patents
Municipal effluent denitrogenation dephosphorizing treatment system Download PDFInfo
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- CN204550200U CN204550200U CN201520146819.9U CN201520146819U CN204550200U CN 204550200 U CN204550200 U CN 204550200U CN 201520146819 U CN201520146819 U CN 201520146819U CN 204550200 U CN204550200 U CN 204550200U
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- transfer lime
- contact reacts
- mixed
- membrane bioreactor
- pond
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- Separation Using Semi-Permeable Membranes (AREA)
- Activated Sludge Processes (AREA)
Abstract
The utility model belongs to water treatment field.Municipal effluent denitrogenation dephosphorizing treatment system, it comprises the first transfer lime, contact reacts pond, sponge iron, the second transfer lime, membrane bioreactor, compressed air pipe, aeration head, mixed-liquor return pipe, reflux pump, the time relay, mixed solution delivery pipe, the 3rd transfer lime, suction pump; Contact reacts pond is built with sponge iron; The input terminus of mixed-liquor return pipe is connected logical with the bottom water outlet of membrane bioreactor, the output terminal of mixed-liquor return pipe is connected logical with the water-in in contact reacts pond.This treatment system cost is low, water treatment efficiency good, particularly high to nitrogen, phosphoric and organic removal rate in sewage, make COD and nitrogen in the water outlet after process, the content of phosphorus can reach " urban wastewater treatment firm pollutant emission standard " (GB 18918-2002) first discharge standard A standard.
Description
Technical field
The utility model belongs to water treatment field, is specifically related to a kind for the treatment of system of new sewage denitrification and dephosphorization.
Background technology
Nitrogen and phosphorus are the important substance causing body eutrophication and environmental pollution.In China, nitrogen and phosphorus pollution oneself become the primary index affecting surface water quality of water environment.Biochemical wastewater treatment technology is the major technique in sewage disposal, cost-effective in section as one, is preventing water pollution, improves function of water body aspect and plays extremely important effect.
A
2/ 0 technique is own through being widely used in urban wastewater treatment firm, it is good to the removal effect of COD, but Nitrogen/Phosphorus Removal haves much room for improvement, particularly dephosphorization, in water outlet after process, the content of phosphorus is often higher than 0.5mg/L, first discharge standard A standard that water outlet does not reach " urban wastewater treatment firm pollutant emission standard " (GB 18918-2002), conventional terms of settlement is at A
2add chemical agent in water outlet after/0 art breading and chemical precipitation removal is carried out to phosphorus; but the problem such as have that chemical consumption amount is large, the large and cost of sludge yield is higher; simultaneously due to the fluctuation of phosphorus concentration of intaking, often to there will be adding of agent excessive, has the risk bringing secondary pollution.In addition in operational process, energy consumption and material consumption are all higher, second pond is adopted to carry out mud-water separation in its treatment process, solid-liquid separation efficiency is low, sludge condensation weak effect, the activated sludge concentration being back to anaerobic pond can only maintain 2000mg/L ~ 3000mg/L, makes the microorganism in biochemical reaction tank be difficult to maintain higher concentration, causes sewage work's processing power to be in lower level all the time.Although biochemical wastewater treatment technique is constantly upgraded in recent years, but it is large to the process ubiquity investment of nitrogen, phosphoric and hardly degraded organic substance, the problem that effect is undesirable, therefore, improve biochemical wastewater treatment effect, the particularly treatment effect of nitrogen, phosphorus, reducing running cost, is subject matter urgently to be resolved hurrily in current biochemical wastewater treatment.
Summary of the invention
Problem to be solved in the utility model is to provide a kind of municipal effluent denitrogenation dephosphorizing treatment system, this treatment system cost is low, water treatment efficiency good, particularly high to nitrogen, phosphoric and organic removal rate in sewage, make COD and nitrogen in the water outlet after process, the content of phosphorus can reach " urban wastewater treatment firm pollutant emission standard " (GB 18918-2002) first discharge standard A standard.
For achieving the above object, technical solution adopted in the utility model is: municipal effluent denitrogenation dephosphorizing treatment system, and it comprises the first transfer lime, contact reacts pond, sponge iron, the second transfer lime, membrane bioreactor, compressed air pipe, aeration head, mixed-liquor return pipe (or claiming mud mixed liquid return line), reflux pump (or claiming mud mixed liquid reflux pump), the time relay, mixed solution delivery pipe (or claiming mud mixed liquid delivery pipe), the 3rd transfer lime, suction pump;
The input termination of the first transfer lime is through pretreated municipal effluent (i.e. sanitary sewage), the output terminal of the first transfer lime is communicated with the bottom water-in in contact reacts pond, contact reacts pond is built with sponge iron, the input terminus of the second transfer lime is connected logical with the top water outlet in contact reacts pond, the output terminal of the second transfer lime is connected logical with the water-in of membrane bioreactor, be provided with MBR separatory membrane in membrane bioreactor and (or claim MBR film, membrane module), the input terminus of the 3rd transfer lime is connected logical with the water outlet of MBR separatory membrane, water outlet after the direct output processing of output terminal of the 3rd transfer lime, 3rd transfer lime is provided with suction pump, the bottom of membrane bioreactor is provided with aeration head, and aeration head is connected logical with compressed air pipe, the input terminus of mixed-liquor return pipe is connected logical with the bottom water outlet of membrane bioreactor, the output terminal of mixed-liquor return pipe is connected logical with the water-in in contact reacts pond, mixed-liquor return pipe is provided with reflux pump, the time relay is connected with reflux pump by control circuit, be provided with mixed solution delivery pipe bottom the pond of membrane bioreactor, mixed solution delivery pipe (or claiming active sludge intermixture delivery pipe) is provided with manually-operated gate (regular spoil disposal).
Principle of the present utility model following (utilize contact reacts and the combination of MBR membrane biological reaction, and carry out mud mixing to have a rest night the technique of reflow treatment municipal effluent):
1) first: through pre-treatment (with grid interception floating matter and settling pit to municipal effluent in part inorganic suspended particles thing carry out the pre-treatment such as precipitation) after municipal effluent enter contact reacts pond by the first transfer lime, granular sponge iron is provided with as filler in contact reacts pond, the alloy that sponge iron is made up of iron and carbon, namely by pure iron and Fe
3c and some impurity composition, Fe
3c and other impurity particles are dispersed in sponge iron with the form of minimum particle, because their electropotential is than the height of iron, numerous galvanic cell is just defined when being in electrolyte solution, and sponge iron to have porosity because of its special loose spongy structure high, the feature that specific surface area is large, specific surface energy is high, thus has stronger electrochemistry enrichment, redox, physical adsorption and flocculation sediment performance.When effluent stream is through contact reacts pond, following reaction can be there is:
Anode: Fe → Fe
2++ 2e-
Negative electrode: 2H under acidic conditions
++ 2e-→ 2 [H] → H
2↑
Alkalescence or neutrallty condition under 0
2+ 2H
20+4e → 40H
-
The nascent state [H] that electrode reaction produces and Fe
2+can with the organic pollutant generation redox reaction in waste water, meanwhile, anodic product Fe
2+and Fe
3+with OH
-the Fe (OH) formed
2with Fe (OH)
3there is stronger coagulation, under precipitation, flocculation, absorption and the volume effect of sweeping etc., the organism in municipal effluent (waste water), nitrogen, phosphorus concentration are significantly reduced.
Greatly, therefore use sponge iron as the carrier filler in contact reacts pond (or claiming biochemical reactor) because sponge iron has adsorption surface area, sufficient space can be provided on the one hand for the enrichment and growth of microorganism, for collaborative, the symbiosis of double oxygen various in biochemical reactor and anaerobion provide good " microenvironment ", ensure that carrying out smoothly of anoxic denitrification denitrogenation, also ensure that carrying out smoothly of anaerobic phosphorus release simultaneously, for follow-up aerobic suction phosphorus provides sufficient condition, ensure that phosphoric is effectively removed.
2) through contact reacts pond, reacted water outlet gravity flow enters membrane bioreactor, membrane bioreactor or claim membrane biological reaction pond) in be provided with MBR separating film module, the nitrifier that MBR separating film module energy effectively catching generation time is longer, and make to keep higher sludge concentration in membrane biological reaction pond.Under aerobic condition, complete microorganism remove organic matter degradation, complete nitration reaction and aerobic suction phosphorus.
3) mixed-liquor return pipe, reflux pump is utilized to be back in contact reacts pond off and on by the mud mixed liquid in membrane bioreactor, when reflux pump refluxes, mud mixed liquid has brought a certain amount of oxygen into and nitrate nitrogen enters contact reacts pond, at this moment contact reacts pond is in anoxic condition, and nitric nitrogen is now converted into nitrogen through denitrification and is removed.When reflux pump stops backflow, the oxygen in contact reacts pond is depleted gradually and enters anaerobic state, and the microorganism now in contact reacts pond carries out anaerobic phosphorus release and puts aside the power of follow-up aerobic suction phosphorus.Simultaneously under anaerobic condition, the organic acid that the organism in contact reacts pond produces in anaerobic hydrolysis process makes the PH of waste water between 5.6 ~ 6.8, and makes electrode reaction 2Fe+4H
+→ 2Fe
2+the balance of+4 [H] moves right, and nascent state [H] increases, and increases with the chance of Organic Pollutants in Wastewater matter generation redox reaction.Larger molecular organics can be degraded into more small-molecule substance, be convenient to be degraded by microorganisms removal in follow-up membrane bioreactor.
Like this in whole treatment scheme, microflora can experience anoxic, anaerobism, aerobic stage successively on space-time, thus nitrated and denitrification, anaerobic phosphorus release, aerobic suction phosphorus and organic matter degradation are strengthened.
Carried out qualified discharge after solid-liquid separation by MBR separatory membrane under the suction function of waste water suction pump in membrane bioreactor of above-mentioned art breading flow process.Suction pump adopts intermittent operation mode, controlled by the time relay, open 8min (adjustable), stop 3min (adjustable), intermittent suction operator scheme is adopted to be intended to be filtered by regular stopper film, make deposition mud on the surface of the film come off out from film surface under hydraulic action, the strainability of film is recovered.
The beneficial effects of the utility model are: adopt contact reacts pond and membrane bioreactor (or claiming membrane biological reaction pond) composite processing system, this system carries out intermittent cycle by controlling active sludge intermixture flexibly between membrane biological reaction pond, contact reacts pond, make microbial population experience anoxic, anaerobism, aerobic stage successively on space-time, thus reach the object of intensified denitrification and dephosphorization.Sponge iron in the utility model can commercially directly be bought, structures are simple, and the equipment of needs is few, flexible operation, and according to the change of flooding quantity and water quality, effluent quality can be met by adjustment aeration rate, mixed solution (or claiming active sludge intermixture) quantity of reflux etc.Water outlet is made to meet " urban wastewater treatment firm pollutant emission standard " (GB 18918-2002) first discharge standard A standard.
This treatment system cost is low, water treatment efficiency good, degradation speed is fast, particularly high to nitrogen, phosphoric and organic removal rate in sewage, make COD and nitrogen in the water outlet after process, the content of phosphorus can reach " urban wastewater treatment firm pollutant emission standard " (GB 18918-2002) first discharge standard A standard.
Accompanying drawing explanation
Fig. 1 is the structural representation of the utility model municipal effluent denitrogenation dephosphorizing treatment system.
In figure: 1-first transfer lime; 2-contact reacts pond; 3-sponge iron; 4-second transfer lime; 5-membrane bioreactor; 6-MBR separatory membrane; 7-compressed air pipe; 8-aeration head; 9-mixed-liquor return pipe; 10-reflux pump; The 11-time relay; 12-mixed solution delivery pipe; 13-the 3rd transfer lime; 14-suction pump.
Embodiment
In order to understand the utility model better, illustrate content of the present utility model further below in conjunction with embodiment, but content of the present utility model is not only confined to the following examples.
As shown in Figure 1, municipal effluent denitrogenation dephosphorizing treatment system, it comprises the first transfer lime 1, contact reacts pond 2, sponge iron 3, second transfer lime 4, membrane bioreactor 5, compressed air pipe 7, aeration head 8, mixed-liquor return pipe (or claiming mud mixed liquid return line) 9, reflux pump (or claiming mud mixed liquid reflux pump) 10, the time relay 11, mixed solution delivery pipe (or claiming mud mixed liquid delivery pipe) the 12, the 3rd transfer lime 13, suction pump 14;
The input termination of the first transfer lime 1 is through pretreated municipal effluent (i.e. sanitary sewage), the output terminal of the first transfer lime 1 is communicated with the bottom water-in in contact reacts pond 2, contact reacts pond 2 is built with sponge iron 3, the input terminus of the second transfer lime 4 is connected logical with the top water outlet in contact reacts pond 2, the output terminal of the second transfer lime 4 is connected logical with the water-in of membrane bioreactor 5, be provided with MBR separatory membrane in membrane bioreactor 5 and (or claim MBR film, membrane module) 6, the input terminus of the 3rd transfer lime 13 is connected logical with the water outlet of MBR separatory membrane 6, water outlet after the direct output processing of output terminal of the 3rd transfer lime 13, 3rd transfer lime 13 is provided with suction pump 14, the bottom of membrane bioreactor 5 is provided with aeration head 8, and aeration head 8 is connected logical with compressed air pipe 7, the input terminus of mixed-liquor return pipe 9 is connected logical with the bottom water outlet of membrane bioreactor 5, the output terminal of mixed-liquor return pipe 9 is connected logical with the water-in in contact reacts pond 2, mixed-liquor return pipe 9 is provided with reflux pump 10, the time relay 11 is connected with reflux pump 10 by control circuit, be provided with mixed solution delivery pipe 12 bottom the pond of membrane bioreactor 5, mixed solution delivery pipe (or claiming active sludge intermixture delivery pipe) 12 is provided with manually-operated gate (regular spoil disposal).
As shown in Figure 1, a kind of new municipal effluent denitrogenation dephosphorizing treatment process, it comprises the steps:
1) municipal effluent denitrogenation dephosphorizing treatment system is prepared;
2) enter contact reacts pond through pretreated municipal effluent by the first transfer lime, adopt water intake mode from bottom to top, the reaction times of municipal effluent in contact reacts pond (or claiming biological contact chamber) is 4 ~ 6 hours; The particle diameter of the sponge iron in contact reacts pond is 2 ~ 6mm, and the packing height of sponge iron is 1500 ~ 2000mm;
3) through contact reacts pond, reacted water outlet gravity flow enters membrane bioreactor, and the hydraulic detention time of membrane bioreactor (or claiming MBR membrane biological reaction pond) is 5 ~ 8 hours, and the sludge loading of membrane bioreactor is 0.3 ~ 0.5kgCOD/kgMLSS d; Continue in membrane bioreactor to pass into pressurized air, make the content of dissolved oxygen in membrane bioreactor remain on 3 ~ 4mg/L;
4) mixed-liquor return pipe, reflux pump is utilized to be back in contact reacts pond off and on by the mud mixed liquid in membrane bioreactor, reflux pump is cycling service, under the time relay controls, 1 ~ 2h(is adjustable for each periodic duty 0.5 ~ 1 h (adjustable), stoppage in transit), return current ratio of the mixed liquid is that 200% ~ 400%(is adjustable); Water outlet carries out qualified discharge after solid-liquid separation by MBR separatory membrane under the suction function of suction pump.
Described sponge iron is made up of following raw material weight per-cent: full iron 78 ~ 95%; Manganese: 0.26 ~ 15%; Chromium: O.01 ~ 0.02%; Nickel: O.035 ~ 1.8%; CaO:< 0.01%; MgO:0.05 ~ 0.32%; Surplus is carbon and other impurity.
MBR separatory membrane in membrane bioreactor is hollow-fibre membrane, and material is polyethylene, the pore size of MBR separation membrane surface be O.1 ~ O.5
m.
Suction pump adopts intermittent operation mode, is controlled, opens 8min (adjustable), stop 3min (adjustable) by the time relay.
application Example 1
Through pretreated municipal effluent (i.e. sanitary sewage) water quality be: COD:366mg/L, total nitrogen 42.4mg/L, total phosphorus 8.2mg/L.Sewage enters contact reacts pond 2, in contact reacts pond, the packing height of sponge iron filler is 1600mm, 4.5 hours contact reacts time, water outlet gravity flow after contact reacts enters membrane bioreactor (or claiming membrane biological reaction pond) 5, it is 6 hours in the reaction times of membrane bioreactor (in be provided with MBR separatory membrane 6), sludge loading is 0.35kgCOD/kgMLSS d, in membrane bioreactor (or claiming membrane biological reaction pond), dissolved oxygen content is 3.5mg/L, and membrane flux is 16.2 L/ (m
2h), fenestra used is through being 0.2
m, return current ratio of the mixed liquid 250%, reflux pump is at each periodic duty 0.55 h, stoppage in transit 1.2h.Suction pump intermittent suction runs, and each periodic duty 8 minutes, stops 3 minutes.
Effluent quality after above-mentioned art breading: COD:22.6mg/L, total nitrogen 6.8mg/L, total phosphorus 0.24mg/L, meet " urban wastewater treatment firm pollutant emission standard " (GB 18918-2002) first discharge standard A standard.
Bound, the interval value of each processing parameter (as the time etc.) cited by the utility model can realize the utility model, do not enumerate embodiment at this.
Claims (1)
1. municipal effluent denitrogenation dephosphorizing treatment system, is characterized in that comprising the first transfer lime (1), contact reacts pond (2), sponge iron (3), the second transfer lime (4), membrane bioreactor (5), compressed air pipe (7), aeration head (8), mixed-liquor return pipe (9), reflux pump (10), the time relay (11), mixed solution delivery pipe (12), the 3rd transfer lime (13), suction pump (14);
The input termination of the first transfer lime (1) is through pretreated municipal effluent, the output terminal of the first transfer lime (1) is communicated with the bottom water-in of contact reacts pond (2), contact reacts pond (2) is built with sponge iron (3), the input terminus of the second transfer lime (4) is connected logical with the top water outlet of contact reacts pond (2), the output terminal of the second transfer lime (4) is connected logical with the water-in of membrane bioreactor (5), MBR separatory membrane (6) is provided with in membrane bioreactor (5), the input terminus of the 3rd transfer lime (13) is connected logical with the water outlet of MBR separatory membrane (6), water outlet after the direct output processing of output terminal of the 3rd transfer lime (13), 3rd transfer lime (13) is provided with suction pump (14), the bottom of membrane bioreactor (5) is provided with aeration head (8), and aeration head (8) is connected logical with compressed air pipe (7), the input terminus of mixed-liquor return pipe (9) is connected logical with the bottom water outlet of membrane bioreactor (5), the output terminal of mixed-liquor return pipe (9) is connected logical with the water-in of contact reacts pond (2), mixed-liquor return pipe (9) is provided with reflux pump (10), the time relay (11) is connected with reflux pump (10) by control circuit, be provided with mixed solution delivery pipe (12) bottom the pond of membrane bioreactor (5), mixed solution delivery pipe (12) is provided with manually-operated gate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201520146819.9U CN204550200U (en) | 2015-03-13 | 2015-03-13 | Municipal effluent denitrogenation dephosphorizing treatment system |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201520146819.9U CN204550200U (en) | 2015-03-13 | 2015-03-13 | Municipal effluent denitrogenation dephosphorizing treatment system |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105366809A (en) * | 2015-11-14 | 2016-03-02 | 常州大学 | Efficient nitrogen and phosphorus removal MBR process and integrated device |
| CN108862828A (en) * | 2018-06-22 | 2018-11-23 | 即墨市污水处理有限公司 | A kind of municipal sewage denitrogenation dephosphorizing treatment process |
-
2015
- 2015-03-13 CN CN201520146819.9U patent/CN204550200U/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105366809A (en) * | 2015-11-14 | 2016-03-02 | 常州大学 | Efficient nitrogen and phosphorus removal MBR process and integrated device |
| CN108862828A (en) * | 2018-06-22 | 2018-11-23 | 即墨市污水处理有限公司 | A kind of municipal sewage denitrogenation dephosphorizing treatment process |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150812 Termination date: 20160313 |