CN204497343U - A kind of waste and old electrokinetic cell extracts cobaltous sulfate evaporated crystallization device - Google Patents

A kind of waste and old electrokinetic cell extracts cobaltous sulfate evaporated crystallization device Download PDF

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Publication number
CN204497343U
CN204497343U CN201520238162.9U CN201520238162U CN204497343U CN 204497343 U CN204497343 U CN 204497343U CN 201520238162 U CN201520238162 U CN 201520238162U CN 204497343 U CN204497343 U CN 204497343U
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CN
China
Prior art keywords
crystallizing tank
cobaltous sulfate
waste
paddle
electrokinetic cell
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Expired - Fee Related
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CN201520238162.9U
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Chinese (zh)
Inventor
区汉成
孟笑
谢丰海
黄国英
杨勇
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Ganzhou Highpower Technology Co Ltd
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Ganzhou Highpower Technology Co Ltd
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Priority to CN201520238162.9U priority Critical patent/CN204497343U/en
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Publication of CN204497343U publication Critical patent/CN204497343U/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/84Recycling of batteries or fuel cells

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Abstract

The utility model relates to a kind of waste and old electrokinetic cell evaporated crystallization device, particularly relates to a kind of waste and old electrokinetic cell and extracts cobaltous sulfate evaporated crystallization device.The technical problem solved is to provide a kind of waste and old electrokinetic cell and extracts cobaltous sulfate evaporated crystallization device.Provide so a kind of waste and old electrokinetic cell and extract cobaltous sulfate evaporated crystallization device, include crystallizing tank, electric boiling plate, paddle, servomotor, control system etc.; On the inwall of crystallizing tank, symmetrical expression is provided with electric boiling plate, and the inside of crystallizing tank is provided with paddle, and paddle is provided with multiple through hole; Above crystallizing tank, be provided with servomotor, servomotor is connected with paddle, and reservoir is connected by feed tube with crystallizing tank, and feed tube is respectively arranged with gage probe and electromagnetically operated valve I; Drain pipe is connected with in the bottom of crystallizing tank.The waste and old electrokinetic cell provided extracts cobaltous sulfate evaporated crystallization device, achieves automation mechanized operation, adopts electric boiling plate to heat, easy controlling and adjustment heating-up temperature.

Description

A kind of waste and old electrokinetic cell extracts cobaltous sulfate evaporated crystallization device
Technical field
The utility model relates to a kind of waste and old electrokinetic cell evaporated crystallization device, particularly relates to a kind of waste and old electrokinetic cell and extracts cobaltous sulfate evaporated crystallization device.
Background technology
Electrokinetic cell is the power supply in powered tools source, the storage battery that many fingers are electric automobile, electric train, electric bicycle, golf cart provide power.Waste and old electrokinetic cell, used and discarded electrokinetic cell exactly.Containing cobaltous sulfate in waste and old electrokinetic cell.
Cobaltous sulfate, rose crystallization.Take on a red color after dehydration powder, and water-soluble and methyl alcohol, is slightly soluble in ethanol.For ceramic glaze and paint drier, also contain cobalt pigment and other cobalt product, also for catalyst, analytical reagent, feed addictive, tire sealant stick, lithopone additive etc. for plating, alkaline battery, production.
Crystallization refers to the process that solid solute is separated out from (mistake) saturated solution.The solute of separating out from solution is broadly divided into crystalline precipitate and amorphous sediment.Crystalline precipitate is easy to leach from solution.The particle of crystal larger and evenly time, entrainment mother liquor is few, is easy to washing; The too thin and uneven crystal of crystallization, often form thick paste thing, entrainment mother liquor is more, not only not easily washs and is even difficult to filter, sometimes also can through filter paper.
The cobaltous sulfate contained in the waste and old electrokinetic cell retrieved, can be extracted by the mode of evaporative crystallization.But existing extraction cobaltous sulfate evaporated crystallization device, do not possess control system, cannot realize automation mechanized operation, crystalline rate is low, and crystallization effect is poor.
Utility model content
(1) technical problem that will solve
The utility model is in order to overcome existing extraction cobaltous sulfate evaporated crystallization device, do not possess control system, automation mechanized operation cannot be realized, crystalline rate is low, the shortcoming of crystallization effect difference, the technical problems to be solved in the utility model is to provide a kind of waste and old electrokinetic cell and extracts cobaltous sulfate evaporated crystallization device.
(2) technical scheme
In order to solve the problems of the technologies described above, the utility model provides so a kind of waste and old electrokinetic cell and extracts cobaltous sulfate evaporated crystallization device, includes crystallizing tank, electric boiling plate, paddle, pressure sensor, thermometer, servomotor, pressure gauge, pressure-regulating valve, reservoir, gage probe, electromagnetically operated valve I, control system, feed tube, drain pipe, electromagnetically operated valve II, connects fluid cylinder;
On the inwall of crystallizing tank, symmetrical expression is provided with electric boiling plate, and the inside of crystallizing tank is provided with paddle, and paddle is provided with multiple through hole; Above crystallizing tank, be provided with servomotor, crystallizing tank is arranged porose, servomotor is connected with paddle, is disposed with pressure sensor, thermometer, pressure gauge, pressure-regulating valve respectively at the top right-to-left of crystallizing tank;
The upper left side of crystallizing tank is provided with reservoir, and reservoir is connected by feed tube with crystallizing tank, and feed tube is respectively arranged with gage probe and electromagnetically operated valve I, and gage probe is arranged on the top of electromagnetically operated valve I; Be connected with drain pipe in the bottom of crystallizing tank, drain pipe is provided with electromagnetically operated valve II, be provided with in the below of drain pipe and connect fluid cylinder;
Electric boiling plate, pressure sensor, thermometer, servomotor, pressure gauge, pressure-regulating valve, gage probe, electromagnetically operated valve I, electromagnetically operated valve II are connected with control system all respectively.
Operation principle: when preparation, first puts into the solution containing cobaltous sulfate in reservoir.Restart control system, control system Controlling solenoid valve I is opened.The solution containing cobaltous sulfate be contained in reservoir is flowed in crystallizing tank by feed tube.Be arranged on the gage probe on feed tube, constantly the solution containing cobaltous sulfate flow through in feed tube measured, and metrical information is fed back to control system.Control system, according to the metrical information of feedback, controls the amount of the solution containing cobaltous sulfate entered in crystallizing tank.When gage probe metering reaches the number range of setting by the solution containing cobaltous sulfate in feed tube, control system is closed according to metrical information Controlling solenoid valve I.
Control system controls servomotor and carries out action.Servomotor drives the paddle be attached thereto to rotate, and paddle is provided with multiple hole, can improves mixing effect.With it simultaneously, control system also starts to control electric boiling plate and heats the solution containing cobaltous sulfate.After electric boiling plate carries out the heating regular hour to the solution containing cobaltous sulfate, under the stirring that paddle continues, the solution containing cobaltous sulfate is constantly evaporated, and cobaltous sulfate is separated out from containing the solution of cobaltous sulfate in the mode of crystallization.
In the process that cobaltous sulfate is separated out from containing the solution of cobaltous sulfate in the mode of crystallization, have high-temperature gas and generate, what the pressure gauge that crystallization tank deck is arranged can be real-time shows the pressure information in crystallizing tank, and information is passed to control system.In order to the pressure information recorded is more accurate, crystallization tank deck is also provided with pressure sensor, and pressure sensor detects the pressure in crystallizing tank continuously, and information is passed to control system.The pressure information that control system is fed back according to pressure gauge and pressure sensor, controlled pressure adjuster valve carries out action.Pressure-regulating valve can adjust the pressure in crystallizing tank.The thermometer that crystallization tank deck is arranged can be real-time the Temperature displaying in crystallizing tank out, and information is passed to control system.Control system adjusts the height of the heating-up temperature of electric boiling plate according to thermometer feedack.
When the cobaltous sulfate contained in the solution of cobaltous sulfate in crystallizing tank will all be separated out, control system first controls electric boiling plate and stops heating, utilizes the waste heat in crystallizing tank, under the stirring continued, complete whole precipitations of cobaltous sulfate, last control system controls servomotor again and stops action.
Control system Controlling solenoid valve II is opened, and the cobaltous sulfate crystal of separating out in crystallizing tank is drained into by drain pipe and connects in fluid cylinder.After the cobaltous sulfate crystal of separating out in crystallizing tank is all discharged, control system again Controlling solenoid valve II is closed.Repeat last operation, until crystallization work completes.
(3) beneficial effect
The waste and old electrokinetic cell of one provided by the utility model extracts cobaltous sulfate evaporated crystallization device, there is control system, achieve automation mechanized operation, pay close attention in real time without the need to artificial, decrease cost of labor, adopt electric boiling plate to heat, can adjust accurately temperature and control, evaporative crystallization be effective, efficiency is high, structure is simple, easy to use, is easy to maintenance and repair.
Accompanying drawing explanation
Fig. 1 is front view structural representation of the present utility model.
Being labeled as in accompanying drawing: 1-crystallizing tank, 2-electric boiling plate, 3-paddle, 4-pressure sensor, 5-thermometer, 6-servomotor, 7-pressure gauge, 8-pressure-regulating valve, 9-reservoir, 10-gage probe, 11-electromagnetically operated valve I, 12-control system, 13-feed tube, 14-drain pipe, 15-electromagnetically operated valve II, 16-connects fluid cylinder.
Embodiment
Below in conjunction with drawings and Examples, the utility model is further described.
embodiment 1
A kind of waste and old electrokinetic cell extracts cobaltous sulfate evaporated crystallization device, as shown in Figure 1, include crystallizing tank 1, electric boiling plate 2, paddle 3, pressure sensor 4, thermometer 5, servomotor 6, pressure gauge 7, pressure-regulating valve 8, reservoir 9, gage probe 10, electromagnetically operated valve I 11, control system 12, feed tube 13, drain pipe 14, electromagnetically operated valve II 15, connect fluid cylinder 16.
On the inwall of crystallizing tank 1, symmetrical expression is provided with electric boiling plate 2, and the inside of crystallizing tank 1 is provided with paddle 3, and paddle 3 is provided with multiple through hole; Above crystallizing tank 1, be provided with servomotor 6, crystallizing tank 1 arranged porose, servomotor 6 is connected with paddle 3, is disposed with pressure sensor 4, thermometer 5, pressure gauge 7, pressure-regulating valve 8 respectively at the top right-to-left of crystallizing tank 1.
The upper left side of crystallizing tank 1 is provided with reservoir 9, and reservoir 9 is connected by feed tube 13 with crystallizing tank 1, and feed tube 13 is respectively arranged with gage probe 10 and electromagnetically operated valve I 11, and gage probe 10 is arranged on the top of electromagnetically operated valve I 11; Be connected with drain pipe 14 in the bottom of crystallizing tank 1, drain pipe 14 is provided with electromagnetically operated valve II 15, be provided with in the below of drain pipe 14 and connect fluid cylinder 16.
Electric boiling plate 2, pressure sensor 4, thermometer 5, servomotor 6, pressure gauge 7, pressure-regulating valve 8, gage probe 10, electromagnetically operated valve I 11, electromagnetically operated valve II 15 are connected with control system 12 all respectively.
Operation principle: when preparation, first puts into the solution containing cobaltous sulfate in reservoir 9.Restart control system 12, control system 12 Controlling solenoid valve I 11 is opened.The solution containing cobaltous sulfate be contained in reservoir 9 is flowed in crystallizing tank 1 by feed tube 13.Be arranged on the gage probe 10 on feed tube 13, constantly the solution containing cobaltous sulfate flow through in feed tube 13 measured, and metrical information is fed back to control system 12.Control system 12, according to the metrical information of feedback, controls the amount of the solution containing cobaltous sulfate entered in crystallizing tank 1.When gage probe 10 measure by feed tube 13 reach the number range of setting containing the solution of cobaltous sulfate time, control system 12 is closed according to metrical information Controlling solenoid valve I 11.
Control system 12 controls servomotor 6 and carries out action.Servomotor 6 drives the paddle 3 be attached thereto to rotate, and paddle 3 is provided with multiple hole, can improves mixing effect.With it simultaneously, control system 12 also starts to control electric boiling plate 2 and heats the solution containing cobaltous sulfate.After electric boiling plate 2 carries out the heating regular hour to the solution containing cobaltous sulfate, under the stirring that paddle 3 continues, the solution containing cobaltous sulfate is constantly evaporated, and cobaltous sulfate is separated out from containing the solution of cobaltous sulfate in the mode of crystallization.
In the process that cobaltous sulfate is separated out from containing the solution of cobaltous sulfate in the mode of crystallization, have high-temperature gas to generate, the real-time pressure information in crystallizing tank 1 is shown of pressure gauge 7 meeting arranged on crystallizing tank 1 pushes up, and information is passed to control system 12.In order to the pressure information recorded is more accurate, on crystallizing tank 1 pushes up, be also provided with pressure sensor 4, pressure sensor 4 detects the pressure in crystallizing tank 1 continuously, and information is passed to control system 12.The pressure information that control system 12 is fed back according to pressure gauge 7 and pressure sensor 4, controlled pressure adjuster valve 8 carries out action.Pressure-regulating valve 8 can adjust the pressure in crystallizing tank 1.The thermometer 5 arranged on crystallizing tank 1 pushes up can real-time the Temperature displaying in crystallizing tank 1 out, and information is passed to control system 12.Control system 12 adjusts the height of the heating-up temperature of electric boiling plate 2 according to thermometer 5 feedack.
When the cobaltous sulfate contained in the solution of cobaltous sulfate in crystallizing tank 1 will all be separated out, control system 12 first controls electric boiling plate 2 and stops heating, utilize the waste heat in crystallizing tank 1, under the stirring continued, complete whole precipitations of cobaltous sulfate, last control system 12 controls servomotor 6 again and stops action.
Control system 12 Controlling solenoid valve II 15 is opened, and the cobaltous sulfate crystal of separating out in crystallizing tank 1 is drained into by drain pipe 14 and connects in fluid cylinder 16.After the cobaltous sulfate crystal of separating out in crystallizing tank 1 is all discharged, control system 12 again Controlling solenoid valve II 15 is closed.Repeat last operation, until crystallization work completes.
The above embodiment only have expressed preferred implementation of the present utility model, and it describes comparatively concrete and detailed, but therefore can not be interpreted as the restriction to the utility model the scope of the claims.It should be pointed out that for the person of ordinary skill of the art, without departing from the inventive concept of the premise, can also make some distortion, improvement and substitute, these all belong to protection range of the present utility model.Therefore, the protection range of the utility model patent should be as the criterion with claims.

Claims (1)

1. a waste and old electrokinetic cell extracts cobaltous sulfate evaporated crystallization device, it is characterized in that, include crystallizing tank (1), electric boiling plate (2), paddle (3), pressure sensor (4), thermometer (5), servomotor (6), pressure gauge (7), pressure-regulating valve (8), reservoir (9), gage probe (10), electromagnetically operated valve I (11), control system (12), feed tube (13), drain pipe (14), electromagnetically operated valve II (15), connect fluid cylinder (16);
On the inwall of crystallizing tank (1), symmetrical expression is provided with electric boiling plate (2), and the inside of crystallizing tank (1) is provided with paddle (3), and paddle (3) is provided with multiple through hole; The top of crystallizing tank (1) is provided with servomotor (6), crystallizing tank (1) is arranged porose, servomotor (6) is connected with paddle (3), is disposed with pressure sensor (4), thermometer (5), pressure gauge (7), pressure-regulating valve (8) respectively at the top right-to-left of crystallizing tank (1);
The upper left side of crystallizing tank (1) is provided with reservoir (9), reservoir (9) is connected by feed tube (13) with crystallizing tank (1), feed tube (13) is respectively arranged with gage probe (10) and electromagnetically operated valve I (11), and gage probe (10) is arranged on the top of electromagnetically operated valve I (11); Be connected with drain pipe (14) in the bottom of crystallizing tank (1), drain pipe (14) is provided with electromagnetically operated valve II (15), be provided with in the below of drain pipe (14) and connect fluid cylinder (16);
Electric boiling plate (2), pressure sensor (4), thermometer (5), servomotor (6), pressure gauge (7), pressure-regulating valve (8), gage probe (10), electromagnetically operated valve I (11), electromagnetically operated valve II (15) are connected with control system (12) all respectively.
CN201520238162.9U 2015-04-18 2015-04-18 A kind of waste and old electrokinetic cell extracts cobaltous sulfate evaporated crystallization device Expired - Fee Related CN204497343U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201520238162.9U CN204497343U (en) 2015-04-18 2015-04-18 A kind of waste and old electrokinetic cell extracts cobaltous sulfate evaporated crystallization device

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Application Number Priority Date Filing Date Title
CN201520238162.9U CN204497343U (en) 2015-04-18 2015-04-18 A kind of waste and old electrokinetic cell extracts cobaltous sulfate evaporated crystallization device

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10995014B1 (en) 2020-07-10 2021-05-04 Northvolt Ab Process for producing crystallized metal sulfates

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10995014B1 (en) 2020-07-10 2021-05-04 Northvolt Ab Process for producing crystallized metal sulfates

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C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20150722

Termination date: 20180418