CN204434301U - Metallurgy industry sintering machine head end electro-precipitating dust extracts the equipment of sylvite - Google Patents
Metallurgy industry sintering machine head end electro-precipitating dust extracts the equipment of sylvite Download PDFInfo
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- CN204434301U CN204434301U CN201520081836.9U CN201520081836U CN204434301U CN 204434301 U CN204434301 U CN 204434301U CN 201520081836 U CN201520081836 U CN 201520081836U CN 204434301 U CN204434301 U CN 204434301U
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Abstract
The utility model relates to a kind of equipment extracting sylvite from metallurgy industry sintering machine head end electro-precipitating dust.Equipment comprises sintering ash leaching pond and connects one-level press filtration unit, rich solution bin, chemical precipitation tank, emchanically centrifugal separation unit, evaporative crystallization unit successively.The utility model uses service water directly to leach electro-precipitating dust and carries sylvite; The formation precipitation that chemical process makes the foreign metal ion in leaching liquid quick, stable, product purity is higher; Emchanically centrifugal separation is adopted to carry out high efficiency separation to the solution after precipitation; Add the water of condensation that service water and evaporative crystallization unit return and secondary leaching is carried out to filter residue, and the lean solution that secondary press filtration and centrifugal separation unit produce is returned as the grey leaching liquid of sintering, both ensure that in sintering ash, sylvite extracted to greatest extent, also ensure that the properly distributed of whole system leaching liquid, arrange outward without waste water.The utility model structure is simple, and economic and reliable, after evaporative crystallization drying, can obtain highly purified sylvite product.
Description
Technical field
The utility model belongs to solid waste resource recovery technical field of comprehensive utilization, also belongs to chemical production technical field simultaneously, is specifically related to a kind of equipment extracting sylvite from metallurgy industry sintering machine head end electro-precipitating dust.
Background technology
Metallurgy industry is a mainstay industry of China's rapid economic development, but is also one of industry of high energy consumption and high pollution simultaneously.Wherein, a large amount of dust produced in sintering process are one of primary pollution source of metallurgy industry.According to statistics, up to about 1,500 ten thousand tons, it contains the elements such as a large amount of iron, calcium, silicon, carbon, potassium, sodium, chlorine to the sintering machine head end electro-precipitating dust (being called for short sintering ash) that China produces every year, simultaneously also containing a small amount of heavy metal element such as lead, zinc, copper.Therefore, how rationally to dispose sintering ash, and its efficient resource of Appropriate application, the Sustainable development for environment protection and metallurgy industry all has great importance.
Owing to sintering in ash the heavy metal element being rich in potassium soluble in water, sodium salt and there is hazardness, therefore, should not store up or landfill disposal it.At present, for the comprehensive treating process of sintering ash, it is directly returned former operation and again prepares burden, sinters by domestic metallurgy industry mostly, to recycle the useful elements such as the iron that wherein contains and residual carbon.Although this method achieves the grey process of sintering and recycling to a certain extent, return in the process of sintering in continuous circulation, the harmful element such as potassium, sodium, zinc, lead contained in sintering ash can continuous enrichment.Especially the enrichment of the alkali metal such as potassium, sodium, not only can cause corrosion to damage to blast-furnace body and utility appliance, have a strong impact on the normal operation of former operation, also can reduce efficiency of dust collection and the operation stability of electric precipitator.Meanwhile, the wasting of resources that sintering also result in wherein part metals element is directly returned.Therefore, how more reasonably recycling sintering ash, receives increasing concern.
Detection analysis shows, containing more potassium element in sintering electro-precipitating dust, and exists with the form such as Repone K, potassium sulfate.As the China of large agricultural country, Potassic fertilizer resources lacks and skewness, needs a large amount of import.Therefore, from sintering ash, extract sylvite, effectively can solve basic metal enrichment to the metallurgical process normally operation problem that can have a negative impact, effectively can alleviate China's potash fertilizer present situation in short supply again, have great importance and wide prospect.
Patent CN101428832 discloses a kind of method extracting potassium sulfate and preparation thereof from sintering dust separation ash.This invention adopts the soak at room temperature mode of 3 days to carry out lixiviate potassium sulfate to sintering dust separation ash, length consuming time, and leaching efficiency is low; In addition, the method, by adding a large amount of organic solvent methane amides, improves the crystallization yields of potassium sulfate, but other foreign metal ion removed and contain in leach liquor of not adopting an effective measure, so that affect the potassium product purity finally obtained.
In addition, CN101234766 discloses a kind of steel works sintering electro-precipitating dust that utilizes to produce the method for Repone K.What the method adopted is vibration leaching, and realizes solid-liquid separation by the mode of natural subsidence, length consuming time, and efficiency is low, and especially less to particle diameter sintering ash, is difficult to reach efficient solid-liquid separation; In addition, this invention adopts Slow cooling, fractional crystallization, length consuming time.
Summary of the invention
The purpose of this utility model is to provide a kind of equipment extracting sylvite from metallurgy industry sintering machine head end electro-precipitating dust, with solve in existing operation sinter ash return sintering circuit time, the alkali metals such as its potassium contained, sodium can produce the problem of serious disadvantageous effect to former operation because of continuous enrichment, make the sylvite extracted meet the requirement of agriculture articles for use simultaneously, alleviate the present situation of China's sylvite shortage.
The purpose of this utility model is realized by following technical solution: in sintering machine head end electro-precipitating dust, potassium element exists with the form such as Repone K, potassium sulfate, adopts and be directly dissolved in water, and the sylvite in sintering ash just can be made to dissolve and proceed in liquid phase.But due in the process of dissolving, the metallic element such as iron, calcium, magnesium, copper, zinc, aluminium, manganese, lead contained in sintering ash, also generating portion dissolving can enter liquid phase, form Fe
3+, Ca
2+, Mg
2+, Cu
2+, Zn
2+, Al
3+, Mn
2+, Pb
2+deng.Therefore, for efficiently removing insoluble composition in the grey leaching liquid of sintering and foreign metal ion, obtain high purity sylvite, the utility model have employed and stirs the operation such as leaching, chemical process precipitation, emchanically centrifugal separation and evaporative crystallization.Wherein, chemical precipitation operation is by adding the alkaline matter such as potassium hydroxide, salt of wormwood or sulfide realizes, and emchanically centrifugal separation unit is then horizontal spiral discharge sedimentation centrifuge.
From metallurgy industry sintering machine head end electro-precipitating dust, extract an equipment for sylvite, sintering ash leaches pond and connects one-level press filtration unit, rich solution bin, chemical precipitation tank, emchanically centrifugal separation unit, evaporative crystallization unit successively.
Described one-level press filtration unit also connects filter residue and leaches pond, and filter residue leaches pond and connects secondary press filtration unit.
Described emchanically centrifugal separation unit is horizontal spiral discharge sedimentation centrifuge.
Adopt that aforesaid device leaches sintering ash, is separated, the method for purification sylvite, comprise the steps.
(1) add service water, sintering ash is leached under the condition stirred, after having leached, the suspension liquid of formation is delivered to one-level press filtration unit and carries out solid-liquid separation; Be separated the rich solution being rich in sylvite produced and enter into rich solution bin, filter cake then enters into filter residue and leaches pond, again leaches.
(2) after filter cake carries out stirring leaching in filter residue leaching pond, be delivered to secondary press filtration unit with pump to filter, the filter residue of generation directly returns former operation after drying, again prepares burden, sinters, filtrate then returns sintering ash and leaches pond, is used as the leaching liquid of sintering ash.
(3) be stored in the rich solution in rich solution bin, after transferring to chemical precipitation tank with pump, add the alkaline matter such as potassium hydroxide, salt of wormwood, the pH value of rich solution in chemical precipitation tank is adjusted to 8 ~ 9; Now, following reaction will be there is in the solution:
Fe
3++ 3OH
- = Fe(OH)
3↓
Cu
2++ 2OH
- = Cu (OH)
2↓
Al
3++ 3OH
- = Al (OH)
3↓
Zn
2++ 2OH
- = Zn (OH)
2↓
Mn
2++ 2OH
- = Mn (OH)
2↓
Pb
2++ 2OH
- = Pb (OH)
2↓
After pH value is adjusted to 8 ~ 9, the most of foreign metal ion in solution all can generate precipitation by reaction and enter solid phase.
(4), after pH regulator completes, solution is delivered to emchanically centrifugal separation unit and carries out precipitation removal.
(5) by the effect of horizontal spiral discharge sedimentation centrifuge in emchanically centrifugal separation unit, high efficiency separation can go out GOLD FROM PLATING SOLUTION and belong to the insoluble compositions such as precipitation of hydroxide, even if the particulate matter that particle diameter is less, also can realize effective separation.
(6) rich solution being rich in sylvite after realizing solid-liquid separation enters into subsequent evaporation crystalline element, carries out the production of sylvite; The filter residue produced in centrifugal separation processes then enters into filter residue leaching pond and again leaches, to extract a small amount of sylvite that wherein still may contain.
The beneficial effects of the utility model are: use service water to carry out directly leaching to sintering machine head end electro-precipitating dust and carry sylvite, the method of mechanical separation is adopted to carry out solid-liquid separation to the suspension liquid formed after leaching, more efficient, feasible compared with adopting the mode of natural subsidence to carry out solid-liquid separation in patent CN101234766; By chemical process, quick, the stable formation of the foreign metal ion in leaching liquid precipitated and enter solid phase, compare with the product finally obtained in patent CN101234766, impurity metallic elements is less, and product purity is higher; Adopt horizontal spiral discharge sedimentation centrifuge to carry out high efficient solid and liquid separation to the solution after precipitation simultaneously, even if the particulate matter that particle diameter is less, also can realize effective separation; In addition, in the present invention, adopt and add the water of condensation that service water and evaporative crystallization unit return secondary leaching is carried out to filter residue, and the lean solution that secondary press filtration and centrifugal separation unit produce is returned as the grey leaching liquid of sintering, both ensure that in sintering ash, sylvite extracted to greatest extent, also ensure that the properly distributed of whole system leaching liquid, arrange outward without waste water.Whole leaching separation apparatus structure is simple, economic and reliable, energy high efficiency extraction also isolates the sylvite sintered in ash, after evaporative crystallization drying, highly purified sylvite product can be obtained, all have positive effect to the problem that the present situation and basic metal enrichment that effectively solve China's sylvite shortage can have a negative impact.
Accompanying drawing explanation
Fig. 1 is equipment drawing of the present utility model.
Embodiment
Below in conjunction with accompanying drawing, the utility model is described further.
From metallurgy industry sintering machine head end electro-precipitating dust, extract an equipment for sylvite, sintering ash leaches pond and connects one-level press filtration unit, rich solution bin, chemical precipitation tank, emchanically centrifugal separation unit, evaporative crystallization unit successively.
Described one-level press filtration unit also connects filter residue and leaches pond, and filter residue leaches pond and connects secondary press filtration unit.
Described emchanically centrifugal separation unit is horizontal spiral discharge sedimentation centrifuge.
From metallurgy industry sintering machine head end electro-precipitating dust, extract a method for sylvite, step comprises: stir leaching, chemical precipitation, emchanically centrifugal separation and evaporative crystallization.
Described stirring leaching step comprises:
(1) add service water, sintering ash is leached under the condition stirred, after having leached, the suspension liquid of formation is delivered to one-level press filtration unit and carries out solid-liquid separation; Be separated the rich solution being rich in sylvite produced and enter into rich solution bin, filter cake then enters into filter residue and leaches pond, again leaches;
(2) after filter cake carries out stirring leaching in filter residue leaching pond, be delivered to secondary press filtration unit with pump to filter, the filter residue of generation directly returns former sintering circuit after drying, again prepares burden, sinters, filtrate then returns sintering ash and leaches pond, is used as the leaching liquid of sintering ash.
Described chemical precipitation step comprises:
(3) be stored in the rich solution in rich solution bin, after transferring to chemical precipitation tank with pump, add the alkaline matter such as potassium hydroxide, salt of wormwood, the pH value of rich solution in chemical precipitation tank is adjusted to 8 ~ 9; There is chemical precipitation reaction in the solution: the foreign metal ion in solution generates precipitation by reaction and enters solid phase;
(4), after pH regulator completes, solution is delivered to emchanically centrifugal separation unit.
Described emchanically centrifugal separation step comprises:
(5) solution of emchanically centrifugal separation unit is delivered to, insoluble composition in solution is isolated by horizontal spiral discharge sedimentation centrifuge in emchanically centrifugal separation unit, solid-state insoluble composition is filter residue, and liquid for being rich in the rich solution of sylvite, insoluble composition is precipitate metal hydroxides.
Described evaporative crystallization steps comprises:
(6) rich solution being rich in sylvite after solid-liquid separation enters in evaporative crystallization unit, carries out the production of sylvite.
The filter residue produced in described emchanically centrifugal separation step (5) then enters into filter residue leaching pond and again leaches.
In above-mentioned steps (1), (2), after sintering ash is stored in sintering ash silo, be delivered to sintering ash and leached pond, add service water, leach under the condition stirred, only need to leach in pond to sintering ash when system starts to add water, after whole system works well, do not need to add new service water again, but lean solution secondary press filtration unit and centrifugal separation unit returned is used as the leaching liquid of sintering ash.
In above-mentioned steps (1), (2), after sintering liming takes into, the suspension liquid that sintering ash leaches in pond is delivered to one-level press filtration unit, carries out solid-liquid separation; The rich solution being rich in sylvite after separation enters rich solution bin and stores, and purifies as later separation; Filter cake then transfers to filter residue and leaches pond, adds service water, again carries out stirring leaching.
After the filter residue leaching of leaching in pond completes, solution is wherein delivered to secondary press filtration unit and carries out solid-liquid separation; Obtain solid slag after separation, be rich in ferro element, directly return former operation after drying and again prepare burden, sinter; Filtrate still containing soluble salts such as a small amount of sylvite, directly may be back to sintering ash and leaches in pond the leaching liquid being used as to sinter ash.
In above-mentioned steps (3), (4), the rich solution in rich solution bin being delivered in chemical precipitation tank, coming pH value to 8 ~ 9 of regulator solution by adding the alkaline matter such as potassium hydroxide, salt of wormwood wherein.In this step, pH value is adjusted to 8 ~ 9, and the pH value that part metals ion precipitates completely is a little more than this pH value range.Therefore, after most precipitation by metallic ion is separated out, still having part metals ion in solution cannot be fully formed precipitation of hydroxide and be removed, and mainly contains Mn
2+, Mg
2+, Pb
2+deng, then now need to add a small amount of sulfide in chemical precipitation tank, to make these metal ions be able to further removal, in this step, the main reaction occurred is:
Mn
2++ S
2-= MnS↓
Mg
2++ S
2-= CuS↓
Pb
2++ S
2-= PbS ↓。
To be precipitated complete after, the solution in chemical precipitation tank is delivered to emchanically centrifugal separation unit, carry out precipitated metal separation remove.
In above-mentioned steps (5), the tripping device adopted is horizontal spiral discharge sedimentation centrifuge, by its centrifugation, high efficiency separation can go out GOLD FROM PLATING SOLUTION and belong to the insoluble compositions such as precipitation of hydroxide, even if the particulate matter that particle diameter is less, also can realize effective separation, thus obtain highly purified potassium salt soln.
The isolated solid slag of horizontal spiral discharge sedimentation centrifuge, is mainly precipitated metal thing, directly returns filter residue and leaches pond, again leach, to extract a small amount of sylvite that wherein still may contain together with the isolated filter cake of one-level press filtration unit.
Eliminate the potassium salt soln of foreign metal ion, enter evaporative crystallization unit and carry out condensing crystal, the sylvite concentrated solution after concentrated enters follow-up centrifugation, drying unit, makes sylvite product.In this step, the water of condensation that evaporative crystallization unit produces returns filter residue and leaches pond as filter residue leaching liquid, and the lean solution produced in centrifugation then returns sintering ash and leaches pond, is used as to sinter grey leaching liquid.
Claims (3)
1. from metallurgy industry sintering machine head end electro-precipitating dust, extract an equipment for sylvite, it is characterized in that sintering ash leaching pond connects one-level press filtration unit, rich solution bin, chemical precipitation tank, emchanically centrifugal separation unit, evaporative crystallization unit successively.
2. a kind of equipment extracting sylvite from metallurgy industry sintering machine head end electro-precipitating dust as claimed in claim 1, it is characterized in that one-level press filtration unit also connects filter residue and leaches pond, filter residue leaches pond and connects secondary press filtration unit.
3. a kind of equipment extracting sylvite from metallurgy industry sintering machine head end electro-precipitating dust as claimed in claim 1, is characterized in that emchanically centrifugal separation unit is horizontal spiral discharge sedimentation centrifuge.
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|---|---|---|---|
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109368666A (en) * | 2018-12-21 | 2019-02-22 | 中冶南方都市环保工程技术股份有限公司 | One kind proposing sylvite system |
| CN109557079A (en) * | 2018-11-06 | 2019-04-02 | 河钢股份有限公司 | The ICP-OES measuring method of constituent content in sintering dust separation ash |
-
2015
- 2015-02-05 CN CN201520081836.9U patent/CN204434301U/en active Active
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109557079A (en) * | 2018-11-06 | 2019-04-02 | 河钢股份有限公司 | The ICP-OES measuring method of constituent content in sintering dust separation ash |
| CN109368666A (en) * | 2018-12-21 | 2019-02-22 | 中冶南方都市环保工程技术股份有限公司 | One kind proposing sylvite system |
| CN109368666B (en) * | 2018-12-21 | 2023-11-14 | 中冶南方都市环保工程技术股份有限公司 | Potassium salt extracting system |
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