CN204429842U - A kind of device of high-efficiency photocatalysis oxidization process organic polluted soil - Google Patents
A kind of device of high-efficiency photocatalysis oxidization process organic polluted soil Download PDFInfo
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- CN204429842U CN204429842U CN201520059089.9U CN201520059089U CN204429842U CN 204429842 U CN204429842 U CN 204429842U CN 201520059089 U CN201520059089 U CN 201520059089U CN 204429842 U CN204429842 U CN 204429842U
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- China
- Prior art keywords
- reative cell
- screen cloth
- gas treatment
- utility
- conveyer belt
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000002689 soil Substances 0.000 title claims abstract description 23
- 238000000034 method Methods 0.000 title claims abstract description 13
- 238000007254 oxidation reaction Methods 0.000 title claims abstract description 13
- 230000001699 photocatalysis Effects 0.000 title claims abstract description 11
- 238000007146 photocatalysis Methods 0.000 title claims abstract description 11
- 239000004744 fabric Substances 0.000 claims abstract description 19
- CBENFWSGALASAD-UHFFFAOYSA-N ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims abstract description 17
- 230000001590 oxidative Effects 0.000 claims abstract description 8
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 6
- 238000003786 synthesis reaction Methods 0.000 claims abstract description 6
- 230000002194 synthesizing Effects 0.000 claims abstract description 6
- 239000007789 gas Substances 0.000 abstract description 19
- 239000000463 material Substances 0.000 abstract description 7
- 238000006243 chemical reaction Methods 0.000 abstract description 5
- 238000005265 energy consumption Methods 0.000 abstract description 3
- 230000000875 corresponding Effects 0.000 abstract description 2
- 239000002912 waste gas Substances 0.000 abstract description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 5
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 230000002079 cooperative Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- -1 active oxygen Chemical compound 0.000 description 1
- 238000009303 advanced oxidation process reaction Methods 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000000249 desinfective Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- HRKQOINLCJTGBK-UHFFFAOYSA-N dihydroxidosulfur Chemical compound OSO HRKQOINLCJTGBK-UHFFFAOYSA-N 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000006011 modification reaction Methods 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 238000006053 organic reaction Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 238000003900 soil pollution Methods 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 230000004083 survival Effects 0.000 description 1
Abstract
The utility model discloses a kind of device of high-efficiency photocatalysis oxidization process organic polluted soil, comprise the first reative cell and the second reative cell, described second reative cell connects filter; The first conveyer belt, one-level screen cloth, agitator, secondary screen cloth and the second conveyer belt is set gradually from top to bottom in described first reative cell; Arrange gas treatment chamber and microwave generator in described second reative cell, described gas treatment indoor arrange ozone generator and oxidative synthesis system; Described first reative cell connects gas treatment chamber by pipeline, and described pipeline arranges blower fan.The utility model operating cost is low, without any mechanical action, noiselessness, without the need to personal management and regular maintenance, only need make regular check on, equipment energy consumption is low, and without the need to adding any material, as long as arrange corresponding exhaust duct and air draft power, making waste gas by the utility model decomposing, purifying, participating in chemical reaction without the need to adding other materials.
Description
Technical field
The utility model belongs to field of Environment Protection, and what be specifically related to is a kind of device of high-efficiency photocatalysis oxidization process organic polluted soil.
Background technology
Soil is the material base and the valuable source that maintain human survival and development, but along with the fast development in China cities and towns, soil contamination problem highlights gradually, show since the 1950's according to related statistical data, between 30 years of rapid industrial development, the Cultivated Land Area Decrease of China more than 14,000 ten thousand mu, the economic loss caused due to the heavy metal pollution of agricultural product only just reached 32,000,000,000 yuans in 2000, and the agricultural economy caused by Industrial Pollution is lost in more than 10,000,000,000.Soil pollution not only causes direct economic loss, also brings the secondary pollution of the surrounding medium such as air, water body, constitutes serious threat to ecological safety and health, and therefore soil contamination problem receives and pays close attention to more and more widely.
The device of current disposal organic polluted soil, cause because of not carrying out pretreatment to soil treatment effeciency comparatively the end, do not consider that pollutant characteristic causes easily producing secondary pollution.
Summary of the invention
The purpose of this utility model is the above problem overcoming prior art existence, a kind of device of high-efficiency photocatalysis oxidization process organic polluted soil is provided, solves that common process organic polluted soil treatment effeciency is low, energy consumption is high, may produce the problem of secondary pollution.
For realizing above-mentioned technical purpose, reach above-mentioned technique effect, the utility model is achieved through the following technical solutions:
A device for high-efficiency photocatalysis oxidization process organic polluted soil, comprises the first reative cell and the second reative cell, and described second reative cell connects filter;
The first conveyer belt, one-level screen cloth, agitator, secondary screen cloth and the second conveyer belt is set gradually from top to bottom in described first reative cell;
Arrange gas treatment chamber and microwave generator in described second reative cell, described gas treatment indoor arrange ozone generator and oxidative synthesis system;
Described first reative cell connects gas treatment chamber by pipeline, and described pipeline arranges blower fan.
Preferably, the order number 4-5 of described one-level screen cloth.
Preferably, the order number 20-30 of described secondary screen cloth.
Described second conveyer belt runs through described first reative cell and described second reative cell.
The beneficial effects of the utility model are:
The utility model carries out pretreatment to soil, reduces contaminated soil particle diameter, coordinates heating using microwave, dusty gas is discharged effectively from soil, and the dusty gas discharged is removed under the synergy of ultraviolet light and ozone.
Gas treatment chamber efficiently can remove stench, removes the major pollutants such as volatile organic matter, inorganic matter, hydrogen sulfide, ammonia, thio-alcohol; Effectively can also prevent secondary pollution, the dusty gas of escaping out when pretreatment collected by pipeline is set in soil screening teeter chamber, is evacuated in microwave heating system by vavuum pump and carry out subsequent treatment.
The utility model operating cost is low, without any mechanical action, noiselessness, without the need to personal management and regular maintenance, only need make regular check on, equipment energy consumption is low, and without the need to adding any material, as long as arrange corresponding exhaust duct and air draft power, making waste gas by the utility model decomposing, purifying, participating in chemical reaction without the need to adding other materials.
Accompanying drawing explanation
Accompanying drawing described herein is used to provide further understanding of the present utility model, and form a application's part, schematic description and description of the present utility model, for explaining the utility model, is not formed improper restriction of the present utility model.In the accompanying drawings:
Fig. 1 overall structure schematic diagram.
Number in the figure illustrates: 1, the first conveyer belt, 2, one-level screen cloth, 3, agitator, 4, secondary screen cloth, 5, pipeline, 6, blower fan, 7, microwave generator, 8, ozone generator, 9, oxidative synthesis system, 10, filter, 11, the first reative cell, 12, the second reative cell, the 13, second conveyer belt, 14, gas treatment chamber.
Detailed description of the invention
Below with reference to the accompanying drawings and in conjunction with the embodiments, describe the utility model in detail.
With reference to shown in Fig. 1, a kind of device of high-efficiency photocatalysis oxidization process organic polluted soil, comprise the first reative cell 11 and the second reative cell 12, described second reative cell 12 connects filter 10;
The first conveyer belt 1, one-level screen cloth 2, agitator 3, secondary screen cloth 4 and the second conveyer belt 13 is set gradually from top to bottom in described first reative cell 11;
In described second reative cell 12, gas treatment chamber 14 and microwave generator 7 are set, ozone generator 8 and oxidative synthesis system 9 are set in described gas treatment chamber 14;
Described first reative cell 11 connects gas treatment chamber 14 by pipeline 5, and described pipeline 5 arranges blower fan 6.
Preferably, the order number 4-5 of described one-level screen cloth.
Preferably, the order number 20-30 of described secondary screen cloth.
Described second conveyer belt 13 runs through described first reative cell 11 and described second reative cell 12.
The operation principle of the present embodiment is as follows:
Soil is transported to one-level screen cloth 2 by the first conveyer belt 1, bulky stone filters out by one-level screen cloth 2, stirred by agitator 3 again, by the second conveyer belt, soil is transported to microwave generator 7 after again being fallen by contaminant filter by secondary screen cloth 4 again after being pulverized by stone larger for volume, through microwave disinfection, the residual gas of generation is sent to gas treatment chamber 14 by conduit.The gas produced in the first reative cell is sent to gas treatment chamber 14 by pipeline 5, through ozone generator and oxidative synthesis system, gas is resolved into carbon dioxide and water.
This technology is that the oxygen molecule utilizing high energy ultraviolet Line beam to decompose in air produces free oxygen, i.e. active oxygen, because negative ions entrained by free oxygen is uneven so need be combined with oxygen molecule, and then produces ozone.Organic Pollution material is converted into the simple inorganic matter such as carbon dioxide, water of nonhazardous by the highly active ion-oxygen (carboxyl free radical) that the oxidability of ozone and ozone produce under the irradiation of ultraviolet light, thus reaching the object of purifying exhaust air, this course of reaction is a kind of advanced oxidation processes under high energy ultraviolet beta radiation and ozone cooperative effect.
Ultraviolet light and the more independent ozone oxidation efficiency height of ozone cooperative effect are a lot, the decomposition of the irradiation meeting accelerate ozone of ultraviolet light, the oxidizing potential (2.07ev) of the ozone that the oxidizing potential (2.8ev) of living radical OH produced is more extremely strong than oxidisability is also high by 35%, therefore carboxyl free radical and organic reaction speed exceed several order of magnitude, and the reaction of carboxyl free radical to oxidize contaminants is non-selectivity, chain reaction can be caused, therefore organic pollution materials, stench can not only by ozone direct oxidation, and can be oxidized by the product carboxyl free radical of ozone decomposed, and the latter occupies an leading position under action of ultraviolet light.
The foregoing is only preferred embodiment of the present utility model, be not limited to the utility model, for a person skilled in the art, the utility model can have various modifications and variations.All within spirit of the present utility model and principle, any amendment done, equivalent replacement, improvement etc., all should be included within protection domain of the present utility model.
Claims (4)
1. a device for high-efficiency photocatalysis oxidization process organic polluted soil, is characterized in that: comprise the first reative cell (11) and the second reative cell (12), and described second reative cell (12) connects filter (10);
The first conveyer belt (1), one-level screen cloth (2), agitator (3), secondary screen cloth (4) and the second conveyer belt (13) is set gradually from top to bottom in described first reative cell (11);
Gas treatment chamber (14) and microwave generator (7) are set in described second reative cell (12), ozone generator (8) and oxidative synthesis system (9) are set in described gas treatment chamber (14);
Described first reative cell (11) connects described gas treatment chamber (14) by pipeline (5), described pipeline (5) is arranged blower fan (6).
2. the device of high-efficiency photocatalysis oxidization process organic polluted soil according to claim 1, is characterized in that: the order number 4-5 of described one-level screen cloth.
3. the device of high-efficiency photocatalysis oxidization process organic polluted soil according to claim 1, is characterized in that: the order number 20-30 of described secondary screen cloth.
4. the device of high-efficiency photocatalysis oxidization process organic polluted soil according to claim 1, is characterized in that: described second conveyer belt (13) runs through described first reative cell (11) and described second reative cell (12).
Priority Applications (1)
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CN201520059089.9U CN204429842U (en) | 2015-01-28 | 2015-01-28 | A kind of device of high-efficiency photocatalysis oxidization process organic polluted soil |
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CN201520059089.9U CN204429842U (en) | 2015-01-28 | 2015-01-28 | A kind of device of high-efficiency photocatalysis oxidization process organic polluted soil |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105457996A (en) * | 2015-12-18 | 2016-04-06 | 广东工业大学 | Method for remediating organic-contaminated place soil by using microwave in collaboration with sodium percarbonate |
CN106670223A (en) * | 2016-12-26 | 2017-05-17 | 上海岩土工程勘察设计研究院有限公司 | Two-phase ozone-ultraviolet light catalytic remediation method for organic polluted soil |
CN107716537A (en) * | 2017-09-08 | 2018-02-23 | 水利部交通运输部国家能源局南京水利科学研究院 | A kind of advanced oxidation reaction unit for purifying petroleum-contaminated soil |
CN113083883A (en) * | 2021-03-30 | 2021-07-09 | 常州大学 | Contaminated site heat-preservation in-situ remediation system and method |
-
2015
- 2015-01-28 CN CN201520059089.9U patent/CN204429842U/en not_active Expired - Fee Related
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105457996A (en) * | 2015-12-18 | 2016-04-06 | 广东工业大学 | Method for remediating organic-contaminated place soil by using microwave in collaboration with sodium percarbonate |
CN106670223A (en) * | 2016-12-26 | 2017-05-17 | 上海岩土工程勘察设计研究院有限公司 | Two-phase ozone-ultraviolet light catalytic remediation method for organic polluted soil |
CN106670223B (en) * | 2016-12-26 | 2020-04-28 | 上海勘察设计研究院(集团)有限公司 | Two-phase ozone-ultraviolet light catalysis repairing method for organic polluted soil |
CN107716537A (en) * | 2017-09-08 | 2018-02-23 | 水利部交通运输部国家能源局南京水利科学研究院 | A kind of advanced oxidation reaction unit for purifying petroleum-contaminated soil |
CN113083883A (en) * | 2021-03-30 | 2021-07-09 | 常州大学 | Contaminated site heat-preservation in-situ remediation system and method |
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C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CF01 | Termination of patent right due to non-payment of annual fee | ||
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Granted publication date: 20150701 Termination date: 20170128 |