CN204352744U - A kind of low-temperature flue gas oxidation and denitration system - Google Patents

A kind of low-temperature flue gas oxidation and denitration system Download PDF

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Publication number
CN204352744U
CN204352744U CN201420813558.7U CN201420813558U CN204352744U CN 204352744 U CN204352744 U CN 204352744U CN 201420813558 U CN201420813558 U CN 201420813558U CN 204352744 U CN204352744 U CN 204352744U
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China
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flue gas
oxidation
spraying layer
low
oxidizing tower
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CN201420813558.7U
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Chinese (zh)
Inventor
张汝松
刘畅
王猛
邓徐帧
展茂源
于鹏
刘清安
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Shandong Huate Environmental Protection Technology Co ltd
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SHANDONG SHANDA WIT ENVIRONMENT ENGINEERING Co Ltd
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Abstract

The utility model relates to a kind of low-temperature flue gas oxidation and denitration system, comprise oxidizing tower, oxidizing tower is divided into demist section, spray-absorption section, oxidation panel, the gas approach of oxidation panel divides two-way one tunnel to connect low-temperature flue gas pipe to be clean, leading up to chlorine dioxide blender, chlorine dioxide air blast communicates with chlorine dioxide gas generator, spray-absorption section comprises circulation fluid spraying layer, absorbing liquid spraying layer, absorbing liquid spraying layer connects absorption liquid bath by absorbing liquid spray pump, and circulation fluid spraying layer is communicated with the absorption liquid pool bottom oxidizing tower by oxidation cycle pump.The utility model selects ClO 2gas fully mixes with flue gas, realizes 50 ~ 80 DEG C of low-temperature denitrations, solves waste water handling problem, and the circulationization simultaneously achieving resource utilizes.Denitration efficiency of the present utility model can reach more than 85%.

Description

A kind of low-temperature flue gas oxidation and denitration system
Technical field
The utility model relates to a kind of coal-fired flue-gas oxidation and denitration system, particularly relates to a kind of low-temperature flue gas oxidation and denitration system, belongs to environmental protection technical field.
Background technology
Containing SO in the flue gas of coal-burning boiler 2, the pollutant such as NOx and heavy metal (Hg and Ag), day by day become the primary pollution source of air and soil pollution." 12 " period, China is NO xregion overall control scope is included in as the binding indicator.Therefore, NO is increased in existing flue-gas purification equipment xpurifier, become the inexorable trend of industry.
Research shows, the NOx total amount that in steel plant, various equipment is released accounts for second in fixing occurring source, is only second to SO 2discharge capacity.Wherein, about sintering production process NOx discharge accounts for the half of steel plant's NOx emission total amount.Therefore, to the strict control of sinter fume NOx discharge, the discharge capacity of the NOx of steel mill effectively can be reduced.
Sinter fume is after sinter mixture igniting, the dust-laden exhaust gas produced in high temperature sintering forming process, have that exhaust gas volumn is large, compared with high, flue gas, flue-gas temperature carry that dust is many, water capacity large, in flue gas containing being corrosive and the main feature such as toxic gas.Wherein: SO 2with the change of divergence of NOx concentration with iron ore raw material and fuel, SO 2concentration is generally within the scope of 300 ~ 800ppm, and high reaches 2000 ~ 4000ppm; NOx concentration generally changes within the scope of 150 ~ 300ppm, reaches as high as 500ppm.
In numerous denitration technology, only have SNCR and SCR method to obtain the application of good business at large coal-fired power plant.
SNCR (SNCR method) denitration technology is by NH 3, the reducing agent such as urea sprays in Boiler Furnace and carries out selective reaction with NOx, without catalyst, therefore must add reducing agent in high-temperature region.Reducing agent sprays into the region that fire box temperature is 850 ~ 1100 DEG C, and rapid thermal decomposition becomes NH3, reacts generate N with the NOx in flue gas 2and water, this technology take burner hearth as reactor.The denitration efficiency of SNCR gas denitrifying technology is generally 30% ~ 60%, very large by boiler structure size impact.
SCR selective catalytic reduction (selective catalytic reduction) denitration technology refers under the effect of catalyst, at reaction temperature 320 ~ 450 DEG C.Reducing agent (liquefied ammonia) generates harmless N with the reaction of nitrogen oxides in flue gas 2and water, thus remove the NOx in flue gas.Selectively refer to reducing agent NH 3there is reduction reaction with the NOx in flue gas, and do not react with the oxygen in flue gas.The denitration efficiency of SCR gas denitrifying technology can up to 95%.
Oxidative absorption method utilizes strong oxidizer NO partial oxidation to be become the NO soluble in water of high-valence state 2, then utilize absorbent to NO 2remove, good removal effect can be reached.Conventional oxidant has ozone, chlorine dioxide, hydrogen peroxide, sodium chlorite, clorox, potassium permanganate, chloric acid etc.Conventional absorbent has calcium hydroxide, NaOH, sodium sulfite, urea, ammoniacal liquor etc.Although oxidative absorption method can obtain higher denitration efficiency, but due to oxidant and absorbent price all costly, therefore, need by selecting economical and practical oxidant and absorbent, efficient process system is set, to ensure that oxidative absorption method becomes a kind of denitration technology of efficient, low cost.
SNCR denitration reaction temperature window is 850 DEG C ~ 1100 DEG C, and SCR denitration reaction temperature window is 320 DEG C ~ 450 DEG C.And steel works sintering flue-gas temperature is generally at 120 ~ 150 DEG C, therefore, if adopt SCR technology, also need to carry out heat temperature raising to flue gas, considerably increase operating cost.Therefore, the applicable coal-fired low-temperature denitration of flue gas technology of research is extremely urgent.
Utility model content
The purpose of this utility model overcomes above-mentioned deficiency, and provide a kind of low-temperature flue gas oxidation and denitration system, solves waste water handling problem, and the circulationization simultaneously achieving resource utilizes.
The technical scheme that the utility model is taked is:
A kind of low-temperature flue gas oxidation and denitration system, comprise oxidizing tower, oxidizing tower is divided into demist section, spray-absorption section, oxidation panel, the gas approach of oxidation panel divides two-way one tunnel to connect low-temperature flue gas pipe to be clean, leading up to chlorine dioxide blender, chlorine dioxide air blast communicates with chlorine dioxide gas generator, spray-absorption section comprises circulation fluid spraying layer, absorbing liquid spraying layer, absorbing liquid spraying layer connects absorption liquid bath by absorbing liquid spray pump, and circulation fluid spraying layer is communicated with the absorption liquid pool bottom oxidizing tower by oxidation cycle pump.
Liquid waste discharge pump is connected with bottom described oxidizing tower.
The top of described oxidizing tower is communicated with discharge chimney by exhanst gas outlet.
The aqueous solution being added with calcium oxide in described absorption liquid bath makes absorbent.
The utility model selects ClO 2gas fully mixes with flue gas, is oxidized to by NO and is easy to absorbed NO 2and N 2o 3, realize 50 ~ 80 DEG C of low-temperature denitrations.Select calcium oxide solution cheap and easy to get as absorbent, generate calcium nitrate, calcium nitrite, through removal of impurities, evaporation and concentration, crystallization after nitrous acid calcium solution is saturated, after purification processes, produce calcium nitrite.Thus solving waste water handling problem, the circulationization simultaneously achieving resource utilizes.Denitration efficiency of the present utility model can reach more than 85%.
Advantage of the present utility model is:
(1) ClO is selected 2gas instead of liquid be oxidant based on: chlorine dioxide gas-air mixer is abundant higher than gas-liquid mixing, and the uniformity is high, denitration efficiency is high; Gas-gas haptoreaction speed is fast, and gas-gas method oxidation and denitration reaction time needs about 1s, and oxidation panel only needs the height of 3 meters.Liquid-gas oxidation time is at more than 4s, and the height of oxidation panel needs more than 10m.In addition, liquid oxidation anti-corrosion measure is high; Chlorine Dioxide Gas and NO react the product NO produced 2still exist in gaseous form, then enter absorber portion and be removed.According to liquid spray, HCl and NO that reaction is produced 2once occur, will be dissolved in ClO 2 solution, be formed containing the watery hydrochloric acid of chlorine dioxide and dust technology mixed solution, corrosion is caused to denitrating tower and subsidiary pipeline, pump, and this acid solution be more difficult.
(2) selective oxidation calcium solution as absorbent based on: calcium oxide is cheap and easy to get, and small investment, operating cost are low, efficiency is high, can, simultaneously for flue gas desulfurization, be easy to realize desulfurization and denitrification integral.Have adaptation condition condition ability strong, invest the circulationization that little, that low-loss and energy-saving, efficiency are high and security performance is high technical advantage, particularly byproduct calcium nitrite achieve resource and utilize, simultaneously for enterprise brings newly-increased economic benefit.
(3) the utility model is particularly suitable for sintering machine, Industrial Boiler, furnace flue gas cigarette temperature instability, and the situation that load variations is large, without the requirement of SCR, SNCR reaction temperature window.The utility model proposes low-temperature denitration of flue gas system and can form integration desulfurization denitration technology with Wet Limestone-gypsum flue gas desulfurization.
Accompanying drawing explanation
Fig. 1 is the structural representation of the utility model embodiment;
Wherein 1-oxidizing tower, 2-absorbs liquid pool, 3-liquid waste discharge pump, 4-chlorine dioxide gas generator, 5-chlorine dioxide air blast, 6-chlorine dioxide blender, 7-oxidation cycle pump, 8-absorbing liquid spray pump, 9-absorbs liquid bath, 10-gas approach, 11-circulation fluid spraying layer, 12-absorbing liquid spraying layer, 13-demister, 14-exhanst gas outlet, 15-chimney.
Detailed description of the invention
Further illustrate below in conjunction with detailed description of the invention and embodiment.
As shown in Figure 1, a kind of low-temperature flue gas oxidation and denitration system, comprise oxidizing tower 1, oxidizing tower 1 is divided into demist section, spray-absorption section, oxidation panel, gas approach 10 points of two-way one tunnels of oxidation panel connect low-temperature flue gas pipe to be clean, lead up to chlorine dioxide blender 6, chlorine dioxide air blast 5 communicates with chlorine dioxide gas generator 4, spray-absorption section comprises circulation fluid spraying layer 11, absorbing liquid spraying layer 12, absorbing liquid spraying layer 12 connects absorption liquid bath 9 by absorbing liquid spray pump 8, circulation fluid spraying layer 11 is communicated with the absorption liquid pool 2 bottom oxidizing tower 1 by oxidation cycle pump 7.
Chlorine dioxide and denitration flue gas hybrid reaction before gas approach.Adopt chlorine dioxide and without chlorine dioxide liquid, be abundant in order to mix, react completely.Mixed flue gas enters oxidizing tower 1 from gas approach 10 and oxidation reaction occurs, and NO, at 50 ~ 80 DEG C, is oxidized into NO by reaction temperature 2and N 2o 3.Calcium oxide slurry storage is in slurry tank 9, slurries spray into oxidizing tower through slurries spray pump 8 from slurries spraying layer 12, loop slurry is extracted out in absorbing liquid storage tank 2, sprays into oxidizing tower through oxidation cycle pump 7 from circulation fluid spraying layer 11, and calcium oxide slurries and loop slurry fully absorb the NO after oxidation 2and N 2o 3; Absorbing liquid storage tank 2, liquid waste discharge pump 3 are that absorbing liquid storage and waste liquid discharge section, and the slurries after spray store at absorbing liquid storage tank 2, and major part is used for cyclic absorption spray, and after small part is concentrated, waste liquid discharges process by analysis afterwards.Flue gas after denitration enters chimney 15 through exhanst gas outlet 14 after demister 13 demist.
Embodiment
Illustrate for certain steel works sintering flue gas.Sintering device flue gas is after Limestone-gypsum Wet Flue Gas Desulfurization Process, flue-gas temperature now with denitration is at about 50 DEG C, the chlorine dioxide that chlorine dioxide gas generator 4 produces enters in chlorine dioxide blender 6 through chlorine dioxide air blast 5 drum, chlorine dioxide fully mixes with flue gas, and mixed flue gas enters oxidizing tower 1.NO xoxidizability control about 50%, ClO in oxidizing tower 1 2nO is oxidized to and is easy to absorbed NO by gas 2and N 2o 3.Absorbent lime liquid is first stored in and absorbs in liquid bath 9, the concentration of controlled oxidization calcium uptake liquid, absorbing liquid sprays into oxidizing tower through absorbing liquid spray pump 8 from absorbing liquid spraying layer 12, extract out in the absorption liquid pool 2 of circulating absorption solution bottom oxidizing tower, spray into oxidizing tower through oxidation cycle pump 7 from circulation fluid spraying layer 11, absorbing liquid and circulating absorption solution fully absorb the NO after oxidation 2and N 2o 3.Complete the neat stress after denitration to remove after droplet through demister 13 and enter chimney 15.In order to ensure spray-absorption effect, the absorbing liquid after spray stores at the absorption liquid pool 2 of bottom, and major part is used for cyclic absorption spray, and after small part is concentrated, waste liquid discharges process by analysis afterwards.Mainly containing calcium nitrite in waste liquid, containing small part calcium nitrate, through removal of impurities, evaporation and concentration, crystallization after nitrous acid calcium solution is saturated, produce solid calcium nitrite after purification processes, residue waste water enters enterprise's cesspool.Thus solve waste water handling problem, the circulationization achieving resource utilizes simultaneously.

Claims (3)

1. a low-temperature flue gas oxidation and denitration system, comprise oxidizing tower, oxidizing tower is divided into demist section, spray-absorption section, oxidation panel, it is characterized in that, the gas approach of oxidation panel divides two-way one tunnel to connect low-temperature flue gas pipe to be clean, leading up to chlorine dioxide blender, chlorine dioxide air blast communicates with chlorine dioxide gas generator, spray-absorption section comprises circulation fluid spraying layer, absorbing liquid spraying layer, absorbing liquid spraying layer connects absorption liquid bath by absorbing liquid spray pump, and circulation fluid spraying layer is communicated with the absorption liquid pool bottom oxidizing tower by oxidation cycle pump.
2. a kind of low-temperature flue gas oxidation and denitration system according to claim 1, is characterized in that, be connected with liquid waste discharge pump bottom described oxidizing tower.
3. a kind of low-temperature flue gas oxidation and denitration system according to claim 1, is characterized in that, the top of described oxidizing tower is communicated with discharge chimney by exhanst gas outlet.
CN201420813558.7U 2014-12-19 2014-12-19 A kind of low-temperature flue gas oxidation and denitration system Expired - Fee Related CN204352744U (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104437037A (en) * 2014-12-19 2015-03-25 山东山大华特环保工程有限公司 Low-temperature fume oxidizing and denitration method and system
CN107789967A (en) * 2017-11-27 2018-03-13 江苏垦乐节能环保科技有限公司 One kind sintering flue gas low-temperature denitrification apparatus and its implementation
CN111085100A (en) * 2019-12-31 2020-05-01 北京科吉发节能技术有限公司 Device and method for low-temperature denitration by industrial kiln dry method
CN111650972A (en) * 2020-06-12 2020-09-11 重庆科技学院 Multi-component dynamic gas distribution test system with mixer

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104437037A (en) * 2014-12-19 2015-03-25 山东山大华特环保工程有限公司 Low-temperature fume oxidizing and denitration method and system
CN107789967A (en) * 2017-11-27 2018-03-13 江苏垦乐节能环保科技有限公司 One kind sintering flue gas low-temperature denitrification apparatus and its implementation
CN107789967B (en) * 2017-11-27 2023-12-08 江苏垦乐节能环保科技有限公司 Sintering flue gas low-temperature denitration device and implementation method thereof
CN111085100A (en) * 2019-12-31 2020-05-01 北京科吉发节能技术有限公司 Device and method for low-temperature denitration by industrial kiln dry method
CN111650972A (en) * 2020-06-12 2020-09-11 重庆科技学院 Multi-component dynamic gas distribution test system with mixer

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Address after: 250101 Huate building, Shanda Science Park, Yingxiu Road, high tech Zone, Jinan City, Shandong Province

Patentee after: Shandong Shanda Huate Environmental Protection Technology Co.,Ltd.

Address before: 250101 Huate building, Shanda Science Park, Yingxiu Road, Lixia District, Jinan City, Shandong Province

Patentee before: SHANDONG SHANDA WIT ENVIRONMENTAL ENGINEERING Co.,Ltd.

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Address after: 250101 Huate building, Shanda Science Park, Yingxiu Road, high tech Zone, Jinan City, Shandong Province

Patentee after: Shandong Huate Environmental Protection Technology Co.,Ltd.

Address before: 250101 Huate building, Shanda Science Park, Yingxiu Road, high tech Zone, Jinan City, Shandong Province

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Granted publication date: 20150527