CN204234105U - A kind of online hydrogen type cation exchange resin regenerating unit - Google Patents

A kind of online hydrogen type cation exchange resin regenerating unit Download PDF

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Publication number
CN204234105U
CN204234105U CN201420495314.9U CN201420495314U CN204234105U CN 204234105 U CN204234105 U CN 204234105U CN 201420495314 U CN201420495314 U CN 201420495314U CN 204234105 U CN204234105 U CN 204234105U
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unit
resin
acid solution
cation exchange
exchange resin
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CN201420495314.9U
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严文群
陈晓宏
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Pangang Group Xichang Steel and Vanadium Co Ltd
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Pangang Group Xichang Steel and Vanadium Co Ltd
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Abstract

Of the present utility modelly provide a kind of online hydrogen type cation exchange resin regenerating unit.Described regenerating unit comprises: resin holds unit, acid solution memory cell, alkali lye memory cell, acid solution pipe, alkali liquor pipe and discharging tube, and wherein, described resin holds in unit and is contained with hydrogen type cation exchange resin; Acid soak is stored in described acid solution storage element; Described alkali lye memory cell contains alkaline soak; The entrance that the outlet of the acid solution of acid solution storage element and resin hold unit is communicated with by described acid solution pipe; The entrance that the outlet of the alkali lye of alkali storage unit and resin hold unit is communicated with by described alkali liquor pipe; Described discharging tube and resin hold the outlet of unit.The utility model, without the need to arranging ion exchange bed, directly can carry out on-line regeneration process to hydrogen type cation exchange resin.

Description

A kind of online hydrogen type cation exchange resin regenerating unit
Technical field
The utility model relates to hydrogen conductivity detection auxiliary equipment, specifically, relates to a kind of device that can carry out on-line regeneration to the form ion exchange resin for measuring hydrogen conductivity.
Background technology
Usually, in the process of water quality judging the water bodys such as such as condensed water in boiler, feedwater, steam, need by monitoring its hydrogen conductivity to judge the quality of water quality delicately.Therefore, can Accurate Determining hydrogen conductivity value, be related to and can judge the contaminated degree of the water body such as boiler or steam system in time, exactly.Hydrogen conductivity is after continuously flowing through form ion exchange resin by detected water sample, carries out to its electrical conductivity the conductivity value that on-line monitoring obtains.
And form ion exchange resin regeneration is incomplete or rinse insufficient, discharging foreign ion can cause positive error, the low polymer impurity discharged, and can reduce detection sensitivity, and the effect of thus resin regeneration is directly connected to the degree of accuracy of testing result.
Inventor finds, for the mode by ion exchange bed regeneration process form ion exchange resin, its equipment requirement is high, it is high to invest, and on-line continuous can not carry out regeneration and process.Therefore, a kind of device that can carry out on-line regeneration process to form ion exchange resin of research and development is needed badly.
Utility model content
The purpose of this utility model is at least one item solved in the problems referred to above of prior art existence.
Such as, one of the purpose of this utility model is to provide a kind of need arrange ion exchange bed and directly carry out online at the device becoming process form ion exchange resin.
Of the present utility modelly provide a kind of online hydrogen type cation exchange resin regenerating unit.Described regenerating unit comprises: resin holds unit, acid solution memory cell, alkali lye memory cell, acid solution pipe, alkali liquor pipe and discharging tube, and wherein, described resin holds in unit and is contained with hydrogen type cation exchange resin; Acid soak is stored in described acid solution storage element; Described alkali lye memory cell contains alkaline soak; The entrance that the outlet of the acid solution of acid solution storage element and resin hold unit is communicated with by described acid solution pipe; The entrance that the outlet of the alkali lye of alkali storage unit and resin hold unit is communicated with by described alkali liquor pipe; Described discharging tube and resin hold the outlet of unit.
In an exemplary embodiment of the present utility model, described regenerating unit also can comprise fluid cushion container, and this fluid cushion container to be arranged on acid solution pipe and/or alkali liquor pipe and to be positioned at described resin and holds on the entrance of unit.
In an exemplary embodiment of the present utility model, described regenerating unit also can comprise rinse water feed unit, this rinse water feed unit and fluid cushion reservoir to fluid cushion supply for receptacles rinse water.
In an exemplary embodiment of the present utility model, described regenerating unit also can comprise the fluid pump be arranged on acid solution pipe and/or alkali liquor pipe, and fluid pump is positioned at fluid cushion vessels upstream.
Compared with prior art, the utility model, without the need to arranging ion exchange bed, directly can carry out on-line regeneration process to hydrogen type cation exchange resin.
Accompanying drawing explanation
Fig. 1 shows the structural representation of an exemplary embodiment of online form ion exchange resin regenerating unit of the present utility model.
Description of reference numerals is as follows:
1-resin holds unit, 2-acid solution tank, 3-alkali liquid tank, 4-acid solution pipe, 5-alkali liquor pipe, 6-fluid pump, 7-drainpipe and 8-fluid cushion container.
Detailed description of the invention
Hereinafter, online form ion exchange resin regenerating unit of the present utility model will be described in detail in conjunction with exemplary embodiment and accompanying drawing thereof.
As shown in Figure 1, in an exemplary embodiment of the present utility model, online form ion exchange resin regenerating unit comprises: resin holds unit 1, acid solution memory cell 2, alkali lye memory cell 3, acid solution pipe 4, alkali liquor pipe 5, fluid pump 6, drainpipe 7, fluid cushion container 8 and rinse water feed unit (not shown).
Wherein, it can be tank body or a body with entrance and exit that resin holds unit (such as, resin cartridge), is contained with hydrogen type cation exchange resin in this tank body or body.Such as, resin holds unit can be the pitch tube of hydrogen conductivity measuring instrument.Resin holds the vertical setting of unit, namely with its entrance be positioned at top and its outlet below mode arrange.
Store acid soak in acid solution storage element, it has acid solution outlet.Such as, acid solution storage element can for storing the acid solution tank of acidic liquid.Acidic liquid in acid solution tank can be watery hydrochloric acid (HCl) solution, such as, can be the HCl solution of 5%.
Alkali storage element memory contains alkaline soak, and it has alkali lye outlet.Such as, alkali storage unit can for storing the alkali liquid tank of akaline liquid.Akaline liquid in alkali liquid tank can be sig water (as NaOH solution), such as, can be the NaOH solution of 2%.
The entrance that the outlet of the acid solution of acid solution storage element and resin hold unit is communicated with by acid solution pipe, thus the acid soak in acid solution storage element can be held unit to resin and provide.The entrance that the outlet of the alkali lye of alkali storage unit and resin hold unit is communicated with by alkali liquor pipe, thus the alkaline soak in alkali storage unit can be held unit to resin and provide.Discharging tube and resin hold the outlet of unit, to discharge soaking the acid soak of hydrogen type cation exchange resin or alkaline soak or rinse water.In addition, online form ion exchange resin regenerating unit also can comprise the waste liquid barrel for containing acid pickle or the spent lye of discharging in discharging tube.
Fluid cushion container to be arranged on acid solution pipe and/or alkali liquor pipe and to be positioned at resin and holds on the entrance of unit.Fluid cushion container can enter before resin holds unit at acid soak or alkaline soak, plays cushioning effect to fluid.Rinse water feed unit and fluid cushion reservoir to fluid cushion supply for receptacles rinse water, the resin that rinse water is used for cleaning resin holds in unit cleans.
Fluid pump 6 (such as, vavuum pump) is arranged on acid solution pipe and/or alkali liquor pipe, and fluid pump is positioned at fluid cushion vessels upstream.That is, fluid pump is between fluid cushion container and acid solution memory cell or alkali lye memory cell.
In addition, as shown in Figure 1, the tract of alkali liquor pipe and the tract of acid solution pipe can merge into same pipeline by triple valve.
The online hydrogen type cation exchange resin regenerating unit of this exemplary embodiment can be used for carrying out regeneration process to new hydrogen type cation exchange resin; Also may be used for the hydrogen type cation exchange resin after to inefficacy and carry out regeneration process.
The process new hydrogen type cation exchange resin being carried out regenerating to process can be: pending resin is loaded resin and holds in unit by (1), with low discharge flushing water, the resin that resin holds in unit is rinsed, in production of resins process, the impurity be mixed in the surplus materials of reaction and manufacture process is not participated in, till backwash is limpid with draining with removing.(2) soak resin 4 hours with the HCl solution of 5%, then rinse to neutral, to remove the inorganic impurity in resin with flushing water.(3) soak resin 4 hours by the NaOH solution of 2%, bleed off alkali lye afterflush resin to draining close to neutral, to remove the organic matter in resin.
Process hydrogen type cation exchange resin after inefficacy being carried out regenerating to process can be: rinsed well by resin flushing water, then soaks clean resin 4 hours with the hydrochloric acid solution of 5%, is rinsed well by resin rear for subsequent use with pure water.
Preferably should note following item when regenerating: A, new resin should be avoided it dewater before pre-processing, otherwise not directly process it, for the new resin normally do not dewatered can directly colourless to draining with water flushing, carry out pretreatment again without after hardness.The volume of B, soak generally gets 2 times to the volume of resin, in the hope of fully being soaked by resin.C, for marginally changing resin, can to carry out in outside anticorrosion container, not pretreated new resin should be avoided directly to dose in interchanger.D, for carrying out the pretreated interchanger of new resin, before regeneration, must big reverse washing be carried out, and should small reverse washing be carried out before big reverse washing.
Online hydrogen type cation exchange resin regenerating unit of the present utility model can effectively solve without ion exchange bed, resin replacement present situation frequently, directly on-line regeneration process is carried out to resin, and can reduce and safeguard labour intensity, save maintenance cost, there is good reliability and practicality.
Although describe the utility model with exemplary embodiment by reference to the accompanying drawings above, those of ordinary skill in the art should be clear, when not departing from the spirit and scope of claim, can carry out various amendment to above-described embodiment.

Claims (4)

1. an online hydrogen type cation exchange resin regenerating unit, it is characterized in that, described regenerating unit comprises: resin holds unit, acid solution memory cell, alkali lye memory cell, acid solution pipe, alkali liquor pipe and discharging tube, wherein, described resin holds in unit and is contained with hydrogen type cation exchange resin; Acid soak is stored in described acid solution storage element; Described alkali lye memory cell contains alkaline soak; The entrance that the outlet of the acid solution of acid solution storage element and resin hold unit is communicated with by described acid solution pipe; The entrance that the outlet of the alkali lye of alkali storage unit and resin hold unit is communicated with by described alkali liquor pipe; Described discharging tube and resin hold the outlet of unit.
2. online hydrogen type cation exchange resin regenerating unit according to claim 1, it is characterized in that, described regenerating unit also comprises fluid cushion container, and this fluid cushion container to be arranged on acid solution pipe and/or alkali liquor pipe and to be positioned at described resin and holds on the entrance of unit.
3. online hydrogen type cation exchange resin regenerating unit according to claim 2, it is characterized in that, described regenerating unit also comprises rinse water feed unit, this rinse water feed unit and fluid cushion reservoir to fluid cushion supply for receptacles rinse water.
4. online hydrogen type cation exchange resin regenerating unit according to claim 2, it is characterized in that, described regenerating unit also comprises the fluid pump be arranged on acid solution pipe and/or alkali liquor pipe, and fluid pump is positioned at fluid cushion vessels upstream.
CN201420495314.9U 2014-08-29 2014-08-29 A kind of online hydrogen type cation exchange resin regenerating unit Active CN204234105U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105482018A (en) * 2015-12-24 2016-04-13 新疆中泰化学股份有限公司 Hydrogen type chelating resin and preparation method and regeneration method thereof
CN112808325A (en) * 2021-02-01 2021-05-18 国投钦州发电有限公司 Hydrogen type cation exchange resin regeneration device and operation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105482018A (en) * 2015-12-24 2016-04-13 新疆中泰化学股份有限公司 Hydrogen type chelating resin and preparation method and regeneration method thereof
CN105482018B (en) * 2015-12-24 2018-06-19 新疆中泰化学股份有限公司 Hydrogen chelating resin and preparation method thereof and regeneration method
CN112808325A (en) * 2021-02-01 2021-05-18 国投钦州发电有限公司 Hydrogen type cation exchange resin regeneration device and operation method thereof

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