CN204208576U - For the equipment of coated substrates - Google Patents
For the equipment of coated substrates Download PDFInfo
- Publication number
- CN204208576U CN204208576U CN201420308233.3U CN201420308233U CN204208576U CN 204208576 U CN204208576 U CN 204208576U CN 201420308233 U CN201420308233 U CN 201420308233U CN 204208576 U CN204208576 U CN 204208576U
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- China
- Prior art keywords
- coating
- sensor
- matrix
- coating room
- room
- Prior art date
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- Expired - Lifetime
Links
- 239000000758 substrate Substances 0.000 title claims abstract description 11
- 238000000576 coating method Methods 0.000 claims abstract description 170
- 239000011248 coating agent Substances 0.000 claims abstract description 169
- 239000011159 matrix material Substances 0.000 claims abstract description 51
- 239000007788 liquid Substances 0.000 claims abstract description 31
- 239000003054 catalyst Substances 0.000 claims abstract description 14
- 230000004323 axial length Effects 0.000 claims abstract description 5
- 230000002093 peripheral effect Effects 0.000 claims abstract description 5
- 239000000463 material Substances 0.000 abstract description 31
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 13
- 239000007789 gas Substances 0.000 description 13
- 238000000034 method Methods 0.000 description 12
- 229910052751 metal Inorganic materials 0.000 description 11
- 239000002184 metal Substances 0.000 description 11
- 241000264877 Hippospongia communis Species 0.000 description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- 229910045601 alloy Inorganic materials 0.000 description 6
- 239000000956 alloy Substances 0.000 description 6
- 230000003197 catalytic effect Effects 0.000 description 6
- 239000000945 filler Substances 0.000 description 6
- 239000000919 ceramic Substances 0.000 description 5
- 239000000725 suspension Substances 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 4
- 238000006555 catalytic reaction Methods 0.000 description 4
- 230000002349 favourable effect Effects 0.000 description 4
- 239000012530 fluid Substances 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- 238000005086 pumping Methods 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 3
- 238000004061 bleaching Methods 0.000 description 3
- 229910052804 chromium Inorganic materials 0.000 description 3
- 239000011651 chromium Substances 0.000 description 3
- 238000006073 displacement reaction Methods 0.000 description 3
- 230000001788 irregular Effects 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 239000002243 precursor Substances 0.000 description 3
- 229910052726 zirconium Inorganic materials 0.000 description 3
- 241001466460 Alveolata Species 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 229910052581 Si3N4 Inorganic materials 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910000323 aluminium silicate Inorganic materials 0.000 description 2
- HEHRHMRHPUNLIR-UHFFFAOYSA-N aluminum;hydroxy-[hydroxy(oxo)silyl]oxy-oxosilane;lithium Chemical compound [Li].[Al].O[Si](=O)O[Si](O)=O.O[Si](=O)O[Si](O)=O HEHRHMRHPUNLIR-UHFFFAOYSA-N 0.000 description 2
- CNLWCVNCHLKFHK-UHFFFAOYSA-N aluminum;lithium;dioxido(oxo)silane Chemical compound [Li+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O CNLWCVNCHLKFHK-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 239000008199 coating composition Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 229910052878 cordierite Inorganic materials 0.000 description 2
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229910052809 inorganic oxide Inorganic materials 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 229910052746 lanthanum Inorganic materials 0.000 description 2
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 2
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 2
- 239000000391 magnesium silicate Substances 0.000 description 2
- 229910052919 magnesium silicate Inorganic materials 0.000 description 2
- 235000019792 magnesium silicate Nutrition 0.000 description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 2
- 229910001092 metal group alloy Inorganic materials 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 229910052863 mullite Inorganic materials 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- 229910052670 petalite Inorganic materials 0.000 description 2
- 239000011819 refractory material Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 2
- 229910052642 spodumene Inorganic materials 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 2
- 229910052845 zircon Inorganic materials 0.000 description 2
- 229910052684 Cerium Inorganic materials 0.000 description 1
- 229910052692 Dysprosium Inorganic materials 0.000 description 1
- 229910052691 Erbium Inorganic materials 0.000 description 1
- 229910052693 Europium Inorganic materials 0.000 description 1
- 229910001200 Ferrotitanium Inorganic materials 0.000 description 1
- 229910052688 Gadolinium Inorganic materials 0.000 description 1
- 244000287680 Garcinia dulcis Species 0.000 description 1
- 229910052689 Holmium Inorganic materials 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- 229910052779 Neodymium Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 1
- IOVCWXUNBOPUCH-UHFFFAOYSA-N Nitrous acid Chemical compound ON=O IOVCWXUNBOPUCH-UHFFFAOYSA-N 0.000 description 1
- 229910052777 Praseodymium Inorganic materials 0.000 description 1
- 229910052773 Promethium Inorganic materials 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 229910052772 Samarium Inorganic materials 0.000 description 1
- 229910052771 Terbium Inorganic materials 0.000 description 1
- 229910052775 Thulium Inorganic materials 0.000 description 1
- 229910052769 Ytterbium Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- KBQHZAAAGSGFKK-UHFFFAOYSA-N dysprosium atom Chemical compound [Dy] KBQHZAAAGSGFKK-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- UYAHIZSMUZPPFV-UHFFFAOYSA-N erbium Chemical compound [Er] UYAHIZSMUZPPFV-UHFFFAOYSA-N 0.000 description 1
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- KJZYNXUDTRRSPN-UHFFFAOYSA-N holmium atom Chemical compound [Ho] KJZYNXUDTRRSPN-UHFFFAOYSA-N 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229910052622 kaolinite Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 description 1
- YXVOBWSDHRTYCG-UHFFFAOYSA-N nitrous acid platinum Chemical compound [Pt].N(=O)O YXVOBWSDHRTYCG-UHFFFAOYSA-N 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- GPNDARIEYHPYAY-UHFFFAOYSA-N palladium(ii) nitrate Chemical compound [Pd+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O GPNDARIEYHPYAY-UHFFFAOYSA-N 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- NWAHZABTSDUXMJ-UHFFFAOYSA-N platinum(2+);dinitrate Chemical compound [Pt+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O NWAHZABTSDUXMJ-UHFFFAOYSA-N 0.000 description 1
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- VQMWBBYLQSCNPO-UHFFFAOYSA-N promethium atom Chemical compound [Pm] VQMWBBYLQSCNPO-UHFFFAOYSA-N 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 239000003870 refractory metal Substances 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- KZUNJOHGWZRPMI-UHFFFAOYSA-N samarium atom Chemical compound [Sm] KZUNJOHGWZRPMI-UHFFFAOYSA-N 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- GZCRRIHWUXGPOV-UHFFFAOYSA-N terbium atom Chemical compound [Tb] GZCRRIHWUXGPOV-UHFFFAOYSA-N 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Landscapes
- Catalysts (AREA)
- Exhaust Gas After Treatment (AREA)
Abstract
The utility model relates to a kind of equipment for coated substrates, described matrix is used to generate the exhaust gas purifying catalyst for motor vehicle, described matrix is cylindrical carrier and all has two end faces, peripheral surface and axial length L, and is horizontally through by the passage that many scribble liquid coating from the first end face to the second end face.Described equipment comprises: coating room; Described coating room comprises the device checking the height of coating in coating room by measuring a certain variable.Described device can: independently by lower sensor and at least described variable measured by first sensor and the second sensor; And the variable recorded is compared to each other.It is be ready to be delivered to material all in one piece or need to give replacing before coating material all in one piece directly test that the utility model achieves for the coating in coating room.
Description
Technical field
The utility model relates to a kind of equipment improving the accuracy of coated ceramic body or metallic honeycomb bodies, and described ceramic body or metallic honeycomb bodies can be used as the catalyst reducing motor vehicle exhaust gases usually.It is be ready to be delivered to material all in one piece or need to give replacing before coating material all in one piece directly test that the utility model achieves for the coating in coating room.
Background technology
With liquid coated media (so-called aqueous coating) coated with under be referred to as the ceramic body of matrix or material all in one piece or metallic honeycomb bodies/filter during can produce various problem.A kind of feasible program for coated substrates impels the opening of matrix side to be formed with the coated media that can obtain from the below of material all in one piece or top to contact, and pass through the passage extracting liquid coated media of matrix by applying vacuum to the opposite side of matrix.If plan only applies passage in a part of length of passage, so cause due to the inevitable flow behavior occurred when using these deemed-to-satisfy4 means and apply different passages with different length, this is disadvantageous.
If overcoming gravity forces by pressure is pressed in passage by coated media, so just need to check when (normally being checked by sensor) occurs liquid at top when completing passage coating.When applying a part of length of passage, the liquid-column height of the coated media in passage is generally by with sensor (capacitance sensor; Vision sensor; Infrared sensor; Vibrating sensor) directly or indirectly measure and determine.But be in this case equally, if such as coating starts with the irregular coating surface formed in the coating room below material all in one piece, that just may cause coating uneven in the passage of material all in one piece anterior.Especially, if apply fast coating speed and coating tends to be pumped in coating room at short notice time become turbulent flow, that just there will be this situation below.
A kind of preferred coating equipment and method is disclosed in DE102010007499A1, wherein cylindrical carrier all has two end faces, peripheral surface and axial length L, and is horizontally through by the passage that many scribble liquid-liquid coated media from the first end face to the second end face.Described equipment has cylinder that liquid is housed and has piston, and the cylinder that liquid is wherein housed is communicated with tank, is arranged in such a way displacement body in the inside of tank: when piston moves, displacement body is moved pro rata by liquid.Tank is communicated with the coating unit for matrix, and displacement body acts in liquid coated media thus, consequently causes the proportional change (Fig. 1 see this application) of the liquid level of liquid coated media in coating unit.Two sensors are arranged on the phase co-altitude in coating equipment, and object is to check whether the paint surface locations in coating room has reached certain liquid level.
It is evident that the painting method can implementing coating processing in order to disposable coating parts as much as possible is more rapidly preferred.This process should not reduce the accuracy of coating certainly; Particularly when regionality coating material all in one piece, the area end that the accuracy of coating height must be applicable to the coating allowed in monolith channels in the threshold range of ± 5mm, preferably in ± 3mm or even less threshold range.
If coating speed increases, so the filler of coating room must carry out in the short period of time.This just causes the filler that the turbulent flow in the coating room of the characteristic of bearing aqueous coating and erecting tools is possibly stronger, causes irregular coating surface in coating room or cause to occur bubble significantly around the coating near coating room wall portion.If coating processing continues, this just will also cause irregular coating anterior in the passage of material all in one piece, and therefore will increase the coated substandard risk of parts.
Therefore target of the present utility model is to provide a kind of equipment and using method thereof for reducing above-mentioned adverse effect when performing the coating of automotive catalysts.Especially, which coating surface described equipment directly and easily should be able to distinguish between the coating surface in coating room relative to out-of-flatness or slightly to rise and fall may be maybe smooth containing those coating surfaces alveolate.If coating continue, so out-of-flatness or slightly rise and fall maybe may containing alveolate coating surface will make the mistake coating parts.
Utility model content
Consider prior art, the various targets that it will be apparent to those skilled in the art that solve according to equipment described in the utility model by applying in the method for applying honeycomb-type monolith.
There is provided herein a kind of for the equipment of coated substrates for generation exhaust gas purifying catalyst, described exhaust gas purifying catalyst is especially for motor vehicle, described matrix is cylindrical carrier and all has two end faces, peripheral surface and axial length L, and is horizontally through by the passage that many scribble liquid coating from the first end face to the second end face;
Described equipment comprises:
Coating room, described coating room is designed to receive described matrix from top and described matrix is attached to described coating room in the mode of hydraulic seal, and described coating room can also receive described coating from below;
Described coating room also comprises the device checking the height of described coating in described coating room by measuring a certain variable;
Described device has a sensor relative to the lower position place of at least first sensor and the second sensor in described coating room, and described at least first sensor and the second sensor are installed on height identical in described coating room;
Described device can:
-measure described variable independently by described lower sensor and described at least first sensor and the second sensor; And
-variable recorded is compared to each other.
Preferably, described at least first sensor and the second sensor around described coating room with Distance positioning maximum to each other.
Preferably, described variable is electronic variable and can selects from the group be made up of electric current, electric capacity and frequency.
Preferably, if the time delay between described electronic variable is lower than predetermined value, then described device provides prompting.
Preferably, described matrix is wall-flow filter or flow-through monolith.
Accompanying drawing explanation
Fig. 1 shows the device for the passage in coated substrates of the present utility model;
Fig. 2 shows the enlarged drawing of a part in Fig. 1 shown device.
Detailed description of the invention
A kind of favourable process for applying described matrix is realized by the utility model.Can check whether the coating be introduced in coating room 100 has been ready to be accepted by attached material all in one piece 121 by equipment of the present utility model.Coating seems out-of-flatness or comprises bubble in some cases, as by the agency of (Fig. 2).If coating processing continues, this forms disturbed coating by causing in the passage 110 of material all in one piece.For the coating processing only performed in a part of length of material all in one piece, this causes the different zone length for different passage in itself, thus correspondingly obviously increases the coated substandard risk of material all in one piece.If coating speed increases further, and the speed therefore introducing coating in coating room increases further, and this situation even can become more obvious.
But, if the surface exhibits being pumped into the coating 130 in coating room is smooth outward appearance (Fig. 1), so coating processing is just obtained by coating 113 or even the material all in one piece 121 of humidity, and in the passage 110 of material all in one piece, form the coating 132 of equal area width.At this, equipment in the utility model can carry out detecting and distinguishing between the surface of smooth and out-of-flatness just before will applying material all in one piece in coating room 100 or disturbed coating 130, coating processing can produce the material all in one piece of mistake coating and must destroy subsequently or even cause client reject before interrupt in time.On the contrary, if necessary, after emptying coating room along backflow direction 118, can be introduced by pipeline 116 and start the new filler of coating room 110 along filler flow direction 117 in advance, and if equipment shows smooth coating surface 130 in coating room, so advantageously just material all in one piece can be applied at this moment.
The measurement of the apparent height of the coating in coating room 100 is implemented by the sensor 123-125 being connected to CPU 140.From below 116,117 in coating room 100 during pumping coating, first coating arrive the sensor 124 of coating room 100 compared with low side, and then, in the ideal case, sensor 124 is contacted by liquid coating with 125 simultaneously.Therefore, processing unit 140 detects the signal from two sensors within certain still very short time period.Whether smooth in order to check the surface of coating, described at least the first and second sensors preferably around coating room with Distance positioning maximum to each other.Contribute to the possibility maximizing flat appearance coating really being detected like this.When have such as have three or four sensors more than two higher sensors, be similar to the first and second sensors, described sensor is respective but the distribution on identical height advantageously realizes according to these rules in coating room 100.Therefore, more three sensors around coating room 100 with the angle orientation of 120 degree to each other, by that analogy.Processing unit 140 is connected to like these more sensor class.
Coating surface 130 arrive sensor 123 and 125 and respectively by these sensors and sensor 124 bridge joint time, send signal to processing unit 140 and the accuracy being calculated coating surface 130 by processing unit 140 whether in threshold range.Some values that can be measured by sensor 123-125 can be considered by those skilled in the art.
Can select in this respect can for all the sensors of those skilled in the art (
http:// en.wikipedia.org/wiki/Level_sensor).In a kind of advantageous applications, the utility model uses electronic variable in this respect, and described electronic variable can be selected from the group be made up of electric current, electric capacity and frequency.In possibility, can use vibrating sensor such as liquid-level switch (
http:// www.vega.com/en/Level_switch_vibration.htm).
As mentioned above, processing unit 140 determines that whether coating surface 130 is enough accurate, and object is the process in order to continue to apply material all in one piece 121.The time delay preferably arrived between unit 140 according to the signal sent from sensor 123 and 125 respectively and two signals about the analysis whether continued is carried out.Therefore, if the time delay between the variable recorded is greater than predetermined value, then described device provides prompting is favourable.This delay value depends on the coating of use and the overall coating speed of imagination to a great extent, and for conventional coating/coating, more preferably be set to be less than 1 second, more preferably be set to be less than 0.5 second further, and be most preferably set to be less than 0.1 second or or even be less than 0.01 second (vide infra).
The material all in one piece that can be used for coating processing of the present utility model or coating equipment is well known by persons skilled in the art.Preferably, be so-called wall-flow filter or flow-through monolith with the matrix that equipment of the present utility model applies.Matrix can be made up of those materials being generally used for Kaolinite Preparation of Catalyst as used herein, and preferably includes pottery or metal honeycomb structure.Suitable matrix can be used such as to have neat, the parallel gas flow channel such material all in one piece formula matrix extended through from the input face of matrix to output face wherein, flow therethrough (being referred to as honeycomb circulation type matrix) for allowing fluid to make channel opener.Substantially be that the passage extending to its fluid outlet from its fluid input port is defined by wall portion, in wall portion or in wall portion, apply catalysis material as aqueous coating to make to flow through the gas contact catalysis material of passage.The flow channel of material all in one piece formula matrix is thin-walled channels, and flow channel can be the shape of cross section of any appropriate and size such as trapezoidal, rectangle, square, waveform, hexagon, ellipse, circle etc.Such structure can comprise about 400-900 or more gas input port (namely grid) (i.e. 62-140 grid/cm in cross-sectional area per square inch
2).
Ceramic matrix can be made up of the refractory material of any appropriate, such as cordierite, cordierite-aluminium oxide, silicon nitride, zirconium mullite, spodumene, magnesia-alumina-silica, zirconium silicate, magnesium silicate, zircon, petalite, aluminium oxide, aluminosilicate etc.The matrix being effective to catalyst component of the present utility model can be also metal in essence, and can be made up of one or more metal or metal alloy.Metallic matrix can use with the form of various shape such as corrugated plating or material all in one piece.Preferred metallic carrier comprises heating resisting metal and metal alloy such as titanium and stainless steel and other is alloy that is basic or key component with iron.Such alloy can comprise in nickel, chromium and/or aluminium one or more, and the total amount of these metals can advantageously form alloy at least about 15% weight, the such as chromium of about 10-25% weight, the aluminium of about 3-8% weight and the nickel of the highest about 20% weight.Alloy also can comprise other metal such as manganese, copper, vanadium, titanium etc. of a small amount of or micro-one or more.The surface of metallic matrix can be oxidized under such as about 1000 DEG C and higher high temperature, thus by forming the corrosion resistance that oxide layer improves alloy on the surface of matrix.The oxidation that such high temperature causes can strengthen refractory metal oxide carriers and promote that the metal component of catalysis is to the tack of matrix.
Matrix also can be honeycomb wall-flow filters.Wall-flow type matrix for carrying coating composition has that many longitudinal axis along matrix extend, neat, substantially parallel gas flow channel.Usually, each passage is closed in one end of matrix and the passage replaced is closed at relative end face.Particular wall streaming matrix for using in equipment of the present utility model comprises thin porous wall honeycombs (material all in one piece), and fluid flows therethrough and can not cause excessive back pressure rising or the pressure drop across object.Usually, the existence of clean wall-flow type object will form the back pressure of 0.036psi to 10psi.These ceramic wall flow matrixes can be made up of the refractory material of any appropriate, such as cordierite, cordierite-aluminium oxide, silicon nitride, zirconium mullite, spodumene, magnesia-alumina-silica, zirconium silicate, magnesium silicate, zircon, petalite, aluminium oxide, aluminosilicate etc.They are preferably made up of at least about the material of 5 microns (such as from 5 microns to 30 microns) at least about 40% (such as from 40% to 70%), average pore size porosity.More preferably, matrix has the porosity of at least 46% and has the average pore size of at least 10 microns.When there is the matrix of such porosity and such average pore size with the coating of above-mentioned equipment, to realize splendid contamination transform efficiency and to burn cigarette ash on the hole that enough coating compositions can be loaded into matrix and/or in hole.Although these matrixes are loaded with catalyst also still can keep enough exhaust-gas flow characteristics i.e. acceptable back pressure.Such as in US Patent No. 4329162, disclose suitable wall-flow type matrix.
Term " coating " should be understood to imply the catalytically-active materials and/or storage component that apply on the basic carrier for inertia, and described carrier can build by the mode of above-mentioned wall-flow filter or flow-through monolith.Coating performs actual catalysis and comprises and is usually deposited on storage medium on the metal oxide of temperature stabilization, high surface area and/or catalytically-active metals (vide infra) with the form of high degree of dispersion.Normally by the wall portion that become by the water of storage medium and/or catalytic active component suspension (being also referred to as aqueous coating) to be applied to inert carrier and/or carried out coating in wall portion.After applying suspension, carrier is dried, and if properly also calcined at higher temperatures.Coating can be made up of or be applied to by overlapping each other carrier multilayer one deck forms (form of multilayer) and/or is made up of (form in multiple region) the multilayer being applied to carrier offset relative to each other.
Liquid coating 113 is such as suspension for applying motor vehicles exhaust gas catalyst or outstanding bleaching liquor (" aqueous coating "), wherein comprise catalytic active component or its precursor and inorganic oxide such as aluminium oxide, titanium dioxide, zirconium dioxide or its combination, can adulterate such as silicon or lanthanum in the oxide.Vanadium, chromium, manganese, iron, zirconium, copper, zinc, nickel or rare earth metal such as lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium or its oxide combined can be used as catalytic active component.Precious metals such as platinum, palladium, gold, rhodium, iridium, osmium, ruthenium and combination thereof also can be used as catalytic active component.These metals also can show as each other or with the alloy of other metals or oxide.Metal also can show as nitrate, the nitrite or organic compound and composition thereof of precursor such as described noble metal, and especially, palladium nitrate, nitrous acid palladium, platinum nitrate, nitrous acid platinum or Pt (NH
3)
4(NO
3)
2can use in liquid coated media.By calcining at about 400 DEG C to about 700 DEG C, catalytic active component can obtain subsequently from precursor.In order to coated substrates is for the exhaust gas catalyst of production machine motor-car, first the suspension of inorganic oxide or outstanding bleaching liquor can be used to coating, after this, in coating step subsequently, can apply to comprise the suspension of one or more catalytic active component or outstanding bleaching liquor.But, liquid coated media also can be allowed to comprise this two kinds of components.Liquid coated media (coating) often has the viscosity between solids content between 35% to 52% and 15cps to 300cps.
In another embodiment of the present utility model, disclose and equipment of the present utility model is used for coated substrates for the using method generating exhaust gas purifying catalyst, described exhaust gas purifying catalyst is especially for motor vehicle.
Described painting method comprises the following steps:
-send into cylindrical carrier 121 from top to equipment 122 of the present utility model, described cylindrical carrier 121 has two end faces, peripheral surface and axial length L, and described carrier is horizontally through by many passages from the first end face to the second end face;
-described carrier 12 1 is attached to described equipment 122 in the mode of hydraulic seal;
-from below to pumping coating 113 in coating room 100, measure a certain variable by sensor 123,124,125 simultaneously;
If-be satisfied for the condition processing coating operation further or be not satisfied, then send signal.
Without the preferred and favourable content that the above-mentioned all preferred and favourable contents that it should be noted that for equipment of the present utility model are also for its using method similarly.
Coating processing starts usually like this: be pumped in coating room 100 by pipeline 116 by a certain amount of coating, until sensor 123 and 125 sends in signal designation coating room 100 reach correct coating height.Meanwhile, from top, matrix 121 to be placed on coating room and fastening, described in the utility model 201420126144.7 at DE102010007499A1, DE102010008700A1 or China.These open source literatures are also advantageously of the present disclosurely preferably perform the relevant a part of content of coating processing to how utilizing equipment of the present utility model.
If be suitably filled with coating room 100, that is just in the next step further to pumping coating 130 in matrix 121, till the coating height 132 reaching expectation.Subsequently, unnecessary coating is extracted out from matrix 121, and by identical aqueous coating coated substrates again, or from coating room, discharge matrix and process further, such as again apply from another direction, or or even from identical direction with the coating of different aqueous coatings second time, or advance to weigh, dry or calcining unit.
Fig. 1 shows the device for the passage 110 in coated substrates 121 of the present utility model.Liquid coating 113 injects coating equipment 122 by line segments 116, and wherein coating equipment 122 is provided with matrix 121 and the sensor 123,124,125 for determining the first liquid level 130 and accuracy thereof.The numerical value determined by sensor (by sensor 123 and 124 and by sensor 123 and 125) is transferred to control unit 140, and the effect of control unit 140 is the further pumping or the extraction that at least control coating according to above-mentioned analysis.
Realizing filling along filler flow direction 117 coating 113 after coating equipment 122 reaches the first liquid level 130, and after reaching the second liquid level 132 in matrix 121, coating can be sucked out along backflow direction 118, is sent to for excess coating material 113 and for retaining coating 113 storage tank in order to follow-up use.Exported by central control unit 140 like for this reason required all control instruction preferred class.
Be suitable for the completed matrix manufactured for the waste gas filter of motor vehicle and there is coating height consistent especially, it is characterized in that the coated length difference to each other of different passage is no more than 5mm, be no more than 3mm especially, this point is applicable at least 95% of all passages in matrix, advantageously be applicable at least 99% of all passages in matrix, be particularly advantageously applicable to 100% of all passages in matrix.The defect of matrix self may mean that flow in some passage and pressure state and other passage are very different, and its impact is that liquid coating is obviously more difficult or obviously more easily go deep into and be deposited in length shorter or longer in individual passage under coating state.In these cases, the consistent coated length expected can only realize when portion of channel, but this portion of channel is normally greater than 95% of all passages.
The utility model is to be very easy to but still to be that beat all effective means achieves this result.At this, more sensor is positioned in coating room in the mode of intelligence, not only directly can measures the liquid level of coating in coating room, but also can determine whether coating is in correct shape and is further processed for determining whether.Contribute to so very much shortening circulation timei (applying the time needed for a main body), and it is less to be also provided for substandard coating material all in one piece on the other hand.Therefore, the utility model allows the economy of the process greatly improved for applying exhaust gas catalyst.According to the instruction of prior art during the utility model applying date, the realization of this point is not apparent.
Reference numerals list
100 coating rooms
Passage in 110 matrixes 121
113 coating
116 line segments
117 filler flow directions
118 for removing the backflow direction of coating 113
121 matrixes
122 coating equipments
121 for detecting the first sensor of liquid level 130
124 for detecting the comparatively low sensor of liquid level 130
125 for detecting the second sensor of liquid level 130
First liquid level of 130 coating 113 in coating unit 122
Second liquid level of 132 coating 113 in matrix 121
140 control units.
Claims (5)
1. the equipment for coated substrates (121), described matrix is used to generate the exhaust gas purifying catalyst for motor vehicle, described matrix (121) is cylindrical carrier and all has two end faces, peripheral surface and axial length L, and is horizontally through from the first end face to the second end face by the passage that many scribble liquid coating (113);
It is characterized in that, described equipment comprises:
Coating room (100), described coating room (100) is designed to receive described matrix (121) from top and described matrix is attached to described coating room (100) in the mode of hydraulic seal, and described coating room (100) can also receive described coating (113) from below;
Described coating room (100) also comprises the device checking the height of described coating in described coating room (100) by measuring a certain variable;
Described device has a sensor (124) relative to the lower position place of at least first sensor (123) and the second sensor (125) in described coating room, and described at least first sensor (123) and the second sensor (125) are installed on height identical in described coating room (100);
Described device can:
-measure described variable independently by described lower sensor and described at least first sensor and the second sensor; And
-variable recorded is compared to each other.
2. equipment according to claim 1,
It is characterized in that, described at least first sensor (123) and the second sensor (125) around described coating room (100) with Distance positioning maximum to each other.
3. equipment according to claim 1,
It is characterized in that, described variable is electronic variable and can selects from the group be made up of electric current, electric capacity and frequency.
4. the equipment according to any one in claims 1 to 3,
It is characterized in that, if the time delay between described variable is lower than predetermined value, then described device provides prompting.
5. equipment according to claim 1,
It is characterized in that, described matrix (121) is wall-flow filter or flow-through monolith.
Priority Applications (1)
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CN201420308233.3U CN204208576U (en) | 2014-06-11 | 2014-06-11 | For the equipment of coated substrates |
Applications Claiming Priority (1)
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---|---|---|---|
CN201420308233.3U CN204208576U (en) | 2014-06-11 | 2014-06-11 | For the equipment of coated substrates |
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CN204208576U true CN204208576U (en) | 2015-03-18 |
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ID=52977287
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CN201420308233.3U Expired - Lifetime CN204208576U (en) | 2014-06-11 | 2014-06-11 | For the equipment of coated substrates |
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2014
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