Summary of the invention
The technical problems to be solved in the utility model is to provide the process recovery system of a kind of oil refining and chemical engineering sewage, the basis of the patent No. " CN200520130414.2 " " recovery and utilization equipment of oil refining and chemical engineering sewage " concentrates the dense water of reverse osmosis unit again through reverse osmosis membrane or nanofiltration membrane, produce water and enter desalination pond, dense water enters mechanical vapor-compression system, the principle adopting vapour compression concentration and evaporation is condensed water and solid crystal dense water evaporative condenser, condensed water sends into desalination pond, xln recycles or presses solid waste process, reach the object of not outwardly waste discharge.
For reaching above-mentioned purpose, the process recovery system of a kind of oil refining of the utility model and chemical engineering sewage, this equipment comprises the following device be mechanically linked in sequence together: hybrid reaction groove, multistagely join biological filter, anti-blocking air flotation pool, clean water basin, accurate filter, ejector, ozonizer, mixing tank, intermediate pool, biologic active carbon filtration device, water purifying tank, hollow fiber ultrafiltration film or microfiltration membrane and reverse osmosis membrane apparatus, wherein on the ozonizer outlet that is attempted by anti-blocking air flotation pool respectively and ejector, this device also comprises reverse osmosis membrane or nanofiltration membrane and mechanical vapor-compression system, the water outlet of reverse osmosis membrane apparatus is divided into two pipelines, one of them pipeline and reverse osmosis membrane or nanofiltration membrane and mechanical vapor-compression system link together, another pipeline and desalination pond link together.
Wherein multistage biological filter of joining comprises inlet mouth, water-in and at least two packing layers.
Wherein hollow fiber ultrafiltration film or microfiltration membrane and reverse osmosis membrane link together in a series arrangement.
Wherein the water outlet of water purifying tank is divided into two pipelines, and the water-in of one of them pipeline and hollow fiber ultrafiltration film or microfiltration membrane links together in a series arrangement, and another pipeline is connected with industrial pipe network.
Wherein reverse osmosis membrane or nanofiltration membrane and mechanical vapor-compression system link together in a series arrangement.
Wherein the water outlet of reverse osmosis membrane or nanofiltration membrane and mechanical vapor-compression system and desalination pond link together.
Wherein anti-blocking air flotation pool and multistagely join biological filter location swap.
The utility model difference from prior art is that the utility model achieves following technique effect:
The utility model equipment by adding reverse osmosis membrane or nanofiltration membrane and mechanical vapor-compression system after reverse osmosis membrane apparatus, the dense water of reverse osmosis unit is concentrated through reverse osmosis membrane or nanofiltration membrane again, produce water and enter desalination pond, dense water enters mechanical vapor-compression system, the principle adopting vapour compression concentration and evaporation is condensed water and solid crystal dense water evaporative condenser, condensed water sends into desalination pond, and xln recycles or by solid waste process, reaches not the object of outwardly waste discharge.
Reverse osmosis membrane effect above carries out desalination to the water outlet of device before, making it produce water is de-salted water, dense water is Halite water, for increasing reuse water water production rate, also later crystallization burden is reduced, add again one section of reverse osmosis membrane to the last period reverse osmosis membrane dense water concentrate further, the dense water yield is reduced further, and nanofiltration membrane also can play concentrating and desalinating effect.
The ton Chemicals water loss external at petrochemical system is starkly lower than China, and as processed 1 ton of crude oil water loss abroad below 0.5 ton of fresh water, and China is on average about 1.5.If sewage not reuse, ton crude oil processing water loss be down to less than 1.0 be do not have possible.That is reusing sewage is water-saving and emission-reducing, reduces the Bi Hangzhi road of ton crude oil water loss.Its economic benefit is also fairly obvious, and general city fresh water is all more than 2.00 yuan, and some place is higher.And reusing sewage cost (comprising the expenses such as depreciation) is generally between 0.65-0.70 unit ton (not desalination), general medium-sized petrochemical plant reusing sewage water field scale is in 12000-24000 ton/sky, for 12000 tons/day, fresh water deducts cost 0.70 yuan/ton by 2.00 yuan/ton, for profit per ton 1.40/ yuan of ton, within 1 year, can save water rate is 613.2 ten thousand yuan/year.
What more than calculate is economic benefit without embrane method desalination, if the economic benefit after desalination is more obvious.General de-salted water is 70% of sewage total amount, so desalination water yield is 12000*0.70 ton/sky, such reuse water cost is greatly between 2.00-2.50 yuan/ton, and desalination water price is between 8.50-13.00 yuan/ton, calculate with its minimum rate: 12000*0.70* (8.50-2.00) * 365=1992.9 ten thousand yuan/year.So, within 1 year, will save nearly 20,000,000 yuan, the annual sewage discharge also reducing 4,380,000 tons is simultaneously gone in rivers,lakes and seas.
Below in conjunction with accompanying drawing, the utility model is described in further detail.
Embodiment
Below in conjunction with drawings and Examples, to above-mentioned being described in more detail with other technical characteristic and advantage of the utility model.
As shown in Figure 2, the process recovery system of the utility model oil refining and chemical engineering sewage, comprise the following device be mechanically linked in sequence together: hybrid reaction groove 1, multistagely join biological filter 3, anti-blocking air flotation pool 2, clean water basin 4, accurate filter 5, ejector 6, ozonizer 7, mixing tank 8, intermediate pool 9, biologic active carbon filtration device 10, water purifying tank 11, hollow fiber ultrafiltration film or microfiltration membrane 12 and reverse osmosis membrane apparatus 13, wherein on ozonizer 7 outlet that is attempted by anti-blocking air flotation pool 2 respectively and ejector 6, the water outlet of reverse osmosis membrane apparatus 13 is divided into two pipelines, one of them pipeline and reverse osmosis membrane or nanofiltration membrane 15 and mechanical vapor-compression system 16 link together, another pipeline and desalination pond 14 link together, water outlet and the desalination pond 14 of reverse osmosis membrane or nanofiltration membrane 15 and mechanical vapor-compression system 16 link together.; Multistage biological filter 3 of joining comprises inlet mouth, water-in and at least two packing layers, and hollow fiber ultrafiltration film or microfiltration membrane 12 link together in a series arrangement with reverse osmosis membrane 13; The water outlet of water purifying tank 11 is divided into two pipelines, and the water-in of one of them pipeline and hollow fiber ultrafiltration film or microfiltration membrane 12 links together in a series arrangement, and another pipeline is connected with industrial pipe network; Reverse osmosis membrane or nanofiltration membrane 15 link together in a series arrangement with mechanical vapor-compression system 16.
Compared to existing installation as shown in Figure 1, the utility model equipment adds reverse osmosis membrane or nanofiltration membrane 15 and mechanical vapor-compression system 16.
Embodiment 1:
As shown in Figure 3, there is shown for implementing oil refining according to the method for the utility model first embodiment and chemical engineering sewage recycling equipment, this equipment comprises the hybrid reaction groove 1 be connected in turn, anti-blocking air flotation pool 2, multistagely joins biological filter 3, clean water basin 4, High-efficient Accurate Filter 5, ejector 6, ozonizer 7, mixing tank 8, intermediate pool 9, biological activity char filter 10, water purifying tank 11, make use of if reuse water does not need desalination just can enter industrial pipe network.If need desalination to increase hollow fiber ultrafiltration film (or hollow microfiltration membrane) 12 and RO reverse osmosis membrane 13 and desalination pond 14 again.
The oil refining of the utility model embodiment 1 and the workflow of chemical engineering sewage recycling equipment be as shown in Figure 4:
A, enter into hybrid reaction groove 1 through the oil refining of second-stage treatment, chemical engineering sewage, after generating alumen ustum with added medicament polymerize aluminum chloride (PAC) and the abundant hybrid reaction of the polyacrylamide after being hydrolyzed (PAM), enter anti-blocking air flotation pool 2 and be separated.
B, anti-blocking air flotation pool 2 water outlet, according to water quality situation, directly can enter and multistagely join biological filter 3, also can add part ozone, enter multistagely to join biological filter 3 after degradation period, carry out biochemical treatment and filteration.Multistagely join biological filter 3, water outlet enters clean water basin 4.
C, clean water basin 4 water promote through pump and enter into High-efficient Accurate Filter 5, and after High-efficient Accurate Filter 5 filters, water outlet enters into ejector 6, add at ejector 6 O that ozonizer 7 produces
3after, enter into mixing tank 8 hybrid reaction, after reaction, enter intermediate pool 9.
D, intermediate pool 9 water enter biologic active carbon filtration device 10 through pump, and in its biological degradation and absorption again, biologic active carbon filtration device 10 water outlet enters water purifying tank 11.If saltiness is not high in sewage, when there is no desalination requirement, in water purifying tank 11, water just can send industrial pipe network or directly enter circulating cooling make-up water reuse.If desired desalination or partially desalted, so also needs through desalting treatment.
E, if desired, also can carry out desalting treatment: in water purifying tank 11, water extraction liter enters hollow fiber ultrafiltration (UF) or micro-filtration (MF) film group 12, carrying out oil removing and continue to reduce suspended substance, then carrying out desalination through boosting to RO reverse osmosis membrane group 13.The concentrated water drainage produced falls, and the product water of reverse osmosis membrane 13 enters desalination pond 14, then to send between boiler chemical water treatment vehicle etc. to use water spot.Or partially desalted water removes pond 11, the water purification blending into low saline salinity with former water purification send circulating cooling make-up water.
Embodiment 2:
As shown in Figure 2, there is shown for implementing oil refining according to the method for the utility model second embodiment and chemical engineering sewage recycling equipment, this equipment comprises the hybrid reaction groove 1 be connected in turn, multistagely join biological filter 3, air flotation pool 2, clean water basin 4, High-efficient Accurate Filter 5, ejector 6, ozonizer 7, mixing tank 8, intermediate pool 9, biological activity char filter 10, water purifying tank 11, make use of if reuse water does not need desalination just can enter industrial pipe network.If need desalination to increase hollow fiber ultrafiltration film (or hollow microfiltration membrane) 12 and RO reverse osmosis membrane 13 and desalination pond 14 again.
The oil refining of the utility model embodiment 2 and the workflow of chemical engineering sewage recycling equipment be as shown in Figure 5:
A, enter hybrid reaction groove 1 through the oil refining of second-stage treatment, chemical engineering sewage, medicament polymerize aluminum chloride (PAC), polyacrylamide (PAM) and the sewage added is reacted and generates alumen ustum, enter again multistagely to join biological filter 3, biological treatment Organic substance in water and filter suspended substance etc.
B, multistagely join biological filter 3 water outlet and enter in air flotation pool 2 and be separated.Water outlet enters clean water basin 4.
C, clean water basin 4 water promote through pump and enter into High-efficient Accurate Filter 5, carry out water filtration, reduce the laggard ejector 6 of suspended substance, add the O3 produced by ozonizer 7, hybrid reaction in mixing tank 8, enter intermediate pool 9 after reaction at ejector 6.
D, intermediate pool 9 water promote into biologic active carbon filtration device 10 through pump, biological degradation and adsorb organic compound again.Biologic active carbon filtration device 10 water outlet enters water purifying tank 11.If sewage saltiness is not high, when requiring without desalination, the reuse water in water purifying tank 11 just can send industrial pipe network or directly enter circulating cooling make-up water.If desired desalination or partially desaltedly also to need through desalting treatment.
E, desalting treatment: the water in water purifying tank 11 carries out desalination through boosting to RO reverse osmosis membrane group 13 through promoting after super (micro-) filter membrane group 12 of hollow removes oil and suspended substance, the de-salted water produced enters desalination pond 14, then send between boiler chemical waterwheel, or partly removing pond 11 blends into low saline salinity water purification.
Embodiment 3:
As shown in Figure 1, there is shown for implementing oil refining according to the method for the utility model the 3rd embodiment and chemical engineering sewage recycling equipment, this equipment comprises the hybrid reaction groove 1 be connected in turn, multistagely join biological filter 3, anti-blocking air flotation pool 2, clean water basin 4, High-efficient Accurate Filter 5, ejector 6, ozonizer 7, mixing tank 8, intermediate pool 9, biological activity char filter 10, water purifying tank 11, hollow fiber ultrafiltration film (or hollow microfiltration membrane) 12, RO reverse osmosis membrane 13, desalination pond 14, reverse osmosis (nanofiltration) film 15, mechanical vapor-compression system 16.
The oil refining of the utility model embodiment 3 and the workflow of chemical engineering sewage recycling equipment be as shown in Figure 6:
A, enter hybrid reaction groove 1 through the oil refining of second-stage treatment, chemical engineering sewage, medicament polymerize aluminum chloride (PAC), polyacrylamide (PAM) and the sewage added is reacted and generates alumen ustum, go forward side by side and multistagely join biological filter 3, biological treatment Organic substance in water and filter suspended substance etc.
B, multistagely join biological filter 3 water outlet and enter in anti-blocking air flotation pool 2 and be separated.Water outlet enters clean water basin 4.
C, clean water basin 4 water promote through pump and enter into High-efficient Accurate Filter 5, carry out water filtration, reduce the laggard ejector 6 of suspended substance, add the O produced by ozonizer 7 at ejector 6
3, hybrid reaction in mixing tank 8, enters intermediate pool 9 after reaction.
D, intermediate pool 9 water promote into biologic active carbon filtration device 10 through pump, biological degradation and adsorb organic compound again.Biologic active carbon filtration device 10 water outlet enters water purifying tank 11.If sewage saltiness is not high, when requiring without desalination, the reuse water in water purifying tank 11 just can send industrial pipe network or directly enter circulating cooling make-up water.If desired desalination or partially desaltedly also to need through desalting treatment.
E, desalting treatment: the water in water purifying tank 11 carries out desalination through boosting to RO reverse osmosis membrane group 13 through promoting after super (micro-) filter membrane group 12 of hollow removes oil and suspended substance, and the de-salted water of generation enters desalination pond 14.
The dense water of f, reverse osmosis membrane group 13 filters through reverse osmosis (nanofiltration) film 15 again, concentrated further, produce water and enter desalination pond 14, dense water enters mechanical steam compression system 16, carry out evaporative crystallization, the condensed water that mechanical vapor-compression system 16 produces enters desalination pond 14, the crystallization otherwise processed of generation.
Lectotype selection:
The capacity of equipment of the utility model method flow by 720t/ days (30t/h) scales to 24000t/ days every day (1000t/h) not etc.Fairly largely some production lines can be adopted to compose in parallel.
Through the sewage of hollow fiber ultrafiltration film or microfiltration membrane and reverse osmosis membrane processing, produce water can directly recycle, but dense water often can not qualified discharge or do not allow discharge, when considering zero release, in hollow fiber ultrafiltration film or microfiltration membrane and reverse osmosis membrane apparatus rear end, concentration systems is set, the dense water produced after reverse osmosis membrane desalination, the technique arranging reverse osmosis or nanofiltration concentrates, the waste water water yield of supersalinity is reduced gradually, mechanical steam compression system is entered when dense water saltiness acquires a certain degree, the advanced interchanger of dense water, heat exchange is carried out with the distilled water produced in vaporizer, remove O
2and CO
2gas, the dense water after heat exchange enters in evaporation concentrator and carries out evaporation concentration, and dense water is condensed water and solid crystal by evaporative condenser.
Illustrated as can be seen from above, multistage biological filter of joining has biological degradation organism and filters two kinds of effects, thus improves the degree of purification of polluted water.Adopt hollow fiber ultrafiltration film or microfiltration membrane and reverse osmosis membrane to carry out desalting treatment to polluted water, make reuse water be suitable for industrial application.Owing to have employed reverse osmosis membrane or nanofiltration membrane and mechanical vapor-compression system, condensing crystal process is carried out to polluted water again, outwardly waste discharge can be accomplished not.
Above-described embodiment is only be described preferred implementation of the present utility model; not scope of the present utility model is limited; under the prerequisite not departing from the utility model design spirit; the various distortion that those of ordinary skill in the art make the technical solution of the utility model and improvement, all should fall in protection domain that the utility model claims determine.