CN204111523U - Percolate short-cut nitrification and denitrification denitrogenation special purpose device - Google Patents
Percolate short-cut nitrification and denitrification denitrogenation special purpose device Download PDFInfo
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- CN204111523U CN204111523U CN201420469160.6U CN201420469160U CN204111523U CN 204111523 U CN204111523 U CN 204111523U CN 201420469160 U CN201420469160 U CN 201420469160U CN 204111523 U CN204111523 U CN 204111523U
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- denitrification
- nitrification
- multistage
- percolate
- tank
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 60
- 238000010992 reflux Methods 0.000 claims description 11
- 239000010802 sludge Substances 0.000 claims description 10
- 238000005276 aerator Methods 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 9
- 238000000034 method Methods 0.000 abstract description 24
- 230000008569 process Effects 0.000 abstract description 17
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 14
- 229910052799 carbon Inorganic materials 0.000 abstract description 14
- 238000006243 chemical reaction Methods 0.000 abstract description 11
- JVMRPSJZNHXORP-UHFFFAOYSA-N ON=O.ON=O.ON=O.N Chemical compound ON=O.ON=O.ON=O.N JVMRPSJZNHXORP-UHFFFAOYSA-N 0.000 abstract description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 10
- 229910052760 oxygen Inorganic materials 0.000 abstract description 10
- 239000001301 oxygen Substances 0.000 abstract description 10
- 238000009825 accumulation Methods 0.000 abstract description 7
- 238000005273 aeration Methods 0.000 abstract description 3
- 238000005265 energy consumption Methods 0.000 abstract description 3
- 150000003384 small molecules Chemical class 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 26
- 229910052757 nitrogen Inorganic materials 0.000 description 13
- 238000006396 nitration reaction Methods 0.000 description 9
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 description 8
- 238000000926 separation method Methods 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 239000002351 wastewater Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 239000010813 municipal solid waste Substances 0.000 description 3
- 241000108664 Nitrobacteria Species 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000013459 approach Methods 0.000 description 1
- 230000001651 autotrophic effect Effects 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000000149 chemical water pollutant Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 239000010815 organic waste Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
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- Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)
Abstract
A kind of percolate short-cut nitrification and denitrification denitrogenation special purpose device, it is characterized in that: it comprises anaerobic reactor (1), denitrification pond (2), nitrification tank (3), multistage denitrification pond (4), multistage nitrification tank (5), mud and water separating equipment (6), raw water box (7), intake pump (8), produces water tank (12); First macromole hardly degraded organic substance in percolate being decomposed into small molecules by anaerobic reaction can biochemical carbon source, makes full use of original carbon source in percolate and carries out short-cut nitrification and denitrification denitrogenation, decrease the dosage of additional carbon, obvious economic; Secondly can strictly control lower, stable dissolved oxygen concentration, ensure that nitrite nitrogen accumulation rate is high and stable, have higher nitric efficiency, and decrease aeration rate in denitrification process, save energy consumption, running cost is low; Finally can realize the denitrogenation processing of the percolate under different load, ensure that effluent quality reaches standard.
Description
Technical field
The utility model belongs to environmental technology field, specifically just relates to a kind of percolate short-cut nitrification and denitrification denitrogenation special purpose device.
Background technology
No matter refuse treatment is take landfill, or the mode of burning, and the process of percolate is all technical barrier wherein.Percolate is a kind of high ammonia nitrogen high concentrated organic wastewater, water quality and quantity poor stability, microbial nutrition element ratio is lacked of proper care, ammonia nitrogen element is too high causes contaminated wastewater soil and environment, along with the raising of people's living standard, people's environmental consciousness is strengthened day by day, imperative to the denitrogenation processing of percolate.Difficulty in treatment and focusing in current high ammonia nitrogen leachate denitrification process, the carbon source wretched insufficiency needed for denitrification.
Traditional biological denitrification process comprises Autotrophic nitrification and two stages of heterotrophic denitrification, this technique is applicable to the denitrogenation processing of the low ammonia nitrogen organic waste water of high carbon source, not only nitrobacteria growth is suppressed for high ammonia nitrogen landfill leachate, and lower C/N can not meet the demand of carbon source far away than in denitrification denitrogenation process, cause in denitrification process and need to add denitrification organic carbon source in a large number; In addition, in this traditional technology process, nitrobacteria rate of propagation causes total hrt longer slowly, structures volume is increased, thus causes whole technique to there is the higher weak point of working cost, through engineering approaches application on a large scale can not be widely used in.
In order to improve the denitrification ability of conventional garbage percolate further, market is developed a kind of novel biological denitrification process---short-cut nitrification and denitrification technique.Short-cut nitrification and denitrification technique is in the nitrite nitrogen stage by the oxidation control of ammonia nitrogen, reach a large amount of accumulation of nitrite nitrogen in system, intrasystem cultured water can using ammonia nitrogen or organism matrix as redox electron donor, and direct reaction generates nitrogen, reaches the object removing total nitrogen.This process shortens reaction mechanism, do not need additional carbon, dissolved oxygen concentration is low, have higher nitric efficiency etc.But in two principal reaction steps of the short-cut nitrification and denitrification of this technique, the denitrification stage easily controls, but how by NH
4 +-N oxidation control is at NO
2  ̄in-N the stage, stop the wayward of its further oxidation, make that nitrite nitrogen accumulation in whole treating processes is unstable and accumulation rate is low, total nitrogen removal efficiency is low.
Utility model content
The purpose of this utility model is in above-mentioned conventional garbage percolate denitrogenation nitration treatment technique, nitrite nitrogen accumulates instability and the technological deficiency that accumulation rate is low, total nitrogen removal efficiency is low, there is provided percolate denitrification process and special purpose device thereof, by the NH in rubbish percolate denitrogenation nitration treatment technique
4 +-N oxidation control is at NO
2  ̄in-N the stage, stop it to be oxidized further, effectively improve total nitrogen removal efficiency.
Technical scheme
In order to realize above-mentioned technical purpose, the utility model designs a kind of percolate short-cut nitrification and denitrification denitrification process, and it is characterized in that, it comprises following step:
The first step, anaerobic treatment: percolate is carried out anaerobic treatment, achieves gas-liquid-solid three-phase and is separated, obtain anaerobic effluent;
Second step, denitrification: the anaerobic effluent in step 1 is carried out denitrification process, reduces nitrogen content;
3rd step, nitrated: by the denitrification water outlet of step 2, to carry out nitration treatment, obtain nitrified effluent;
4th step, multistage denitrification: multistage denitrification is carried out in the water outlet of step 3 nitrification tank, obtains multistage denitrification water outlet;
5th step, multistage nitrated: multistage nitration treatment is carried out in multistage denitrification pond water outlet step 4 obtained, and obtains multistage nitrified effluent;
6th step, mud-water separation: multistage nitrified effluent step 5 obtained passes into mud and water separating equipment, carries out mud-water separation, and water outlet enters product water tank.
Further, in the described the first step, anaerobic reaction temperature controls the scope at 25 ~ 55 DEG C.
In described second step, anti-nitration reaction temperature is 20 ~ 40 DEG C, pH is 7.0 ~ 8.3, dissolved oxygen DO≤0.2mg/L.
In described 3rd step, nitration reaction temperature is 20 ~ 40 DEG C, and DO is 0.6 ~ 1.2mg/L, and pH value is 7.0 ~ 8.6.
In described 4th step, multistage anti-nitration reaction temperature is 20 ~ 40 DEG C, pH value is 7.0 ~-8.3, dissolved oxygen DO≤0.2mg/L.
In described 5th step, multistage nitration reaction temperature is 20 ~ 40 DEG C, and DO is 0.6 ~ 1.2mg/L, pH is 7.0 ~ 8.6.
In described 6th step, mud-water separation temperature of reaction is 20 ~ 40 DEG C, and DO is 1.0 ~ 4.0mg/L, and pH value is 7.0 ~ 8.6.
For the special purpose device of above-mentioned percolate short-cut nitrification and denitrification denitrogenation, it is characterized in that: it comprises anaerobic reactor, denitrification pond, nitrification tank, multistage denitrification pond, multistage nitrification tank, mud and water separating equipment, raw water box, intake pump, produce water tank;
Raw water box is connected with anaerobic reactor, connecting pipeline is equipped with intake pump, anaerobic reactor output terminal connects denitrification pond, denitrification pond output terminal is connected to nitrification tank, nitrification tank output terminal is connected to multistage denitrification pond, multistage denitrification pond output terminal is connected to multistage nitrification tank, and multistage nitrification tank output terminal is connected to mud and water separating equipment, and mud and water separating equipment output terminal connects product water tank.
Further, be provided with radiator valve in described anaerobic reactor, bottom anaerobic reactor and between top, be connected with circulation return pipe;
Further, the first stirrer is provided with in described denitrification pond;
Further, in described nitrification tank, be provided with the first aerator, between nitrification tank with denitrification pond, have return line to be connected, connecting pipeline is equipped with the first nitrification liquid reflux pump.
Further, the second stirrer is provided with in described multistage denitrification pond.
Further, in described multistage nitrification tank, be provided with the second aerator, between multistage nitrification tank with multistage denitrification pond, have return line to be connected, connecting pipeline is equipped with the second nitrification liquid reflux pump.
Further, be provided with the 3rd aerator in described mud and water separating equipment, between mud and water separating equipment with denitrification pond, have sludge reflux pump to be connected, the sludge part in mud and water separating equipment can be back to denitrification pond.
Beneficial effect
First macromole hardly degraded organic substance in percolate to be decomposed into small molecules by anaerobic reaction by the utility model can biochemical carbon source, make full use of original carbon source in percolate and carry out short-cut nitrification and denitrification denitrogenation, decrease the dosage of additional carbon, obvious economic; Secondly can strictly control lower, stable dissolved oxygen concentration, ensure that nitrite nitrogen accumulation rate is high and stable, have higher nitric efficiency, and decrease aeration rate in denitrification process, save energy consumption, running cost is low; Finally can realize the denitrogenation processing of the percolate under different load, ensure that effluent quality reaches standard.
Accompanying drawing explanation
Accompanying drawing 1 is process flow sheet of the present utility model.
Accompanying drawing 2 is equipment connecting relation schematic diagram of the present utility model.
Embodiment
Below in conjunction with drawings and Examples, the utility model is described further.
Embodiment
As shown in Figure 2, for the special purpose device of above-mentioned percolate short-cut nitrification and denitrification denitrogenation, it is characterized in that: it comprises anaerobic reactor 1, denitrification pond 2, nitrification tank 3, multistage denitrification pond 4, multistage nitrification tank 5, mud and water separating equipment 6, raw water box 7, intake pump 8, produces water tank 12;
Raw water box 7 is connected with anaerobic reactor 1, intake pump 8 connecting pipeline is equipped with, anaerobic reactor 1 output terminal connects denitrification pond 2, denitrification pond 2 output terminal is connected to nitrification tank 3, nitrification tank 3 output terminal is connected to multistage denitrification pond 4, multistage denitrification pond 4 output terminal is connected to multistage nitrification tank 5, and multistage nitrification tank 5 output terminal is connected to mud and water separating equipment 6, and mud and water separating equipment 6 output terminal connects product water tank 12.
Be provided with radiator valve 13 in described anaerobic reactor 1, bottom anaerobic reactor 1 and between top, be connected with circulation return pipe 9;
The first stirrer 14 is provided with in described denitrification pond 2;
Be provided with the first aerator 15 in described nitrification tank 3, between nitrification tank 3 with denitrification pond 2, have return line to be connected, connecting pipeline is equipped with the first nitrification liquid reflux pump 10.
The second stirrer 14 ' is provided with in described multistage denitrification pond 4.
Be provided with the second aerator 15 ' in described multistage nitrification tank 5, between multistage nitrification tank 5 with multistage denitrification pond 4, have return line to be connected, connecting pipeline is equipped with the second nitrification liquid reflux pump 10 '.
The 3rd aerator 15 is provided with in described mud and water separating equipment 6 ", there is sludge reflux pump 11 to be connected between mud and water separating equipment 6 with denitrification pond 2, the sludge part in mud and water separating equipment 6 can be back to denitrification pond 2.
The technological process utilizing above-mentioned special purpose device to carry out percolate denitrogenation processing is:
The first step anaerobic treatment: percolate enters from the bottom of anaerobic reactor, under the effect of circulation return pipe, waste water and mud fully mix and rise fast, be under the condition of 25 ~ 55 DEG C in temperature of reaction, large amount of organic be decomposed produce biogas rise rapidly, after gas-liquid-solid three-phase rises to triphase separator, mud returns anaerobic reactor main body through the sedimentation face of triphase separator, biogas is discharged via the collection chamber of triphase separator, sewage containing suspended sludge enters the negative area of triphase separator, discharge from anaerobic reactor top water outlet after precipitation.
Second step denitrification: in the nitrated phegma of above-mentioned anaerobic effluent and nitrification tank, mud and water separating equipment, returned sluge is mixed into denitrification pond, denitrification is provided with stirrer in pond, temperature be 20 ~ 40 DEG C, dissolved oxygen DO≤0.2mg/L, pH=7.0 ~ 8.3 condition under carry out denitrification retroaction, change nitrite nitrogen and nitric nitrogen into nitrogen to overflow from reactor, water outlet enters nitrification tank.
3rd step is nitrated: the denitrification pond water outlet of above-mentioned second step enters nitrification tank, microorganism temperature be 20 ~ 40 DEG C, dissolved oxygen DO=0.6 ~ 1.2mg/L, pH=7.0 ~ 8.6 condition under, carry out nitrification, mineralized nitrogen in waste water is become nitrite nitrogen and nitric nitrogen, simultaneously, according to the reflux ratio of R≤30, final nitrification liquid is back to denitrification pond, for denitrification process provides sufficient electron acceptor(EA), nitrification tank water outlet enters multistage denitrification pond.
Nitration denitrification Operation system setting, according to the difference of organic loading, can be multistage by the multistage denitrification of the 4th step: the nitrification tank water outlet of above-mentioned 3rd step enters multistage denitrification pond.Wherein, in multistage denitrification pond temperature of reaction be 20 ~ 40 DEG C, pH=7.0 ~ 8.3, dissolved oxygen DO≤0.2mg/L, provide sufficient nitrite nitrogen and nitric nitrogen by the backflow nitrification liquid of this grade, can denitrification denitrogenation be carried out.
5th step is multistage nitrated: the multistage denitrification pond water outlet of above-mentioned 4th step enters multistage nitrification tank, in multistage nitrification tank, temperature of reaction is 20 ~ 40 DEG C, DO=0.6 ~ 1.2mg/L, pH=7.0 ~ 8.6, nitrification liquid is back to multistage denitrification pond, reflux ratio R≤30 simultaneously.
6th step mud-water separation: above-mentioned 5th step nitrification tank water outlet enters mud and water separating equipment, temperature be 20 ~ 40 DEG C, dissolved oxygen DO=1.0 ~ 4.0mg/L, pH=7.0 ~ 8.6 condition under, be on the one hand by biochemical treatment above after mud mixture be separated, that the pollutents such as SS, COD, ammonia nitrogen and total nitrogen in water are degraded on the other hand, base sludge is back to denitrification pond according to a certain percentage simultaneously, prevent system sludge amount from reducing and improve the clearance of nitrogen, excess sludge carries out periodic exhaustion, and the water outlet after mud-water separation enters product water tank.
First macromole hardly degraded organic substance in percolate to be decomposed into small molecules by anaerobic reaction by the utility model can biochemical carbon source, make full use of original carbon source in percolate and carry out short-cut nitrification and denitrification denitrogenation, decrease the dosage of additional carbon, obvious economic; Secondly can strictly control lower, stable dissolved oxygen concentration, ensure that nitrite nitrogen accumulation rate is high and stable, have higher nitric efficiency, and decrease aeration rate in denitrification process, save energy consumption, running cost is low; Finally can realize the denitrogenation processing of the percolate under different load, ensure that effluent quality reaches standard.
Claims (7)
1. a percolate short-cut nitrification and denitrification denitrogenation special purpose device, it is characterized in that: it comprises anaerobic reactor (1), denitrification pond (2), nitrification tank (3), multistage denitrification pond (4), multistage nitrification tank (5), mud and water separating equipment (6), raw water box (7), intake pump (8), produces water tank (12);
Raw water box (7) is connected with anaerobic reactor (1), intake pump (8) connecting pipeline is equipped with, anaerobic reactor (1) output terminal connects denitrification pond (2), denitrification pond (2) output terminal is connected to nitrification tank (3), nitrification tank (3) output terminal is connected to multistage denitrification pond (4), multistage denitrification pond (4) output terminal is connected to multistage nitrification tank (5), multistage nitrification tank (5) output terminal is connected to mud and water separating equipment (6), and mud and water separating equipment (6) output terminal connects product water tank (12).
2. percolate short-cut nitrification and denitrification denitrogenation special purpose device as claimed in claim 1, it is characterized in that: in described anaerobic reactor (1), be provided with radiator valve (13), between anaerobic reactor (1) bottom and top, be connected with circulation return pipe (9).
3. percolate short-cut nitrification and denitrification denitrogenation special purpose device as claimed in claim 1, is characterized in that: be provided with the first stirrer (14) in described denitrification pond (2).
4. percolate short-cut nitrification and denitrification denitrogenation special purpose device as claimed in claim 1, it is characterized in that: in described nitrification tank (3), be provided with the first aerator (15), there is return line to be connected between nitrification tank (3) with denitrification pond (2), connecting pipeline is equipped with the first nitrification liquid reflux pump (10).
5. percolate short-cut nitrification and denitrification denitrogenation special purpose device as claimed in claim 1, is characterized in that: be provided with the second stirrer (14 ') in described multistage denitrification pond (4).
6. percolate short-cut nitrification and denitrification denitrogenation special purpose device as claimed in claim 1, it is characterized in that: in described multistage nitrification tank (5), be provided with the second aerator (15 '), there is return line to be connected between multistage nitrification tank (5) with multistage denitrification pond (4), connecting pipeline is equipped with the second nitrification liquid reflux pump (10 ').
7. percolate short-cut nitrification and denitrification denitrogenation special purpose device as claimed in claim 1, it is characterized in that: be provided with the 3rd aerator (15 ") in described mud and water separating equipment (6); have sludge reflux pump (11) to be connected between mud and water separating equipment (6) with denitrification pond (2), the sludge part in mud and water separating equipment (6) can be back to denitrification pond (2).
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106145351A (en) * | 2016-08-08 | 2016-11-23 | 北京润宇环保工程有限公司 | The processing equipment of garbage incinerating power plant Leachate site |
CN107902853A (en) * | 2017-12-28 | 2018-04-13 | 嘉园环保有限公司 | A kind of landfill leachate biochemical treatment system |
WO2022013464A1 (en) * | 2020-07-16 | 2022-01-20 | Nova Inmobiliaria 2003, Sl | Method and system for mineralising leachates or slurry |
-
2014
- 2014-08-19 CN CN201420469160.6U patent/CN204111523U/en not_active Expired - Lifetime
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106145351A (en) * | 2016-08-08 | 2016-11-23 | 北京润宇环保工程有限公司 | The processing equipment of garbage incinerating power plant Leachate site |
CN107902853A (en) * | 2017-12-28 | 2018-04-13 | 嘉园环保有限公司 | A kind of landfill leachate biochemical treatment system |
WO2022013464A1 (en) * | 2020-07-16 | 2022-01-20 | Nova Inmobiliaria 2003, Sl | Method and system for mineralising leachates or slurry |
ES2891380A1 (en) * | 2020-07-16 | 2022-01-27 | Nova Inmobiliaria 2003 Sl | Leachate or slurry mineralization procedure and system (Machine-translation by Google Translate, not legally binding) |
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GR01 | Patent grant | ||
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Address after: 200081 room 3, floor 22, No. 196, Ouyang Road, Hongkou District, Shanghai Patentee after: SHANGHAI JINGYU ENVIRONMENTAL ENGINEERING Co.,Ltd. Address before: Room 1501, No. 612, North Road, Hongkou District station, Shanghai, Shanghai Patentee before: SHANGHAI GE-WE ENVIRONMENT ENGINEERING CO.,LTD. |
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Granted publication date: 20150121 |
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