CN204111312U - A kind of chlorine dioxide generator reactive system - Google Patents
A kind of chlorine dioxide generator reactive system Download PDFInfo
- Publication number
- CN204111312U CN204111312U CN201420592978.7U CN201420592978U CN204111312U CN 204111312 U CN204111312 U CN 204111312U CN 201420592978 U CN201420592978 U CN 201420592978U CN 204111312 U CN204111312 U CN 204111312U
- Authority
- CN
- China
- Prior art keywords
- feed device
- reaction chamber
- water
- chlorine dioxide
- dioxide generator
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 title claims abstract description 48
- 239000004155 Chlorine dioxide Substances 0.000 title claims abstract description 24
- 235000019398 chlorine dioxide Nutrition 0.000 title claims abstract description 24
- 238000006243 chemical reaction Methods 0.000 claims abstract description 35
- 239000000956 alloy Substances 0.000 claims abstract description 27
- 229910001347 Stellite Inorganic materials 0.000 claims abstract description 26
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 26
- AHICWQREWHDHHF-UHFFFAOYSA-N chromium;cobalt;iron;manganese;methane;molybdenum;nickel;silicon;tungsten Chemical compound C.[Si].[Cr].[Mn].[Fe].[Co].[Ni].[Mo].[W] AHICWQREWHDHHF-UHFFFAOYSA-N 0.000 claims abstract description 26
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 16
- BZSXEZOLBIJVQK-UHFFFAOYSA-N 2-methylsulfonylbenzoic acid Chemical compound CS(=O)(=O)C1=CC=CC=C1C(O)=O BZSXEZOLBIJVQK-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000463 material Substances 0.000 claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 44
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract description 13
- 239000000460 chlorine Substances 0.000 abstract description 13
- 229910052801 chlorine Inorganic materials 0.000 abstract description 13
- 230000009286 beneficial effect Effects 0.000 abstract description 7
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract description 6
- 239000010936 titanium Substances 0.000 abstract description 6
- 229910052719 titanium Inorganic materials 0.000 abstract description 6
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 abstract description 5
- 229910052751 metal Inorganic materials 0.000 abstract description 3
- 239000002184 metal Substances 0.000 abstract description 3
- 150000002978 peroxides Chemical class 0.000 description 12
- 229910017052 cobalt Inorganic materials 0.000 description 6
- 239000010941 cobalt Substances 0.000 description 6
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- RTKIYNMVFMVABJ-UHFFFAOYSA-L thimerosal Chemical compound [Na+].CC[Hg]SC1=CC=CC=C1C([O-])=O RTKIYNMVFMVABJ-UHFFFAOYSA-L 0.000 description 4
- 229940033663 thimerosal Drugs 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 238000005273 aeration Methods 0.000 description 2
- 238000005275 alloying Methods 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- QBACCBHDCANWCQ-UHFFFAOYSA-N chromium cobalt molybdenum tungsten Chemical compound [Co][Cr][Mo][W] QBACCBHDCANWCQ-UHFFFAOYSA-N 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 229910052758 niobium Inorganic materials 0.000 description 2
- 239000010955 niobium Substances 0.000 description 2
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000003206 sterilizing agent Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910052715 tantalum Inorganic materials 0.000 description 2
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 229910001069 Ti alloy Inorganic materials 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000001877 deodorizing effect Effects 0.000 description 1
- 230000000249 desinfective effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
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- Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)
Abstract
The utility model discloses a kind of chlorine dioxide generator reactive system, comprise the first feed device, the second feed device and reaction chamber, in the first feed device, store sodium chlorate solution, in the second feed device, store hydrochloric acid soln; First feed device and the second feed device are all connected to reaction chamber by pipeline, it is characterized in that, the material of reaction chamber adopts Si Taili (stellite) alloy, its beneficial effect is, adopt the reaction chamber that Si Taili (stellite) alloy is made, while guarantee heat-conduction coefficient, solve dry chlorine gas and the potential hidden danger of catching fire of reaction chamber, because chlorine does not react with stellite.While guarantee chlorine dioxide generator high heat transfer, effective potential safety hazard solving employing titanium metal and exist, improve the safety and stability of chlorine dioxide generator, good heat conduction efficiency can be ensured, simultaneously, Si Taili (stellite) alloy also has satisfactory stability, can not react with chlorine, hidden danger of not catching fire.
Description
Technical field
The utility model relates to field of environment protection equipment, particularly a kind of chlorine dioxide generator reactive system.
Background technology
As a kind of novel oxygenant and sterilizing agent, the outstanding person that dioxide peroxide is efficient with it, wide spectrum, noresidue, the disinfecting power of no coupling product and decolouring, deodorizing, the Strong oxdiative ability such as to eliminate the unusual smell have become water treatment field.Compare dioxide peroxide with traditional sterilizing agent such as ultraviolet, ozone, clorox, liquid chlorine and have unique advantage, it more and more becomes insider's first and selects.
In the middle of traditional chlorine dioxide production technique, be all adopt PVC material to make reactive system, and carry out heating in water bath, but this method heat conduction efficiency be low, cause that speed of response is slow, weak effect; In order to strengthen heat conductivity, had the reactive system adopting titanium alloy material to make afterwards, and adopt electromagnetic heating technique, this method solves the problem of heat conduction efficiency really.But after chlorine dioxide generator quits work, may remain chlorine in the middle of reactive system, in dry chlorine gas, even also can there is vigorous reaction and generate titanium tetrachloride, and have hidden danger of catching fire in titanium and its alloys below 0 DEG C.
Utility model content
The purpose of this utility model is to provide that a kind of structure is simple, heat conduction efficiency is high, can not has the chlorine dioxide generator reactive system of hidden danger of catching fire simultaneously.
According to an aspect of the present utility model, a kind of chlorine dioxide generator reactive system provided, comprises the first feed device, the second feed device and reaction chamber,
Store sodium chlorate solution in first feed device, in the second feed device, store hydrochloric acid soln;
First feed device and the second feed device are all connected to reaction chamber by pipeline, it is characterized in that,
The material of reaction chamber adopts Si Taili (Stellite) alloy, namely usually said cobalt chromium tungsten (molybdenum) alloy or cobalt base alloy.Its beneficial effect is, stellite is the Wimet of a kind of ability all kinds abrasion and corrosion and high temperature oxidation.Namely usually said cobalt base alloy, stellite is invented in 1907 by American Elwood Hayness.Stellite is using cobalt as main component, containing alloying elements such as a considerable amount of nickel, chromium, tungsten and a small amount of molybdenum, niobium, tantalum, titanium, lanthanums, and the class alloy once in a while yet containing iron.Under general applying working condition, Si Taili (Stellite) alloy is all have wear-resistant high temperature resistant or wear-resistant corrosion resistant situation concurrently.
Adopt the reaction chamber made of Si Taili (Stellite) alloy, while guarantee heat-conduction coefficient, solve dry chlorine gas and the potential hidden danger of catching fire of reaction chamber, because chlorine does not react with stellite.While guarantee chlorine dioxide generator high heat transfer, effective potential safety hazard solving employing titanium metal and exist, improve the safety and stability of chlorine dioxide generator, good heat conduction efficiency can be ensured, simultaneously, Si Taili (Stellite) alloy also has satisfactory stability, can not react with chlorine, hidden danger of not catching fire.
In some embodiments, material employing department too vertical No. 6 (Stellite 6) alloys of reaction chamber.Its beneficial effect is that stellite has Multiple Type, and through many experiments, the effect that result shows to take charge of too vertical No. 6 alloys is optimum.
In some embodiments, be provided with the first volume pump between the first feed device and reaction chamber, the first volume pump is for controlling the feed of the first feed device.Its beneficial effect is, the first volume pump can control the feeding speed of the first feed device, ensures that the infeed of sodium chlorate solution is sufficient and stable.
In some embodiments, be provided with the second volume pump between the second feed device and reaction chamber, the second volume pump is for controlling the feed of the second feed device.Its beneficial effect is, the second volume pump can control the feeding speed of the second feed device, ensures that the infeed of hydrochloric acid soln is sufficient and stable.
In some embodiments, the top of reaction chamber is provided with vapor pipe, vapor pipe and water-supply pipe cross connection, the junction of vapor pipe and water-supply pipe is provided with water sprayer, water sprayer comprises vacuum breaker, be positioned at the inlet mouth in the middle part of water sprayer and be positioned at water inlet and the water outlet at water sprayer two ends, water inlet is connected with water-supply pipe respectively with water outlet, and inlet mouth is connected with vapor pipe, and vacuum breaker is in the inside of water sprayer and between water inlet and water outlet.Its beneficial effect is, the dioxide peroxide of discharging in the middle of reactor and chlorine can enter in the middle of water sprayer by inlet mouth, dioxide peroxide and chlorine carry out with water being mixed to form dioxide peroxide mixing thimerosal in the middle of water sprayer, and along with forwards carrying in the direction of current.Meanwhile, vacuum breaker can ensure the single flow direction of current, prevents backflow phenomenon.
Principle of work of the present utility model is: hydrochloric acid, sodium chlorate solution are quantitatively transported in reaction chamber through the first feed device, the second feed device under condition of negative pressure, the mixed gas of dioxide peroxide and chlorine is produced by negative pressure aeration reaction, after mixing with water again, form certain density dioxide peroxide mixing thimerosal.
Accompanying drawing explanation
Fig. 1 is the structural representation of a kind of chlorine dioxide generator reactive system of the utility model one embodiment;
Fig. 2 is the structural representation of the water sprayer of a kind of chlorine dioxide generator reactive system of the utility model one embodiment.
Embodiment
Below in conjunction with accompanying drawing 1 to Fig. 2, the utility model is described in further detail.
Fig. 1 show schematically show a kind of chlorine dioxide generator reactive system according to a kind of embodiment of the present utility model, as shown in Figure 1 to Figure 2, a kind of chlorine dioxide generator reactive system, it comprises the first feed device 1, second feed device 2 and reaction chamber 4.
Store sodium chlorate solution in first feed device 1, store hydrochloric acid soln in the second feed device 2, the first feed device 1 and the second feed device 2 all can adopt the chemical barrel or chemical industry groove with a constant volume.
First feed device 1 and the second feed device 2 are all connected to reaction chamber 4 by pipeline.
The material of reaction chamber 4 adopts Si Taili (Stellite) alloy, namely usually said cobalt chromium tungsten (molybdenum) alloy or cobalt base alloy.Its beneficial effect is, stellite is the Wimet of a kind of ability all kinds abrasion and corrosion and high temperature oxidation.Namely usually said cobalt base alloy, stellite is invented in 1907 by American Elwood Hayness.Stellite is using cobalt as main component, containing alloying elements such as a considerable amount of nickel, chromium, tungsten and a small amount of molybdenum, niobium, tantalum, titanium, lanthanums, and the class alloy once in a while yet containing iron.Under general applying working condition, Si Taili (Stellite) alloy is all have wear-resistant high temperature resistant or wear-resistant corrosion resistant situation concurrently.
Adopt the reaction chamber 4 made of Si Taili (Stellite) alloy, while guarantee heat-conduction coefficient, solve dry chlorine gas and the potential hidden danger of catching fire of reaction chamber 4, because chlorine does not react with stellite.While guarantee chlorine dioxide generator high heat transfer, effective potential safety hazard solving employing titanium metal and exist, improve the safety and stability of chlorine dioxide generator, good heat conduction efficiency can be ensured, simultaneously, Si Taili (Stellite) alloy also has satisfactory stability, can not react with chlorine, hidden danger of not catching fire.
In the middle of the present embodiment, Advantageous materials employing department too vertical No. 6 (Stellite 6) alloys of reaction chamber 4.Because stellite has Multiple Type, applicant is through many experiments, and the effect that result shows to take charge of too vertical No. 6 alloys is optimum.
The first volume pump 5, first volume pump 5 is provided with for controlling the feed of the first feed device 1 between the first feed device 1 and reaction chamber 4.Because the feeding speed of the first feed device 1 can be controlled by the first volume pump 5, ensure that the infeed of sodium chlorate solution is sufficient and stable.The second volume pump 6, second volume pump 6 is provided with for controlling the feed of the second feed device 2 between the second feed device 2 and reaction chamber 4.Because the feeding speed of the second feed device 2 can be controlled by the second volume pump 6, ensure that the infeed of hydrochloric acid soln is sufficient and stable.
Vapor pipe 7 is provided with at the top of reaction chamber 4, vapor pipe 7 and water-supply pipe 8 cross connection, vapor pipe 7 is provided with water sprayer 9 with the junction of water-supply pipe 8, as shown in Figure 2, water sprayer 9 comprises vacuum breaker 91, be positioned at the inlet mouth 92 in the middle part of water sprayer 9 and be positioned at water inlet 93 and the water outlet 94 at water sprayer 9 two ends, water inlet 93 is connected with water-supply pipe 8 respectively with water outlet 94, and inlet mouth 92 is connected with vapor pipe 7, and vacuum breaker 91 is in the inside of water sprayer 9 and between water inlet 93 and water outlet 94.The dioxide peroxide of discharging in the middle of reactor and chlorine can enter in the middle of water sprayer 9 by inlet mouth 92, and dioxide peroxide carries out being mixed to form dioxide peroxide mixing thimerosal with water in the middle of water sprayer 9 with chlorine, and along with forwards carrying in the direction of current.Meanwhile, vacuum breaker 91 can ensure the single flow direction of current, prevents backflow phenomenon.
Principle of work of the present utility model is: hydrochloric acid, sodium chlorate solution are quantitatively transported in reaction chamber 4 through the first feed device 1, second feed device 2 under condition of negative pressure, the mixed gas of dioxide peroxide and chlorine is produced by negative pressure aeration reaction, after mixing with water again, form certain density dioxide peroxide mixing thimerosal.
Above is only embodiments more of the present utility model.For the person of ordinary skill of the art, under the prerequisite not departing from the utility model creation design, can also make some distortion and improvement, these all belong to protection domain of the present utility model.
Claims (6)
1. a chlorine dioxide generator reactive system, comprises the first feed device (1), the second feed device (2) and reaction chamber (4),
Store sodium chlorate solution in described first feed device (1), in described second feed device (2), store hydrochloric acid soln;
Described first feed device (1) and described second feed device (2) are all connected to reaction chamber (4) by pipeline, it is characterized in that,
The material of described reaction chamber (4) adopts Si Taili (Stellite) alloy.
2. chlorine dioxide generator reactive system according to claim 1, is characterized in that, material employing department too vertical No. 6 (Stellite 6) alloys of described reaction chamber (4).
3. chlorine dioxide generator reactive system according to claim 1, it is characterized in that, be provided with the first volume pump (5) between described first feed device (1) and reaction chamber (4), described first volume pump (5) is for controlling the feed of described first feed device (1).
4. chlorine dioxide generator reactive system according to claim 1, it is characterized in that, be provided with the second volume pump (6) between described second feed device (2) and reaction chamber (4), described second volume pump (6) is for controlling the feed of described second feed device (2).
5. chlorine dioxide generator reactive system according to claim 1, it is characterized in that, the top of described reaction chamber (4) is provided with vapor pipe (7), described vapor pipe (7) and water-supply pipe (8) cross connection, described vapor pipe (7) is provided with water sprayer (9) with the junction of described water-supply pipe (8).
6. chlorine dioxide generator reactive system according to claim 1, it is characterized in that, described water sprayer (9) comprises vacuum breaker (91), be positioned at the inlet mouth (92) at water sprayer (9) middle part and be positioned at water inlet (93) and the water outlet (94) at water sprayer (9) two ends, described water inlet (93) is connected with water-supply pipe (8) respectively with water outlet (94), described inlet mouth (92) is connected with described vapor pipe (7), described vacuum breaker (91) is positioned at the inside of water sprayer (9) and is positioned between water inlet (93) and water outlet (94).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201420592978.7U CN204111312U (en) | 2014-10-14 | 2014-10-14 | A kind of chlorine dioxide generator reactive system |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201420592978.7U CN204111312U (en) | 2014-10-14 | 2014-10-14 | A kind of chlorine dioxide generator reactive system |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN204111312U true CN204111312U (en) | 2015-01-21 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201420592978.7U Expired - Lifetime CN204111312U (en) | 2014-10-14 | 2014-10-14 | A kind of chlorine dioxide generator reactive system |
Country Status (1)
| Country | Link |
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| CN (1) | CN204111312U (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108328578A (en) * | 2018-01-29 | 2018-07-27 | 荣成海奥斯生物科技有限公司 | The filling apparatus of gaseous state effective chlorine aqueous solution |
-
2014
- 2014-10-14 CN CN201420592978.7U patent/CN204111312U/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108328578A (en) * | 2018-01-29 | 2018-07-27 | 荣成海奥斯生物科技有限公司 | The filling apparatus of gaseous state effective chlorine aqueous solution |
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |