CN204102997U - A kind of Ribbon-type energy storage battery - Google Patents
A kind of Ribbon-type energy storage battery Download PDFInfo
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- CN204102997U CN204102997U CN201420458195.XU CN201420458195U CN204102997U CN 204102997 U CN204102997 U CN 204102997U CN 201420458195 U CN201420458195 U CN 201420458195U CN 204102997 U CN204102997 U CN 204102997U
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Abstract
The utility model relates to a kind of Ribbon-type energy storage battery, and in its battery container, isolation has state-of-charge material loading area, electrolyte region and electric discharge state material loading area; The positive electrode of load battery on its one group of conductive substrates band, forms positive conductive band, the negative material of load battery on its other one group of conductive strips, forms negative conductive band; The two ends of positive conductive band and negative conductive band are wound on two rollers respectively, wherein one end is placed in state-of-charge material loading area, one end is in discharge condition material loading area in addition, two roller mid portions are placed on the electrolyte region of many group directive wheels simultaneously, the conductive strips position of mid portion is in electrolyte.It had not only had high discharge volume power ratio, but also had had the feature of Mass storage energy, was adapted to regulate the crest of electrical network, trough and the portable power source as electric automobile.
Description
Technical field
The utility model belongs to the battery technology of new energy field, relates to a kind of being adapted to and regulates the crest of electrical network, trough and the Ribbon-type energy storage battery as electric automobile portable power source.
Background technology
Flow battery is a kind of large-scale energy storage device, and its basic functional principle is the both positive and negative polarity of battery or a certain pole active material is fluid liquid oxidation-reduction pair.Because flow battery can store respectively by Conversion of Energy to electrolyte, because have the advantage of ultra-large stored energy, because this feature flow battery is applicable to the energy storage technology of the generation of electricity by new energy such as wind energy, solar energy.At present with all-vanadium flow battery most development potentiality in flow battery.But in full flow battery, the pentavalent vanadium in vanadium cell positive pole liquid easily separates out vanadic oxide precipitation in standing or temperature higher than when 45 DEG C, the precipitation blocking runner of precipitation, carbon coated felt fiber, deterioration Performance data, until pile is scrapped.And graphite electrode plate is easily etched by positive pole liquid in the cell, and pile electrolyte temperature in long-play process can easily exceed 45 DEG C, if user operation is improper, once charging just can allow graphite cake etch completely, and pile can only be scrapped.Also to there is discharge current density low for this battery simultaneously, the low density feature of volumetric specific power.
Summary of the invention
In order to overcome the above-mentioned shortcoming of prior art, the utility model provides a kind of and had not only had high discharge volume power ratio, but also has the Ribbon-type energy storage battery of Mass storage energy feature.
The utility model solves the technical scheme that its technical problem adopts: a kind of Ribbon-type energy storage battery, and in its battery container, isolation has state-of-charge material loading area, electrolyte region and electric discharge state material loading area; The positive electrode of load battery on its one group of conductive substrates band, forms positive conductive band, the negative material of load battery on its other one group of conductive strips, forms negative conductive band; The two ends of positive conductive band and negative conductive band are wound on two rollers respectively, wherein one end is placed in state-of-charge material loading area, one end is in discharge condition material loading area in addition, two roller mid portions are placed on the electrolyte region of many group directive wheels simultaneously, make the conductive strips position of mid portion be in electrolyte; When this battery is in the complete state of charging, the charged material loading area of positive conductive band and negative conductive band is in the full state of winding, and corresponding another section electric discharge state material loading area is then empty Spindle Status; During this battery discharge, the conductive strips of charged state are rotated by the micromotor coaxial with roller, after allowing two groups to be coated with the conductive strips superposition compression of coated positive pole material and negative material respectively, enter electrolysis discharge in liquid together, the conductive strips of discharge off move out outside the electrolytic cell containing electrolyte, be again wound by the empty axle of correspondence be outward kept in electric discharge state material loading area at electrolytic cell; Then contrary process is carried out during the charging of this battery.
Described state-of-charge material loading area refers to the memory space of the roller of roller and the negative conductive band that reeled simultaneously being mounted with the positive conductive band that reeled, and positive conductive band and negative conductive band are all in the state being full of electricity; The roller being wound with positive conductive band and negative conductive band of described state-of-charge material loading area is connected by gear mechanism and enables equidirectional synchronous axial system, and it rotates is realized by a micro-step motor.
Described electric discharge state material loading area refers to the memory space of the roller of roller and the negative conductive band that reeled simultaneously being mounted with the positive conductive band that reeled, and positive pole roller and negative pole roller are all in the state of discharging completely; The roller being wound with positive conductive band and negative conductive band of described electric discharge electricity condition material loading area is connected by gear mechanism and enables equidirectional synchronous axial system, and it rotates is realized by a micro-step motor.
Described electrolyte region refers to the space being mounted with electrolyte, and positive conductive band and negative conductive band carry out charging or discharging in this region, and electrolyte is wherein organic electrolyte or inorganic electrolyte.
Described conductive substrates band refers to that plating, evaporation and these class methods of magnetron sputtering obtain the coat of metal formation conductive substrates band of one or more layers structure on plastic tape; Or the porous strip that the metal tape to be formed by metal Direct Rolling or porous foam metal are formed, or the metal fiber felt sintered into by metal fiber wire is by cutting the porous, electrically conductive band obtained, and the composite conducting band obtained by their one or several compounds; The metal that conductive substrates band uses refers to Cu, Fe, this metalloid of Cr, W, Mo, V, Al, Sn, Bi, Pb, In, Ni, Co and the elemental metals formed by one or more in them or alloy.
The described conductive strips with one fixed width are finger widths is 1um ~ 10m, and thickness is the conductive ribbon material within the scope of 0.1um ~ 1mm; The load-carrying cell positive material of described positive conductive is positive electrode or the air electrode of this kind of battery of MnO2, Ni (OH) O, PbO2, LiCoO2, and battery directly uses the oxygen in air to be oxidant, forms fuel cell; The load-carrying cell negative electrode material of described negative conductive can be the negative material of Mg, Al, Zn, Cd, Pb and this kind of battery of hydrogen bearing alloy.
Described conductive electrode band refers to the positive conductive band that on conductive substrates band load electrode active material obtains and negative conductive band.
Described conduction load-carrying battery cathode pole material deposits on conductive strips by the method for electro-deposition, adopts Zn, Cd, Pb metal species negative material, or then obtained by rolling by being coated onto on porous metals conductive strips by metal dust pulp spraying; The load-carrying cell positive material of described positive conductive deposits on porous, electrically conductive band by the method for electro-deposition, adopt MnO2, Ni (OH) O this kind of positive electrode, or spray on porous metals conductive strips then obtained by rolling by positive electrode being made powder slurries.
The stepping motor of described Ribbon-type energy storage battery charged material loading area when charging rotates, the stepping motor passive movement of region of discharge; Upon discharging, the stepping motor of region of discharge rotates, the stepping motor passive rotation in charged region.
Good effect of the present utility model is: adopted by the electrode material of battery the special way stored to realize the unconfined increase of battery capacity; This battery has the ion exchange resin membrane without the need to costliness, has cheap feature; Such battery has higher power output mutually; This battery is Mass storage electric energy, provides good energy storage scheme for regulating crest, the trough of electrical network; If the positive pole use air cell of this battery is suitable as the portable power source of electric automobile by having larger energy density.
Accompanying drawing explanation
Fig. 1 is structural representation of the present utility model;
Fig. 2 is the cutaway view of Fig. 1;
Fig. 3 is the structure chart of micro-step motor;
Fig. 4 is electrode structure schematic diagram;
In figure: 1-charging state loading area, 2-electrolysis liquid zone, 3-electric discharge state material loading area, 4-positive pole, 5-negative pole, 6-barrier film, 7-directive wheel, 8-micro-step motor, 9-positive pole band, 10-negative pole band.
Embodiment
Below in conjunction with embodiment and accompanying drawing, the utility model is further illustrated.
A kind of Ribbon-type energy storage battery, it belongs to the battery technology of new energy field, relates to design and production method that a kind of belt, long-life and Large Copacity fill energy battery; The utility model provide a kind of by the reducing agent of flow battery and oxidant all by load on plastic tape or metal tape, then preserve by the way of winding the method that the reducing agent of battery and oxidant realize Mass storage energy, the advantage that this battery has a similar common batteries height discharge volume power ratio has the feature of flow battery Mass storage energy simultaneously.
Process a battery container, and battery container is isolated into three regions, be respectively state-of-charge material loading area, electrolyte region and electric discharge state material loading area.Process two groups of conductive substrates bands, respectively the positive electrode of load battery on the conductive substrates band of a group wherein, form positive conductive band, the negative material of load battery on other one group of conductive strips, form negative conductive band.Positive conductive band and negative conductive band two ends are wound on two rollers respectively, wherein one end is positioned over state-of-charge material loading area, one end is in discharge condition material loading area in addition, be placed on electrolyte region at two roller mid portions simultaneously, this region exists organizes directive wheel more, and the conductive strips position of mid portion is in electrolyte.When this battery is in the complete state of charging, then the charged material loading area of positive conductive band and negative conductive band is in the full state of winding, and corresponding another section electric discharge state material loading area is then empty Spindle Status.During this battery discharge, by the conductive strips of charged state by and the coaxial micromotor of roller rotate allow two groups be coated with respectively coated positive pole material after the conductive strips superposition compression of negative material together with enter electrolysis discharge in liquid, the conductive strips of discharge off move out outside the electrolytic cell containing electrolyte, be again wound by the empty axle of correspondence be outward kept in electric discharge state material loading area at electrolytic cell; Then contrary process is carried out during the charging of this battery.
Described state-of-charge material loading area refers to the memory space of the roller of roller and the negative conductive band that reeled simultaneously being mounted with the positive conductive band that reeled, and positive conductive band and negative conductive band are all in the state being full of electricity.
Described electric discharge state material loading area refers to the memory space of the roller of roller and the negative conductive band that reeled simultaneously being mounted with the positive conductive band that reeled, and positive pole roller and negative pole roller are all in the state of discharging completely.
Described electrolyte region refers to the space being mounted with electrolyte, and positive conductive band and negative conductive band carry out charging or discharging in this region, and electrolyte wherein can be organic electrolyte also can be inorganic electrolyte.
Described conductive substrates band refers to that plating, evaporation and these class methods of magnetron sputtering obtain the coat of metal formation conductive substrates band of one or more layers structure on plastic tape; Or the porous strip that the metal tape to be formed by metal Direct Rolling or porous foam metal are formed, or the metal fiber felt sintered into by metal fiber wire is by cutting the porous, electrically conductive band obtained, and the metal that the conductive substrates band described in composite conducting band obtained by their one or several compounds uses refers to Cu, Fe, Cr, W, Mo, V, Al, Sn, Bi, Pb, In, the metals such as Ni, Co and one or more are formed by them elemental metals or alloy.
The described conductive strips with one fixed width are finger widths is 1um ~ 10m, and thickness is the conductive ribbon material within the scope of 0.1um ~ 1mm.
Described conductive electrode band refers to the positive conductive band that on conductive substrates band load electrode active material obtains and negative conductive band.
The load-carrying cell positive material of described positive conductive can be positive electrode or the air electrode of this kind of battery of MnO2, Ni (OH) O, PbO2, LiCoO2, and battery directly uses the oxygen in air to be oxidant, forms fuel cell.
The load-carrying cell negative electrode material of described negative conductive can be the negative material of Mg, Al, Zn, Cd, Pb and this kind of battery of hydrogen bearing alloy.
Described conduction load-carrying battery cathode pole material deposits on conductive strips by the method for electro-deposition, Zn, Cd, Pb metal species negative material, or then obtained by rolling by being coated onto on porous metals conductive strips by metal dust pulp spraying.
The load-carrying cell positive material of described positive conductive deposits on porous, electrically conductive band by the method for electro-deposition, this kind of positive electrode of MnO2, Ni (OH) O, or spray on porous metals conductive strips then obtained by rolling by positive electrode being made powder slurries.
The roller being wound with positive conductive band and negative conductive band of described state-of-charge material loading area is connected by gear mechanism and enables equidirectional synchronous axial system, and it rotates is realized by a micro-step motor.
The roller being wound with positive conductive band and negative conductive band of described electric discharge electricity condition material loading area is connected by gear mechanism and enables equidirectional synchronous axial system, and it rotates is realized by a micro-step motor.
The stepping motor of described Ribbon-type energy storage battery charged material loading area when charging rotates, the stepping motor passive movement of region of discharge; Upon discharging, the stepping motor of region of discharge rotates, the stepping motor passive rotation in charged region.
The electrode material of battery adopts the special way stored to realize the unconfined increase of battery capacity by the utility model; This battery has the ion exchange resin membrane without the need to costliness, has cheap feature; Such battery has higher power output mutually; This battery is Mass storage electric energy, provides good energy storage scheme for regulating crest, the trough of electrical network; If the positive pole use air cell of this battery is suitable as the portable power source of electric automobile by having larger energy density.
Embodiment 1:
The scheme illustrated by accompanying drawing 1 adopts PP plastic processing growth × wide × height to be the plastic channel of 700 × 150 × 200mm, plastic channel is separated in the longitudinal direction 300+100+100mm tri-part, is respectively charged material loading area, electrolyte region and electric discharge electric material loading area.Outside charged material loading area plastic channel, gear linkage mechanism and stepping motor are installed respectively according to shown in Fig. 2,3, positive conductive band rotation axis and negative conductive band rotation axis are installed inside groove, installation 5 groups of directive wheels are shown according to Fig. 2 in electrolyte region, one group of parallel connection wherein connects the cathode output end of battery afterwards, is connected to the cathode output end of battery after one group of parallel connection above.Outside discharge material loading area plastic channel, gear linkage mechanism and stepping motor are installed equally, positive conductive band rotation axis and negative conductive band rotation axis are installed inside groove.And above-mentioned motor is connected with controller respectively.Positive conductive band sinters Ni-based porous metal fiber felt into 5um metallic nickel filament, then cuts into that 140mm is wide, the metal fiber tape of thickness 0.17mm is as anode floor conductive strips.Then NiO (OH) and carbon black, polyflon are configured to slurry according to the weight ratio row of 80:14: 6, utilize the method for spraying to uniformly spray on positive conductive band.After fully drying under 80 DEG C of conditions, side superposition barrier film is wherein rolled integralization positive pole band.The crome metal that negative conductive band is, thickness wide with 140mm is 10um for 0.1mm stainless steel strip electroplating thickness obtains base conductive band, on conductive strips, then electroplates the metallic zinc after 0.1mm as negative conductive band.Positive conductive band, negative pole road electricity band are wound on the roller bearing of charged material loading area and discharge material loading area respectively, and making positive conductive band conducting surface directly can contact positive conductive wheel simultaneously, negative conductive band can directly contact negative pole directive wheel.Then obtain described battery with dissolving the 30%KOH solution of saturated zinc oxide and joining as electrolyte in the separate slot in electrolysis region, above-mentioned battery open circuit voltage is 1.6 volts.
Embodiment 2:
The scheme illustrated by accompanying drawing 1 adopts PP plastic processing growth × wide × height to be the plastic channel of 3500 × 500 × 750mm, plastic channel is separated in the longitudinal direction 1600+500+1600mm tri-part, is respectively charged material loading area, electrolyte region, electric discharge electric material loading area.According to Fig. 2,3 show and outside charged material loading area plastic channel, install gear linkage mechanism and stepping motor respectively, install positive conductive band rotation axis and negative conductive band rotation axis inside groove.Show installation 10 groups of directive wheels in electrolyte region according to Fig. 2, one group of parallel connection wherein connects the cathode output end of battery afterwards, is connected to the cathode output end of battery after one group of parallel connection above.Outside discharge material loading area plastic channel, gear linkage mechanism and stepping motor are installed equally, positive conductive band rotation axis and negative conductive band rotation axis are installed inside groove.And above-mentioned motor is connected with controller respectively.Positive conductive band sinters Ni-based porous metal fiber felt into 5um metallic nickel filament, then cuts into that 490mm is wide, the metal fiber tape of thickness 0.17mm is as anode floor conductive strips.Then Ni (OH) O and carbon black, polyflon are configured to slurry according to the weight ratio row of 80:14: 6, utilize the method for spraying to uniformly spray on positive conductive band.After fully drying under 80 DEG C of conditions, side superposition barrier film is wherein rolled integralization positive pole band.Negative conductive band sinters Ni-based porous metal fiber felt into 5um metallic nickel filament, then cuts into that 490mm is wide, the metal fiber tape of thickness 0.17mm is as negative pole base conductive band.Then hydrogen storing alloy powder, polyflon are configured to slurry according to the weight ratio row of 90: 10, utilize the method for spraying to uniformly spray on negative conductive band.After fully drying under 80 DEG C of conditions, be rolled into positive conductive band.Positive conductive band, negative pole road electricity band are wound on the roller bearing of charged material loading area and discharge material loading area respectively, and making positive conductive band conducting surface directly can contact positive conductive wheel simultaneously, negative conductive band can directly contact negative pole directive wheel.Then to join as electrolyte with 30%KOH solution in the separate slot in electrolysis region and obtain described battery, above-mentioned battery open circuit voltage is 1.2 volts.
Claims (9)
1. a Ribbon-type energy storage battery, is characterized in that: in its battery container, isolation has state-of-charge material loading area, electrolyte region and electric discharge state material loading area; The positive electrode of load battery on its one group of conductive substrates band, forms positive conductive band, the negative material of load battery on its other one group of conductive strips, forms negative conductive band; The two ends of positive conductive band and negative conductive band are wound on two rollers respectively, wherein one end is placed in state-of-charge material loading area, one end is in discharge condition material loading area in addition, two roller mid portions are placed on the electrolyte region of many group directive wheels simultaneously, make the conductive strips position of mid portion be in electrolyte; When this battery is in the complete state of charging, the charged material loading area of positive conductive band and negative conductive band is in the full state of winding, and corresponding another section electric discharge state material loading area is then empty Spindle Status; During this battery discharge, the conductive strips of charged state are rotated by the micromotor coaxial with roller, after allowing two groups to be coated with the conductive strips superposition compression of coated positive pole material and negative material respectively, enter electrolysis discharge in liquid together, the conductive strips of discharge off move out outside the electrolytic cell containing electrolyte, be again wound by the empty axle of correspondence be outward kept in electric discharge state material loading area at electrolytic cell; Then contrary process is carried out during the charging of this battery.
2. Ribbon-type energy storage battery as described in claim 1, it is characterized in that: described state-of-charge material loading area refers to the memory space of the roller of roller and the negative conductive band that reeled simultaneously being mounted with the positive conductive band that reeled, and positive conductive band and negative conductive band are all in the state being full of electricity; The roller being wound with positive conductive band and negative conductive band of described state-of-charge material loading area is connected by gear mechanism and enables equidirectional synchronous axial system, and it rotates is realized by a micro-step motor.
3. Ribbon-type energy storage battery as described in claim 1, it is characterized in that: described electric discharge state material loading area refers to the memory space of the roller of roller and the negative conductive band that reeled simultaneously being mounted with the positive conductive band that reeled, and positive pole roller and negative pole roller are all in the state of discharging completely; The roller being wound with positive conductive band and negative conductive band of described electric discharge electricity condition material loading area is connected by gear mechanism and enables equidirectional synchronous axial system, and it rotates is realized by a micro-step motor.
4. Ribbon-type energy storage battery as described in claim 1, it is characterized in that: described electrolyte region refers to the space being mounted with electrolyte, positive conductive band and negative conductive band carry out charging or discharging in this region, and electrolyte is wherein organic electrolyte or inorganic electrolyte.
5. Ribbon-type energy storage battery as described in claim 1, is characterized in that: described conductive substrates band refers to that plating, evaporation and these class methods of magnetron sputtering obtain the coat of metal formation conductive substrates band of one or more layers structure on plastic tape; Or the porous strip that the metal tape to be formed by metal Direct Rolling or porous foam metal are formed, or the metal fiber felt sintered into by metal fiber wire is by cutting the porous, electrically conductive band obtained, and the composite conducting band obtained by their one or several compounds; The metal that conductive substrates band uses refers to Cu, Fe, this metalloid of Cr, W, Mo, V, Al, Sn, Bi, Pb, In, Ni, Co and the elemental metals formed by one or more in them or alloy.
6. Ribbon-type energy storage battery as described in claim 1, is characterized in that: the described conductive strips with one fixed width are finger widths is 1um ~ 10m, and thickness is the conductive ribbon material within the scope of 0.1um ~ 1mm; The load-carrying cell positive material of described positive conductive is positive electrode or the air electrode of this kind of battery of MnO2, Ni (OH) O, PbO2, LiCoO2, and battery directly uses the oxygen in air to be oxidant, forms fuel cell; The load-carrying cell negative electrode material of described negative conductive can be the negative material of Mg, Al, Zn, Cd, Pb and this kind of battery of hydrogen bearing alloy.
7. Ribbon-type energy storage battery as described in claim 1, is characterized in that: conductive electrode band refers to the positive conductive band that on conductive substrates band load electrode active material obtains and negative conductive band.
8. Ribbon-type energy storage battery as described in claim 1, it is characterized in that: described conduction load-carrying battery cathode pole material deposits on conductive strips by the method for electro-deposition, adopt Zn, Cd, Pb metal species negative material, or then obtained by rolling by metal dust pulp spraying is coated onto on porous metals conductive strips; The load-carrying cell positive material of described positive conductive deposits on porous, electrically conductive band by the method for electro-deposition, adopt MnO2, Ni (OH) O this kind of positive electrode, or spray on porous metals conductive strips then obtained by rolling by positive electrode being made powder slurries.
9. Ribbon-type energy storage battery as described in claim 1, is characterized in that: the stepping motor of described Ribbon-type energy storage battery charged material loading area when charging rotates, the stepping motor passive movement of region of discharge; Upon discharging, the stepping motor of region of discharge rotates, the stepping motor passive rotation in charged region.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201420458195.XU CN204102997U (en) | 2014-08-14 | 2014-08-14 | A kind of Ribbon-type energy storage battery |
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| CN201420458195.XU CN204102997U (en) | 2014-08-14 | 2014-08-14 | A kind of Ribbon-type energy storage battery |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2017097228A1 (en) * | 2015-12-08 | 2017-06-15 | The Chinese University Of Hong Kong | High-energy density and low-cost flow electrochemical devices |
| CN109666908A (en) * | 2018-11-30 | 2019-04-23 | 汽解放汽车有限公司 | Solid-state hydrogen storage core and preparation method thereof |
-
2014
- 2014-08-14 CN CN201420458195.XU patent/CN204102997U/en not_active Expired - Fee Related
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2017097228A1 (en) * | 2015-12-08 | 2017-06-15 | The Chinese University Of Hong Kong | High-energy density and low-cost flow electrochemical devices |
| CN107210480A (en) * | 2015-12-08 | 2017-09-26 | 香港中文大学 | High-energy-density and inexpensive liquid galvanochemistry device |
| JP2019506700A (en) * | 2015-12-08 | 2019-03-07 | ザ チャイニーズ ユニバーシティー オブ ホンコン | High energy density and low cost flow electrochemical equipment |
| CN107210480B (en) * | 2015-12-08 | 2022-05-27 | 香港中文大学 | High energy density and low cost liquid flow electrochemical device |
| US11784341B2 (en) | 2015-12-08 | 2023-10-10 | The Chinese University Of Hong Kong | High-energy density and low-cost flow electrochemical devices with moving rechargeable anode and cathode belts |
| CN109666908A (en) * | 2018-11-30 | 2019-04-23 | 汽解放汽车有限公司 | Solid-state hydrogen storage core and preparation method thereof |
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Granted publication date: 20150114 Termination date: 20180814 |