CN204097571U - Ultrasonic pickler - Google Patents
Ultrasonic pickler Download PDFInfo
- Publication number
- CN204097571U CN204097571U CN201420530629.2U CN201420530629U CN204097571U CN 204097571 U CN204097571 U CN 204097571U CN 201420530629 U CN201420530629 U CN 201420530629U CN 204097571 U CN204097571 U CN 204097571U
- Authority
- CN
- China
- Prior art keywords
- pickling tank
- ultrasonic
- cell body
- pickler
- pickling
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000005554 pickling Methods 0.000 claims abstract description 42
- 239000007788 liquid Substances 0.000 claims abstract description 24
- 210000005056 cell body Anatomy 0.000 claims abstract description 23
- 238000010438 heat treatment Methods 0.000 claims abstract description 12
- 239000012530 fluid Substances 0.000 claims abstract description 9
- 239000000523 sample Substances 0.000 claims abstract description 5
- 239000002253 acid Substances 0.000 abstract description 24
- 238000000034 method Methods 0.000 abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 10
- YWYZEGXAUVWDED-UHFFFAOYSA-N triammonium citrate Chemical compound [NH4+].[NH4+].[NH4+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O YWYZEGXAUVWDED-UHFFFAOYSA-N 0.000 abstract description 8
- 238000004140 cleaning Methods 0.000 abstract description 7
- 230000008569 process Effects 0.000 abstract description 6
- 229910000831 Steel Inorganic materials 0.000 abstract description 4
- 230000008901 benefit Effects 0.000 abstract description 4
- 239000010959 steel Substances 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 230000005611 electricity Effects 0.000 abstract description 2
- 238000003912 environmental pollution Methods 0.000 abstract description 2
- 239000002918 waste heat Substances 0.000 abstract description 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 12
- 239000003595 mist Substances 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 5
- 241000270666 Testudines Species 0.000 description 3
- 235000011114 ammonium hydroxide Nutrition 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 2
- BWKOZPVPARTQIV-UHFFFAOYSA-N azanium;hydron;2-hydroxypropane-1,2,3-tricarboxylate Chemical compound [NH4+].OC(=O)CC(O)(C(O)=O)CC([O-])=O BWKOZPVPARTQIV-UHFFFAOYSA-N 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- FRHBOQMZUOWXQL-UHFFFAOYSA-L ammonium ferric citrate Chemical compound [NH4+].[Fe+3].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O FRHBOQMZUOWXQL-UHFFFAOYSA-L 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 229960004643 cupric oxide Drugs 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000005485 electric heating Methods 0.000 description 1
- 229960004642 ferric ammonium citrate Drugs 0.000 description 1
- 235000019850 ferrous citrate Nutrition 0.000 description 1
- 239000011640 ferrous citrate Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 239000004313 iron ammonium citrate Substances 0.000 description 1
- 235000000011 iron ammonium citrate Nutrition 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- APVZWAOKZPNDNR-UHFFFAOYSA-L iron(ii) citrate Chemical compound [Fe+2].OC(=O)CC(O)(C([O-])=O)CC([O-])=O APVZWAOKZPNDNR-UHFFFAOYSA-L 0.000 description 1
- 235000015110 jellies Nutrition 0.000 description 1
- 239000008274 jelly Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000002000 scavenging effect Effects 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000007779 soft material Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
Landscapes
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Abstract
The utility model relates to a kind of ultrasonic pickler steel being carried out to pickling.Ultrasonic pickler, comprise the pickling tank with fluid inlet and liquid outlet, fluid inlet is arranged at pickling tank cell body top, liquid outlet is arranged at pickling tank cell body bottom, described pickling tank cell body inner bottom part is provided with heating tube, also comprises the air shooter that port stretches into pickling tank cell body and the ultrasonic probe be sticked under pickling tank.The utility model is the pickler designed for ultrasonic ammonium citrate acid cleaning process, and first it has advantage free from environmental pollution; Secondly the utility model has two kinds of type of heating, and water vapour can adopt waste heat boiler to provide, can save electricity, for enterprise saves production cost, increases the benefit.
Description
Technical field
The utility model relates to a kind of device steel being carried out to pickling, particularly relates to a kind of ultrasonic pickler.
Background technology
Appear at the oxide skin on surface after steel annealing, in prior art, the general inorganic acid that uses carries out pickling, and pickling tub is for avoiding corrosion, and normally cement is built.Such mode of production is unfavorable for environment protection.Application number is the Chinese invention patent of 201310212622.6, disclose a kind of pickling tub, it comprises acid bath, standard acid solution bucket, electronics pH meter, electronic liquid level gauge and strong acid liquid bucket, described electronics pH counts and electronic liquid level gauge is placed on a sidewall of acid bath, described electronics pH meter is connected with described strong acid liquid bucket, described electronic liquid level gauge is connected with standard acid solution bucket, and described standard acid solution bucket is all communicated with described acid bath with strong acid liquid bucket.This technical scheme, by arranging pH meter and liquidometer in pickling tub, can supplement suitable acid solution to pickling tub in time, makes the acidity of pickling tub keep constant, thus continues to have good pickling ability.Although this pickling tub user, still cannot the problem of contaminated solution environment.Application number is the new patent of Chinese utility model of 2009201160322, disclose a kind of pickling tub, this comprises the pond body of holding acid solution, acid mist gas exhaust duct and acid mist cover, acid mist gas exhaust duct and body upper end, pond communicate, described acid mist cover is made up of soft material, covers on the body of described pond himself Telescopic movable.This utility model utilizes the acid mist cover of telescopic moving to hide acid mist, and the duration of contact of acid mist and workman is shortened as far as possible.Foregoing invention is created and conveniently can be produced to a certain extent or protect workers ' health to avoid room air pollution, but pollution scale removal cannot contained from source and produce.Therefore, this area a kind of new pickler of needing a kind of new pickling mode badly and matching with it.
Utility model content
The utility model will solve the problems of the technologies described above, thus provides a kind of ultrasonic pickler being applicable to ultrasonic organic acid acid cleaning process.
The technical scheme that the utility model solves the problem is as follows:
Ultrasonic pickler, comprise the pickling tank with fluid inlet and liquid outlet, fluid inlet is arranged at pickling tank cell body top, liquid outlet is arranged at pickling tank cell body bottom, described pickling tank cell body inner bottom part is provided with heating tube, also comprises the air shooter that port stretches into pickling tank cell body and the ultrasonic probe be sticked under pickling tank.
Ultrasonic pickler in the utility model technique scheme coordinates ultrasonic ammonium citrate acid cleaning process and researches and develops.Ultrasonic ammonium citrate acid cleaning process, the main oxide skin of ammonium citrate solution to steel surface that adopts is cleaned, and is aided with ultrasonic, strengthening pickling effect.Ammonium citrate to be coordinated with ammoniacal liquor by citric acid and produces, and the mechanism of its cleaning oxide skin has three layers: the first level, the rust deposite of some metal oxides such as citric acid solubilized ferric oxide, cupric oxide.But the ironic citrate solubleness generated due to reaction is little, and often jelly body is attached on metallic surface, becomes the membranaceous material being difficult to rinse out; Second aspect, adds the ammonium citrate that ammoniacal liquor is formed in citric acid, by above-mentioned membranaceous substance dissolves, can generate ferric ammonium citrate and ferrous citrate ammonium complex compound.Thus system can be discharged with scavenging solution, reach the object of cleaning.Which solve the problem easily producing mud in prior art.And for the process of complex compound, just quite simple.Due to the material that complex compound is not a kind of steady state, only need changing the acid-basicity of dispersion liquid, as adjusted with citric acid is counter, will sedimentation be produced, then utilize pressure filter just can by this kind of separating substances out.Therefore this technical scheme also solves the reluctant problem of the heavy metallic salt of processable in prior art; Third layer face, the Fe in acid condition in oxide skin
2o
3and Fe
3o
4huge legendary turtle can be there is with ammonium citrate at 80 ~ 90 DEG C and close reaction, form ironic citrate ammonia huge legendary turtle compound, ironic citrate ammonia huge legendary turtle compound is water-soluble under ammoniacal liquor state, and fine and close oxide skin is separated from body, be aided with the ul-trasonic irradiation of high-power high-frequency rate, the object of rapid descaling can be reached.
Preferred as technique scheme, described air shooter is moisture vapor transport pipe.
In technique scheme of the present invention, have two heater wires, one is by moisture vapor transport pipe, conveying water vapour, and adopt water vapour to liquid direct heating, water vapour meets cold direct liquefaction Cheng Shui, does not produce bubble; Also electric heating tube can be adopted to heat liquid.
Preferred as technique scheme, the aperture of described moisture vapor transport pipe is 0.2 ~ 2cm, 5 ~ 10cm bottom the port distance pickling tank cell body of described moisture vapor transport pipe.
Water vapour heating has limitation, if air-flow velocity is excessive, then water vapour have little time to conduct heat after liquefaction, escape into surrounding environment, greatly strengthen indoor humidity while causing room temp to raise, be unfavorable for Working environment construction; Gas velocity crosses slow or flow is too low, then heats is not obvious, can not utilize the heattransfer effect of water vapour well.Therefore should need a kind of slower and be the mode of movement of large discharge, this just relates to quantity, the arrangement of moisture vapor transport pipe and bore is isoparametric defines.Moisture vapor transport pipe and bottom are pasted too closely then can affect operational throughput, too far away, the heat transfer effect distance of water vapour and liquid can be shortened, usual moisture vapor transport is as entered in liquid, an air-flow can be produced downwards, this reduction of speed limit, air-flow limit disappears subsequently, and after reducing as far as possible, then limit rising edge disappears, until completely dissolve, this is the mode of motion that a kind of desirable water vapour air-flow as heat-transfer medium enters liquid.According to this theory, contriver is through repeatedly putting into practice, and by as follows for each parameter adjustment: the aperture of described moisture vapor transport pipe is 0.2 ~ 2cm, the port of described moisture vapor transport pipe is apart from 5 ~ 10cm bottom pickling tank cell body; The spacing of adjacent moisture vapor transport pipe is 5 ~ 15cm.
Preferred as technique scheme, the quantity of described moisture vapor transport pipe is multiple.
Preferred as technique scheme, the spacing of adjacent moisture vapor transport pipe is 5 ~ 15cm.
Preferred as technique scheme, described heating tube is the non-closed ring-type of dish in cell body, and described liquid outlet is arranged on the non-closed place of this non-closed ring.
In sum, the utility model has following beneficial effect:
The utility model is the pickler designed for ultrasonic ammonium citrate acid cleaning process, and first it has advantage free from environmental pollution; Secondly the utility model has two kinds of type of heating, and water vapour can adopt waste heat boiler to provide, can save electricity, for enterprise saves production cost, increases the benefit.
Accompanying drawing explanation
Fig. 1 is cross section structure schematic diagram of the present utility model;
Fig. 2 is plan structure schematic diagram of the present utility model;
In figure, 1-pickling tank, 11-fluid inlet, 12-liquid outlet, 2-heating tube, 3-air shooter, 4-ultrasonic probe, 5-supply lead.
Embodiment
Below in conjunction with accompanying drawing, the utility model is further detailed.
This embodiment is only to explanation of the present utility model, is not to restriction of the present utility model.Any amendment that those skilled in the art are done after having read specification sheets of the present utility model, as long as in the protection domain of claim, all will be subject to the protection of patent law.
As shown in Figure 1-2, ultrasonic pickler, comprise the pickling tank 1 with fluid inlet 11 and liquid outlet 12, fluid inlet, 11 are arranged at pickling tank 1 cell body top, liquid outlet 12 is arranged at pickling tank 1 cell body bottom, and described pickling tank 1 cell body inner bottom part is provided with heating tube 2, also comprises the air shooter 3 that port stretches into pickling tank 1 cell body and the ultrasonic probe 4 be sticked under pickling tank 1.Described air shooter 3 is moisture vapor transport pipe.The aperture of described moisture vapor transport pipe is 1cm, 6cm bottom port distance pickling tank 1 cell body of described moisture vapor transport pipe.The quantity of described moisture vapor transport pipe is 3.The spacing of adjacent moisture vapor transport pipe is 10cm.Described heating tube 2 is the non-closed ring-type of dish in cell body, and described liquid outlet 12 is arranged on the non-closed place of this non-closed ring.
Claims (6)
1. ultrasonic pickler, comprise the pickling tank (1) with fluid inlet (11) and liquid outlet (12), fluid inlet (11) is arranged at pickling tank (1) cell body top, liquid outlet (12) is arranged at pickling tank (1) cell body bottom, it is characterized in that: described pickling tank (1) cell body inner bottom part is provided with heating tube (2), also comprise the air shooter (3) that port stretches into pickling tank (1) cell body and the ultrasonic probe (4) be sticked under pickling tank (1).
2. ultrasonic pickler according to claim 1, is characterized in that: described air shooter (3) is moisture vapor transport pipe.
3. ultrasonic pickler according to claim 2, is characterized in that: the aperture of described moisture vapor transport pipe is 0.2 ~ 2cm, 5 ~ 10cm bottom port distance pickling tank (1) cell body of described moisture vapor transport pipe.
4. ultrasonic pickler according to claim 3, is characterized in that: the quantity of described moisture vapor transport pipe is multiple.
5. ultrasonic pickler according to claim 4, is characterized in that: the spacing of adjacent moisture vapor transport pipe is 5 ~ 15cm.
6. ultrasonic pickler according to claim 1, is characterized in that: described heating tube (2) is the non-closed ring-type of dish in cell body, and described liquid outlet (12) is arranged on the non-closed place of this non-closed ring.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201420530629.2U CN204097571U (en) | 2014-09-16 | 2014-09-16 | Ultrasonic pickler |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201420530629.2U CN204097571U (en) | 2014-09-16 | 2014-09-16 | Ultrasonic pickler |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN204097571U true CN204097571U (en) | 2015-01-14 |
Family
ID=52266016
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201420530629.2U Expired - Fee Related CN204097571U (en) | 2014-09-16 | 2014-09-16 | Ultrasonic pickler |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN204097571U (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105195476A (en) * | 2015-09-09 | 2015-12-30 | 瓮福达州化工有限责任公司 | Phase separation tank cleaning device and method |
-
2014
- 2014-09-16 CN CN201420530629.2U patent/CN204097571U/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105195476A (en) * | 2015-09-09 | 2015-12-30 | 瓮福达州化工有限责任公司 | Phase separation tank cleaning device and method |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CP03 | Change of name, title or address | ||
| CP03 | Change of name, title or address |
Address after: 313100, Zhejiang City, Huzhou province Changxing County Heping Town Industrial Zone Patentee after: Huzhou Zhicheng precision metal Technology Co.,Ltd. Address before: 313100, Zhejiang, Changxing County, Huzhou Province town of peace Ridge Industrial Park, Huzhou Zhicheng precision metal Technology Co., Ltd. Patentee before: HUZHOU ZHICHENG PRECISION METAL TECHNOLOGY Co.,Ltd. |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150114 |