CN204067445U - An anti-expansion lithium-ion power battery case - Google Patents

An anti-expansion lithium-ion power battery case Download PDF

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Publication number
CN204067445U
CN204067445U CN201420373871.3U CN201420373871U CN204067445U CN 204067445 U CN204067445 U CN 204067445U CN 201420373871 U CN201420373871 U CN 201420373871U CN 204067445 U CN204067445 U CN 204067445U
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battery
upper cover
pole
ion power
battery container
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姚耀春
米如中
张英杰
杨斌
李晓东
戴永年
方海升
黄瑞安
杨桂玲
吴鉴
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Kunming University of Science and Technology
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Filling, Topping-Up Batteries (AREA)
  • Secondary Cells (AREA)
  • Sealing Battery Cases Or Jackets (AREA)

Abstract

The utility model relates to a kind of anti-expansion lithium ion power battery shell, belongs to secondary accumulator battery technical field.This anti-expansion lithium ion power battery shell, comprise battery container, the upper cover coordinated with battery container and pole, described battery casing surface installs some rice font reinforcement groups be made up of reinforcement, described upper exterior surface both sides are provided with pole column hole, upper cover centre position is provided with liquid injection hole, and the pole column hole of upper interior surface is provided with holddown groove and fixed leg, to prevent the solid time-shifting of pole, when battery core being placed in battery container, battery core is connected with upper cover by pole.On face, four, these battery container front, rear, left and right transversely, longitudinally and be obliquely provided with reinforcement, the voltage endurance capability of battery case can greatly be improved.

Description

一种防膨胀锂离子动力电池壳An anti-expansion lithium-ion power battery case

技术领域 technical field

本实用新型涉及一种防膨胀锂离子动力电池壳,属于二次蓄电池技术领域。 The utility model relates to an anti-expansion lithium ion power battery shell, which belongs to the technical field of secondary storage batteries.

背景技术 Background technique

随着全球化石能源的日益紧张和环境污染的日益加剧,新能源汽车和分布式能源站的快速发展,小型锂离子电池已经不能满足电动汽车、电力储能和错峰调节等方面的需求,世界各国政府、研究机构和生产企业都投入巨资研究大容量、高功率锂离子动力电池。大容量、高功率的锂离子动力电池在充放电使用过程中,一些副反应的发生会产生一些气体,从而使锂离子电池出现不同程度的胀气、鼓肚、泄露等问题,从而严重影响锂离子电池的安全性能和循环寿命。尤其是市场上现有的大容量塑壳锂离子电池,由于壳体涉及不合理导致电池耐压程度低,在电池使用一段时间后鼓胀更为明显,导致电池质量急速下降,并有可能引起严重的安全问题。 With the increasing tension of global fossil energy and the increasing environmental pollution, and the rapid development of new energy vehicles and distributed energy stations, small lithium-ion batteries can no longer meet the needs of electric vehicles, power storage and peak-shift regulation. Governments, research institutes and manufacturers of various countries have invested heavily in the research of large-capacity, high-power lithium-ion power batteries. During the charging and discharging process of large-capacity and high-power lithium-ion power batteries, some side reactions will generate some gases, which will cause problems such as flatulence, bulging, and leakage in lithium-ion batteries to varying degrees, which will seriously affect the lithium-ion batteries. Battery safety performance and cycle life. Especially for the existing large-capacity plastic-case lithium-ion batteries on the market, due to the unreasonable design of the casing, the battery’s withstand voltage is low, and the swelling is more obvious after the battery has been used for a period of time, resulting in a rapid decline in battery quality and may cause severe damage. security issues.

发明内容 Contents of the invention

针对上述现有技术存在的问题及不足,本实用新型提供一种防膨胀锂离子动力电池壳。该电池壳体前、后、左、右四个面上沿横向、纵向以及斜向设置有加强筋,可以大大提高电池壳的耐压能力,本实用新型通过以下技术方案实现。 Aiming at the problems and deficiencies in the above-mentioned prior art, the utility model provides an anti-expansion lithium-ion power battery case. The front, back, left and right sides of the battery case are provided with reinforcing ribs along the transverse, longitudinal and oblique directions, which can greatly improve the pressure resistance of the battery case. The utility model is realized through the following technical solutions.

一种防膨胀锂离子动力电池壳,包括电池壳体1、与电池壳体1配合的上盖6和极柱2, 所述电池壳体1表面安装若干由加强筋11构成的米字型加强筋组,所述上盖6外表面两侧设有极柱孔8,上盖6中间位置设有注液孔7,上盖6内表面的极柱孔8上设有固定槽9和固定柱10,以防止极柱固定时移位,当将电芯14置于电池壳体1内时,电芯14通过极柱2与上盖6连接。 An anti-expansion lithium-ion power battery case, comprising a battery case 1, an upper cover 6 matched with the battery case 1 and a pole 2, the surface of the battery case 1 is equipped with a plurality of rice-shaped reinforcements composed of reinforcing ribs 11 There are pole holes 8 on both sides of the outer surface of the upper cover 6, a liquid injection hole 7 in the middle of the upper cover 6, and a fixing groove 9 and a fixing column on the pole holes 8 on the inner surface of the upper cover 6. 10, to prevent displacement when the pole is fixed, when the battery cell 14 is placed in the battery case 1, the battery cell 14 is connected to the upper cover 6 through the pole 2.

所述极柱2为中间位置设有空心柱体的立方台,空心柱体外表面设有为外螺纹的螺纹12,空心柱体内表面设有为内螺纹的螺纹12,立方台表面设有与固定柱10配合的凹槽,立方台上设有与电芯14极耳连接的连接孔13;电池安装时,在空心柱体外表面安装密封圈3后与上盖6连接。 Described pole 2 is the cube platform that is provided with hollow cylinder in the middle position, and the outer surface of hollow cylinder is provided with thread 12 that is external thread, and the inner surface of hollow cylinder is provided with thread 12 that is internal thread, and the surface of cube platform is provided with and fixed The groove that the post 10 matches, the cube platform is provided with the connection hole 13 that is connected with the battery cell 14 pole ears;

    所述米字型加强筋组根据电池壳体1的大小均匀分布在电池壳体1的前、后、左、右四侧,每条加强筋11的厚度为电池壳体1总厚度的10~30%。 The rice-shaped reinforcing rib group is evenly distributed on the front, rear, left and right sides of the battery case 1 according to the size of the battery case 1, and the thickness of each reinforcing rib 11 is 10~10% of the total thickness of the battery case 1. 30%.

所述上盖6外表面的极柱孔8旁边分别标有“+”、“—”标注,以区分电池正负极。 The pole holes 8 on the outer surface of the upper cover 6 are respectively marked with "+" and "-" to distinguish the positive and negative poles of the battery.

所述当电芯14置于电池壳体1并盖好上盖6时,将安全阀5焊接于注液孔7上,一方面可以将注液口密封,另一方面当电池内部压力过大时可以冲破安全阀防止电池爆炸。 When the battery cell 14 is placed in the battery case 1 and the upper cover 6 is covered, the safety valve 5 is welded to the liquid injection hole 7. On the one hand, the liquid injection port can be sealed, and on the other hand, when the internal pressure of the battery is too high The safety valve can be broken through to prevent the battery from exploding.

所述电池壳体1和上盖6的材料为阻燃ABS塑料、PE塑料或PP塑料。 The battery case 1 and the upper cover 6 are made of flame-retardant ABS plastic, PE plastic or PP plastic.

所述的极柱2、安全阀5、注液孔7的数量和大小可以根据电池容量增减。 The number and size of the pole 2, the safety valve 5, and the liquid injection hole 7 can be increased or decreased according to the battery capacity.

该已电池壳安装电芯14的方法为:首先将电芯14置于电池壳体1内部,然后将极柱2上的连接孔13连接电芯14的极耳,极柱2上的空心柱体安装密封圈3后与上盖6的极柱孔8连接,然后安装螺帽4进行固定,最后将电解液从注液孔7注入到电芯14中,完成后将安全阀5焊接于注液孔7上,极柱2上的空心柱体上的内螺纹用于电池与外端用电设备相连。 The method of installing the battery cell 14 in the battery case is as follows: firstly, the battery cell 14 is placed inside the battery case 1, and then the connection hole 13 on the pole 2 is connected to the tab of the battery cell 14, and the hollow column on the pole 2 After the seal ring 3 is installed on the body, it is connected to the pole hole 8 of the upper cover 6, and then the nut 4 is installed to fix it, and finally the electrolyte is injected into the battery cell 14 from the injection hole 7, and the safety valve 5 is welded to the injection hole after completion. On the liquid hole 7, the internal thread on the hollow cylinder on the pole 2 is used for connecting the battery with the electrical equipment at the outer end.

本实用新型的有益效果是:该电池壳体前、后、左、右四个面上沿横向、纵向以及斜向设置有加强筋,可以大大提高电池壳的耐压能力,降低电池膨胀率和内阻,防止电池在充放电过程中鼓胀变形所引起的安全问题,延长电池循环寿命。 The beneficial effects of the utility model are: the front, rear, left and right sides of the battery case are provided with reinforcing ribs along the transverse, longitudinal and oblique directions, which can greatly improve the pressure resistance of the battery case and reduce the battery expansion rate and Internal resistance prevents safety issues caused by battery swelling and deformation during charging and discharging, and prolongs battery cycle life.

附图说明 Description of drawings

图1是本实用新型结构示意图; Fig. 1 is a structural representation of the utility model;

图2是本实用新型上盖俯视示意图; Fig. 2 is a top view schematic diagram of the utility model upper cover;

图3是本实用新型上盖仰视示意图; Fig. 3 is a schematic view of the upper cover of the present invention;

图4是本实用新型壳体示意图; Fig. 4 is a schematic diagram of the housing of the utility model;

图5是本实用新型极柱示意图; Fig. 5 is a schematic diagram of the pole of the utility model;

图6是本实用新型装配结构示意图。 Fig. 6 is a schematic diagram of the assembly structure of the utility model.

图中:1-电池壳体,2-极柱,3-密封圈,4-螺帽,5-安全阀,6-上盖,7-注液孔,8-极柱孔,9-固定槽,10-固定柱,11-加强筋,12-螺纹,13-连接孔,14-电芯。 In the figure: 1-battery shell, 2-pole, 3-sealing ring, 4-nut, 5-safety valve, 6-top cover, 7-liquid injection hole, 8-pole hole, 9-fixing groove , 10-fixing column, 11-reinforcing rib, 12-thread, 13-connecting hole, 14-cell.

具体实施方式 Detailed ways

下面结合附图和具体实施方式,对本实用新型作进一步说明。 Below in conjunction with accompanying drawing and specific embodiment, the utility model is described further.

实施例1 Example 1

如图1至6所示,该防膨胀锂离子动力电池壳,包括电池壳体1、与电池壳体1配合的上盖6和极柱2, 所述电池壳体1表面安装若干由加强筋11构成的米字型加强筋组,所述上盖6外表面两侧设有极柱孔8,上盖6中间位置设有注液孔7,上盖6内表面的极柱孔8上设有固定槽9和固定柱10,以防止极柱固定时移位,当将电芯14置于电池壳体1内时,电芯14通过极柱2与上盖6连接。 As shown in Figures 1 to 6, the anti-expansion lithium-ion power battery case includes a battery case 1, an upper cover 6 and a pole 2 that cooperate with the battery case 1, and a number of ribs are installed on the surface of the battery case 1. 11 constitutes a rice-shaped reinforcing rib group, the two sides of the outer surface of the upper cover 6 are provided with pole holes 8, the middle position of the upper cover 6 is provided with a liquid injection hole 7, and the pole holes 8 on the inner surface of the upper cover 6 are provided with There are fixing slots 9 and fixing columns 10 to prevent displacement when the poles are fixed. When the battery cells 14 are placed in the battery case 1 , the battery cells 14 are connected to the upper cover 6 through the poles 2 .

其中极柱2为中间位置设有空心柱体的立方台,空心柱体外表面设有为外螺纹的螺纹12,空心柱体内表面设有为内螺纹的螺纹12,立方台表面设有与固定柱10配合的凹槽,立方台上设有与电芯14极耳连接的连接孔13;电池安装时,在空心柱体外表面安装密封圈3后与上盖6连接;米字型加强筋组根据电池壳体1的大小均匀分布在电池壳体1的前、后、左、右四侧,每条加强筋11的厚度为电池壳体1总厚度的10%;上盖6外表面的极柱孔8旁边分别标有“+”、“—”标注,以区分电池正负极;当电芯14置于电池壳体1并盖好上盖6时,将安全阀5焊接于注液孔7上,一方面可以将注液口密封,另一方面当电池内部压力过大时可以冲破安全阀防止电池爆炸;电池壳体1和上盖6的材料为阻燃ABS塑料。 Wherein the pole 2 is a cubic platform provided with a hollow cylinder in the middle, the outer surface of the hollow cylinder is provided with a thread 12 for an external thread, the inner surface of the hollow cylinder is provided with a thread 12 for an internal thread, and the surface of the cubic platform is provided with a fixed column. 10 matching grooves, the cube table is provided with connection holes 13 connected to the 14 poles of the battery; when the battery is installed, install the sealing ring 3 on the outer surface of the hollow cylinder and connect it to the upper cover 6; The size of the battery case 1 is evenly distributed on the front, rear, left and right sides of the battery case 1, and the thickness of each rib 11 is 10% of the total thickness of the battery case 1; The holes 8 are marked with "+" and "-" to distinguish the positive and negative poles of the battery; when the battery cell 14 is placed in the battery case 1 and the upper cover 6 is covered, the safety valve 5 is welded to the liquid injection hole 7 On the one hand, the liquid injection port can be sealed, and on the other hand, when the internal pressure of the battery is too high, the safety valve can be broken to prevent the battery from exploding; the material of the battery case 1 and the upper cover 6 is flame-retardant ABS plastic.

实施例2 Example 2

如图1至6所示,该防膨胀锂离子动力电池壳,包括电池壳体1、与电池壳体1配合的上盖6和极柱2, 所述电池壳体1表面安装若干由加强筋11构成的米字型加强筋组,所述上盖6外表面两侧设有极柱孔8,上盖6中间位置设有注液孔7,上盖6内表面的极柱孔8上设有固定槽9和固定柱10,以防止极柱固定时移位,当将电芯14置于电池壳体1内时,电芯14通过极柱2与上盖6连接。 As shown in Figures 1 to 6, the anti-expansion lithium-ion power battery case includes a battery case 1, an upper cover 6 and a pole 2 that cooperate with the battery case 1, and a number of ribs are installed on the surface of the battery case 1. 11 constitutes a rice-shaped reinforcing rib group, the two sides of the outer surface of the upper cover 6 are provided with pole holes 8, the middle position of the upper cover 6 is provided with a liquid injection hole 7, and the pole holes 8 on the inner surface of the upper cover 6 are provided with There are fixing slots 9 and fixing columns 10 to prevent displacement when the poles are fixed. When the battery cells 14 are placed in the battery case 1 , the battery cells 14 are connected to the upper cover 6 through the poles 2 .

其中极柱2为中间位置设有空心柱体的立方台,空心柱体外表面设有为外螺纹的螺纹12,空心柱体内表面设有为内螺纹的螺纹12,立方台表面设有与固定柱10配合的凹槽,立方台上设有与电芯14极耳连接的连接孔13;电池安装时,在空心柱体外表面安装密封圈3后与上盖6连接;米字型加强筋组根据电池壳体1的大小均匀分布在电池壳体1的前、后、左、右四侧,每条加强筋11的厚度为电池壳体1总厚度的30%; Wherein the pole 2 is a cubic platform provided with a hollow cylinder in the middle, the outer surface of the hollow cylinder is provided with a thread 12 for an external thread, the inner surface of the hollow cylinder is provided with a thread 12 for an internal thread, and the surface of the cubic platform is provided with a fixed column. 10 matching grooves, the cube table is provided with connection holes 13 connected to the 14 poles of the battery; when the battery is installed, install the sealing ring 3 on the outer surface of the hollow cylinder and connect it to the upper cover 6; The size of the battery case 1 is evenly distributed on the front, rear, left and right sides of the battery case 1, and the thickness of each rib 11 is 30% of the total thickness of the battery case 1;

上盖6外表面的极柱孔8旁边分别标有“+”、“—”标注,以区分电池正负极;当电芯14置于电池壳体1并盖好上盖6时,将安全阀5焊接于注液孔7上,一方面可以将注液口密封,另一方面当电池内部压力过大时可以冲破安全阀防止电池爆炸;电池壳体1和上盖6的材料为PE塑料。 The pole holes 8 on the outer surface of the upper cover 6 are marked with "+" and "-" respectively to distinguish the positive and negative electrodes of the battery; when the battery cell 14 is placed in the battery case 1 and the upper cover 6 is covered, the The valve 5 is welded on the liquid injection hole 7. On the one hand, it can seal the liquid injection port. On the other hand, when the internal pressure of the battery is too high, it can break through the safety valve to prevent the battery from exploding; the material of the battery case 1 and the upper cover 6 is PE plastic .

实施例3 Example 3

如图1至6所示,该防膨胀锂离子动力电池壳,包括电池壳体1、与电池壳体1配合的上盖6和极柱2, 所述电池壳体1表面安装若干由加强筋11构成的米字型加强筋组,所述上盖6外表面两侧设有极柱孔8,上盖6中间位置设有注液孔7,上盖6内表面的极柱孔8上设有固定槽9和固定柱10,以防止极柱固定时移位,当将电芯14置于电池壳体1内时,电芯14通过极柱2与上盖6连接。 As shown in Figures 1 to 6, the anti-expansion lithium-ion power battery case includes a battery case 1, an upper cover 6 and a pole 2 that cooperate with the battery case 1, and a number of ribs are installed on the surface of the battery case 1. 11 constitutes a rice-shaped reinforcing rib group, the two sides of the outer surface of the upper cover 6 are provided with pole holes 8, the middle position of the upper cover 6 is provided with a liquid injection hole 7, and the pole holes 8 on the inner surface of the upper cover 6 are provided with There are fixing slots 9 and fixing columns 10 to prevent displacement when the poles are fixed. When the battery cells 14 are placed in the battery case 1 , the battery cells 14 are connected to the upper cover 6 through the poles 2 .

其中极柱2为中间位置设有空心柱体的立方台,空心柱体外表面设有为外螺纹的螺纹12,空心柱体内表面设有为内螺纹的螺纹12,立方台表面设有与固定柱10配合的凹槽,立方台上设有与电芯14极耳连接的连接孔13;电池安装时,在空心柱体外表面安装密封圈3后与上盖6连接;米字型加强筋组根据电池壳体1的大小均匀分布在电池壳体1的前、后、左、右四侧,每条加强筋11的厚度为电池壳体1总厚度的20%;上盖6外表面的极柱孔8旁边分别标有“+”、“—”标注,以区分电池正负极;当电芯14置于电池壳体1并盖好上盖6时,将安全阀5焊接于注液孔7上,一方面可以将注液口密封,另一方面当电池内部压力过大时可以冲破安全阀防止电池爆炸;电池壳体1和上盖6的材料为阻燃PP塑料。 Wherein the pole 2 is a cubic platform provided with a hollow cylinder in the middle, the outer surface of the hollow cylinder is provided with a thread 12 for an external thread, the inner surface of the hollow cylinder is provided with a thread 12 for an internal thread, and the surface of the cubic platform is provided with a fixed column. 10 matching grooves, the cube table is provided with connection holes 13 connected to the 14 poles of the battery; when the battery is installed, install the sealing ring 3 on the outer surface of the hollow cylinder and connect it to the upper cover 6; The size of the battery case 1 is evenly distributed on the front, rear, left and right sides of the battery case 1, and the thickness of each rib 11 is 20% of the total thickness of the battery case 1; The holes 8 are marked with "+" and "-" to distinguish the positive and negative poles of the battery; when the battery cell 14 is placed in the battery case 1 and the upper cover 6 is covered, the safety valve 5 is welded to the liquid injection hole 7 On the one hand, the liquid injection port can be sealed, and on the other hand, when the internal pressure of the battery is too high, the safety valve can be broken to prevent the battery from exploding; the battery case 1 and the upper cover 6 are made of flame-retardant PP plastic.

Claims (6)

1. an anti-expansion lithium ion power battery shell, comprise battery container (1), the upper cover (6) coordinated with battery container (1) and pole (2), it is characterized in that: some rice font reinforcement groups be made up of reinforcement (11) are installed on described battery container (1) surface, described upper cover (6) outer surface both sides are provided with pole column hole (8), upper cover (6) centre position is provided with liquid injection hole (7), the pole column hole (8) of upper cover (6) inner surface is provided with holddown groove (9) and fixed leg (10), when battery core (14) is placed in battery container (1), battery core (14) is connected with upper cover (6) by pole (2).
2. anti-expansion lithium ion power battery shell according to claim 1, it is characterized in that: described pole (2) is provided with cube platform of hollow cylinder for centre position, hollow cylinder outer surface is provided with as externally threaded screw thread (12), hollow cylinder inner surface is provided with the screw thread (12) into internal thread, cube platform surface is provided with the groove coordinated with fixed leg (10), and cube platform is provided with the connecting hole (13) be connected with battery core (14) lug; When battery is installed, at hollow cylinder outer surface, sealing ring (3) is installed and is connected with upper cover (6) afterwards.
3. anti-expansion lithium ion power battery shell according to claim 1, it is characterized in that: described rice font reinforcement group is evenly distributed on the side, front, rear, left and right four of battery container (1) according to the size of battery container (1), the thickness of every bar reinforcement (11) is 10 ~ 30% of battery container (1) gross thickness.
4. anti-expansion lithium ion power battery shell according to claim 1, is characterized in that: pole column hole (8) side of described upper cover (6) outer surface indicates "+", "-" mark respectively.
5. anti-expansion lithium ion power battery shell according to claim 1, is characterized in that: described when battery core (14) is placed in battery container (1) and builds upper cover (6), is welded on liquid injection hole (7) by safety valve (5).
6., according to the arbitrary described anti-expansion lithium ion power battery shell of claim 1 to 5, it is characterized in that: the material of described battery container (1) and upper cover (6) is flame-proof ABS plastics, PE plastics or PP plastics.
CN201420373871.3U 2014-07-08 2014-07-08 An anti-expansion lithium-ion power battery case Expired - Fee Related CN204067445U (en)

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Publication number Priority date Publication date Assignee Title
CN108258370A (en) * 2018-01-17 2018-07-06 重庆鼎工机电有限公司 A kind of novel monomeric aluminium-air cell
CN108321344A (en) * 2018-01-17 2018-07-24 重庆鼎工机电有限公司 A kind of aluminium-air cell, battery pack and generating set
CN108847458A (en) * 2018-07-12 2018-11-20 深圳市景正电子技术开发有限公司 A kind of insulating part structure and its preparation process
CN109768190A (en) * 2018-12-26 2019-05-17 安徽理士电源技术有限公司 A kind of battery cover anti-deforming structure of matrix structure big battery
CN110416443A (en) * 2019-07-31 2019-11-05 安徽相源新能源有限公司 A kind of lithium cell for being not easy to lose and its production method
CN110662375A (en) * 2018-06-28 2020-01-07 比亚迪股份有限公司 Motor controller cover, motor controller, drive assembly and vehicle

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108258370A (en) * 2018-01-17 2018-07-06 重庆鼎工机电有限公司 A kind of novel monomeric aluminium-air cell
CN108321344A (en) * 2018-01-17 2018-07-24 重庆鼎工机电有限公司 A kind of aluminium-air cell, battery pack and generating set
CN108321344B (en) * 2018-01-17 2021-05-07 重庆鼎工机电有限公司 Aluminum-air battery, battery pack and generator set
CN110662375A (en) * 2018-06-28 2020-01-07 比亚迪股份有限公司 Motor controller cover, motor controller, drive assembly and vehicle
CN108847458A (en) * 2018-07-12 2018-11-20 深圳市景正电子技术开发有限公司 A kind of insulating part structure and its preparation process
CN109768190A (en) * 2018-12-26 2019-05-17 安徽理士电源技术有限公司 A kind of battery cover anti-deforming structure of matrix structure big battery
CN110416443A (en) * 2019-07-31 2019-11-05 安徽相源新能源有限公司 A kind of lithium cell for being not easy to lose and its production method

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