Polluted water ozone hydrogen peroxide throwing device
Technical field
The utility model relates to sewage treatment area, particularly relates to a kind of polluted water ozone hydrogen peroxide throwing device.
Background technology
There are nearly 50 national serious water shortages in the current whole world, and united state of China confirms as one of serious water shortage country.But China about has hundreds of hundred million tons of utilizable sewage of advanced treatment not utilize every year to be discharged, and cause the waste of water resources, therefore, realizing sewage recycling has been the task of top priority.
The formation of so-called " sewage ".Formed through production process is contaminated by fresh water.We will utilize sewage dirty water pollutant must be removed as much as possible, and pollutent mainly contains: oil, organism, suspended substance, organic salt etc.Oil wherein, suspended substance and a part of organism are dispelled by the method for flocculating, precipitating and filtering, but a part of organism and inorganic salt could carry out degrading and adsorbing after needing oxide treatment further in subsequent process.The ozone that make use of ozonizer generation in the technical equipment of patent No. ZL99112689.0 carries out oxide treatment to sewage, but in this scenario, there is ozone mixes uneven with sewage, inefficient problem, application number is in the patent of 200520142055.2, and ozone itself has extremely strong oxidisability, can remove large amount of organic, but poor to organic oxidation effectiveness such as some halohydrocarbon and agricultural chemicals etc., to there is in polluted water pollutant removal not comprehensively and thoroughly problem.
Utility model content
The technical problems to be solved in the utility model is to provide one and a part of organic substance in polluted water or contaminated Natural Water (river, river, lake water etc.) is oxidized to CO
2and water, another part organic substance in polluted water is oxidized to intermediate, namely larger molecular organics matter and cyclic organic materials are oxidized to small organic molecule matter and short chain organic substance, the organic substance that this oxidation generates afterwards is easy to be fallen to fall with the charcoal absorption in finishing operations by biochemical degradation, simultaneously oxidablely dispel the inorganicss such as iron contained in polluted water and manganese, and polluted water is played de-taste, decolour, the high efficiency device of sterilization.
For reaching above-mentioned purpose, the throwing device of a kind of polluted water ozone of the utility model hydrogen peroxide, described throwing device comprises ozonizer, hydrogen peroxide holder, adds pipe fitting, ozone hydrogen peroxide reaction tank and ozone residual air resorber, described ozonizer is connected described ozone hydrogen peroxide reaction tank with hydrogen peroxide holder respectively by adding pipe fitting, described ozone hydrogen peroxide reaction tank connects described ozone residual air resorber, is provided with input pipe arranging device in described ozone hydrogen peroxide reaction tank.
The wherein said pipe fitting that adds also comprises and is connected to described ozonizer and the ozone ejector between described hydrogen peroxide holder and described input pipe arranging device and ozone hydrogen peroxide mixing tank, described ozonizer and described hydrogen peroxide holder connect described ozone ejector respectively, and described ozone ejector connects described ozone hydrogen peroxide mixing tank.
The wherein said pipe fitting that adds also comprises the input pipe arranging device being placed on ozone reaction device linked together with ozonizer.
The main line of wherein said input pipe arranging device is communicated with and arranges arm more.
The main line of wherein said input pipe arranging device is communicated with on many row's arms and has multiple aperture.
The main line of wherein said input pipe arranging device is communicated with many row's arms and is arranged in rectangle or circle.
The main line of wherein said input pipe arranging device is communicated with many row's arms and is arranged in rectangle or circle.
Wherein said ozone residual air resorber is pot type structure, in-built absorption filtering material.
Wherein said ozone residual air resorber is pot type structure, in-built absorption filtering material.
Wherein said ozone hydrogen peroxide reaction tank can substitute by ozone hydrogen peroxide retort.
The utility model difference from prior art is that the utility model achieves following technique effect:
Ozone itself has extremely strong oxidisability, can remove large amount of organic, but poor to organic oxidation effectiveness such as some halohydrocarbon and agricultural chemicals etc., is combined by ozone, greatly can improves oxidation efficiency with hydrogen peroxide.The reaction mechanism of ozone and pollutent comprises direct reaction and ozone and organism direct reaction and indirect reaction and ozone decomposed produces OH and organism reacts.Direct reaction has stronger selectivity, and a selectivity is not generally had in indirect reaction, and namely sphere of action is wider.In ozone water solution, add hydrogen peroxide can significantly accelerate the speed that ozone decomposed produces OH, its reaction is
O
3+OH
-→HO
2 -+O
2
When there is H in solution
2o
2time, it can produce HO by partial dissociation
-
2H
2O
2→HO
2 -+H
3O
+
The HO that above-mentioned reaction generates
2-be the inducer that OH is formed.Its mechanism is as follows
O
3+HO
2 -→HO
2·+O
3 -· HO
2·→H
++O
2 -·
O
2 -·+O
3→O
2+O
3 - O
2 -·+H
+→HO
3
HO
3→OH·+O
2 OH·+O
3→HO
2·+O
2
Pollutent is at O
3/ H
2o
2faster than single oxidising process 2 ~ 200 times of degradation rate in oxidising process.
Below in conjunction with accompanying drawing, the utility model is described in further detail.
Accompanying drawing explanation
Fig. 1 is structure, the schematic flow sheet of the utility model embodiment one;
Fig. 2 is structure, the schematic flow sheet of the utility model embodiment two;
Fig. 3 is structure, the schematic flow sheet of the utility model embodiment three;
Fig. 4 is ozone ejector schematic diagram;
Fig. 5 is ozone hydrogen peroxide mixing tank schematic diagram;
Fig. 6 is for throwing in pipe arranging device schematic diagram;
Fig. 7 is ozone residual air resorber schematic diagram.
Embodiment
Below in conjunction with drawings and Examples, to above-mentioned being described in more detail with other technical characteristic and advantage of the utility model.
Embodiment 1
The input pipe arranging device in ozone hydrogen peroxide reaction tank 4 or retort 8 directly sent into by the hydrogen peroxide that the ozone gas produce ozonizer 1 and hydrogen peroxide holder 7 produce, after fully mixing with polluted water, react with the organic substance in water, iron, manganese, residual ozone gas is absorbed by ozone residual air resorber 5, and pure qi (oxygen) is by pipeline high altitude discharge.The main line being placed on the input pipe arranging device 6 in ozone hydrogen peroxide reaction tank 4 or retort 8 is communicated with and arranges arm more, many row's arms establish multiple aperture, and the arm of input pipe arranging device 6 lines up rectangle or circle.Ozone residual air resorber 5 is the absorption filtering materials such as pot type structure, in-built gac, Stainless Steel Cloth.
Embodiment 2
The hydrogen peroxide that the ozone gas that ozonizer 1 produces by ozone ejector 2, hydrogen peroxide holder 7 produce and contaminated water flow inject ozone hydrogen peroxide mixing tank 3 jointly, the input pipe arranging device 6 entered in ozone hydrogen peroxide reaction tank 4 or retort 8 through ozone hydrogen peroxide mixing tank 3 water out fully reacts, residual ozone gas is absorbed by ozone residual air resorber 5, and pure qi (oxygen) is by pipeline high altitude discharge.The main line being placed on the input pipe arranging device 6 in ozone hydrogen peroxide reaction tank 4 or retort 8 is communicated with and arranges arm more, many row's arms have multiple aperture, and the arm of input pipe arranging device lines up rectangle or circle.Ozone residual air resorber 5 is the absorbing and filtering materials such as pot type structure, in-built gac, Stainless Steel Cloth.
Embodiment 3
Ozonizer 1 produces the hydrogen peroxide of water-ozone gas and hydrogen peroxide holder 7 generation, one tunnel enters the input pipe arranging device 6 of ozone hydrogen peroxide reaction tank 4 or retort 8, after fully mixing with polluted water, react with the organic substance in water, iron, manganese, residual ozone gas is absorbed by ozone residual air resorber 5, and pure qi (oxygen) is by pipeline high altitude discharge; Another road and contaminated water flow inject ozone hydrogen peroxide mixing tank 3 by ozone ejector 2 jointly, the input pipe arranging device 6 entered in ozone hydrogen peroxide reaction tank 4 or retort 8 through ozone hydrogen peroxide mixing tank 3 water out fully reacts, residual ozone is absorbed by ozone residual air resorber 5, and pure qi (oxygen) is by pipeline high altitude discharge.The main line being placed on the input pipe arranging device 6 in ozone hydrogen peroxide reaction tank 4 or retort 8 is communicated with manifold, and many row's arms are provided with multiple aperture, and the arm throwing in pipe arranging device 6 lines up rectangle or circle.Ozone residual air resorber 5 is the absorption filtering materials such as pot type structure, in-built gac, Stainless Steel Cloth.
Above-described embodiment is only be described preferred implementation of the present utility model; not scope of the present utility model is limited; under the prerequisite not departing from the utility model design spirit; the various distortion that those of ordinary skill in the art make the technical solution of the utility model and improvement, all should fall in protection domain that the utility model claims determine.