CN203932216U - Based on the stacked passive direct methanol fuel cell group of polymer bipolar end plates - Google Patents

Based on the stacked passive direct methanol fuel cell group of polymer bipolar end plates Download PDF

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Publication number
CN203932216U
CN203932216U CN201420290623.2U CN201420290623U CN203932216U CN 203932216 U CN203932216 U CN 203932216U CN 201420290623 U CN201420290623 U CN 201420290623U CN 203932216 U CN203932216 U CN 203932216U
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China
Prior art keywords
polymer
end plates
metal collector
bipolar end
plates
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Expired - Fee Related
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CN201420290623.2U
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Chinese (zh)
Inventor
王路文
王高峰
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Hangzhou Dianzi University
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Hangzhou Dianzi University
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

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Abstract

It is a kind of based on the stacked passive direct methanol fuel cell group of polymer bipolar end plates that the utility model provides.Comprise an anode polymer monopolar terminal plates, negative electrode polymer monopolar terminal plates, one or more polymer bipolar end plates, metal collector and a membrane electrode.Two polymer monopolar terminal plates are oppositely arranged on the two ends of battery pack, on relative two faces of two polymer monopolar terminal plates, be provided with the metal collector of monolithic, between two unitary piece of metal collector electrodes, be provided with the identical unit of a plurality of structures, battery pack is connected in series according to the order of the metal collector of the metal collector of anode polymer monopolar terminal plates, monolithic, a plurality of unit, monolithic, negative electrode polymer monopolar terminal plates, and is bolted.The utility model novel structure, lightweight, install simply, the cost of material is low, easily processing, mechanical strength is higher, is a kind of very convenient compact power.

Description

Based on the stacked passive direct methanol fuel cell group of polymer bipolar end plates
Technical field
The field that the utility model relates to is direct methanol fuel cell, is specifically related to a kind of stacked passive direct methanol fuel cell group based on polymer bipolar end plates.
Background technology
Direct methanol fuel cell (DMFC) is as a kind of minitype portable energy, and higher specific energy and energy conversion efficiency are its main advantages that attracts people.Fixing external structure and the liquid fuel that can fill at any time simultaneously, be also user's condition of providing convenience, and it is simple in structure, and the response time is short, operates also very convenient.With respect to active direct methanol fuel cell, passive direct methanol fuel cell does not need as active auxiliary equipment feed fuels such as pump, fans, directly utilize the principles such as diffusion and free convection to carry out fuel supply to battery, not only greatly reduce the complexity of battery system, be conducive to integrated application, and reduced parasitic energy loss, improved the energy density of battery system.Current passive direct methanol fuel cell group mostly is planarized structure, and by 6 joints or to be less than 6 joint list ponds integrated, this structure is subject to the restriction of usage space for the integrated meeting of more piece (being greater than 10), and integrated level is lower.And traditional polymer plated film bipolar plates poorly conductive, is difficult to meet the demand of high-power output.
Summary of the invention
The utility model is for the deficiencies in the prior art, a kind of stacked passive direct methanol fuel cell group based on polymer bipolar end plates is provided, solve passive direct methanol fuel cell group cannot more piece the integrated and lower problem of polymer plated film bipolar plates power.
Stacked passive direct methanol fuel cell group based on polymer bipolar end plates, comprises an anode polymer monopolar terminal plates, negative electrode polymer monopolar terminal plates, one or more polymer bipolar end plates, metal collector and a membrane electrode.Two polymer monopolar terminal plates are oppositely arranged on the two ends of battery pack, on relative two faces of two polymer monopolar terminal plates, be provided with the metal collector of monolithic, between two unitary piece of metal collector electrodes, be provided with the identical unit of a plurality of structures, each unit comprises four rubber cushions, two membrane electrodes, a polymer bipolar end plates and a biplate metal collector, by being linked in sequence of rubber cushion, membrane electrode, rubber cushion, polymer bipolar end plates, rubber cushion, membrane electrode, rubber cushion, biplate metal collector is arranged on the two ends of polymer bipolar end plates; Battery pack is connected in series according to the order of the metal collector of the metal collector of anode polymer monopolar terminal plates, monolithic, a plurality of unit, monolithic, negative electrode polymer monopolar terminal plates, and is bolted.
Described polymer bipolar end plates anode-side center is provided with square indentations, and cathode side is provided with gas feed groove;
The metal collector of described monolithic is stainless steel thin slice, and opens a plurality of through holes with transfer reaction thing,
Described biplate metal collector is two and is connected and the metal collector of the monolithic that be arranged in parallel, the biplate metal collector structure that is formed in one;
The metal collector of described monolithic and biplate metal collector carry out sputter or chemical plating is processed, and coating is Au, Pt or TiN;
Described center, anode polymer monopolar terminal plates side is provided with square indentations;
Described negative electrode polymer monopolar terminal plates side is provided with gas feed groove;
It is identical with the effective area of membrane electrode that square indentations in described anode polymer monopolar terminal plates and bipolar end plates anode-side center are provided with the effective area of square indentations.
The material of described polymer bipolar end plates, anode polymer monopolar terminal plates, negative electrode polymer monopolar terminal plates is polymethyl methacrylate, ABS or engineering plastics.
The utility model has the advantage of: this battery pack has novel structure, lightweight, install simply, the cost of material is low, easily processing, and mechanical strength, compared with advantages of higher, is applicable to portable electrical power applications.Stacked assembling design, makes the shared small volume of this battery pack, and when the more battery of joint number is connected, this structure stands good.It is bad that the employing of collector electrode has solved traditional polymer bipolar plates metal-coated membrane conductivity, the problem that output performance is low.The integrated of collector electrode also makes the internal resistance of battery pack integral body lower, effectively reduces power loss.This battery pack adopts full passive type feed liquor mode, can greatly reduce the volume of battery pack system, does not need external power supply and auxiliary equipment, has quick startup and higher-wattage output effect property, is a kind of effective compact power.
Accompanying drawing explanation
Fig. 1 is the explosive view of the utility model battery pack;
Fig. 2 is polymer bipolar end plates anode construction schematic diagram;
Fig. 3 is polymer bipolar end plates end view;
Fig. 4 is polymer bipolar end plates cathode construction schematic diagram;
Fig. 5 is biplate metal collector structural representation;
Fig. 6 is design sketch after the assembling of the utility model battery pack.
Embodiment
For a more detailed description to the utility model for example below in conjunction with accompanying drawing:
As shown in Figure 1, a stacked passive direct methanol fuel cell group based on polymer bipolar end plates, comprises an anode polymer monopolar terminal plates 1, negative electrode polymer monopolar terminal plates 6, one or more polymer bipolar end plates, metal collector and a membrane electrode.Two polymer monopolar terminal plates are oppositely arranged on the two ends of battery pack, on relative two faces of two polymer monopolar terminal plates, be provided with the metal collector of monolithic, between two unitary piece of metal collector electrodes, be provided with the identical unit of a plurality of structures, each unit comprises four rubber cushions 2, two membrane electrodes 3, polymer bipolar end plates 4 and a biplate metal collector 5, by being linked in sequence of rubber cushion, membrane electrode, rubber cushion, polymer bipolar end plates, rubber cushion, membrane electrode, rubber cushion, biplate metal collector is arranged on the two ends of polymer bipolar end plates;
As shown in Figure 2, Figure 3, Figure 4, described polymer bipolar end plates anode-side center is provided with square indentations, and for storing methanol aqueous solution, cathode side is provided with gas feed groove, for obtaining reacting gas; Center, anode polymer monopolar terminal plates side is provided with square indentations; Negative electrode polymer monopolar terminal plates side is provided with gas feed groove;
The metal collector of described monolithic is stainless steel thin slice, and opens a plurality of through holes with transfer reaction thing;
As shown in Figure 5, described biplate metal collector is two and is connected and the metal collector of the monolithic that be arranged in parallel, the biplate metal collector structure that is formed in one;
The metal collector of described monolithic and biplate metal collector plated surface Au coating;
It is identical with the effective area of membrane electrode that square indentations in described anode polymer monopolar terminal plates and bipolar end plates anode-side center are provided with the effective area of square indentations.
As shown in Figure 6, battery pack is connected in series according to the order of the metal collector of the metal collector of anode polymer monopolar terminal plates, monolithic, a plurality of unit, monolithic, negative electrode polymer monopolar terminal plates, and is bolted.

Claims (9)

1. based on the stacked passive direct methanol fuel cell group of polymer bipolar end plates, it is characterized in that: comprise an anode polymer monopolar terminal plates, a negative electrode polymer monopolar terminal plates, one or more polymer bipolar end plates, two polymer monopolar terminal plates of metal collector and membrane electrode are oppositely arranged on the two ends of battery pack, on relative two faces of two polymer monopolar terminal plates, be provided with the metal collector of monolithic, between two unitary piece of metal collector electrodes, be provided with the identical unit of a plurality of structures, each unit comprises four rubber cushions, two membrane electrodes, a polymer bipolar end plates and a biplate metal collector, press rubber cushion, membrane electrode, rubber cushion, polymer bipolar end plates, rubber cushion, membrane electrode, being linked in sequence of rubber cushion, biplate metal collector is arranged on the two ends of polymer bipolar end plates, battery pack is connected in series according to the order of the metal collector of the metal collector of anode polymer monopolar terminal plates, monolithic, a plurality of unit, monolithic, negative electrode polymer monopolar terminal plates, and is bolted.
2. according to claim 1 based on the stacked passive direct methanol fuel cell group of polymer bipolar end plates, it is characterized in that: described polymer bipolar end plates anode-side center is provided with square indentations, and cathode side is provided with gas feed groove.
3. according to claim 1 based on the stacked passive direct methanol fuel cell group of polymer bipolar end plates, it is characterized in that: the metal collector of described monolithic is stainless steel thin slice, and open a plurality of through holes.
4. according to claim 1 based on the stacked passive direct methanol fuel cell group of polymer bipolar end plates, it is characterized in that: described biplate metal collector is two and is connected and the metal collector of the monolithic that be arranged in parallel the biplate metal collector structure that is formed in one.
5. according to claim 1 based on the stacked passive direct methanol fuel cell group of polymer bipolar end plates, it is characterized in that: the metal collector of described monolithic and biplate metal collector carry out sputter or chemical plating is processed, and coating is Au, Pt or TiN.
6. according to claim 1 based on the stacked passive direct methanol fuel cell group of polymer bipolar end plates, it is characterized in that: described center, anode polymer monopolar terminal plates side is provided with square indentations.
7. according to claim 1 based on the stacked passive direct methanol fuel cell group of polymer bipolar end plates, it is characterized in that: described negative electrode polymer monopolar terminal plates side is provided with gas feed groove.
8. according to claim 1 based on the stacked passive direct methanol fuel cell group of polymer bipolar end plates, it is characterized in that: it is identical with the effective area of membrane electrode that the square indentations in described anode polymer monopolar terminal plates and bipolar end plates anode-side center are provided with the effective area of square indentations.
9. according to claim 1 based on the stacked passive direct methanol fuel cell group of polymer bipolar end plates, it is characterized in that: the material of described polymer bipolar end plates, anode polymer monopolar terminal plates, negative electrode polymer monopolar terminal plates is polymethyl methacrylate, ABS or engineering plastics.
CN201420290623.2U 2014-05-30 2014-05-30 Based on the stacked passive direct methanol fuel cell group of polymer bipolar end plates Expired - Fee Related CN203932216U (en)

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CN201420290623.2U CN203932216U (en) 2014-05-30 2014-05-30 Based on the stacked passive direct methanol fuel cell group of polymer bipolar end plates

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109449455A (en) * 2018-10-22 2019-03-08 杭州电子科技大学温州研究院有限公司 A kind of membrane electrode of low internal resistance and fuel cell containing the membrane electrode

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109449455A (en) * 2018-10-22 2019-03-08 杭州电子科技大学温州研究院有限公司 A kind of membrane electrode of low internal resistance and fuel cell containing the membrane electrode

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Granted publication date: 20141105

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