CN203922829U - Integrated synchronous oxidation desalting device - Google Patents

Integrated synchronous oxidation desalting device Download PDF

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Publication number
CN203922829U
CN203922829U CN201420091884.1U CN201420091884U CN203922829U CN 203922829 U CN203922829 U CN 203922829U CN 201420091884 U CN201420091884 U CN 201420091884U CN 203922829 U CN203922829 U CN 203922829U
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response device
concentration response
waste water
simultaneous oxidation
storage tank
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梅凯
陈晔
周健岳
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Wuxi Zhongyue Petrochemical Equipment Co ltd
Nanjing Tech University
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Wuxi Zhongyue Petrochemical Equipment Co ltd
Nanjing Tech University
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Abstract

The utility model discloses a synchronous oxidation desalination device of integration, the device is according to the organic matter synthesis heat absorption, the exothermic principle of inorganic decomposition, utilize the heat that the organic matter among high salt, the high concentration waste water mineralized the release under specific condition, heat energy when as water vaporization, it is concentrated to make waste water vaporization, the vapor of vaporization is constantly discharged, salt in the waste water can be concentrated, when the salt is the oversaturated state in the concentrate, salt then crystallization out, reach synchronous oxidation and desalination purpose. The device mainly comprises a treatment liquid water inlet system, a synchronous oxidation concentration reactor system, a gas collecting system and a crystallization desalting system, wherein the treatment liquid water inlet system supplies water to the synchronous oxidation concentration reactor system after intercepting suspended matters and oil in the wastewater, the synchronous oxidation concentration reactor system is used for completing the inorganic formation of organic matters in the wastewater and the concentration of salt, the gas collecting system collects and condenses gas and sends the gas to a gas-water separator, and the gas evacuation of condensed water is separated.

Description

A kind of Integral synchronous oxidation desalination plant
Technical field
The utility model relates to a kind of high salt high concentrated organic wastewater treatment unit, more specifically to a kind of Integral synchronous oxidation desalination plant.
background technology
Current, water resources is that countries in the world generally face one of urgent problem.According to World Resources Institute of United Nations research, World Water money is all faced with than other resource and compares in the past all more severe situation aspect quality and quantity.6 years global industrial water consumptions of global 200d are 2.07 tcms according to statistics, and this phenomenon situation is far from it all over the world, demand and limited can be extremely inadaptable by water resources, and the whole world is 4200 billion cubic meters discharged to industry and the sanitary wastewater of natural water every year, cause more than 35% Freshwater resources to be polluted, thereby pollution control of water will be particularly important.
China's wastewater emission amount is 46,000,000,000 tons, and trade effluent reaches 212.4 hundred million tons, wherein 3,700,000,000 tons of Discharge Quantity of Wastewater from Chemical Industries, and high-concentration organic chemical wastewater reaches 1,000,000,000 tons of left and right, wherein more than 70% fails effectively to process direct discharge and enters water body.
High concentrated organic wastewater mainly has following characteristics:
1 high organism, high salt are also deposited: concentration generally more than 20,000 mg/L, have even up to several ten thousand and even hundreds of thousands of mg/L, biodegradability is poor, the ratio of BOD and COD is less than 0.1, microorganism can not survive under such envrionment conditions.Cannot adopt single treatment process, and need to adopt the treatment process of built-up type multiple-unit series connection could be up to standard, treatment process route length, complicated operation, running cost be high.
2 waste water complicated components: organism is in the majority with aromatic hydrocarbon, the halogenated hydrocarbon compound of ring-type, heterocycle and long-chain, more than contain sulfide, nitride, heavy metal and toxic organic compound.
3 colourities are high, and smell is large: some waste water gives out pungent stench, causes detrimentally affect to surrounding environment.
4 have strong acid and strong base, and corrodibility is strong.
The hazardness of high concentrated organic wastewater:
Dissolved oxygen in 1 a large amount of consumption water bodys, destroys water body habitat: due to biological degradation, high concentrated organic wastewater makes even anaerobism of receiving water body anoxic, and most hydrobionts are by death, and biologic chain is blocked, water environment degradation, water body Habitat destruction.
2 sense organ contact scars: high concentrated organic wastewater not only makes water body lose use value, more have a strong impact near the people's of water body orthobiosis.
3 cause toxicity hazard: in ultra-high concentration organic wastewater, contain a large amount of toxic organic compounds, can in the physical environments such as water body, constantly accumulate, store, finally enter human body, be detrimental to health.
High salt, high concentration organic contaminant waste water are mainly from industries such as chemical industry, fine chemistry industry, medicine, agricultural chemicals, and conventional treatment process mainly adopts multiple-effect evaporation+biochemistry+bis-film combinations to process.
Biochemical process must be (villaumite <5000mg/L, vitriol <3000mg/L) operation under low-salt conditions, and high-salt wastewater must just can enter biochemical system after desalination.So biochemical process is serially connected in after multiple-effect evaporation method after evaporation desalination, it utilizes microorganism to remove biodegradable organic pollutant in waste water.Although its working cost is low, operational path is long, and floor space is large, and capacity of resisting impact load requires high, and management maintenance complexity, cannot ensure in most situation that system stable effluent quality is up to standard.
Two embrane methods are to adopt below SF(ultrafiltration at biochemical system) film+RO film or NF(nanofiltration) film+RO(reverse osmosis) film is as advanced treatment, and further hold back and in waste water, be difficult to biodegradable pollutent.Although it can partly solve biochemical process effluent quality problem up to standard, but short, the dense aquatic products rate in work-ing life of pollution, film that exists film is high, investment and the problem (its producing water ratio also only has 70%~75%) such as working cost is large, exists dense water (the dense water yield approximately 30%~25%) ultimate disposal problem.
Multiple-effect evaporation method is by several evaporator series operations, and waste water is heated to vaporize to realize with lower boiling pollutent and separates with high boiling point salt.Multiple-effect evaporator is to utilize the latent heat of higher level's vaporizer secondary steam again to utilize as subordinate's vaporizer thermal source, utilizes and is once referred to as an effect.Because the secondary steam of each effect is all as the heating steam of lower 1st effective evaporator, steam thermal energy is repeatedly utilized, improve the utilising efficiency of original steam.Due to thermosteresis, the reasons such as temperature difference loss, unit steam consumption can not reach the object of all being utilized, and the raising of original steam utilization ratio obtains as cost to reduce its production intensity.Under identical operational condition, the throughput of the single-effect evaporator that the throughput of multiple-effect evaporator is identical unlike heat transfer area is large.And the increase of effect number, cost of equipment increases exponentially, so be not that effect number is The more the better.Therefore,, in the time using multiple-effect evaporator, must weigh to determine reasonably to imitate number to installation cost and operational cost.Meanwhile, even multiple-effect evaporation, the secondary steam of the high heat roasting of last effect is also abandoned, and is not made full use of, so its heat power efficiency of multiple-effect evaporation is also quite low.
Therefore, also lack at present the technology that can effectively process high salt, high concentration organic contaminant waste water simultaneously, existing high salt, high concentration organic contaminant waste water combination treatment method exist that operational path validity, reliability and stability long, that process are poor, investment is large, working cost is high, Operation, Administration and Maintenance is complicated, and effluent quality is difficult to the problem of guarantee.Therefore, need to develop a kind of new technology or device to solve problems of the prior art.
Summary of the invention
The purpose of this utility model is to solve above-mentioned high salt, high concentration organic contaminant waste water the deficiencies in the prior art and problem, and a kind of DDISO(Desalting device integrated synchronous oxidation is provided) Integral synchronous oxidation desalination plant.This DDISO Integral synchronous oxidation desalination plant absorbs heat according to organic synthesis, the principle of inorganicization decomposition caused heat release, the heat that utilizes organism in high salt, high-concentration waste water to discharge in inorganicization process under given conditions, heat energy during as water vapor, makes waste water vaporization concentrated, and the water vapour of vaporization is constantly discharged, salt in waste water is concentrated, in the time that the salt in concentrated solution is hypersaturated state, salt is crystallization, reaches Simultaneous Oxidation organism and desalination object.In Simultaneous Oxidation desalting process, be oxidized and concentrate by organic pollutant and analyse salt, high salt, high concentration organic contaminant waste water are purified, when removal apparatus starts in Simultaneous Oxidation desalting process, need outside heat supply consumption of calorie not while normally operation.The integrated equipment of this patent, has compact construction, an advantage such as operational path is short, floor space is little, running maintenance is convenient, hygienic safety, running cost are low.
The technical solution of the utility model is as follows:
DDISO Integral synchronous oxidation desalination plant of the present utility model, it mainly includes treatment solution water inlet system, Simultaneous Oxidation concentration response device system, gas gathering system and crystal desalination system, treatment solution water inlet system enters treatment solution storage tank 1 after suspended substance in waste water and oil fence are cut, treatment solution storage tank 1 is connected with the Simultaneous Oxidation concentration response device 5 of Simultaneous Oxidation concentration response device system by lift pump 3, and lift pump 3 is sent into Simultaneous Oxidation concentration response device 5 from the interior suction waste water for the treatment of solution storage tank 1 and processed; Processing the mixed gas of generation discharge delivers to gas gathering system collection and separates; Concentration through salt in processing Simultaneous Oxidation concentration response device 5 waste water is more and more higher, in the time that concentration reaches design crystallization concentration, concentrated solution is drained into the crystallizer 2 of crystal desalination system, in tank, concentrated solution decompression is lowered the temperature, make concentrated solution be hypersaturated state, realize crystallization desalination; Crystallizer 2 connects lift pump 3 simultaneously, and by lift pump 3, interior crystallizer 2 liquid circulation is pumped to Simultaneous Oxidation concentration response device 5, carries out cyclic oxidation and concentrates;
Described Simultaneous Oxidation concentration response device system synchronization oxidation concentration response device 5 is made up of inner chamber and external jacket two portions, the built-in KMD-5 catalyzer of reactor inner chamber, reactor external jacket is heat exchange jacket, when reactor start-up, for heating bore, makes it reach oxidizing reaction temperature; In the time of normal work, for cooling, get rid of the heat producing in oxidation concentration process; Simultaneous Oxidation concentration response device 5 connects heat medium storage tank 9 and coolant storage tank 10 by pipeline on one side simultaneously, and the other side connects heat medium storage tank 9 and coolant storage tank 10 by interchanger 27 and cold heat medium circulation pump 11 simultaneously, forms circulation; In heat medium storage tank 9, be provided with electric heater 12 in order to heat the heating agent YRM-2 in heat medium storage tank 9; Simultaneous Oxidation concentration response device 5 is connected with high pressure gas holder 4 simultaneously, the 5 inner chamber waste water heating of Simultaneous Oxidation concentration response device simultaneously, high pressure gas holder 4 from Simultaneous Oxidation concentration response device 5 bottoms by reliever to inner chamber oxygen supply, provide oxidation operation in waste water to react required oxygen;
Described gas gathering system is connected with Simultaneous Oxidation concentration response device 5 by interchanger 1, and collection and confinement of gases condensation is delivered to air water separator 8, and the gas that has separated condensed water is emptying.
DDISO Integral synchronous oxidation desalination plant of the present utility model, its further technical scheme is that Simultaneous Oxidation concentration response device system synchronization oxidation concentration response device 5 is while starting, first heat the heating agent YRM-2 in heat medium storage tank 9 by electric heater 12, heating agent YRM-2 is delivered to waste water in Simultaneous Oxidation concentration response device 5 heat exchange external jacket heating chambers by cold heat medium circulation pump 11, circulate, make wastewater temperature in chamber reach the temperature of reaction of design; Along with oxidation operation reaction in Simultaneous Oxidation concentration response device inner chamber waste water is carried out, chemical energy in organism is released with heat energy, in the time that temperature exceedes design effort temperature, cold heat medium circulation pump 11 starts, force heating agent YRM-circulation, by the heat exchange of interchanger 27, by outside the heat discharge system discharging in oxidizing reaction, maintain the stable of system response temperature.
DDISO Integral synchronous oxidation desalination plant of the present utility model, its further technical scheme can also be that described Simultaneous Oxidation concentration response device 5 is provided with automatic and manual pressure release safety device, to prevent reactor overtemperature, superpressure.
In the utility model:
The task for the treatment of solution water inlet system is suspended substance and oil in interception waste water, supplies water to Simultaneous Oxidation concentration response device 5.Waste water enters the interior adjusting for the treatment of solution storage tank 1 and stores after oil removing and suspended substance pre-treatment, sends into Simultaneous Oxidation concentration response device 5 process by lift pump from the interior suction waste water for the treatment of solution storage tank 1.
The task of Simultaneous Oxidation concentration response device system has been to organic inorganicization in waste water and concentrating salt.Simultaneous Oxidation concentration response device is made up of inner chamber and external jacket two portions.The built-in KMD-5 catalyzer of inner chamber, Simultaneous Oxidation is concentrated to be completed in inner chamber.External jacket is heat exchange jacket, when reactor start-up, takes for heating bore, makes it reach oxidizing reaction temperature; In the time of normal work, for cooling, get rid of the heat producing in oxidation concentration process.When reactor start-up, first heat the heating agent YRM-2 in heat medium storage tank 9 by electric heater 12, heating agent YRM-2 is delivered to waste water in reactor heat exchange external jacket heating chamber by cold heat medium circulation pump 11, circulates, and makes wastewater temperature in chamber reach the temperature of reaction of design.Reactor inner chamber waste water heating simultaneously, high pressure gas holder 4 from reactor bottom by reliever to the oxygen supply of reactor inner chamber, provide oxidation operation in waste water to react required oxygen.Along with oxidation operation reaction in reactor inner chamber waste water is carried out, chemical energy in organism is released with heat energy, in the time that temperature exceedes design effort temperature, cold heat medium circulation pump 11 starts, force heating agent YRM-2 circulation, by the heat exchange of interchanger 27, by outside the heat discharge system discharging in oxidizing reaction, maintain the stable of system response temperature.For ensureing Simultaneous Oxidation concentration response device 5 safety, working reliably, reactor arranges automatic and manual pressure release safety device, prevents reactor overtemperature, superpressure.
The task of gas gathering system is to collect the mixed gas that reaction inner chamber is discharged, safe discharge system.Carry out reactor inner chamber oxidation is concentrated with waste water, the organism in waste water, in the process of inorganicization, forms carbonic acid gas and water, and meanwhile, the water vaporization of being heated forms one deck mixed gas above reactor inner chamber liquid.Under mixture pressure effect, mixed gas, by the wastewater liquid in reactor mist eliminator interception mixed gas, enters interchanger 1, condensation separation is out from mixed gas to make water vapour, deliver to air water separator 8, hold back water of condensation, noncondensable gas is separated emptying.
Along with water vapour in mixed gas is constantly discharged reactor inner chamber, inner chamber waste water is concentrated, in waste water, the concentration of salt is more and more higher, in the time that concentration reaches design crystallization concentration, for preventing, in the crystallization of reactor inner chamber, concentrating and drain into crystallizer 2, in tank, concentrated solution decompression is lowered the temperature, make concentrated solution be hypersaturated state, realize crystallization desalination.After Crystallization Separation, waste water, in unsaturation state, is again circulated and pumps to Simultaneous Oxidation concentration response device 5 by lift pump 3, carries out cyclic oxidation and concentrates.
Compared with prior art the utlity model has following beneficial effect:
1, there is no at present to process the high-concentration waste water technology that organism and salt coexist in Industrial Wastewater Treatment field simultaneously;
2, the utlity model has stronger universality, can process the organism of arbitrary kind, any concentration and the high-concentration waste water that salt coexists, be not subject to pollutant and the kind of salt in waste water, the impact of concentration;
3, the high-concentration waste water that the utility model coexists for the treatment of organism and salt is very thorough, and final product is carbonic acid gas, water, solid-state inorganics and salt, does not produce concentrated solution, non-secondary pollution, odorlessness;
4, the utility model operational path is short, and operation is not subject to impact and the interference of external environment and water quality substantially, and treatment effect is reliable and stable;
5, the utility model handiness is large, can change the adjust operation time according to the water yield, has with opening with the feature of stopping; Also can utilize the electricity price gap of electricity consumption peak regulation time to carry out the adjust operation time, reduce working cost.
6, the utility model level of automation is high, simple to operate, convenient management;
7, the utility model does not need to add any medicament in operational process, and running cost is without medicament expense;
8, when the utility model is except startup, need heat energy, the heat that do not need in service, also can produce waste heat, for other purposes;
9, the utility model working cost is low, is only the 20%-30% of conventional treatment process.
Brief description of the drawings
Fig. 1 is DDISO Integral synchronous oxidation desalination plant structure of the present utility model and principle schematic
In figure: 1-treatment solution storage tank; 2-crystallizer; 3-lift pump; 4-high pressure gas holder; 5-Simultaneous Oxidation concentration response device; 6-interchanger one; 7-interchanger two; 8-air water separator; 9-heat medium storage tank; 10-coolant storage tank is cold; The cold heat medium circulation pump of 11-; 12-electric heater.
Embodiment
As shown in the figure, DDISO Integral synchronous oxidation desalination plant of the present utility model, it mainly includes treatment solution water inlet system, Simultaneous Oxidation concentration response device system, gas gathering system and crystal desalination system, treatment solution water inlet system enters treatment solution storage tank 1 after suspended substance in waste water and oil fence are cut, treatment solution storage tank 1 is connected with the Simultaneous Oxidation concentration response device 5 of Simultaneous Oxidation concentration response device system by lift pump 3, and lift pump 3 is sent into Simultaneous Oxidation concentration response device 5 from the interior suction waste water for the treatment of solution storage tank 1 and processed; Processing the mixed gas of generation discharge delivers to gas gathering system collection and separates; Concentration through salt in processing Simultaneous Oxidation concentration response device 5 waste water is more and more higher, in the time that concentration reaches design crystallization concentration, concentrated solution is drained into the crystallizer 2 of crystal desalination system, in tank, concentrated solution decompression is lowered the temperature, make concentrated solution be hypersaturated state, realize crystallization desalination; Crystallizer 2 connects lift pump 3 simultaneously, and by lift pump 3, interior crystallizer 2 liquid circulation is pumped to Simultaneous Oxidation concentration response device 5, carries out cyclic oxidation and concentrates;
Described Simultaneous Oxidation concentration response device system synchronization oxidation concentration response device 5 is made up of inner chamber and external jacket two portions, the built-in KMD-5 catalyzer of reactor inner chamber, reactor external jacket is heat exchange jacket, when reactor start-up, for heating bore, makes it reach oxidizing reaction temperature; In the time of normal work, for cooling, get rid of the heat producing in oxidation concentration process; Simultaneous Oxidation concentration response device 5 connects heat medium storage tank 9 and coolant storage tank 10 by pipeline on one side simultaneously, and the other side connects heat medium storage tank 9 and coolant storage tank 10 by interchanger 27 and cold heat medium circulation pump 11 simultaneously, forms circulation; In heat medium storage tank 9, be provided with electric heater 12 in order to heat the heating agent YRM-2 in heat medium storage tank 9; Simultaneous Oxidation concentration response device 5 is connected with high pressure gas holder 4 simultaneously, the 5 inner chamber waste water heating of Simultaneous Oxidation concentration response device simultaneously, high pressure gas holder 4 from Simultaneous Oxidation concentration response device 5 bottoms by reliever to inner chamber oxygen supply, provide oxidation operation in waste water to react required oxygen;
Described gas gathering system is connected with Simultaneous Oxidation concentration response device 5 by interchanger 1, and collection and confinement of gases condensation is delivered to air water separator 8, and the gas that has separated condensed water is emptying.
When Simultaneous Oxidation concentration response device system synchronization oxidation concentration response device 5 starts, first heat the heating agent YRM-2 in heat medium storage tank 9 by electric heater 12, heating agent YRM-2 is delivered to waste water in Simultaneous Oxidation concentration response device 5 heat exchange external jacket heating chambers by cold heat medium circulation pump 11, circulate, make wastewater temperature in chamber reach the temperature of reaction of design; Along with oxidation operation reaction in Simultaneous Oxidation concentration response device inner chamber waste water is carried out, chemical energy in organism is released with heat energy, in the time that temperature exceedes design effort temperature, cold heat medium circulation pump 11 starts, force heating agent YRM-circulation, by the heat exchange of interchanger 27, by outside the heat discharge system discharging in oxidizing reaction, maintain the stable of system response temperature.
Described Simultaneous Oxidation concentration response device 5 is provided with automatic and manual pressure release safety device, to prevent reactor overtemperature, superpressure.
The Simultaneous Oxidation concentration response device capacity of the present embodiment is 1m 3calculating is that actual treatment amount is about 1m 3/ h, the reserves for the treatment of solution storage tank 1 are about 1.5m 3; Lift pump 3 is ram pump, and its flow is 2.5m 3/ h, operating pressure is 4~8MPa; The heat interchanging area of interchanger 1 and interchanger 27 is about 80~200m 2; The reserves of heat medium storage tank 9 and coolant storage tank 10 are 2m 3; Cold heat medium circulation pump 11 is diffusion pump, and its flow is about 70m 3/ h.

Claims (3)

1. an Integral synchronous oxidation desalination plant, it is characterized in that mainly including treatment solution water inlet system, Simultaneous Oxidation concentration response device system, gas gathering system and crystal desalination system, treatment solution water inlet system enters treatment solution storage tank (1) after suspended substance in waste water and oil fence are cut, treatment solution storage tank (1) is connected with the Simultaneous Oxidation concentration response device (5) of Simultaneous Oxidation concentration response device system by lift pump (3), lift pump (3) is sent into Simultaneous Oxidation concentration response device (5) from the interior suction for the treatment of solution storage tank (1) waste water and is processed, processing the mixed gas of generation discharge delivers to gas gathering system collection and separates, concentration through salt in processing Simultaneous Oxidation concentration response device (5) waste water is more and more higher, in the time that concentration reaches design crystallization concentration, concentrated solution is drained into the crystallizer (2) of crystal desalination system, in tank, concentrated solution decompression is lowered the temperature, make concentrated solution be hypersaturated state, realize crystallization desalination, crystallizer (2) connects lift pump (3) simultaneously, and by lift pump (3), the interior liquid circulation of crystallizer (2) is pumped to Simultaneous Oxidation concentration response device (5), carries out cyclic oxidation and concentrates,
Described Simultaneous Oxidation concentration response device system synchronization oxidation concentration response device (5) is made up of inner chamber and external jacket two portions, the built-in KMD-5 catalyzer of reactor inner chamber, reactor external jacket is heat exchange jacket, when reactor start-up, for heating bore, makes it reach oxidizing reaction temperature; In the time of normal work, for cooling, get rid of the heat producing in oxidation concentration process; Simultaneous Oxidation concentration response device (5) connects heat medium storage tank (9) and coolant storage tank (10) by pipeline on one side simultaneously, the other side connects heat medium storage tank (9) and coolant storage tank (10) by interchanger two (7) and cold heat medium circulation pump (11) simultaneously, forms circulation; In heat medium storage tank (9), be provided with electric heater (12) in order to heat the heating agent YRM-2 in heat medium storage tank (9); Simultaneous Oxidation concentration response device (5) is connected with high pressure gas holder (4) simultaneously, the heating of Simultaneous Oxidation concentration response device (5) inner chamber waste water simultaneously, high pressure gas holder (4) from Simultaneous Oxidation concentration response device (5) bottom by reliever to inner chamber oxygen supply, provide oxidation operation in waste water to react required oxygen;
Described gas gathering system is connected with Simultaneous Oxidation concentration response device (5) by interchanger one (6), and collection and confinement of gases condensation is delivered to air water separator (8), and the gas that has separated condensed water is emptying.
2. Integral synchronous oxidation desalination plant according to claim 1, it is characterized in that: when Simultaneous Oxidation concentration response device system synchronization oxidation concentration response device (5) starts, first by the heating agent YRM-2 in electric heater (12) heating heat medium storage tank (9), heating agent YRM-2 is delivered to waste water in Simultaneous Oxidation concentration response device (5) heat exchange external jacket heating chamber by cold heat medium circulation pump (11), circulate, make wastewater temperature in chamber reach the temperature of reaction of design; Along with oxidation operation reaction in Simultaneous Oxidation concentration response device inner chamber waste water is carried out, chemical energy in organism is released with heat energy, in the time that temperature exceedes design effort temperature, cold heat medium circulation pump (11) starts, force heating agent YRM-circulation, by the heat exchange of interchanger two (7), by outside the heat discharge system discharging in oxidizing reaction, maintain the stable of system response temperature.
3. Integral synchronous oxidation desalination plant according to claim 1, is characterized in that described Simultaneous Oxidation concentration response device (5) is provided with automatic and manual pressure release safety device, to prevent reactor overtemperature, superpressure.
CN201420091884.1U 2014-03-03 2014-03-03 Integrated synchronous oxidation desalting device Expired - Lifetime CN203922829U (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103848530A (en) * 2014-03-03 2014-06-11 无锡市中岳石化设备有限公司 DDISO integrated synchronous oxidation desalting device
CN107540119A (en) * 2016-06-29 2018-01-05 北京联合创业环保工程股份有限公司 A kind of processing method of the high organic wastewater of high salt
CN108928984A (en) * 2018-08-08 2018-12-04 鞍钢股份有限公司 Method for realizing zero emission of reverse osmosis strong brine in iron and steel enterprises

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103848530A (en) * 2014-03-03 2014-06-11 无锡市中岳石化设备有限公司 DDISO integrated synchronous oxidation desalting device
CN107540119A (en) * 2016-06-29 2018-01-05 北京联合创业环保工程股份有限公司 A kind of processing method of the high organic wastewater of high salt
CN108928984A (en) * 2018-08-08 2018-12-04 鞍钢股份有限公司 Method for realizing zero emission of reverse osmosis strong brine in iron and steel enterprises
CN108928984B (en) * 2018-08-08 2021-07-20 鞍钢股份有限公司 Method for realizing zero emission of reverse osmosis strong brine in iron and steel enterprises

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