CN203904108U - System for purifying sewage generated during desulfuration of ammonia synthesis - Google Patents
System for purifying sewage generated during desulfuration of ammonia synthesis Download PDFInfo
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- CN203904108U CN203904108U CN201420277691.5U CN201420277691U CN203904108U CN 203904108 U CN203904108 U CN 203904108U CN 201420277691 U CN201420277691 U CN 201420277691U CN 203904108 U CN203904108 U CN 203904108U
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Abstract
The utility model discloses a system for purifying sewage generated during desulfuration of ammonia synthesis. The system comprises a hot water tank, a hot water pump, an automatic adjusting valve, a cooling tower, a cold water tank, a cold water pump, a one-way purifier, a chemical adding device, a cooling water use system and a horizontal sedimentation tank. According to the utility model, sewage in the system can be kept in the stable states that scaling is prevented and sulfides cannot volatilize, so that the chemical use amount is greatly reduced, and the cost is lowered; sewage can be timely discharged and recycled, the possibility that sewage in the system is subjected to side reaction is low, and recycled materials can be reused; sulfide foam is not generated on the liquid surface, and sulfides cannot volatilize, so that pollution to the ambient air is avoided; the structure is simple, the effect is excellent, and the system is particularly suitable for being used for the purification of sewage generated during desulfuration of ammonia synthesis in chemical engineering production.
Description
Technical field
The utility model relates to sewage purification technology, more particularly, relates in particular to a kind of chemical enterprise for the synthesis of ammonia Waste Water Containing Sulfur purification system.
Background technology
Production of synthetic ammonia comprises desulfurization workshop section and For Gas-making Process, both absorbs the impurity in semi-water gas with recirculated water spray, and therefore the general newly-built a set of large-scale circulating water device Lai Gongliangge of synthesis ammonia plant workshop section is used, to save space.Desulfurization and gas making sewage enter in settling tank after mixing, and isolate to send in water cooling tower after cinder coolingly again, finally send into Reusability in water cooling pond again.
In above-mentioned prior art, have obvious several shortcoming: 1, all sewage carries out purifying treatment by micro swirl cleaner, the dosage for the treatment of agent needs large, and working cost is high; , easily there is side reaction in 2, recirculated water composition difference, generates scale forming matter, if dosing scale inhibition, dosage is very large; 3, S-contained substance cannot be effectively addressed, and easily causes sewage surface to occur sulphur foam, and in the time of temperature drift, sulfide evaporates by blower fan of cooling tower, causes environmental air pollution.
Utility model content
The purpose of this utility model is for above-mentioned the deficiencies in the prior art, provides that a kind of running cost is low, good impurity removing effect and can greatly reduce the synthetic ammonia Waste Water Containing Sulfur purification system of sulfide content.
The technical solution of the utility model is achieved in that synthetic ammonia Waste Water Containing Sulfur purification system, comprise hot tub, hot water pump, automatic regulating valve, cooling tower, water cooling pond, water supply pump, monobasic cleaner, chemicals dosing plant, water coolant uses system and horizontal sedimentation tank, the water side of described hot tub successively pipeline connects hot water pump, automatic regulating valve, cooling tower, water cooling pond, water supply pump and water coolant use system, described automatic regulating valve the first water outlet connects cooling tower, the second water outlet is the top that purifies liquid-inlet pipe, the end that purifies liquid-inlet pipe connects the feed-water end of monobasic cleaner side, the middle part of described purification liquid-inlet pipe connects chemicals dosing plant, the supernatant liquid outlet of described monobasic cleaner upper end connects water cooling pond, and bottom feed-water end connects the end that cleans liquid-inlet pipe, and the top of described cleaning liquid-inlet pipe is on the pipeline between water supply pump and water coolant use system.
As to further improvement of the utility model, the bottom feed-water end of described monobasic cleaner is three inlet channels, and middle inlet channel is main road water-in, and both sides are bypass water-in, on described three inlet channels, all establish arm, after three arm series connection, connect horizontal sedimentation tank.
As to further improvement of the utility model, on the bottom inlet channel of described monobasic cleaner one side bypass, connect the top of flushing pollution discharge pipe, the end of flushing pollution discharge pipe connects hot tub; Described lateral inflow end is two pipelines, connects respectively opposite side bypass and the main road of monobasic cleaner.
As to further improvement of the utility model, described automatic regulating valve is flow control T-valve, and 80%~90% liquid is sent into the first outlet, and 10%~20% liquid is sent into the second outlet.
The utility model adopts after said structure, by automatic regulating valve, 10%~20% water coolant is sent into monobasic cleaner and carry out circularly purifying, intrasystem sewage is remained on fouling, the nonvolatile steady state of sulfide do not occur, greatly reduced dosing, reduced cost; In time blowdown is also reclaimed, and in system, sewage is difficult for occurring side reaction, and material after reclaiming is recycling; Unlike the prior art, by the shunting of automatic regulating valve and the recovery of flushing pollution discharge pipe, make system enter sulfide concentration in the liquid of cooling tower lower, even fluid surface does not produce sulfide foam when temperature drift, sulfide is non-volatile, can not cause environmental air pollution; The utility model works very well simple in structure, while being particularly suitable for Chemical Manufacture, synthetic ammonia Waste Water Containing Sulfur purifies and uses.
Brief description of the drawings
Below in conjunction with the embodiment in accompanying drawing, the utility model is described in further detail, but do not form any restriction of the present utility model.
Fig. 1 is structural representation of the present utility model.
In figure: 1-hot tub; 2-hot water pump; 3-cooling tower; 4-water cooling pond; 5-water supply pump; 6-automatic regulating valve; 7-monobasic cleaner; 8-chemicals dosing plant; 9-horizontal sedimentation tank; 10-water coolant uses system; 11-purifies liquid-inlet pipe; 12-flushing pollution discharge pipe; 13-cleans liquid-inlet pipe.
Embodiment
Consult shown in Fig. 1, synthetic ammonia Waste Water Containing Sulfur purification system of the present utility model, comprise hot tub 1, hot water pump 2, automatic regulating valve 6, cooling tower 3, water cooling pond 4, water supply pump 5, monobasic cleaner 7, chemicals dosing plant 8, water coolant uses system 10 and horizontal sedimentation tank 9, the water side of described hot tub 1 successively pipeline connects hot water pump 2, automatic regulating valve 6, cooling 3, water cooling pond 4, water supply pump 5 and water coolant use system 10, described automatic regulating valve 6 first water outlets connect cooling tower 3, the second water outlet is the top that purifies liquid-inlet pipe 11, the end that purifies liquid-inlet pipe 11 connects the feed-water end of monobasic cleaner 7 sides, the middle part of described purification liquid-inlet pipe 11 connects chemicals dosing plant 8, the supernatant liquid outlet of described monobasic cleaner 7 upper ends connects water cooling pond 4, and bottom feed-water end connects the end that cleans liquid-inlet pipe 13, and the top of described cleaning liquid-inlet pipe 13 uses on the pipeline between system 10 at water supply pump 5 and water coolant.
In the utility model, the bottom feed-water end of described monobasic cleaner 7 is three inlet channels, and middle inlet channel is main road water-in, and both sides are bypass water-in, on described three inlet channels, all establishes arm, after three arm series connection, connects horizontal sedimentation tank 9.
In the utility model, connect the top of flushing pollution discharge pipe 12 on the bottom inlet channel of described monobasic cleaner 7 one side bypasses, the end of flushing pollution discharge pipe 12 connects hot tub 1; Described lateral inflow end is two pipelines, connects respectively opposite side bypass and the main road of monobasic cleaner 7.
In the utility model, described automatic regulating valve 6 is flow control T-valve, and 80%~90% liquid is sent into the first outlet, and 10%~20% liquid is sent into the second outlet.
When the utility model is implemented, it is rear by hot water pump 2 suction cooling towers 3 that synthetic ammonia sewage enters hot tub 1, sends in water cooling pond 4 after cooling, then pumped to water coolant by water supply pump 5 and use system 10.When hot water pump 2 suction cooling tower 3, the use of carrying out follow-up link in cooling tower 3 sent into 80%~90% liquid by middle automatic regulating valve 6, and 10%~20% liquid, after chemicals dosing plant 8 dosings, is admitted in monobasic cleaner 7.Current are organized into Vertical Flow by monobasic cleaner 7 internal structures, and impurity adsorbs and sedimentation therein repeatedly.The throw out of main road and both sides bypass is all admitted in horizontal sedimentation tank 9 and precipitates and recycling by waterhead, and supernatant liquid is admitted in water cooling pond 4.In the time that the impurity of monobasic cleaner 7 bottoms comparatively stops up, is difficult for being recovered to horizontal sedimentation tank 9, open the manual valve that cleans liquid-inlet pipe 13 tops, three blowdown feed liquor arms that utilization is arranged on main road and two bypass bottommosts wash away impurities at bottom and dredge stifled, wash away rear liquid unification and be rinsed blow-off pipe 12 and send in hot tub 1, when carrying out circularly purifying, can also play the effect of dilution Waste Water Containing Sulfur medium sulphide content concentration.
Claims (4)
1. synthetic ammonia Waste Water Containing Sulfur purification system, comprise hot tub, hot water pump, automatic regulating valve, cooling tower, water cooling pond, water supply pump, monobasic cleaner, chemicals dosing plant, water coolant uses system and horizontal sedimentation tank, it is characterized in that: the water side of described hot tub successively pipeline connects hot water pump, automatic regulating valve, cooling tower, water cooling pond, water supply pump and water coolant use system, described automatic regulating valve the first water outlet connects cooling tower, the second water outlet is the top that purifies liquid-inlet pipe, the end that purifies liquid-inlet pipe connects the feed-water end of monobasic cleaner side, the middle part of described purification liquid-inlet pipe connects chemicals dosing plant, the supernatant liquid outlet of described monobasic cleaner upper end connects water cooling pond, and bottom feed-water end connects the end that cleans liquid-inlet pipe, and the top of described cleaning liquid-inlet pipe is on the pipeline between water supply pump and water coolant use system.
2. synthetic ammonia Waste Water Containing Sulfur purification system according to claim 1, it is characterized in that: the bottom feed-water end of described monobasic cleaner is three inlet channels, middle inlet channel is main road water-in, both sides are bypass water-in, on described three inlet channels, all establish arm, after three arm series connection, connect horizontal sedimentation tank.
3. synthetic ammonia Waste Water Containing Sulfur purification system according to claim 1, is characterized in that: on the bottom inlet channel of described monobasic cleaner one side bypass, connect the top of flushing pollution discharge pipe, the end of flushing pollution discharge pipe connects hot tub; Described lateral inflow end is two pipelines, connects respectively opposite side bypass and the main road of monobasic cleaner.
4. synthetic ammonia Waste Water Containing Sulfur purification system according to claim 1, is characterized in that: described automatic regulating valve is flow control T-valve, and 80%~90% liquid is sent into the first outlet, and 10%~20% liquid is sent into the second outlet.
Priority Applications (1)
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CN201420277691.5U CN203904108U (en) | 2014-05-28 | 2014-05-28 | System for purifying sewage generated during desulfuration of ammonia synthesis |
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CN201420277691.5U CN203904108U (en) | 2014-05-28 | 2014-05-28 | System for purifying sewage generated during desulfuration of ammonia synthesis |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110585830A (en) * | 2019-10-10 | 2019-12-20 | 攀钢集团钒钛资源股份有限公司 | System for wet dust removal of tail gas of rotary kiln |
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2014
- 2014-05-28 CN CN201420277691.5U patent/CN203904108U/en active Active
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110585830A (en) * | 2019-10-10 | 2019-12-20 | 攀钢集团钒钛资源股份有限公司 | System for wet dust removal of tail gas of rotary kiln |
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