CN203890807U - Oxygen-preventing moisture-resisting paper - Google Patents

Oxygen-preventing moisture-resisting paper Download PDF

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Publication number
CN203890807U
CN203890807U CN201420104344.2U CN201420104344U CN203890807U CN 203890807 U CN203890807 U CN 203890807U CN 201420104344 U CN201420104344 U CN 201420104344U CN 203890807 U CN203890807 U CN 203890807U
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CN
China
Prior art keywords
layer
resistance
oxygen
paper
wet
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Expired - Fee Related
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CN201420104344.2U
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Chinese (zh)
Inventor
沈忠升
范腾飞
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Kunshan Printhr Packaging Co., Ltd.
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El Packing (kunshan) Co Ltd
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Priority to CN201420104344.2U priority Critical patent/CN203890807U/en
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Abstract

The utility model discloses a piece of oxygen-preventing moisture-resisting paper which comprises a paper body, wherein an ink layer, a moisture-resisting layer and an oxygen-preventing layer are arranged on the paper body sequentially; the thickness of the moisture-resisting layer is 0.5-1.0mu m; the thickness of the oxygen-preventing layer is 1.0-1.5mu m. The moisture-resisting layer is a water/oil blocking layer; the oxygen-preventing layer is a UV (Ultraviolet) light oil layer. In such a mode, the oxygen-preventing moisture-resisting paper is simple in making process, good in use effect and relatively low in cost, the package property of food is greatly improved, food loss is prevented, and the food inside a package box is prevented from contacting with oxygen.

Description

A kind of resistance oxygen resistance wet paper
Technical field
The utility model relates to pulp technology for making paper, particularly relates to a kind of paper with the wet function of resistance oxygen resistance.
Background technology
Food loss (scalping) is for describing the term of the net loss of product, the appreciable product quality loss that described loss causes owing to packing.Food loses almost always a kind of negative effect, therefore need to minimize this loss by certain methods.Generally to utilize the function barrier material of sealing to stop food and extraneous contacting.Except food loss, oxygen also can produce harmful effect to the flavour of food, structure, color, nutritional labeling etc., if food directly contacts and can cause more serious spoilage problems with oxygen.In addition, oxygen reaction to a lot of food within the storage life of food itself has a facilitation, as rotting etc. of the oxidation of the variation of microbial growth, color, lipoid and fruit.Therefore, thus the oxygen composition of food in just must protected opposing environment when storing.In reality, food is often sold with single packing, and therefore, the importance of finding the packaging material that relative cost is lower and have a balance an of the best between cost and oxygen resistance is a vital factor for food production and packing.
At present, the PE synthetic paper based article of isolation-type be mostly take CPP, CPE as main body base material synthetic paper by curtain coating or
A kind of film article material that has heat sealability and intend paper that person's blow molding process is produced, for air rail sea route freight
Label, food is as cheese, jelly, packaging bag, the packing of metal objects.Owing to take CPP, CPE as main body base material synthetic paper, the barriering effect of its goods is not good, needs the secondary operations production link of dry-lamination process to increase barrier layer for it.Above-mentioned secondary
Processing not only causes goods to have dissolvent residual phenomenon, and it also produced and can bring environmental pollution, and is detrimental to health,
Its diluent using can not thoroughly be eliminated, and easily causes potential safety hazard etc., and secondly synthetic paper is because it has paper
Characteristic, its rigidity is larger, not soft, has limited the scope of its use.And the wrapping paper for packaging for foodstuff of the prior art is in order to meet moisture barrier property, oxygen resistance, the wrapper surface of being everlasting covers not water-permeable membrane class of PE film or other, although this wrapping paper has met moisture barrier property, oxygen resistance, but all bad to the permeability of ink and absorbability by the film covering thereon, the decorative pattern that cannot be beautifully printed in the above, or the decorative pattern of printing is fuzzy, easily decolouring.
Utility model content
The utility model main purpose is to provide a kind of resistance oxygen resistance wet paper of used for packing foods, this packing paper is provided with the wet layer of resistance, oxidation prevention layer, and this resistance oxygen resistance wet paper packaging for foodstuff paper using of the prior art of comparing, manufacture craft is simple, result of use is good, cost is lower, greatly improved packaging for foodstuff performance, avoids the food in food loss and packing box to contact with oxygen.
For achieving the above object, the disclosed technical scheme of the utility model is: a kind of resistance oxygen resistance wet paper, comprise paper body, and on described paper body, be provided with successively ink layer, the wet layer of resistance, oxidation prevention layer; The thickness of the wet layer of described resistance is 0.5-1.0 um, and the thickness of described oxidation prevention layer is 1.0-1.5 um.
Preferably, the wet layer of described resistance is to intercept water oil reservoir.
Preferably, described oxidation prevention layer is UV gloss oil layer.
What preferably, described paper body adopted is paperboard.What the body of paper described in the utility model adopted is paperboard, utilization has the paperboard of certain degree of hardness and thickness to make resistance oxygen resistance wet paper, this resistance oxygen resistance wet paper, owing to having certain hardness and thickness, is applicable to make various packaging bags, packing case and packing box like this.
Preferably, the thickness of described paperboard is between 0.3mm-0.5mm.
For avoiding the pollution to food, what the obstruct water of the obstruct water oil reservoir described in the utility model oil adopted is food stage water oil.Preferably, the component of the obstruct water oil of described obstruct water oil reservoir comprises according to mass percent:
Ethanol 10%-40%
Propylene glycol 5%-20%
Acrylic acid styrol copolymer 40%-60%
Docusate Sodium salt 0-5%
Organic siliconresin 0-3%
Ammonia spirit 0-2%.
The UV gloss oil that oxidation prevention layer described in the utility model adopts, preferably adopts the low migration of low taste UV gloss oil.UV gloss oil described in the utility model is a kind of transparent coating, is also referred to as UV varnish; Its effect be spraying or roller coating after substrate surface, the irradiation through UV lamp, makes it by liquid state, be converted into solid-state, and then reaches surface sclerosis, the effect that its scratch resistance is scratch-resistant, and surface seems light is attractive in appearance, texture is mellow and full.
Preferably, the component of described UV gloss oil layer comprises according to umber:
30 parts-45 parts of acrylic resins;
45 parts-60 parts of reactive diluents;
6.5 parts-8. 5 parts of reactive amines;
3 parts-8 parts of light triggers;
0.2 part-0.8 part of levelling agent;
0.22 part-0.45 part of defoamer;
2.5 parts-3.8 parts of antiwear assistants.UV gloss oil described in the utility model refers to according to volume parts or mass fraction according to umber.The acrylic resin of the UV gloss oil layer described in the utility model is take acrylic acid or acrylic acid derivative as monomer polymerization or take them as main and the prepared polymer of other unsaturated compound combined polymerizations.Acrylic resin described in the utility model can be selected from a kind of in epoxy acrylate, urethane acrylate, polyester acrylate.Reactive diluent described in the utility model refers in molecular structure with the material of epoxy-functional, can not only reduce system viscosity and can also participate in curing reaction, has kept the performance of cured product.Reactive diluent described in the utility model is for dissolving and dilute the acrylic resin of UV gloss oil, and the viscosity of regulation system, participates in Light Curing, affects laser curing velocity, improves or improve the physical property of cured film.Reactive diluent described in the utility model can be selected simple function group reactive diluent, as alkyl acrylate, (methyl) crylic acid hydroxy ester, with (methyl) acrylate, the vinyl monomer of circulus or phenyl ring; Also can select difunctional reactive diluent, as glycols diacrylate, propandiols diacrylate or other glycols diacrylate.
Reactive diluent in the gloss oil of UV described in the utility model, preferred, select difunctional reactive diluent.When being used, difunctional reactive diluent there is following features: laser curing velocity is fast, it is crosslinked to occur during film forming; Be beneficial to the physical and mechanical property and the resistance that improve cured film; Volatility is less, smell is lower.
In the utility model, in described UV gloss oil, add antiwear assistant, utilize antiwear assistant to improve the wear-resisting effect of UV gloss oil, make the paper of preparation not only there is resistance oxygen moisture barrier property, and anti-wear performance is better, is beneficial to transportation and carrying after packaging for foodstuff.Antiwear assistant described in the utility model can be selected a kind of in polysiloxanes, dimethyl silicone polymer, Siloxane-Oxyalkylene Copolymers.
The invention also discloses a kind of preparation method who hinders oxygen resistance wet paper, comprise the steps: in paperboard after printing ink layer, after ink layer is dry, coating one deck intercepts water oil, under the heat-sealing of 100% power, after obstruct water oil reservoir is dry, on described dry obstruct water oil reservoir, be coated with one deck UV gloss oil; The coating speed of described obstruct water oil reservoir is 180-210 M/min, and the thickness of described obstruct water oil reservoir is 0.5-1.0 um; The coating speed of described UV gloss oil layer is 140-180 M/min, and the thickness of described UV gloss oil layer is 1.0-1.5 um.
When the obstruct water oil described in the utility model is coated in paperboard, hole between fiber in paperboard is closed, it is smooth smooth that paper surface becomes, intercept water oil and according to the coating weight of setting, at paper surface, form the rete of one deck even compact, thereby make paper there is the character of not soaking, possess moisture barrier property; Intercept the coating speed of water oil on paperboard surface and can have influence on obstruct water oil in the uniformly dispersed and drying property on paperboard surface, if coating speed is larger, intercepting water oil can not be fully by the sealing of the space between fiber in paperboard; If coating speed is less, can cause and intercept water oil gathering in paperboard, cause paper surface partly to intercept water oil lamella thicker, thereby be unfavorable for subsequent production.UV gloss oil described in the utility model is coated on and intercepts outside water oil reservoir, not only plays oxygen resistance, and can make paper body brighter, makes the printing effect of ink layer better, and plays Anti-scratching performance, improves the packaging character of paper.Water oil reservoir is the same with intercepting, and the coating speed of UV gloss oil layer also directly has influence on the result of use of UV gloss oil rete.In the utility model, utilize to intercept coordinating of water oil reservoir and UV gloss oil layer, utilize double-coating layer of cloth that paper body is played and hinder dampness oxygen effect.
Preferably, described UV gloss oil comprises following component by umber:
35 parts-40 parts of acrylic resins;
48 parts-55 parts of reactive diluents;
7.5 parts-8. 5 parts of reactive amines;
5 parts-8 parts of light triggers;
0.3 part-0.7 part of levelling agent;
0.22 part-0.45 part of defoamer;
2.5 parts-3.8 parts of antiwear assistants; Described obstruct water oil comprises following component by mass percent:
Ethanol 20%-30%
Propylene glycol 5%-18%
Acrylic acid styrol copolymer 40%-55%
Docusate Sodium salt 0-3%
Organic siliconresin 0-2%
Ammonia spirit 0-2%.
Preferably, the preparation method of resistance oxygen described in the utility model resistance wet paper is as follows: in paperboard after printing ink layer, after ink layer is dry, coating one deck intercepts water oil reservoir, under the heat-sealing of 100% power, after obstruct water oil reservoir is dry, on described dry obstruct water oil reservoir, be coated with one deck UV gloss oil; The coating speed of described obstruct water oil reservoir is 185-205 M/min, and the thickness of described obstruct water oil reservoir is 0.6-1.0 um; The coating speed of described UV gloss oil layer is 145-175 M/min, and the thickness of described UV gloss oil layer is 1.0-1.3 um.
The utility model resistance oxygen resistance wet paper is different from packaging for foodstuff paper using of the prior art, in the utility model, adopt printing ink layer on the basis of common paperboard, and then on ink layer, be coated with one deck obstruct water oil reservoir and one deck UV gloss oil layer, utilize obstruct water oil reservoir and UV gloss oil layer to guarantee moisture barrier property and the oxygen resistance of wrapping paper.When the utility model paper is used for packing, first after utilizing ink printing good in the exquisite pattern for packing, after being printing ink layer completion, and then coating intercepts water oil reservoir and UV gloss oil layer, owing to intercepting the effect of water oil reservoir and UV gloss oil layer, not only make the glossiness of printing ink layer better, color is more bright-coloured, and printing ink layer can not decolour.
The beneficial effects of the utility model are: the utility model resistance oxygen resistance wet paper manufacture craft is simple, result of use good, cost is lower, greatly improved packaging for foodstuff performance, avoids the food in food loss and packing box to contact with oxygen.
Accompanying drawing explanation
Fig. 1 is the structural representation of the utility model resistance oxygen resistance wet paper one preferred embodiment;
In accompanying drawing, the mark of each parts is as follows: 1--paper body, 2--ink layer, the wet layer of 3--resistance, 4--oxidation prevention layer.
The specific embodiment
Below in conjunction with accompanying drawing, preferred embodiment of the present utility model is described in detail, thereby so that advantage of the present utility model and feature can be easier to be it will be appreciated by those skilled in the art that, protection domain of the present utility model is made to more explicit defining.
Refer to Fig. 1, the utility model embodiment comprises:
embodiment 1:a resistance oxygen resistance wet paper, comprises paper body 1, is provided with successively ink layer 2, the wet layer 3 of resistance, oxidation prevention layer 4 on paper body 1; The thickness of the wet layer 3 of resistance is 0.5 um, and the thickness of oxidation prevention layer 4 is 1.0 um.
In the present embodiment, the wet layer 3 of resistance is to intercept water oil reservoir.
In the present embodiment, oxidation prevention layer 4 is UV gloss oil layers.
In the present embodiment, the thickness that paper body 1 adopts is the paperboard between 0.3mm-0.5mm.
In the present embodiment, the component of described obstruct water oil comprises according to mass percent: ethanol 30%, propylene glycol 15%, acrylic acid styrol copolymer 50%, Docusate Sodium salt 1%, organic siliconresin 2%, ammonia spirit 2%.
The component of described UV gloss oil layer comprises according to umber: 30 parts of acrylic resins, 45 portions of reactive diluents, 8. 5 parts of reactive amines, 3 parts of light triggers, 0.8 part of levelling agent, 0.22 part of defoamer, 3.8 parts of antiwear assistants.
The preparation method of resistance oxygen in the present embodiment resistance wet paper comprises the steps: in paperboard 1 after printing ink layer 2, after ink layer 2 is dry, coating one deck intercepts water oil, the wet layer 3 of i.e. resistance, under the heat-sealing of 100% power, to intercept water oil reservoir dry after, on dry obstruct water oil reservoir, be coated with one deck UV gloss oil, form oxidation prevention layer 4; The coating speed that intercepts water oil reservoir is 185 M/min, and the thickness that intercepts water oil reservoir is 0.6 um; The coating speed of UV gloss oil layer is 145 M/min, and the thickness of UV gloss oil layer is 1.0 um.
embodiment 2:a resistance oxygen resistance wet paper, comprises paper body 1, is provided with successively ink layer 2, the wet layer 3 of resistance, oxidation prevention layer 4 on paper body 1; The thickness of the wet layer 3 of resistance is 0.7 um, and the thickness of oxidation prevention layer 4 is 1.2 um.
In the present embodiment, the wet layer 3 of resistance is to intercept water oil reservoir.
In the present embodiment, oxidation prevention layer 4 is UV gloss oil layers.
In the present embodiment, the thickness that paper body 1 adopts is the paperboard of 0.3mm.
In the present embodiment, the component of described obstruct water oil comprises according to mass percent: ethanol 40%, propylene glycol 5%, acrylic acid styrol copolymer 50%, Docusate Sodium salt 2%, organic siliconresin 2%, ammonia spirit 1%.
The component of described UV gloss oil layer comprises according to mass fraction: 45 parts of acrylic resins, 50 portions of reactive diluents, 6. 5 parts of reactive amines, 8 parts of light triggers, 0.2 part of levelling agent, 0.45 part of defoamer, 2.5 parts of antiwear assistants.
The preparation method of resistance oxygen in the present embodiment resistance wet paper comprises the steps: in paperboard 1 after printing ink layer 2, after ink layer 2 is dry, coating one deck intercepts water oil, the wet layer 3 of i.e. resistance, under the heat-sealing of 100% power, to intercept water oil reservoir dry after, on dry obstruct water oil reservoir, be coated with one deck UV gloss oil, form oxidation prevention layer 4; The coating speed that intercepts water oil reservoir is 210 M/min, and the thickness that intercepts water oil reservoir is 0.5 um; The coating speed of UV gloss oil layer is 140 M/min, and the thickness of UV gloss oil layer is 1.5 um.
embodiment 3:a resistance oxygen resistance wet paper, comprises paper body 1, is provided with successively ink layer 2, the wet layer 3 of resistance, oxidation prevention layer 4 on paper body 1; The thickness of the wet layer 3 of resistance is 1.0 um, and the thickness of oxidation prevention layer 4 is 1.5 um.
In the present embodiment, the wet layer 3 of resistance is to intercept water oil reservoir.
In the present embodiment, oxidation prevention layer 4 is UV gloss oil layers.
In the present embodiment, the thickness that paper body 1 adopts is the paperboard of 0.5mm.
In the present embodiment, the component of described obstruct water oil comprises according to mass percent: ethanol 10%, propylene glycol 20%, acrylic acid styrol copolymer 60%, Docusate Sodium salt 5%, organic siliconresin 3%, ammonia spirit 2%.
The component of described UV gloss oil layer comprises according to umber: 32 parts of acrylic resins, 60 portions of reactive diluents, 8. 5 parts of reactive amines, 6 parts of light triggers, 0.8 part of levelling agent, 0.35 part of defoamer, 3.8 parts of antiwear assistants.
The preparation method of resistance oxygen in the present embodiment resistance wet paper comprises the steps: in paperboard 1 after printing ink layer 2, after ink layer 2 is dry, coating one deck intercepts water oil, the wet layer 3 of i.e. resistance, under the heat-sealing of 100% power, to intercept water oil reservoir dry after, on dry obstruct water oil reservoir, be coated with one deck UV gloss oil, form oxidation prevention layer 4; The coating speed that intercepts water oil reservoir is 200 M/min, and the thickness that intercepts water oil reservoir is 0.8 um; The coating speed of UV gloss oil layer is 160 M/min, and the thickness of UV gloss oil layer is 1.2 um.
embodiment 4:a resistance oxygen resistance wet paper, comprises paper body 1, is provided with successively ink layer 2, the wet layer 3 of resistance, oxidation prevention layer 4 on paper body 1; The thickness of the wet layer 3 of resistance is 0.6 um, and the thickness of oxidation prevention layer 4 is 1.2 um.
In the present embodiment, the wet layer 3 of resistance is to intercept water oil reservoir.
In the present embodiment, oxidation prevention layer 4 is UV gloss oil layers.
In the present embodiment, the thickness that paper body 1 adopts is the paperboard of 0.4mm.
In the present embodiment, the component of described obstruct water oil comprises according to mass percent: ethanol 30%, propylene glycol 15%, acrylic acid styrol copolymer 50%, Docusate Sodium salt 2%, organic siliconresin 2%, ammonia spirit 1%.
The component of described UV gloss oil layer comprises according to umber: 38 parts of acrylic resins, 50 portions of reactive diluents, 7. 5 parts of reactive amines, 5 parts of light triggers, 0.6 part of levelling agent, 0.40 part of defoamer, 3.0 parts of antiwear assistants.
The preparation method of resistance oxygen in the present embodiment resistance wet paper comprises the steps: in paperboard 1 after printing ink layer 2, after ink layer 2 is dry, coating one deck intercepts water oil, the wet layer 3 of i.e. resistance, under the heat-sealing of 100% power, to intercept water oil reservoir dry after, on dry obstruct water oil reservoir, be coated with one deck UV gloss oil, form oxidation prevention layer 4; The coating speed that intercepts water oil reservoir is 200 M/min, and the thickness that intercepts water oil reservoir is 0.7 um; The coating speed of UV gloss oil layer is 150 M/min, and the thickness of UV gloss oil layer is 1.2 um.
embodiment 5:a resistance oxygen resistance wet paper, comprises paper body 1, is provided with successively ink layer 2, the wet layer 3 of resistance, oxidation prevention layer 4 on paper body 1; The thickness of the wet layer 3 of resistance is 0.8 um, and the thickness of oxidation prevention layer 4 is 1.4 um.
In the present embodiment, the wet layer 3 of resistance is to intercept water oil reservoir.
In the present embodiment, oxidation prevention layer 4 is UV gloss oil layers.
In the present embodiment, the thickness that paper body 1 adopts is the paperboard of 0.3mm.
In the present embodiment, the component of described obstruct water oil comprises according to mass percent: ethanol 18%, propylene glycol 18%, acrylic acid styrol copolymer 54%, Docusate Sodium salt 5%, organic siliconresin 3%, ammonia spirit 2%.
The component of described UV gloss oil layer comprises according to mass fraction: 35 parts of acrylic resins, 45 portions of reactive diluents, 6. 5 parts of reactive amines, 6 parts of light triggers, 0.2 part of levelling agent, 0.22 part of defoamer, 2.5 parts of antiwear assistants.
The preparation method of resistance oxygen in the present embodiment resistance wet paper comprises the steps: in paperboard 1 after printing ink layer 2, after ink layer 2 is dry, coating one deck intercepts water oil, the wet layer 3 of i.e. resistance, under the heat-sealing of 100% power, to intercept water oil reservoir dry after, on dry obstruct water oil reservoir, be coated with one deck UV gloss oil, form oxidation prevention layer 4; The coating speed that intercepts water oil reservoir is 190 M/min, and the thickness that intercepts water oil reservoir is 0.6 um; The coating speed of UV gloss oil layer is 160 M/min, and the thickness of UV gloss oil layer is 1.5 um.
Resistance oxygen resistance wet paper described in the utility model is through the wet test of resistance, the test of resistance oxygen, and properties all reaches and is better than packaging for foodstuff paper using standard, and concrete test experiments and test data are as follows:
Above sample test completes by film health Qxtran 2/21 and PERMATRAN-W 3/33 instrument, and these instruments meet respectively standard A STM D3985 and ASTM F 1249.
The foregoing is only embodiment of the present utility model; not thereby limit the scope of the claims of the present utility model; every equivalent structure or conversion of equivalent flow process that utilizes the utility model description and accompanying drawing content to do; or be directly or indirectly used in other relevant technical fields, be all in like manner included in scope of patent protection of the present utility model.

Claims (5)

1. a resistance oxygen resistance wet paper, is characterized in that, comprises paper body, is provided with successively ink layer, the wet layer of resistance, oxidation prevention layer on described paper body; The thickness of the wet layer of described resistance is 0.5-1.0um, and the thickness of described oxidation prevention layer is 1.0-1.5um.
2. resistance oxygen resistance wet paper according to claim 1, is characterized in that, the wet layer of described resistance is to intercept water oil reservoir.
3. resistance oxygen resistance wet paper according to claim 2, is characterized in that, described oxidation prevention layer is UV gloss oil layer.
4. resistance oxygen resistance wet paper according to claim 3, is characterized in that, what described paper body adopted is paperboard.
5. resistance oxygen resistance wet paper according to claim 4, is characterized in that, the thickness of described paperboard is between 0.3mm-0.5mm.
CN201420104344.2U 2014-03-10 2014-03-10 Oxygen-preventing moisture-resisting paper Expired - Fee Related CN203890807U (en)

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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103821029A (en) * 2014-03-10 2014-05-28 艾捷舒尔物德包装(昆山)有限公司 Antioxidant and moisture-retarding paper and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103821029A (en) * 2014-03-10 2014-05-28 艾捷舒尔物德包装(昆山)有限公司 Antioxidant and moisture-retarding paper and preparation method thereof
CN103821029B (en) * 2014-03-10 2016-08-24 昆山美普森包装有限公司 A kind of resistance oxygen resistance wet paper and preparation method thereof

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C14 Grant of patent or utility model
GR01 Patent grant
C56 Change in the name or address of the patentee
CP03 Change of name, title or address

Address after: 215000 No. 368, Eagle Road, Kunshan Development Zone, Jiangsu, Suzhou, China

Patentee after: Kunshan Printhr Packaging Co., Ltd.

Address before: 215000, No. 368, Eagle Road, Kunshan Development Zone, Suzhou, Jiangsu, Jiangsu

Patentee before: El packing (Kunshan) Co., Ltd.

CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20141022

Termination date: 20210310

CF01 Termination of patent right due to non-payment of annual fee