CN203881727U - Gas chromatograph for analyzing hydrocarbon components of catalytic cracking products of gasoline and diesel - Google Patents
Gas chromatograph for analyzing hydrocarbon components of catalytic cracking products of gasoline and diesel Download PDFInfo
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- CN203881727U CN203881727U CN201420209872.4U CN201420209872U CN203881727U CN 203881727 U CN203881727 U CN 203881727U CN 201420209872 U CN201420209872 U CN 201420209872U CN 203881727 U CN203881727 U CN 203881727U
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Abstract
The utility model discloses a gas chromatograph for analyzing hydrocarbon components of catalytic cracking products of gasoline and diesel. The gas chromatograph comprises a three-way stopping valve, a six-way valve, an eight-way valve, a chromatographic column and a single FID (Flame Ionization Detector), wherein C1-C5 low-carbon hydrocarbon components and C6<+> high-carbon hydrocarbon components of the catalytic cracking products of the gasoline and the diesel are respectively determined by valve-column switching. The gas chromatograph disclosed by the utility model can be applied to the aspects of research on the catalytic cracking reaction mechanism of oil refineries and junior colleges, and is convenient in operation, high in practicability, simple in structure and low in cost.
Description
Technical field
The utility model relates to a kind of analytical instrument of analyzing catalytic cracking production, relates in particular to the gas chromatograph that gasoline, diesel catalytic cracking production hydrocarbon component is analyzed.
Background technology
Gasoline, diesel catalytic cracking reaction is as a kind of conventional means of Cracking catalyst performance evaluation and mechanism research, its product complicated components, span are large, mainly contain lower carbon number hydrocarbons and C6 and the above high-carbon hydrocarbon of permanent gas, C1 ~ C5, selecting single gasoline, diesel model components as certain alkane in C6 ~ C16 or alkene during as raw material, its crackate is mainly lower carbon number hydrocarbons and the C6 of C1 ~ C5
+high-carbon hydrocarbon, the qualitative and quantitative analysis of these components especially C1 ~ C5 lower carbon number hydrocarbons component is had important practical significance for research cracking mechanism.C1 ~ C5 lower carbon number hydrocarbons component boiling point is lower, and character is close, especially larger to the analysis difficulty of C4 alkene, at present the main Al that adopts
2o
3the chromatographic column of filler is carried out compartment analysis to C1 ~ C5 lower carbon number hydrocarbons component, but Al
2o
3post cannot be analyzed C6 and above component, simultaneously C6
+high-carbon hydrocarbon component is easily by Al
2o
3post absorption, thus Al reduced
2o
3the separating property of post.And be used for analyzing C6 and above component and generally select the chromatographic column of low pole siloxane filler, cannot realize the separation to C1 ~ C5 lower carbon number hydrocarbons component.Therefore, the multidimensional gas chromatograph of many gas chromatographs of industrial general employing or many valves multicolumn multi-detector is analyzed it." assay office, 2011,30 (11): 121 " adopt three gas chromatographs to analyze gasoline crackates, wherein a gas chromatograph is used for analyzing permanent gas, another two lower carbon number hydrocarbons and C6 and above high-carbon hydrocarbons that are respectively used to analyze C1 ~ C5.But it,, in the time detecting gasoline, diesel catalytic cracking production hydrocarbon component, need use two gas chromatographs, exist cost of development high, take up room large, need multiple chem workstations the shortcoming such as to process to data.Although a two-dimensional gas chromatography instrument of being furnished with the two fid detectors of two valve three posts can be realized the analysis to above-mentioned product, because it needs two fid detectors, make whole system comparatively complicated, cost of development is still higher.From published data, not yet there is single fid detector of employing, only depend on valve handoff technique, single temperature programme to carry out the gas chromatograph of Realization analysis gasoline, diesel catalytic cracking production hydrocarbon component.
Chinese patent application: 201410135070.8; 201420162899.2 adopt three-way cut-off valve, six-way valve, ten two-port valves and the combination of single fid detector, measure respectively the C6 of C1 ~ C5 lower carbon number hydrocarbons component and gasoline, diesel catalytic cracking production by valve rod handoff technique simultaneously
+high-carbon hydrocarbon component.But it needs a road assisted gas, one to cut in advance blowback chromatographic column, the design of ten two-port valves simultaneously and configure also relative complex.
Utility model content
The purpose of this utility model is the deficiency that makes up prior art, the gas chromatograph that provides a kind of gasoline, diesel catalytic cracking production hydrocarbon component to analyze, adopt three-way cut-off valve, six-way valve, eight logical valves and the combination of single fid detector, only depend on valve handoff technique, single temperature programme to realize the analysis to gasoline, diesel catalytic cracking production hydrocarbon component, comprise the analysis to C1 ~ C5, C6 and above component.
The purpose of this utility model is achieved in that
The gas chromatograph that gasoline, diesel catalytic cracking production hydrocarbon component is analyzed, be characterized in that this chromatograph comprises a six-way valve, one eight logical valve, two three-way cut-off valves, two root chromatogram columns, two quantity tubes and fid detector, the first passage of described six-way valve is connected with first three-way cut-off valve right wing, the Road of first three-way cut-off valve is connected with carrier gas line, the second channel of six-way valve is connected with the first passage of eight logical valves, the 3rd of six-way valve, the 6th passage is connected with the two ends of first quantity tube respectively, the 5th of six-way valve, four-way is the gateway of the first sample, the second channel of eight logical valves is connected with one end of the first root chromatogram column, the other end of the first root chromatogram column is connected with second three-way cut-off valve Zuo road, the third channel of eight logical valves is connected with first three-way cut-off valve Zuo road, the four-way of eight logical valves is connected with one end of the second root chromatogram column, the 5th of eight logical valves, the 8th passage is connected with the two ends of second quantity tube respectively, the 7th of eight logical valves, the 6th passage is the gateway of the second sample, the other end of the second root chromatogram column is connected with the right wing of second three-way cut-off valve, the Road of second three-way cut-off valve is connected with fid detector.
Pipeline between described six-way valve, eight logical valves, three-way cut-off valve, quantity tube, sample gateway and six-way valve and eight logical valves is all placed in heated at constant temperature case, described three root chromatogram columns are placed in post case, and the temperature control scope of heated at constant temperature case and post case is room temperature ~ 350 DEG C.
In described chromatographic column, the first root chromatogram column is for analyzing C6
+the capillary chromatographic column of 5% phenyl 95% methyl polysiloxane carrier of component, the second root chromatogram column is for analyzing the Al of C1 ~ C5 component
2o
3the capillary chromatographic column of carrier.
Above-mentioned two root chromatogram columns also can be selected the chromatography column of identical filler.
Described the first sample inlet pipeline is directly connected with the outlet of gasoline, diesel catalytic cracking tail gas, and tail gas is exported to pipeline between the first sample inlet and is placed in heated at constant temperature band, and the temperature control scope of heating tape is 120 ~ 350 DEG C.
Described the second sample inlet pipeline is directly connected with the gasoline, diesel catalytic cracking tail gas outlet after gas-liquid separation.
Gas chromatograph of the present utility model only adopts a road carrier gas, a fid detector, a temperature programme, realizes the analysis to gasoline, diesel catalytic cracking production hydrocarbon component switching time by variable valve.
The making of gas chromatograph of the present utility model only need be reequiped single injection port general on market and the gas chromatograph of single fid detector, above gas chromatograph, install a heated at constant temperature case additional, the pipelines such as T-valve stop valve, six-way valve, eight logical valves and quantity tube are placed in to above-mentioned heated at constant temperature case, adopt the 316 stainless steel pipelines of 1/16 inch that the chromatographic column in post case is connected on the relevant position of each valve in heated at constant temperature case.
Gas chromatograph of the present utility model in the time analyzing gasoline, diesel catalytic cracking production, lower carbon number hydrocarbons component and the C6 of Main Analysis C1 ~ C5
+high-carbon hydrocarbon component, first analyze the lower carbon number hydrocarbons component of C1 ~ C5, then analyze C6
+high-carbon hydrocarbon component.Wherein, in high-carbon hydrocarbon is analyzed, the lower carbon number hydrocarbons component of C1 ~ C5 also can go out peak, but can occur with group peak form compared with polycomponent, and the total peak area of C1 ~ C5 is only as the conversion ratio that calculates raw material.
The utility model is compared with published technology, has the following advantages:
(1) compare with the gas chromatograph of two fid detectors of needs in the past, the utility model only needs the gas chromatograph of a configuration one tunnel carrier gas, a fid detector just can realize the total analysis to hydrocarbon component in gasoline, diesel catalytic cracking production;
(2) first eight logical valves are applied in modular valve blocks column chromatography system, substitute traditional six-way valve, the purposes such as centralized procurement sample and post selection, in one, have not only greatly been saved cost, and operation is also tending towards simplifying.
The utility model and Chinese patent application: 201410135070.8; 201420162899.2 compare, and gasoline, diesel catalytic cracking tail gas is accessing the second sample channel after gas-liquid separation again, does not need to cut in advance blowback chromatographic column, adopt eight logical valves to replace ten two-port valves, and Zhi Xu mono-tunnel carrier gas, and cost of manufacture significantly reduces again.
Gas chromatograph of the present utility model is particularly suitable for the aspects such as refinery and the universities and colleges research to catalytic cracking mechanism, easy to operate, practical, simple in structure, with low cost.
Brief description of the drawings
Fig. 1 is the structural representation of the utility model holding state;
Fig. 2 is the utility model sampling and the structural representation of analyzing C1 ~ C5 light hydrocarbon component;
Fig. 3 is the utility model sampling and analyzes C6
+the structural representation of heavy constituent;
Fig. 4 is that the utility model is caught up with and is trapped in Al
2o
3a small amount of C6 in post
+the structural representation of component;
Fig. 5 is the chromatogram of the positive octene catalytic cracking production of the utility model analysis hydrocarbon component.
Embodiment
Consult Fig. 1, the gas chromatograph of analysis gasoline, diesel catalytic cracking production of the present utility model comprises nebulizer gas pressure flow control part, a six-way valve, eight logical valves, three-way cut-off valve 1, three-way cut-off valve 2, chromatographic column 1, chromatographic column 2, quantity tube 1, quantity tube 2 and a fid detector.The passage 1 of described six-way valve is connected with three-way cut-off valve 1 right wing, the Road of three-way cut-off valve 1 is connected with carrier gas line, the passage 2 of six-way valve is connected with the passage 21 of eight logical valves, the passage 3 of six-way valve is connected with the two ends of quantity tube 1 respectively with 6, the passage 5 and 4 of six-way valve is respectively the gateway of sample 1, the passage 22 of eight logical valves is connected with one end of chromatographic column 1, the other end of chromatographic column 1 is connected with three-way cut-off valve 2 Zuo roads, the passage 23 of eight logical valves is connected with three-way cut-off valve 1 Zuo road, the passage 24 of eight logical valves is connected with one end of chromatographic column 2, the passage 25 of eight logical valves is connected with the two ends of quantity tube 2 respectively with 28, the passage 27 and 26 of eight logical valves is respectively the gateway of sample 2, the other end of chromatographic column 2 is connected with the right wing of three-way cut-off valve 2, the Road of three-way cut-off valve 2 is connected with fid detector.
Pipeline between described six-way valve, eight logical valves, three-way cut-off valve, quantity tube, sample gateway and six-way valve and eight logical valves is all placed in heated at constant temperature case, described two root chromatogram columns are placed in post case, and the temperature control scope of heated at constant temperature case and post case is room temperature ~ 350 DEG C.
In described chromatographic column, chromatographic column 1 is for analyzing C6
+the capillary chromatographic column of 5% phenyl 95% methyl polysiloxane carrier of component, selects HP-5, and specification is 60 m (length) * 0.32 mm (external diameter) * 0.25 μ m (film); Chromatographic column 2 is for analyzing the Al of C1 ~ C5 component
2o
3the capillary chromatographic column of carrier, selects HP-AL/S, and specification is 50 m (length) * 0.53 mm (external diameter) * 15 μ m (film).
Gasoline, diesel cracking tail gas directly accesses the entrance of sample 1, the entrance of the gasoline, diesel cracking tail gas access sample 2 after gas-liquid separation; The pipeline being exported between sample 1 entrance from gasoline, diesel pyrolysis gas adopts the insulation of heated at constant temperature band, and the temperature of heated at constant temperature band is 120 ~ 350 DEG C.
Embodiment
Consult Fig. 1, instrument is in holding state, carrier gas N
2loop is: the logical left road → three-way cut-off valve 2 Roads → fid detector of valve passage 22 → chromatographic column 1 → three-way cut-off valve 2 of the logical valve passage 21 → eight of carrier gas inlet → three-way cut-off valve 1 Road → three-way cut-off valve 1 right wing → six-way valve passage 1 → six-way valve passage 2 → eight; Sample 1 loop is: six-way valve passage 4 → six-way valve passage 3 → quantity tube 1 → six-way valve passage 6 → six-way valve passage 5; Sample 2 loops are: the logical valve passage 27 of the logical valve passage 28 → eight of the logical valve passage 25 → quantity tube 2 → eight of eight logical valve passages 26 → eight; In post is selected, from three-way cut-off valve 1 to chromatographic column 2 to the detailed route of three-way cut-off valve 2 be again: logical valve passage 24 → chromatographic column 2 → three-way cut-off valve 2 right wings of the logical valve passage 23 → eight of left road → eight of three-way cut-off valve 1.
Consult Fig. 2, switch eight logical valves and three-way cut-off valve 2 to position as shown in Figure 2 and realize on-line sampling and the analysis of C1 ~ C5 light hydrocarbon component, carrier gas N
2loop is: the logical valve passage 24 → chromatographic column 2 → three-way cut-off valve 2 right wings → three-way cut-off valve 2 Roads → fid detector of the logical valve passage 25 → eight of the logical valve passage 28 → quantity tube 2 → eight of the logical valve passage 21 → eight of carrier gas inlet → three-way cut-off valve 1 Road → three-way cut-off valve 1 right wing → six-way valve passage 1 → six-way valve passage 2 → eight; Sample 1 same Fig. 1 in loop; Sample 2 loops are: the logical valve passage 27 of eight logical valve passages 26 → eight; In post is selected, from three-way cut-off valve 1 to chromatographic column 1 to the detailed route of three-way cut-off valve 2 be again: the logical valve passage of left road → eight of three-way cut-off valve 1 23 → eight logical valve passage 22 → chromatographic column 1 → three-way cut-off valve 2 left roads.
Consult Fig. 3, switch six-way valve, eight logical valves and three-way cut-off valve 2 to position as shown in Figure 3 and realize C6
+the sampling of heavy constituent and analysis, carrier gas N
2loop is: the logical left road → three-way cut-off valve 2 Roads → fid detector of valve passage 22 → chromatographic column 1 → three-way cut-off valve 2 of the logical valve passage 21 → eight of carrier gas inlet → three-way cut-off valve 1 Road → three-way cut-off valve 1 right wing → six-way valve passage 1 → six-way valve passage 6 → quantity tube 1 → six-way valve passage 3 → six-way valve passage 2 → eight; Sample 1 loop is: six-way valve passage 4 → six-way valve passage 5; Sample 2 same Fig. 1 in loop; In post is selected, from three-way cut-off valve 1 to chromatographic column 2 to the detailed route of three-way cut-off valve 2 be again: logical valve passage 24 → chromatographic column 2 → three-way cut-off valve 2 right wings of the logical valve passage 23 → eight of left road → eight of three-way cut-off valve 1.
Consult Fig. 4, the purging to chromatographic column 2 is realized in switching three-way stop valve 1, six-way valve, three-way cut-off valve 2 to position as shown in Figure 4, catches up with and is trapped in Al
2o
3a small amount of C6 in post
+component, carrier gas N
2loop is: the logical valve passage 24 → chromatographic column 2 → three-way cut-off valve 2 right wings → three-way cut-off valve 2 Roads → fid detector of the logical valve passage 23 → eight of left road → eight of carrier gas inlet → three-way cut-off valve 1 Road → three-way cut-off valve 1; Sample 1 loop, sample 2 same Fig. 1 in loop; In post is selected, from three-way cut-off valve 1 to chromatographic column 1 to the detailed route of three-way cut-off valve 2 be again: the logical valve passage of three-way cut-off valve 1 right wing → six-way valve passage 1 → six-way valve passage 2 → eight 21 → eight logical valve passage 22 → chromatographic column 1 → three-way cut-off valve 2 left roads.
As shown in Figure 5, the chromatogram of analyzing positive octene catalytic cracking production hydrocarbon component is realized under the following conditions: the temperature setting of heated at constant temperature case is set to 180 DEG C; The heating schedule of post case is 60 DEG C and stops 3 min, is warming up to 100 DEG C with 10 DEG C/min, stops 15 min, then is warming up to 180 DEG C with 20 DEG C/min, stops 3 min; In the time switching eight logical valves and three-way cut-off valve 2 to position as shown in Figure 2, start to start chromatographic working procedure; After moving 8.8 min, chromatographic program switches six-way valve, eight logical valves and three-way cut-off valve 2 to position as shown in Figure 3; After chromatographic program moves 26 min, switching three-way stop valve 1, six-way valve, three-way cut-off valve 2 are to position as shown in Figure 4; Afterwards until chromatographic program end of run.
Claims (5)
1. the gas chromatograph that gasoline, diesel catalytic cracking production hydrocarbon component is analyzed, it is characterized in that this chromatograph comprises a six-way valve, one eight logical valve, two three-way cut-off valves, two root chromatogram columns, two quantity tubes and fid detector, the first passage of described six-way valve is connected with first three-way cut-off valve right wing, the Road of first three-way cut-off valve is connected with carrier gas line, the second channel of six-way valve is connected with the first passage of eight logical valves, the 3rd of six-way valve, the 6th passage is connected with the two ends of first quantity tube respectively, the 5th of six-way valve, four-way is the gateway of the first sample, the second channel of eight logical valves is connected with one end of the first root chromatogram column, the other end of the first root chromatogram column is connected with second three-way cut-off valve Zuo road, the third channel of eight logical valves is connected with first three-way cut-off valve Zuo road, the four-way of eight logical valves is connected with one end of the second root chromatogram column, the 5th of eight logical valves, the 8th passage is connected with the two ends of second quantity tube respectively, the 7th of eight logical valves, the 6th passage is the gateway of the second sample, the other end of the second root chromatogram column is connected with the right wing of second three-way cut-off valve, the Road of second three-way cut-off valve is connected with fid detector.
2. gas chromatograph according to claim 1, it is characterized in that the pipeline between described six-way valve, eight logical valves, three-way cut-off valve, quantity tube, sample gateway and six-way valve and eight logical valves is all placed in heated at constant temperature case, described three root chromatogram columns are placed in post case, and the temperature control scope of heated at constant temperature case and post case is room temperature ~ 350 DEG C.
3. gas chromatograph according to claim 1, is characterized in that in described chromatographic column, and the first root chromatogram column is for analyzing C6
+the capillary chromatographic column of 5% phenyl 95% methyl polysiloxane carrier of component, the second root chromatogram column is for analyzing the Al of C1 ~ C5 component
2o
3the capillary chromatographic column of carrier.
4. gas chromatograph according to claim 1, it is characterized in that described the first sample inlet pipeline is directly connected with the outlet of gasoline, diesel catalytic cracking tail gas, tail gas is exported to pipeline between the first sample inlet and is placed in heated at constant temperature band, and the temperature control scope of heating tape is 120 ~ 350 DEG C.
5. gas chromatograph according to claim 1, is characterized in that described the second sample inlet pipeline is directly connected with the gasoline, diesel catalytic cracking tail gas outlet after gas-liquid separation.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201420209872.4U CN203881727U (en) | 2014-04-28 | 2014-04-28 | Gas chromatograph for analyzing hydrocarbon components of catalytic cracking products of gasoline and diesel |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201420209872.4U CN203881727U (en) | 2014-04-28 | 2014-04-28 | Gas chromatograph for analyzing hydrocarbon components of catalytic cracking products of gasoline and diesel |
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| Publication Number | Publication Date |
|---|---|
| CN203881727U true CN203881727U (en) | 2014-10-15 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201420209872.4U Withdrawn - After Issue CN203881727U (en) | 2014-04-28 | 2014-04-28 | Gas chromatograph for analyzing hydrocarbon components of catalytic cracking products of gasoline and diesel |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103983722A (en) * | 2014-04-28 | 2014-08-13 | 华东师范大学 | A gas chromatograph for hydrocarbon component analysis of a catalytic cracking product of gasoline and diesel |
| CN104265952A (en) * | 2014-10-24 | 2015-01-07 | 北京佰纯润宇生物科技有限公司 | Eight-way valve and chromatographic system based on eight-way valve |
| CN104458978A (en) * | 2014-10-24 | 2015-03-25 | 北京佰纯润宇生物科技有限公司 | Five-position eight-way valve and chromatogram system based on five-position eight-way valve |
-
2014
- 2014-04-28 CN CN201420209872.4U patent/CN203881727U/en not_active Withdrawn - After Issue
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103983722A (en) * | 2014-04-28 | 2014-08-13 | 华东师范大学 | A gas chromatograph for hydrocarbon component analysis of a catalytic cracking product of gasoline and diesel |
| CN103983722B (en) * | 2014-04-28 | 2015-06-24 | 华东师范大学 | A gas chromatograph for hydrocarbon component analysis of a catalytic cracking product of gasoline and diesel |
| CN104265952A (en) * | 2014-10-24 | 2015-01-07 | 北京佰纯润宇生物科技有限公司 | Eight-way valve and chromatographic system based on eight-way valve |
| CN104458978A (en) * | 2014-10-24 | 2015-03-25 | 北京佰纯润宇生物科技有限公司 | Five-position eight-way valve and chromatogram system based on five-position eight-way valve |
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|---|---|---|---|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| AV01 | Patent right actively abandoned |
Granted publication date: 20141015 Effective date of abandoning: 20150624 |
|
| RGAV | Abandon patent right to avoid regrant |