CN203779987U - Waterproof, moisture-permeable and anti-bacteria polyurethane fabric - Google Patents

Waterproof, moisture-permeable and anti-bacteria polyurethane fabric Download PDF

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Publication number
CN203779987U
CN203779987U CN201420191576.6U CN201420191576U CN203779987U CN 203779987 U CN203779987 U CN 203779987U CN 201420191576 U CN201420191576 U CN 201420191576U CN 203779987 U CN203779987 U CN 203779987U
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China
Prior art keywords
layer
polyurethane
base material
carbon fiber
film
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Expired - Fee Related
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CN201420191576.6U
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Chinese (zh)
Inventor
巫永裕
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KING-TEX TECHNOLOGIES (KUNSHAN) Co Ltd
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KING-TEX TECHNOLOGIES (KUNSHAN) Co Ltd
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Abstract

The utility model discloses a waterproof, moisture-permeable and anti-bacteria polyurethane fabric. The polyurethane fabric comprises a base material layer made of thermoplastic polyurethane (TPU) material, wherein a bamboo carbon fiber layer is arranged on one side of the base material layer, a porous polyurethane film and a carbon fiber filled polytetrafluoroethylene protective layer are arranged on the other side of the base material layer, the bamboo carbon fiber layer is bonded with the base material layer by a polyurethane glue layer, the porous polyurethane film is bonded with the base material layer by a silicon rubber layer, and the porous polyurethane film and the protective layer are bonded by a silicone-acrylic latex layer. According to the polyurethane fabric, the bamboo carbon fiber layer can effectively prevent bacteria, the porous polyurethane film has excellent water resisting property and can prevent moisture from entering the base material layer, the protective layer made of carbon fiber filled polytetrafluoroethylene protective layer has good abrasive resistance and improves the abrasive resistance of a composite film, the base material layer is made of a material with multi-micropore distribution, the porous polyurethane film has good gas permeability, so that the composite film has good moisture penetrability.

Description

A kind of Waterproof Breathable, fungi-proofing polyurethane fabric
Technical field
The utility model relates to weaving face fabric technical field, relates in particular to a kind of Waterproof Breathable, fungi-proofing polyurethane fabric.
Background technology
Polyurethane fabric (PU fabric) is a class artificial leather shell material, has the texture of corium, so the artificial leather that is otherwise known as.It is not only durable, and because the ripe price of artificial synthetic technology is comparatively cheap, is widely used at garment industry.The PU fabric of prior art is the fabric of single PU structure sheaf, and because PU fabric resistance to water is poor, thereby the clothes of PU fabric generally can not wash, and can only adopt dry-cleaning, have improved use cost.PU fabric gas permeability is poor, has reduced comfort level when PU fabric clothes is worn, for example, in the time wearing, perspire and cannot discharge.In addition, the poor and surperficial appearance be full of cracks of the wearability of PU fabric, the phenomenon coming off.Because the clothes of PU fabric are because of the erosion of external sweat and other spots, under the higher environment of temperature, easily breed bacteria etc., causes potential harm to human body skin etc.
Utility model content
In view of this, the utility model provides a kind of Waterproof Breathable, fungi-proofing polyurethane fabric, and this polyurethane fabric has stronger fungi-proofing property, preferably waterproof and moisture permeability and preferably wearability.
A kind of Waterproof Breathable, fungi-proofing polyurethane fabric; comprise the substrate layer of TPU material; one side of described substrate layer is provided with bamboo-carbon fibre layer; the opposite side of substrate layer is provided with the protective layer of porous polyurethane film and PTFE Filled with Carbon Fiber material; bamboo-carbon fibre layer and substrate layer are bonding by polyurethane glue-line; porous polyurethane film and substrate layer are bonding by silica gel layer, and porous polyurethane film and protective layer are bonding by silicon the third emulsion layer.
Wherein, the thickness of described bamboo-carbon fibre layer is 50~80 μ m.
Wherein, the thickness of described porous polyurethane film is 25~45 μ m.
Wherein, the thickness of described protective layer is 30~50 μ m.
Wherein, the thickness of described silica gel layer is 5~10 μ m.
Wherein, the thickness of described silicon the third emulsion layer is 2~6 μ m.
Wherein, the thickness of polyurethane glue-line is 4~8 μ m.
In polyurethane fabric of the present utility model, bamboo-carbon fibre layer can effectively prevent bacterium.Porous polyurethane film has more excellent resistance to water, has prevented that moisture from entering substrate layer; The PTFE Filled with Carbon Fiber material that protective layer adopts has good wearability, has improved the mar proof of composite membrane.Substrate layer contains the material that multiple micropores distribute, and porous polyurethane film has good gas permeability, and this makes composite membrane have good poisture-penetrability.
Brief description of the drawings
Fig. 1 is the structural representation of the preferred embodiment of the utility model polyurethane composite material.
In figure:
1-substrate layer; 2-silica gel layer; 3-porous polyurethane film; 4-silicon the third emulsion layer; 5-protective layer; 6-bamboo-carbon fibre layer; 7-polyurethane glue-line.
Detailed description of the invention
Further illustrate the technical solution of the utility model below in conjunction with drawings and Examples.
As shown in Figure 1, provided the structural representation of the utility model polyurethane composite membrane embodiment.Polyurethane composite membrane of the present utility model is mainly made up of substrate layer 1, bamboo-carbon fibre layer 6, porous polyurethane film 3 and protective layer 5.Bamboo-carbon fibre layer 6 is positioned at a side of substrate layer 1; Porous polyurethane film 3 and protective layer 5 are positioned at the opposite side of substrate layer 1.Between bamboo-carbon fibre layer 6 and substrate layer 1, be coated with polyurethane glue-line 7 with bonding both.Between substrate layer 1 and porous polyurethane film 3, be coated with silica gel layer 2, to reach the object that adheres to both.Between porous polyurethane film 3 and protective layer 5, be coated with silicon the third emulsion layer 4, to play the effect that adheres to both.
The thickness of bamboo-carbon fibre layer 6 is 50~80 μ m.Bamboo-carbon fibre material in bamboo-carbon fibre layer 6 is that to get mao bamboon be raw material, adopt pure oxygen high temperature and nitrogen to intercept calcining new technology and the new technology of time delay, more refinement and the honeycomb of micropore that bamboo charcoal is innately had, and then make with thering is the polyester modification section melt spinning of honeycomb microporous structure trend.Bamboo-carbon fibre has stronger antibacterial and bacteriostasis, can effectively reduce the breeding of avoiding in it of each bacterioid.Except this, bamboo-carbon fibre also has following benefit: the absorption affinity that (1) is superpower.Bamboo Charcoal Adsorption ability is the more than 5 times of charcoal, and the harmful substances such as PARA FORMALDEHYDE PRILLS(91,95), benzene, toluene, ammonia and dust can be brought into play absorption, decompose the effect of peculiar smell and smelly eliminating.(2) emitting far-infrared, heat accumulation thermal.Far infrared emissivity is up to 0.87, can heat accumulation thermal, and temperature rise speed is faster than common cotton fabric.(3) damping.High equilibrium moisture regain and water retention, given the function of bamboo-carbon fibre damping.(4) anion releasing.Bamboo-carbon fibre can be launched the anion of the concentration that is equivalent to field, countryside, is of value to health.(5) bamboo-carbon fibre contains potassium, calcium etc. and is of value to healthy mineral matter.
The thickness of substrate layer 1 is 370~670 μ m.Substrate layer 1 is TPU material.TPU material is thermoplastic polyurethane, has good wearability and elastic force, and except this, it also has certain resistance to antibiotic property, can be recycled, more environmental protection.The inside of substrate layer 1 is provided with multiple micropores.Micropore is existing through substrate layer 1 body, has again and is distributed in the surperficial of substrate layer 1.The average diameter of micropore is only hundreds of nanometer, and hydration gas is had to good general's property selected, and gets final product passing through of block water molecule, but allows passing through of gas molecule, and this makes to have good water-proof breathable properties.The density of the distribution of micropore is 40~500,000/square centimeter.What deserves to be explained is, those skilled in the art can know that how realizing substrate layer 1 arranges hole by prior art, for example the various of monomer (for example isocyanates and polyethers) of synthetic PU is poured in latticed mould into moulding at a certain temperature, the then demoulding.
The thickness of protective layer 5 is 30~50 μ m, for example, can be 30 μ m, 40 μ m or 50 μ m.Protective layer 5 is PTFE Filled with Carbon Fiber material.PTFE Filled with Carbon Fiber material is a kind of material obtaining in cavernous polytetrafluoroethylene (PTFE) with filled with carbon fibers.Carbon fiber has good mechanical stretching performance, the further wearability of reinforced TFE.
The thickness of porous polyurethane film 3 is 25~45 μ m.Porous polyurethane film 3 is to have many materials of nanometer level microporous 51, these nanometer level microporous 51 have specific size, liquid water and gaseous state hydrone are had higher selective, allow to pass through with the aqueous water of condensed state form, and prevention hydrone, this gives material with good moisture-inhibiting and water-resistance.In this example, two-layer porous polyurethane film 3 can make skin sweat distribute to external, stops outer 1 moisture endosmosis simultaneously.The preparation technology of porous polyurethane film 3 is specially: by the same PU resin quality in PU resin, 0.4~0.6% levelling agent and 0.4~0.6% help stripping agent be thoroughly mixed to form hybrid resin, by the quality meter of PU resin, 1~2% flatting silica is well-dispersed in organic solvent (by the quality in fire-type PU resin, 15~25% butanone, 15~25% toluene and 25~35%N, dinethylformamide forms) formation mixed liquor.Then, successively divide and be added to hybrid resin three times according to 30%, 30% and 40% addition.Then, glue is inserted and made in bubble machine foaming and form polyurethane foam, the condition foaming by control, reaches the size of the micropore of polyurethane foam.Finally, after polyurethane foam is coated in release liners, release liners is dried, obtains porous polyurethane film 3.
Silica gel layer 2 is to be formed by dry by the glue of organosiloxane composition, and it has preferably heatproof, chemical stability.Its thickness is 5~10 μ m.Silicon the third emulsion layer 4 for example, is formed by dry by silicone ingredients (organosiloxane) modified acrylic acid emulsion, and this emulsion has acrylic emulsion and organosilyl advantage concurrently.The thickness of silicon the third emulsion layer 4 is 2~6 μ m.The thickness of polyurethane glue-line 72 is 1~5 μ m.The thickness of polyurethane glue-line 7 is 4~8 μ m.The coating that polyurethane glue-line 7 forms through cold curing for polyurethane glue.Polyurethane glue is the glue that contains urethano and NCO in strand.Polyurethane glue, due to the isocyanates that contains strong polarity and carbamate groups, has very high reactivity.Great advantage is withstand shock vibrations and flexural fatigue, and peel strength is very high, and particularly resistance to low temperature is extremely excellent.
Polyurethane composite membrane of the present utility model has good water resistant, ventilative and wearability, has the wide using value of sending out and larger market prospects in clothes, rain gear field.
Should be noted that and understand, in the situation that not departing from accompanying claim spirit and scope of the present utility model required for protection, can make various amendments and improvement to the utility model of foregoing detailed description.Therefore, the scope of claimed technical scheme is not subject to the restriction of given any specific exemplary teachings.
Know-why of the present utility model has below been described in conjunction with specific embodiments.These are described is in order to explain principle of the present utility model, and can not be interpreted as by any way the restriction to the utility model protection domain.Based on explanation herein, those skilled in the art does not need to pay performing creative labour can associate other detailed description of the invention of the present utility model, within these modes all will fall into protection domain of the present utility model.

Claims (7)

1. a Waterproof Breathable, fungi-proofing polyurethane fabric, it is characterized in that, comprise the substrate layer (1) of TPU material, one side of described substrate layer (1) is provided with bamboo-carbon fibre layer (6), the opposite side of substrate layer (1) is provided with the protective layer (5) of porous polyurethane film (3) and PTFE Filled with Carbon Fiber material, bamboo-carbon fibre layer (6) is bonding by polyurethane glue-line (7) with substrate layer (1), porous polyurethane film (3) is bonding by silica gel layer (2) with substrate layer (1), porous polyurethane film (3) and protective layer (5) are bonding by silicon the third emulsion layer (4).
2. polyurethane fabric according to claim 1, is characterized in that, the thickness of described bamboo-carbon fibre layer (6) is 50~80 μ m.
3. polyurethane fabric according to claim 1, is characterized in that, the thickness of described porous polyurethane film (3) is 25~45 μ m.
4. polyurethane fabric according to claim 1, is characterized in that, the thickness of described protective layer (5) is 30~50 μ m.
5. polyurethane fabric according to claim 1, is characterized in that, the thickness of described silica gel layer (2) is 5~10 μ m.
6. polyurethane fabric according to claim 1, is characterized in that, the thickness of described silicon the third emulsion layer (4) is 2~6 μ m.
7. polyurethane fabric according to claim 1, is characterized in that, the thickness of described polyurethane glue-line (7) is 4~8 μ m.
CN201420191576.6U 2014-04-18 2014-04-18 Waterproof, moisture-permeable and anti-bacteria polyurethane fabric Expired - Fee Related CN203779987U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201420191576.6U CN203779987U (en) 2014-04-18 2014-04-18 Waterproof, moisture-permeable and anti-bacteria polyurethane fabric

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201420191576.6U CN203779987U (en) 2014-04-18 2014-04-18 Waterproof, moisture-permeable and anti-bacteria polyurethane fabric

Publications (1)

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CN203779987U true CN203779987U (en) 2014-08-20

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107776032A (en) * 2016-08-29 2018-03-09 江苏绿艳高分子材料有限公司 A kind of TPU film and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107776032A (en) * 2016-08-29 2018-03-09 江苏绿艳高分子材料有限公司 A kind of TPU film and preparation method thereof

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C14 Grant of patent or utility model
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CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20140820

Termination date: 20180418

CF01 Termination of patent right due to non-payment of annual fee