CN203754636U - Waste heat recovery device of coke oven ascension pipe - Google Patents

Waste heat recovery device of coke oven ascension pipe Download PDF

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Publication number
CN203754636U
CN203754636U CN201420065782.2U CN201420065782U CN203754636U CN 203754636 U CN203754636 U CN 203754636U CN 201420065782 U CN201420065782 U CN 201420065782U CN 203754636 U CN203754636 U CN 203754636U
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CN
China
Prior art keywords
fused salt
outlet
coke oven
communicated
molten salt
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201420065782.2U
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Chinese (zh)
Inventor
刘小平
张素军
李菊香
杨桂兰
王良虎
董人和
彭友谊
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NANJING HUADIAN ENERGY-SAVING AND ENVIRONMENTAL PROTECTION EQUIPMENT Co Ltd
Nanjing Tech University
Original Assignee
NANJING HUADIAN ENERGY-SAVING AND ENVIRONMENTAL PROTECTION EQUIPMENT Co Ltd
Nanjing Tech University
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Application filed by NANJING HUADIAN ENERGY-SAVING AND ENVIRONMENTAL PROTECTION EQUIPMENT Co Ltd, Nanjing Tech University filed Critical NANJING HUADIAN ENERGY-SAVING AND ENVIRONMENTAL PROTECTION EQUIPMENT Co Ltd
Priority to CN201420065782.2U priority Critical patent/CN203754636U/en
Application granted granted Critical
Publication of CN203754636U publication Critical patent/CN203754636U/en
Anticipated expiration legal-status Critical
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/14Thermal energy storage
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • Y02P20/129Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines

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  • Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)

Abstract

The utility model relates to a waste heat recovery device of a coke oven ascension pipe. The waste heat recovery device comprises an ascension pipe heat exchanger, an evaporator and a salt storage tank, wherein one end of the ascension pipe heat exchanger is a raw coke oven gas inlet communicated with an external ascension pipe, and the other end of the ascension pipe heat exchanger is a raw coke oven gas outlet; the evaporator comprises a soft water inlet and a steam outlet; a molten salt pump and an electric heater are arranged on the salt storage tank, and molten salt is filled in the salt storage tank; the salt storage tank comprises a first molten salt inlet and a first molten salt outlet; the ascension pipe heat exchanger comprises a heat exchange interlayer; the heat exchange interlayer comprises a second molten salt inlet and a second molten salt outlet; the evaporator comprises a heat exchange cavity; the heat exchange cavity comprises a third molten salt inlet and a third molten salt outlet; the first molten salt outlet is communicated with the second molten salt inlet by virtue of a pipeline; the second molten salt outlet is communicated with the third molten salt inlet by virtue of a pipeline; the third molten salt outlet is communicated with the first molten salt inlet by virtue of a pipeline; the molten salt pump comprises a liquid outlet pipe communicated with the first molten salt outlet. The waste heat recovery device disclosed by the utility model adopts the molten salt as a heat exchange medium, and can be used for smoothly realizing the effective recovery of heat brought out by raw coke oven gas.

Description

Coke oven coke oven uprising tube waste-heat recovery device
Technical field
The utility model relates to a kind of waste-heat recovery device, and especially a kind of coke oven coke oven uprising tube waste-heat recovery device, belongs to energy-conserving and environment-protective technical field.
Background technology
According to the applicant understood, coke oven can do high temperature carbonization processing to coal, it is converted to efficiently to the products such as coke, coke-oven gas, coal tar, crude benzol, is efficient energy transformation kiln.Hanker in coke oven expenditure, the heat of taking out of of 650 DEG C of-700 DEG C of raw gas accounts for 36%, has high recycling and is worth.At present, conventionally adopt cooling treatment process to realize the industrial application of raw gas, traditional technology is: spray a large amount of 70 DEG C of-75 DEG C of cyclic ammonia waters to high temperature raw gas and make its cooling, realize waste heat recovery, but this can cause high temperature raw gas to take heat out of wastes because of a large amount of evaporations of cyclic ammonia water.
In the eighties in 20th century, most of coke-oven plant of Japan once reclaims raw gas by thermal oil for upcast and takes heat out of: upcast is made jacket pipe by they, thermal oil is by jacket pipe and high temperature raw gas indirect heat exchange, heated high temperature heat conductive oil can be used for multiple use, for example ammonia still process, Doak Tar Oil, is dried into stove coal etc.Afterwards, China's Ji steel had once carried out similar test at five hole upcasts; The many enterprises such as China's Wuhan Iron and Steel Plant, Ma Gang, Anshan iron and steel plant, ripples steel, Beijing coke-oven plant, Shenyang coal gas two factories, this steel one iron, tafelberg coke-oven plant once adopted water vapor cooling technology to reclaim this part heat at upcast; In addition, Ye You enterprise adopt taking nitrogen as medium, with the method for high temperature raw gas indirect heat exchange.But more or less there is following problem in above the whole bag of tricks: the structure design of heat transfer process is unreasonable, circulation is unobstructed not, raw gas side wall surface tar bonds the problem of expanding with heat and contract with cold that causes stopping up raw gas passage, thermal oil coking and blocking thermal oil passage or can not effectively solve start-stop car and operational process.This makes above method or is difficult to successful implementation, or is difficult to realize gratifying effect.
Utility model content
Technical problem to be solved in the utility model is: overcome the problem that prior art exists, a kind of coke oven coke oven uprising tube waste-heat recovery device is provided, adopt fused salt as heat transferring medium, can realize smoothly raw gas is taken out of to hot efficient recovery.
The technical scheme in the invention for solving the technical problem is as follows:
A kind of coke oven coke oven uprising tube waste-heat recovery device, comprises upcast interchanger and vaporizer; Described upcast interchanger one end is that the raw gas import, the other end that are communicated with outside upcast are raw gas outlet, and described vaporizer has soft water import and vapour outlet; It is characterized in that, also comprise the storage salt cellar that is provided with pump for liquid salts and electric heater, in described storage salt cellar, be mounted with fused salt; Described storage salt cellar has the first fused salt entrance and the outlet of the first fused salt; Described upcast interchanger has heat exchanging interlayer, and described heat exchanging interlayer has the second fused salt entrance and the outlet of the second fused salt; Described vaporizer has heat exchanging chamber, and described heat exchanging chamber has the 3rd fused salt entrance and the outlet of the 3rd fused salt; Described the first fused salt outlet is communicated with the second fused salt entrance through pipeline, and described the second fused salt outlet is communicated with the 3rd fused salt entrance through pipeline, and described the 3rd fused salt outlet is communicated with the first fused salt entrance through pipeline; Described pump for liquid salts has with the first fused salt and exports the drain pipe being communicated with.
When use, in storage salt cellar, fused salt is heated to liquid state by electric heater becomes low-temperature molten salt, by pump for liquid salts, low-temperature molten salt is sent into the heat exchanging interlayer of upcast interchanger; Meanwhile, raw gas continues by upcast interchanger, with the low-temperature molten salt heat exchange in upcast interchanger heat exchanging interlayer, become high-temperature molten salt, high-temperature molten salt enters vaporizer through pipeline, becomes low-temperature molten salt after soft water is added to thermogenesis steam, and gets back to storage salt cellar.
The utility model further perfect technical scheme is as follows:
Preferably, described upcast interchanger comprises the inner and outer tubes of coaxially nested and vertical placement, forms the heat exchanging interlayer of sealing between described inner and outer tubes; Described the second fused salt entrance is positioned at outer tube bottom, and described the second fused salt outlet is positioned at outer tube top; The two ends up and down of described upcast interchanger are respectively equipped with flange; The flange of described upcast interchanger upper end is connected through expansion joint and inner tube.
More preferably, described inner tube wall is provided with one group of vertical straight fins radially extending along inner tube; Described outer wall of inner tube is provided with the helical fin coaxial with inner tube.
Adopt after this structure, straight fins can strengthen radiation and the convective heat exchange of raw gas; Helical fin can make fused salt spiral in heat exchanging interlayer, improves heat exchange efficiency; Expansion joint can be alleviated expanding with heat and contract with cold of upcast interchanger.In addition, in this structure, fused salt and raw gas lead to following current and flow, and can make inner tube wall temperature keep evenly.
Preferably, described vaporizer also has drum and water pot, and described drum is positioned at heat exchanging chamber top, and described water pot is positioned at heat exchanging chamber below; Described soft water import is positioned at drum bottom, and described vapour outlet is positioned at drum top; Described drum is communicated with water pot through the one group vertical pipeline through heat exchanging chamber; Described the 3rd fused salt entrance is positioned at heat exchanging chamber bottom, and described the 3rd fused salt outlet is positioned at heat exchanging chamber top; In described heat exchanging chamber, be also provided with traverse baffle.
More preferably, described soft water import is communicated with soft water source through the pipeline that is provided with water pump; Described water pot bottom is provided with water port.
In this structure, soft water enters vaporizer drum bottom through water pump, and enters in water pot by pipeline under own wt effect; Along with soft water is cumulative in water pot, soft water enters pipeline, and in heat exchanging chamber under the heating of fused salt boiling produce steam water interface, steam water interface is isolated steam after entering drum, steam is discharged by vapour outlet.
Preferably, described storage salt cellar is horizontal placement and is positioned at the below of upcast interchanger and vaporizer, and described electric heater is positioned at the bottom of storage salt cellar, the vertical placement of described pump for liquid salts; Described the first fused salt entrance, the first fused salt outlet lay respectively at storage salt tank top; Described storage salt tank top also has nitrogen pressurization mouthful.
In this structure, storage salt cellar is positioned at the below of complete assembly, in all fused salts when ensureing to stop in system pipeline can pass back into smoothly; Electric heater is heated to liquid state fused salt, by pump for liquid salts, fused salt is pumped to the first fused salt and exports; Can make to store up maintenance in salt cellar in nitrogen pressurization mouthful with nitrogen pressurization, a little more than atmospheric pressure-fired, by effectively isolated to fused salt and atmospheric environment, avoids fused salt rotten.
Preferably, the second fused salt entrance of described upcast interchanger is also communicated with the first fused salt entrance of storage salt cellar through the valvular pipeline of tool; The heat exchanging chamber bottom of described vaporizer is provided with fused salt relief outlet, and described fused salt relief outlet is communicated with the first fused salt entrance of storage salt cellar through the valvular pipeline of tool; Be communicated with the first fused salt outlet and the second fused salt entrance pipeline, is communicated with that the 3rd fused salt exports and the pipeline of the first fused salt entrance has respectively valve.
In this structure, equipment stop or other situation under, can by control each valve unlatching, close, make in vaporizer heat exchanging chamber, fused salt in upcast interchanger heat exchanging interlayer gets back in storage salt cellar smoothly, avoid causing line clogging because of fused salt cooling curing.
The utility model innovation ground is used for reclaiming raw gas waste heat by fused salt, and to this specialized designs support equipment, enable smooth enforcement, efficient recovery raw gas waste heat, simultaneously can avoid occurring that thermal oil meets in the easy coking of high temperature, water vapor technology steam and be prone to the problems such as circulation is not smooth.
The utility model is arranged heat absorbing units (upcast interchanger) and heat release unit (vaporizer) point, belong to separate type, on the one hand because coke oven top is typically provided with tens upcasts, the corresponding multiple heat absorbing units in an available heat release unit, even tens heat absorbing units share a heat release unit, make whole device simpler; On the other hand, be in operation and occur if you have questions easily differentiating, and carry out independent maintenance process.
The utility model waste heat recovery amount is larger, and steam production is larger, even can produce superheated vapour, can be used for multiple industrial use, even can be directly used in turbine driven set and generate electricity.
Brief description of the drawings
Fig. 1 is the structural representation of the utility model embodiment 1, and the arrow in figure represents fluid flow direction.
Fig. 2 is the structural representation of Fig. 1 embodiment upcast interchanger, and the arrow in figure represents fluid flow direction.
Fig. 3 is the vertical view of Fig. 2.
Fig. 4 is the structural representation of Fig. 1 embodiment vaporizer, and the arrow in figure represents fluid flow direction.
Embodiment
With reference to the accompanying drawings and in conjunction with the embodiments the utility model is described in further detail.But the utility model is not limited to given example.
Embodiment 1
The coke oven coke oven uprising tube interchanger waste-heat recovery device basic structure of the present embodiment as shown in Figure 1, comprises upcast interchanger 2 and vaporizer 3; Upcast interchanger 2 one end are that raw gas import 2-1, the other end are raw gas outlet 2-2, and vaporizer 3 has soft water import 3-1 and vapour outlet 3-2.
Also comprise the storage salt cellar 1 that is provided with pump for liquid salts 1-1 and electric heater 1-2, in storage salt cellar 1, be mounted with fused salt; Storage salt cellar 1 has the first fused salt entrance 1-3 and the first fused salt outlet 1-4; Upcast interchanger 2 has heat exchanging interlayer, and heat exchanging interlayer has the second fused salt entrance 2-3 and the second fused salt outlet 2-4; Vaporizer 3 has heat exchanging chamber 3-3, and heat exchanging chamber 3-3 has the 3rd fused salt entrance 3-4 and the 3rd fused salt outlet 3-5; The first fused salt outlet 1-4 is communicated with the second fused salt entrance 2-3 through pipeline 4-1, and the second fused salt outlet 2-4 is communicated with the 3rd fused salt entrance 3-4 through pipeline 4-2, and the 3rd fused salt outlet 3-5 is communicated with the first fused salt entrance 1-3 through pipeline 4-3; Pump for liquid salts 1-1 has the drain pipe 1-5 being communicated with the first fused salt outlet 1-4.
As shown in Figures 2 and 3, upcast interchanger 2 comprises inner tube 2-5 and the outer tube 2-6 of coaxially nested and vertical placement, forms the heat exchanging interlayer of sealing between inner tube 2-5 and outer tube 2-6; The second fused salt entrance 2-3 is positioned at outer tube 2-6 bottom, and the second fused salt outlet 2-4 is positioned at outer tube 2-6 top; The two ends up and down of upcast interchanger 2 are respectively equipped with flange 2-7,2-8; The flange 2-7 of upcast interchanger 2 upper ends is connected through expansion joint 2-9 and inner tube 2-5.Inner tube 2-5 inwall is provided with one group of vertical straight fins 2-10 radially extending along inner tube 2-5; Inner tube 2-5 outer wall is provided with the helical fin 2-11 coaxial with inner tube 2-5.
As shown in Figure 4, vaporizer 3 also has drum 3-6 and water pot 3-7, and drum 3-6 is positioned at heat exchanging chamber 3-3 top, and water pot 3-7 is positioned at heat exchanging chamber 3-3 below; Soft water import 3-1 is positioned at drum 3-6 bottom, and vapour outlet 3-2 is positioned at drum 3-6 top; Drum 3-6 is communicated with water pot 3-7 through the one group vertical pipeline 3-8 through heat exchanging chamber 3-3; The 3rd fused salt entrance 3-4 is positioned at heat exchanging chamber 3-3 bottom, and the 3rd fused salt outlet 3-5 is positioned at heat exchanging chamber 3-3 top; In heat exchanging chamber 3-3, be also provided with traverse baffle 3-9.Soft water import 3-1 is communicated with soft water source 6 through the pipeline 4-4 that is provided with water pump 5; Water pot 3-7 bottom is provided with water port 3-10.
Storage salt cellar 1 is horizontal placement and is positioned at upcast interchanger 2 and the below of vaporizer 3, and electric heater 1-2 is positioned at the bottom of storage salt cellar 1, the vertical placement of pump for liquid salts 1-1; The first fused salt entrance 1-3, the first fused salt outlet 1-4 lay respectively at storage salt cellar 1 top; Storage salt cellar 1 top also has nitrogen pressurization mouthful 1-7.
The second fused salt entrance 2-3 of upcast interchanger 2 is also communicated with the first fused salt entrance 1-3 of storage salt cellar 1 through the pipeline 4-5 with valve 5-1; The heat exchanging chamber 3-3 bottom of vaporizer 3 is provided with fused salt relief outlet 3-11, and fused salt relief outlet 3-11 is communicated with the first fused salt entrance 1-3 of storage salt cellar 1 through the pipeline 4-6 with valve 5-2; Be communicated with the first fused salt outlet 1-4 and the second fused salt entrance 2-3 pipeline 4-1, be communicated with the pipeline 4-3 that the 3rd fused salt exports 3-5 and the first fused salt entrance 1-3 and there is respectively valve 5-3,5-4.
In addition the fused salt that, the present embodiment adopts is by saltpetre, Sodium Nitrite and the SODIUMNITRATE ternary fused salt that 53%:40%:7% forms by weight percentage.
Fused salt, in liquid operating temperature range the highest can be~500 DEG C, improved nearly 200 DEG C, and the inlet temperature of raw gas has conventionally~800 DEG C than the working temperature of heat conduction wet goods heating agent, and this makes fused salt more can adapt to coke oven coke oven uprising tube waste heat recovery than other heating agent.
It should be noted that, fused salt is not innovation of the present utility model, and those skilled in the art can adopt other fused salt of the prior art to make the present embodiment device realize smoothly its function of recovering waste heat completely.
In addition to the implementation, the utility model can also have other embodiments.All employings are equal to the technical scheme of replacement or equivalent transformation formation, all drop on the protection domain of the utility model requirement.

Claims (7)

1. a coke oven coke oven uprising tube waste-heat recovery device, comprises upcast interchanger and vaporizer; Described upcast interchanger one end is that the raw gas import, the other end that are communicated with outside upcast are raw gas outlet, and described vaporizer has soft water import and vapour outlet; It is characterized in that, also comprise the storage salt cellar that is provided with pump for liquid salts and electric heater, in described storage salt cellar, be mounted with fused salt; Described storage salt cellar has the first fused salt entrance and the outlet of the first fused salt; Described upcast interchanger has heat exchanging interlayer, and described heat exchanging interlayer has the second fused salt entrance and the outlet of the second fused salt; Described vaporizer has heat exchanging chamber, and described heat exchanging chamber has the 3rd fused salt entrance and the outlet of the 3rd fused salt; Described the first fused salt outlet is communicated with the second fused salt entrance through pipeline, and described the second fused salt outlet is communicated with the 3rd fused salt entrance through pipeline, and described the 3rd fused salt outlet is communicated with the first fused salt entrance through pipeline; Described pump for liquid salts has with the first fused salt and exports the drain pipe being communicated with.
2. coke oven coke oven uprising tube waste-heat recovery device according to claim 1, is characterized in that, described upcast interchanger comprises the inner and outer tubes of coaxially nested and vertical placement, forms the heat exchanging interlayer of sealing between described inner and outer tubes; Described the second fused salt entrance is positioned at outer tube bottom, and described the second fused salt outlet is positioned at outer tube top; The two ends up and down of described upcast interchanger are respectively equipped with flange; The flange of described upcast interchanger upper end is connected through expansion joint and inner tube.
3. coke oven coke oven uprising tube waste-heat recovery device according to claim 2, is characterized in that, described inner tube wall is provided with one group of vertical straight fins radially extending along inner tube; Described outer wall of inner tube is provided with the helical fin coaxial with inner tube.
4. coke oven coke oven uprising tube waste-heat recovery device according to claim 1, is characterized in that, described vaporizer also has drum and water pot, and described drum is positioned at heat exchanging chamber top, and described water pot is positioned at heat exchanging chamber below; Described soft water import is positioned at drum bottom, and described vapour outlet is positioned at drum top; Described drum is communicated with water pot through the one group vertical pipeline through heat exchanging chamber; Described the 3rd fused salt entrance is positioned at heat exchanging chamber bottom, and described the 3rd fused salt outlet is positioned at heat exchanging chamber top; In described heat exchanging chamber, be also provided with traverse baffle.
5. coke oven coke oven uprising tube waste-heat recovery device according to claim 4, is characterized in that, described soft water import is communicated with soft water source through the pipeline that is provided with water pump; Described water pot bottom is provided with water port.
6. coke oven coke oven uprising tube waste-heat recovery device according to claim 1, is characterized in that, described storage salt cellar is horizontal placement and is positioned at the below of upcast interchanger and vaporizer, and described electric heater is positioned at the bottom of storage salt cellar, the vertical placement of described pump for liquid salts; Described the first fused salt entrance, the first fused salt outlet lay respectively at storage salt tank top; Described storage salt tank top also has nitrogen pressurization mouthful.
7. according to the coke oven coke oven uprising tube waste-heat recovery device described in claim 1 to 6 any one, it is characterized in that, the second fused salt entrance of described upcast interchanger is also communicated with the first fused salt entrance of storage salt cellar through the valvular pipeline of tool; The heat exchanging chamber bottom of described vaporizer is provided with fused salt relief outlet, and described fused salt relief outlet is communicated with the first fused salt entrance of storage salt cellar through the valvular pipeline of tool; Be communicated with the first fused salt outlet and the second fused salt entrance pipeline, is communicated with that the 3rd fused salt exports and the pipeline of the first fused salt entrance has respectively valve.
CN201420065782.2U 2014-02-14 2014-02-14 Waste heat recovery device of coke oven ascension pipe Expired - Fee Related CN203754636U (en)

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Application Number Priority Date Filing Date Title
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103756692A (en) * 2014-02-14 2014-04-30 南京华电节能环保设备有限公司 Riser waste heat recovery device for coke oven
CN104266159A (en) * 2014-09-29 2015-01-07 南京竣业过程机械设备有限公司 Waste heat recovery technology for crude gas of novel coke oven
CN105371260A (en) * 2015-12-10 2016-03-02 南京华电节能环保设备有限公司 Heat source intermittent input and steam continuous output afterheat boiler system

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103756692A (en) * 2014-02-14 2014-04-30 南京华电节能环保设备有限公司 Riser waste heat recovery device for coke oven
CN103756692B (en) * 2014-02-14 2015-11-25 南京华电节能环保设备有限公司 Riser waste heat recovery device for coke oven
CN104266159A (en) * 2014-09-29 2015-01-07 南京竣业过程机械设备有限公司 Waste heat recovery technology for crude gas of novel coke oven
CN104266159B (en) * 2014-09-29 2016-09-28 南京竣业过程机械设备有限公司 A kind of waste heat of coke oven crude gas recovery process
CN105371260A (en) * 2015-12-10 2016-03-02 南京华电节能环保设备有限公司 Heat source intermittent input and steam continuous output afterheat boiler system

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Granted publication date: 20140806

Termination date: 20160214