CN203733895U - Opening forming device of lithium titanate battery - Google Patents
Opening forming device of lithium titanate battery Download PDFInfo
- Publication number
- CN203733895U CN203733895U CN201420004394.3U CN201420004394U CN203733895U CN 203733895 U CN203733895 U CN 203733895U CN 201420004394 U CN201420004394 U CN 201420004394U CN 203733895 U CN203733895 U CN 203733895U
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- Prior art keywords
- air
- battery
- bag
- closed container
- lithium titanate
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title claims abstract description 29
- 229910052744 lithium Inorganic materials 0.000 title claims abstract description 29
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 title claims abstract description 28
- 238000002347 injection Methods 0.000 claims abstract description 21
- 239000007924 injection Substances 0.000 claims abstract description 21
- 239000007788 liquid Substances 0.000 claims abstract description 19
- 238000011084 recovery Methods 0.000 claims abstract description 16
- 230000015572 biosynthetic process Effects 0.000 claims description 34
- 239000002775 capsule Substances 0.000 claims description 21
- 239000007789 gas Substances 0.000 abstract description 23
- 238000000034 method Methods 0.000 abstract description 14
- 239000002912 waste gas Substances 0.000 abstract description 6
- 230000008569 process Effects 0.000 abstract description 4
- 239000000463 material Substances 0.000 description 11
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 7
- 239000003792 electrolyte Substances 0.000 description 7
- 229910001416 lithium ion Inorganic materials 0.000 description 7
- 230000004913 activation Effects 0.000 description 6
- 206010016766 flatulence Diseases 0.000 description 6
- 239000000126 substance Substances 0.000 description 5
- 230000002194 synthesizing effect Effects 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 238000005086 pumping Methods 0.000 description 4
- 230000004087 circulation Effects 0.000 description 3
- OVAQODDUFGFVPR-UHFFFAOYSA-N lithium cobalt(2+) dioxido(dioxo)manganese Chemical compound [Li+].[Mn](=O)(=O)([O-])[O-].[Co+2] OVAQODDUFGFVPR-UHFFFAOYSA-N 0.000 description 3
- 238000007789 sealing Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 210000000170 cell membrane Anatomy 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- QHGJSLXSVXVKHZ-UHFFFAOYSA-N dilithium;dioxido(dioxo)manganese Chemical compound [Li+].[Li+].[O-][Mn]([O-])(=O)=O QHGJSLXSVXVKHZ-UHFFFAOYSA-N 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 238000005247 gettering Methods 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Hybrid Cells (AREA)
Abstract
The utility model discloses an opening forming device of a lithium titanate battery. The opening forming device comprises a forming cabinet, a closed container and an air exhausting device, wherein the forming cabinet comprises an anode test line and a cathode test line which are used for being connected with an anode and a cathode of the battery; the closed container is used for containing the battery and the air exhausting device; the air exhausting device comprises an air bag, a recovery bag and an air valve, the air bag comprises an air inlet and an air outlet, the air inlet of the air bag is connected with a liquid injection hole of the battery, the recovery bag comprises an air inlet and an air outlet, and the air inlet of the recovery bag is connected with the air outlet of the air bag through the air valve. By utilizing the opening forming device of the lithium titanate battery, the generated gas can be timely exhausted, so that the problems of gas expansion and the like in a later use process are avoided; furthermore, the waste gas generated in a forming process of the battery is sequentially transmitted into the air bag and the recovery bag and is communicated with the outside through the recovery bag, so that the battery is not directly contacted with air, and the moisture and the like in the air cannot enter the battery to influence the battery.
Description
Technical field
The utility model relates to lithium ion battery and manufactures field, particularly relates to a kind of lithium titanate battery open formation device.
Background technology
At present, the lithium ion battery that the lithium titanate of take is prepared as negative material because having extended cycle life, good rate capability, rapid charging performance is good and security performance is good etc., and advantage is received researcher's extensive concern, has become the focus of current concern.
In lithium titanate battery practical study, because the embedding lithium current potential of lithium titanate is high, more than 1 volt, according to chemical synthesizing method in the past, plasma membrane can not produce electrolysis when changing into.In actual use, easily produce overpotential, lithium ion battery negative current potential is dropped to below 1V, cause lithium titanate and electrolyte reaction decomposes to produce gas and cannot discharge and cause inflatable, and then affect capacity and the cycle performance of battery.
At present, the most employing of researcher added additive or gettering material to improve lithium titanate flatulence problem in electrolyte.Though there is certain effect, additive is higher to purity requirement, and may bring energy density reduce and disperse inhomogeneous problem, is unfavorable for the practical application of industrialization.
Summary of the invention
For above-mentioned prior art present situation, technical problem to be solved in the utility model is, a kind of lithium titanate battery open formation device is provided, and it can be extracted the gas producing out, and can avoid moisture in air to enter in battery.
In order to solve the problems of the technologies described above, a kind of lithium titanate battery open formation device provided by the utility model, comprise formation cabinet, described formation cabinet includes anodal p-wire and negative pole p-wire, described formation device also comprises closed container and air extractor, described closed container is used for holding battery, and described anodal p-wire is connected with negative pole with the positive pole of battery in described closed container respectively with described negative pole p-wire; Described air extractor comprises air bag, reclaims capsule and air valve, described air bag, recovery capsule and air valve are contained in described closed container, described air bag has air inlet and gas outlet, the air inlet of described air bag is for being connected with the liquid injection port of battery, described recovery capsule has air inlet and gas outlet, and the air inlet of described recovery capsule is connected with the gas outlet of described air bag by described air valve.
In an embodiment, described device also comprises air pump therein, and described air pump is arranged at outside described closed container, and the air inlet of described air pump is connected with the gas outlet of described recovery capsule.
Lithium titanate battery open formation device of the present utility model, can be in time extracts the gas producing out, avoids in later use procedure the problems such as flatulence; And the waste gas producing in battery when battery changes into first imports air bag into, and then pass to and reclaim in capsule, by reclaiming capsule and the external world, contact, so battery is not directly connected with air, avoided water in air to grade and entered in battery, battery is exerted an influence.
Accompanying drawing explanation
Fig. 1 is the schematic diagram of the lithium titanate battery open formation device in one of them embodiment of the utility model;
Fig. 2 is the schematic diagram of the lithium titanate battery open formation device in another embodiment of the utility model;
Fig. 3 is according to the room temperature cycle performance of the lithium titanate battery A-1 of the open formation method activation in the utility model embodiment 1 (B-1 is the battery of usual manner activation, as a comparison reference).
In Fig. 1,2,10, formation cabinet; 20, battery; 21, liquid injection port; 30, air extractor; 31, air bag; 32, air valve; 33, reclaim capsule; 34, air pump; 40, closed container.
Embodiment
Below with reference to accompanying drawing, also the utility model is elaborated in conjunction with the embodiments.It should be noted that, in the situation that not conflicting, the feature in following embodiment and embodiment can combine mutually.
Figure 1 shows that the schematic diagram of the lithium titanate battery open formation device in one of them embodiment of the utility model, open formation device comprises formation cabinet 10, closed container 40 and air extractor 30, wherein, described formation cabinet 10 adopts the formation cabinet of prior art, and it includes anodal p-wire (not shown) and negative pole p-wire (not shown).More preferably, closed container 40 is high temperature oven.Described air extractor 30 is contained in described closed container 40, the waste gas producing while changing into for taking battery 20 away.Described air extractor 30 comprises air bag 31, reclaims capsule 33 and air valve 32, described air bag 31 has air inlet and gas outlet, the air inlet of described air bag 31 is for being connected with the liquid injection port 21 of battery 20, described recovery capsule 33 has air inlet and gas outlet, and the air inlet of described recovery capsule 33 is connected with the gas outlet of described air bag 31 by described air valve 32.While changing into, close gas check valve 32, like this, the waste gas producing in battery 20 formation processes enters in air bag 31; When needs are bled, open air valve 32, the waste gas in air bag 31 enters and reclaims in capsule 33, then by reclaiming capsule 33, discharges, and battery 20 is not directly connected with air, has avoided water in air to grade and has entered in battery 20, and battery 20 is exerted an influence.
Figure 2 shows that the schematic diagram of the lithium titanate battery open formation device in another embodiment of the utility model, different being from lithium titanate battery open formation device in above-described embodiment, described air extractor 30 also comprises air pump 34, described air pump 34 is arranged at outside described closed container 40, and the air inlet of described air pump 34 is connected with the gas outlet of described recovery capsule 33.By air pump 34, fast the waste gas reclaiming in capsule 33 is discharged.
The open formation method of lithium titanate battery of the present utility model, adopts above-mentioned open formation device, and described battery 20 be take lithium titanate as negative material, and described open formation method comprises the following steps:
Step S1, battery 20 is carried out to fluid injection, after fluid injection, under the first preset temperature T1, shelve the first preset time t 1, to guarantee that electrolyte fully infiltrates battery pole piece.
Step S2, described battery is placed in to described closed container 40, the liquid injection port of described battery 20 21 is connected with air bag 31 air inlets of the air extractor 30 of described open formation device, and close described air valve 32, the positive pole of described battery 20 is connected with described negative pole p-wire with described anodal p-wire respectively with negative pole; The temperature of controlling closed container 40 is the second preset temperature T2, then under this second preset temperature T2, shelve the second preset time t 2, so that battery 20 the inside impurity fully react, reach the effect of removing the inner trace water of battery 20 and other impurity, thereby solve the problem that occurs flatulence in battery 20 later stages use.
Step S3, the temperature of controlling described closed container 40 are the 3rd preset temperature T3, under the 3rd preset temperature T3 to described battery 20 with the first predetermined current I1 constant current charge to the first cut-ff voltage U1, and with described the first cut-ff voltage U1 constant voltage charge the 3rd preset time t 3.
Step S4, the temperature of described closed container 40 is reduced to the 4th preset temperature T4, opens described closed container 40, open 32 pairs of described batteries 20 of described air valve and reduce pressure and bleed, after having bled, close described air valve 32, close described closed container 40.
Step S5, control described closed container 40 temperature to described the 3rd preset temperature T3, to described battery 20 with the second predetermined current I2 constant-current discharge to the second cut-ff voltage U2, and with described the second cut-ff voltage U2 constant voltage discharge the 4th preset time t 4, then standing the 5th preset time t 5, described the second predetermined current I2 is less than described the first predetermined current I1.
Step S6, to described battery 20 with the 3rd predetermined current I3 constant current charge to the three predeterminated voltage U3, and with described the 3rd predeterminated voltage U3 constant voltage charge to the four predetermined current I4 or constant voltage charge the 6th preset time t 6, then standing the 7th preset time t 7, described the 3rd predetermined current I3 is less than described the first predetermined current I1.
Step S7, repeat the step S5-step S6 of preset times;
Step S8, the temperature of described closed container 40 is reduced to the 4th preset temperature T4, open described closed container 40, open the air valve 32 of described air extractor 30, described battery 20 is reduced pressure and bled, after having bled, the liquid injection port 21 of described battery 20 is done to encapsulation process.Wherein, liquid injection port 21 sealing means are steel ball sealing, laser welded seal, one or more in the sealing means such as screw-threaded coupling.
Below in conjunction with specific embodiment, further illustrate the open formation method of lithium titanate battery 20 of the present utility model.
Embodiment mono-:
Positive electrode: nickle cobalt lithium manganate, negative material: lithium titanate, aluminum shell column lithium ion battery 20.
Battery 20 is carried out after vacuum pumping liquid injection, at 20 ℃, more than standing 48h, guarantee that battery 20 the inside gases are pumped, pole piece is fully infiltrated by electrolyte.
After standing, battery 20 is placed in high temperature oven, air bag 31 air inlets of air extractor in above-described embodiment are connected with the liquid injection port 21 of battery 20, close gas check valve 32, the anodal p-wire of formation cabinet 10 and negative pole p-wire are connected respectively to positive pole and the negative pole of battery 20, close high temperature oven; High temperature oven is warmed up to 60 ℃, the standing 2h of constant temperature, the temperature of then adjusting high temperature oven is 80 ℃, with the electric current constant current charge of 3C to 1.8V, then constant voltage charge 6h; High temperature oven is cooled to 20 ℃, opens high temperature oven chamber door, and the air valve of air extractor 30 32 is opened, the interior gas of air bag 31 is flowed out and reclaims capsule; After having bled, close the air valve 32 of air extractor 30, close high temperature oven chamber door, then the temperature of adjusting high temperature oven is 40 ℃, then proceeds second step activation, and little electric current 1.5C constant current charge is to 2.7V, constant voltage charge 5min again, after standing 5min, with little electric current 1C constant current charge to 2.7V, then constant voltage charge 5min, then standing 5min, repeat 2 times, activate completely, battery 20 is sealed.
Embodiment bis-:
Anodal: nickle cobalt lithium manganate ternary material, negative pole: lithium titanate material, aluminum shell column lithium ion battery battery 20.
Battery 20 is carried out after vacuum pumping liquid injection, and standing 10h at 45 ℃, guarantees that battery 20 the inside gases are pumped, and pole piece is fully infiltrated by electrolyte.
After standing, battery 20 is placed in high temperature oven, the liquid injection port 21 of battery 20 is turned on, with tracheae 30, the liquid injection port of battery 20 21 is connected to air bag 31 air inlets of the air extractor 30 in above-described embodiment, then the positive pole of battery 20 and negative pole is connected respectively to anodal p-wire and the negative pole p-wire of formation cabinet 10, high temperature oven is warmed up to 90 ℃, the standing 10min of constant temperature, then the temperature of adjusting high temperature oven is 120 ℃, with the electric current constant current charge of 1C to 2.7V, then constant voltage charge 1h; High temperature oven is cooled to 40 ℃, opens high temperature oven chamber door, and the air valve of air extractor 30 32 is opened, bleed off the gas in the air bag 31 of the inside; After having bled, close the air valve 32 of air extractor 30, close warm baking oven chamber door, then the temperature of adjusting high temperature oven is 120 ℃, then proceeds second step activation, and little electric current 0.3C constant current charge is to 2.7V, constant voltage charge 100min again, after standing 60min, with little electric current 0.05C constant current charge to 2.7V, then constant voltage charge 30min, then standing 30min, repeat 6 times, activate completely, battery 20 is sealed.
Embodiment tri-:
Positive electrode: lithium manganate material, negative material: lithium titanate material, aluminum shell column lithium ion battery 20.
Battery 20 is carried out after vacuum pumping liquid injection, at 30 ℃, more than standing 120h, guarantee that battery 20 the inside gases are pumped, pole piece is fully infiltrated by electrolyte.
After standing, battery 20 is placed in high temperature oven, the liquid injection port 21 of battery 20 is turned on, with tracheae 30, the liquid injection port of battery 20 21 is connected to air bag 31 air inlets of the air extractor 30 in above-described embodiment, then the positive pole of battery 20 and negative pole is connected respectively to anodal p-wire and the negative pole p-wire of formation cabinet 10, high temperature oven is warmed up to 60 ℃, the standing 120h of constant temperature, then the temperature of adjusting high temperature oven is 60 ℃, with the electric current constant current charge of 2C to 1.8V, then constant voltage charge 120h; High temperature oven is cooled to 20 ℃, opens high temperature oven chamber door, and the air valve of air extractor 30 32 is opened, bleed off the gas in the air bag 31 of the inside; After having bled, close the air valve 32 of air extractor 30, close warm baking oven chamber door, then the temperature of adjusting high temperature oven is 60 ℃, then proceeds second step activation, and little electric current 0.05C constant current charge is to 1.8V, constant voltage charge 5h again, after standing 60min, with little electric current 0.05C constant current charge to 1.8V, then constant voltage charge 5h, then standing 60min, repeat 6 times, activate completely, battery 20 is sealed.
Embodiment tetra-:
Anodal: nickle cobalt lithium manganate ternary material, negative pole: lithium titanate material, aluminum shell column lithium ion battery 20.
Battery 20 is carried out after vacuum pumping liquid injection, at 40 ℃, more than standing 80h, guarantee that battery 20 the inside gases are pumped, pole piece is fully infiltrated by electrolyte.
After standing, battery 20 is placed in high temperature oven, the liquid injection port 21 of battery 20 is turned on, with tracheae 30, the liquid injection port of battery 20 21 is connected to air bag 31 air inlets of the air extractor 30 in above-described embodiment, then the positive pole of battery 20 and negative pole is connected respectively to anodal p-wire and the negative pole p-wire of formation cabinet 10, high temperature oven is warmed up to 80 ℃, the standing 10h of constant temperature, then the temperature of adjusting high temperature oven is 100 ℃, with the electric current constant current charge of 1C to 2.7V, then constant voltage charge 40h; High temperature oven is cooled to 40 ℃, opens high temperature oven chamber door, and the air valve of air extractor 30 32 is opened, bleed off the gas in the air bag 31 of the inside; After having bled, close the air valve 32 of air extractor 30, close warm baking oven chamber door, then the temperature of adjusting high temperature oven is 80 ℃, then proceeds second step activation, and little electric current 1C constant current charge is to 2.7V, constant voltage charge 1h again, after standing 30min, with little electric current 0.1C constant current charge to 2.7V, then constant voltage charge 3h, then standing 60min, repeat 3 times, activate completely, battery 20 is sealed.
For ease of better understanding the difference that adopts this chemical synthesizing method and common chemical synthesizing method, adopt after the chemical synthesizing method described in embodiment tetra-battery to change into rear battery with employing conventional method and carry out cycle performance contrast.Adopt traditional handicraft to change into the traditional handicraft that rear battery adopts to be: 1C constant current charge is to adopting after cut-ff voltage cut-off current or constant voltage time for as stop condition at normal temperatures.Fig. 3 is that two batteries are at the identical circulation discharge curve discharging and recharging under condition.As shown in Figure 3, adopt the battery after traditional handicraft chemical synthesizing method, after 600 circulations of experience, its discharge capacity of the cell is down to 85% left and right of battery raw capacity, and occurs the phenomenon of flatulence; And adopt after 1250 circulations of battery experience of this chemical synthesis technology, its discharge capacity still remains on 97%, does not occur flatulence phenomenon.This shows to adopt this chemical synthesis technology can better prevent flatulence, better improves the cycle performance of battery.
The above embodiment has only expressed several execution mode of the present utility model, and it describes comparatively concrete and detailed, but can not therefore be interpreted as the restriction to the utility model the scope of the claims.It should be pointed out that for the person of ordinary skill of the art, without departing from the concept of the premise utility, can also make some distortion and improvement, these all belong to protection range of the present utility model.
Claims (2)
1. a lithium titanate battery open formation device, comprise formation cabinet, described formation cabinet includes anodal p-wire and negative pole p-wire, it is characterized in that, described formation device also comprises closed container and air extractor, described closed container is used for holding battery, and described anodal p-wire is connected with negative pole with the positive pole of battery in described closed container respectively with described negative pole p-wire; Described air extractor comprises air bag, reclaims capsule and air valve, described air bag, recovery capsule and air valve are contained in described closed container, described air bag has air inlet and gas outlet, the air inlet of described air bag is for being connected with the liquid injection port of battery, described recovery capsule has air inlet and gas outlet, and the air inlet of described recovery capsule is connected with the gas outlet of described air bag by described air valve.
2. lithium titanate battery open formation device according to claim 1, is characterized in that, described air extractor also comprises air pump, and described air pump is arranged at outside described closed container, and the air inlet of described air pump is connected with the gas outlet of described recovery capsule.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201420004394.3U CN203733895U (en) | 2014-01-03 | 2014-01-03 | Opening forming device of lithium titanate battery |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201420004394.3U CN203733895U (en) | 2014-01-03 | 2014-01-03 | Opening forming device of lithium titanate battery |
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| Publication Number | Publication Date |
|---|---|
| CN203733895U true CN203733895U (en) | 2014-07-23 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201420004394.3U Expired - Lifetime CN203733895U (en) | 2014-01-03 | 2014-01-03 | Opening forming device of lithium titanate battery |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN203733895U (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103700887A (en) * | 2014-01-03 | 2014-04-02 | 国家电网公司 | Lithium titanate battery opening formation device and opening formation method |
| CN104577211A (en) * | 2014-12-30 | 2015-04-29 | 东莞市西特新能源科技有限公司 | Battery preparation method for improving cycle performance of lithium ion battery |
-
2014
- 2014-01-03 CN CN201420004394.3U patent/CN203733895U/en not_active Expired - Lifetime
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103700887A (en) * | 2014-01-03 | 2014-04-02 | 国家电网公司 | Lithium titanate battery opening formation device and opening formation method |
| CN104577211A (en) * | 2014-12-30 | 2015-04-29 | 东莞市西特新能源科技有限公司 | Battery preparation method for improving cycle performance of lithium ion battery |
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| AV01 | Patent right actively abandoned |
Granted publication date: 20140723 Effective date of abandoning: 20151216 |
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| AV01 | Patent right actively abandoned |
Granted publication date: 20140723 Effective date of abandoning: 20151216 |
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| C25 | Abandonment of patent right or utility model to avoid double patenting |