CN203715730U - Non-pumping-discharging acid mist water-saving type strip steel pickling line capable of recycling hydrogen gas - Google Patents

Non-pumping-discharging acid mist water-saving type strip steel pickling line capable of recycling hydrogen gas Download PDF

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Publication number
CN203715730U
CN203715730U CN201320621410.9U CN201320621410U CN203715730U CN 203715730 U CN203715730 U CN 203715730U CN 201320621410 U CN201320621410 U CN 201320621410U CN 203715730 U CN203715730 U CN 203715730U
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acid
water
tank
pressure roller
roller
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蔡满芝
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Abstract

The utility model relates to a non-pumping-discharging acid mist water-saving type strip steel pickling line capable of recycling a hydrogen gas. A steel strip is soaked in a water slot; the direction of an acid slot is arranged close to a water slot pressure roller; the lower end of an end sealing plate in sealing connection is inserted into water of the water slot; the steel strip is soaked in a cleaning slot; in the acid slot direction, an upper liquid surface of the soaked section, an upper plate and side plates of an overflow water sealing assembly form pure space, and a water curtain is arranged in the space to dissolve acid mists on the contact surface. Two acid mist sealing structures at end ports can completely seal acid mists which are produced by the acid slot and diffused in the end ports without escaping outsides. A wet-wire cluster type movable sealing structure can completely dissolve acid mists leaked by a gap formed by penetrating roller diameter through a cap wall, and moreover, the sealing structure is easy to debug, and roller diameter rotation resistance is small. High cap-shaped height space is designed, and hydrogen gas and acid mists in the cap are respectively in different areas according to height by virtue of great weight difference of the gas-state hydrogen gas generated by pickling and acid mists, so that hydrogen gas is recycled from the upper end of the high cap, and acid mist condensing areas are arranged at the middle and lower ends of the high cap.

Description

Recyclable hydrogen is the water-saving strip pickling line of pump drainage acid mist not
Technical field
The utility model relates to the not water-saving strip pickling line of pump drainage acid mist of recyclable hydrogen, belongs to strip pickling manufacturing field of equipment.
Background technology
At present, use conventional hot rolled strip carry out for raw material cold rolling before, generally all must carry out scale removal operation.Conventional thicker oxide skin removal method now, general technology is that first alternating bending makes oxide skin part peel off or loosen, and then pickling; Or adopt again mechanical means.
When pickling, more oxide skin is to react by acid the hydrogen generating with base steel to peel off, so it is effective to descale, is the method that cold rolled strip industry is generally used so far.The process characteristic of acid wash, acid need be warmed to 70 degrees Celsius of left and right (depending on acids), and pickling effect is good.But, increased thus the generation of acid mist.What strip pickling production line was conventional now is roller press type technique, and acid tank respectively has a stone roll in end; Above stone roll, there is forward and backward cover; Each exhaust equipment of installing above forward and backward cover; Acid tank section principal piece, between front and back covers, employing is added a cover, and water is inserted on lid limit, escapes with water seal acid-mist; As band steel passage, import and export are open, or hang the many soft curtains of moulding of formula; Be to rely on the negative pressure forming in the pressure difference of this region and atmosphere into and out of the flow of end vacuum fan exhausting, acid mist suction treating column is further processed, acid mist is not leaked.Follow chemical pickling, have hydrogen to produce, prior art is all that outer row does not reclaim.Band steel out enters open space afterwards from acid tank, is introduced into residual sour operation; Then pass through modified roller assembly, the function of this assembly is by spacing band steel, raise, and in residual sour backflow acid tank, be then that water rinses operation.Enter subsequently Rinsing Area and clean, go out Rinsing Area through modified roller, enter passivation procedure, after purifying, pickling process finishes.More than existing with pickling line conventional equipment and conventional process flow.
Background technology strip pickling line weak point is: the one, and be generally by configuring high-power vacuum fan, the acid mist of generation all can be aspirated in theory, but, importing and exporting cross section each point, the negative pressure forming while work with the vacuum fan with the T-shaped installation of steel direct of travel is discrepant, is in fact difficult for avoiding acid mist to overflow; It is many that high-power vacuum fan consumes sour power consumption, and production cost is higher; At present to escape that acid mist pollutes atmosphere be compared with Universal Problems to strip pickling; The 2nd, acid mist is the gaseous form of acid solution, is waste acid solution by its suction; Vacuum fan power consumption, acid mist treatment tower power consumption, consumptive material, water consumption, acid mist treatment tower also has secondary pollution problem; The 3rd, the hydrogen that the pickling chemical reaction of considerable amount is generated directly enters atmosphere, causes energy dissipation; And hydrogen be suitable for the heat treated protective atmosphere of steel or can be used for the high-grade energy of acid solution heating etc.; The 4th, adopt extensive style drip washing, water consumption is large; Need the water yield of environmental protection treatment many.It is worth mentioning, overflow type pickling has been applied to wire acid cleaning, and acid-mist structure is that one section of the each extension of acid tank in-out end adopts water curtain type water seal.Wire rod and the comparison of band steel, have single wire rod sectional area little, easily exceptionally straight, can entirely be immersed in overflow acid, can side lead-in wire, residual acid is easily let out under cascade between dirty, line can be by the exclusive feature of wire rod into and out of the basic full water seal of end section, it is better that acid-mist escapes effect; Pickling tank Length Ratio is shorter.And band steel does not possess These characteristics, should not adopt overflow type pickling.Existing wire rod overflow type underpickling part is: the one, and an acid solution part for condensation flows into water sealed tank, and the part that acid mist is a considerable number of and cascade are fused, are unfavorable for saving acid water saving; The 2nd, hydrogen is not recycled, and this is also unfavorable for acid mist condensation,
Utility model content
Purpose of design: avoid the weak point in background technology, both recyclable hydrogen of design, pump drainage acid mist not again, and there is the strip pickling line of water-saving result.
Design: the utility model in structure design mainly by forward (FWD) carrying roller; Forward (FWD) tank; Forward (FWD) tank pressure roller; Port lower end plug-in water sealing assembly; Forward (FWD) spacing and changed course assembly; Acid tank; The high cap of acid tank; Acid tank is into and out of band pressure roller; Acid tank is into and out of the high cap of band pressure roller; Go out to be with spacing and changed course assembly; Overflow water sealing assembly; Rinse bath; Rinse bath pressure roller; " wet group's formula " dynamic sealing assembly that acid tank pressure roller and modified roller are used; Air-blowing is swept and drip washing assembly, roller between groove; Purifying groove; Purifying groove pressure roller; Gas sweep module; Go out to be with carrying roller; Acid heating and circulation device; The compositions such as electricity instrument controlling box.Below press pickling process order and set forth the utility model constructional feature:
The utility model is provided with forward (FWD) carrying roller, forward (FWD) tank, forward (FWD) tank pressure roller, forward (FWD) spacing and changed course assembly, above-mentioned setting can make steel band be immersed in forward (FWD) tank, above the submergence section of acid tank direction, be provided with end-plate lower end plug-in water sealing assembly, this assembly is by the capping of condensation downflow system, upper plate, side plate, opening welding flange, acidproof rubber seal part, the compositions such as shrouding, more than arrange and utilize band steel to be immersed in tank, contiguous tank pressure roller, insert in tank water the lower end of the end-plate of sealed attachment, the acid mist spreading in port that acid tank can be produced all seals and does not escape, the capping of condensation downflow system has manhole plate function in addition, forward (FWD) tank secondary role is the dirt with steel face capable of washing.Forward (FWD) modified roller spacing and changed course assembly coordinates formation inclined-plane with forward (FWD) rinse bath pressure roller, make the water of taking out of from forward (FWD) tank with steel flow back to forward (FWD) tank along inclined-plane.
Intensity with steel is larger, has again rolled form deviation, and band steel, in pickling operating mode, can swing and fluctuation up and down, can apply larger reactive force to touching thing.In rinse bath, acid tank and purifying groove, left and right face is granite slab, can limit the band steel scope that swings; Being granite slab below, is grouan roll surface above, can limit the upper and lower fluctuation range of band steel.
Spacing and the changed course module position at forward (FWD), left and right face is granite slab, can limit the band steel scope that swings; For changed course roll surface, playing position-limiting action above below, is upper limit axle.
The utility model upper limit axial wood matter is acid-resistant stainless steel, connect with upper limit axle, also be high-intensity acid resisting material, by upper limit pedestal cap, the power of touching with steel passed to high-intensity mounting bracket from upper limit axle, avoided the less acidproof cover body of intensity; For operation and easy to maintenance, to make dismountablely, upper limit pedestal possesses the function of manhole plate in addition; The water-sealed component arranging does not leak acid mist, and adds the dirty coaming plate of condensation, in very most of condensation acid solution below this lid is drawn and dripped back and cover.
Enter acid tank section, feature of the present utility model is: the original functional part that only plays simple sealing acid mist function being commonly called as acid tank cover, front shroud, back cover is all designed to high hat, and the high cap of called after acid tank, the high cap of acid tank forward (FWD) pressure roller, acid tank go out to be with the high cap of pressure roller respectively.
The object that is designed to high cap shaped is: the height space of utilizing high hat to form, and the gaseous state thing that pickling is produced covers and separates up and down; Gaseous state thing fundamental component is acid mist and hydrogen, and acid mist be by acid volatilize and acid solution in chemical reaction generate the sour gas such as hydrogenchloride or hydrogen sulfide, the solvate of water-soluble steam, the gases such as hydrogenchloride or hydrogen sulfide are very easily water-soluble, and hydrogen is water-soluble hardly; Distinguish by severe, the two differs very large; And hydrogen and acid mist are fused; So the each gaseous state thing in cover is by highly respectively in different zones, two interfaces, region with hydrogen by the speed of pump drainage and upper and lower level fluctuates.
In relative closure space, in high cap gaseous state thing in: high cap upper end is hydrogen region, at the recyclable hydrogen in this region; Appropriate extraction; Newborn hydrogen rises supplementary continually.In high cap, lower end is acid mist region, in this region, the gases such as newly-generated hydrogenchloride or hydrogen sulfide are instant to be fused and become acid mist with water vapour, and------acid mist constantly generate fill the air supplementary---reaches to saturation ratio and to be condensed into acid solution dirty once more after the acid mist degree of reaching capacity of generation, to be condensed into acid solution dirty ..., in dynamic circulation.And when actual production, acid solution need be heated, water vapour abundance; And high cap wall is in atmosphere physical environment, naturally there is condensation effects.Each cap is relatively independent, and between each cap, acid mist is difficult for channelling, and in each cap, hydrogen and acid mist fluctuation are more stable; High hat has also increased condensation area.Under high cap, be inverted U-shaped along periphery, U-shaped base is that high cap seat board is sitting on acid tank side plate and connection board, U-shaped inner edge is that the dirty plate of condensation and high cap wall are integrated together, in order to flowing back to acid tank under suitable limit after acid mist condensation: and this inner edge is long under high cap seat board, inclination when having limited high cap and being subject to side force, (only having flat lifting to certain altitude just can shift out); U-shaped outside is that water seal board inserts in the U-shaped tank that on acid tank, outside U-shaped plate is communicated with biside plate, and the acid mist that sees through gap is carried out to water seal.Like this, the acid solution being formed by condensation seldom flows into outside U-lag, has both economized on acid amount, avoids again the too fast acidifying of water in U-shaped water sealed tank, can water saving.For improving pickling efficiency, band steel acid tank length generally all exceedes 30M, and the high cap of acid tank has multiple, reclaims for hydrogen is unified, between each high cap, contacts with three-way tube valve; And corresponding configuration gas composition analyzer, the controlled hydrogen output valve of this analyser output signal, configuration minute-pressure indicator gauge etc.Band steel goes out acid tank and enters out on backward and be with spacing and changed course assembly, and the structure of this assembly is with function and forward (FWD) is spacing and the assembly that alters course is identical; The most of following current of residual acid is returned acid tank or is splashed into residual sour supporting plate and returns acid tank.
The utility model is provided with overflow water sealing assembly, rinse bath, rinse bath pressure roller, goes out to be with spacing and changed course assembly, above-mentioned setting can make steel band be immersed in rinse bath, upper plate and side plate at this submergence section liquid level of acid tank direction and overflow water sealing assembly form simple space, at this spatial placement cascade.The solvable contact surface acid mist that closes of cascade, the acid mist spreading in port that acid tank can be produced all seals and does not escape; Because band steel acid tank is long, port cascade area always relate to acid mist area with liquid level area with acid tank compared with accounting little, so water-soluble acid mist accounting is little, very most acid mist is condensed into acid solution direct reuse.It must be noted that: above two kinds of ports envelope acid mist structure, be shrouding lower end plug-in water sealing assembly and overflow water sealing assembly, the acid mist spreading in port that acid tank can be produced all seals and does not escape, and can use respectively, also can only use wherein a kind of in two ends.
Not pump drainage of the utility model acid mist, just the stopping property in pickling cover is had to strict requirement, requiring in cover is pressure-fired, so could form acid mist saturation ratio environment, and acid mist not leak be to basic demand of the present utility model, and strip pickling is due to features such as band hardness of steel are large and acid tank is long, the utility model adopts roller press type, the many rollers of pickling line are driven roll, and roll shaft footpath is a large key of the utility model success or failure with the dynamic seal of cover wall.
The utility model is provided with " wet group's formula " dynamic sealing assembly, and principle of design is the characteristic of utilizing acid mist and water electrode easily to mix, and the bootable flowing water of silk group of appropriate degree of tightness fills in the gap of needs sealing.At dynamic seal gap place, roll into a ball around the wet silk in roller footpath the acid mist that gap place is appeared all water-soluble, therefore do not have acid mist to overflow.Sour water recycles after processing.The silk group of appropriateness degree of tightness is little to diameter of axle rotational resistance." wet group's formula " dynamic sealing assembly is mainly made up of water filling pipe valve, upper semi-circle trim ring, acidproof soft group, hydrolock rising pipe, lower half circle trim ring, acid-resisting rubber pad etc., hydrolock rising pipe irrigating gate height is lower than lower end, roller footpath, the silk group of supporting suitable width vertically, fused like this acid solution is unlikely to cross flow vertically, and rising pipe water seal can prevent the middle acid mist that leaks of acidproof soft silk group.Trim ring is divided into semicircle in order that easy to adjust.
" wet group's formula " dynamic seal that acid tank pressure roller and modified roller are used, method is identical, and structure is slightly different.
The residual acid of rinse bath cleaning tape steel face, so groove scavenging solution must neutralize to recycle with alkali solution.Between rinse bath pressure roller and groove, roller coordinates and forms inclined-plane, makes the liquid of taking out of from rinse bath with steel flow back to rinse bath along inclined-plane; Between groove, roller relative level position is slightly high.
Air-blowing sweep and drip washing arrangement of components between rinse bath pressure roller and groove between roller, residual water backflow rinse bath, compact construction like this; This assembly function part is arranged on mobile trolley, expelling dolly with on the position ground track vertical with steel direct of travel, can carry out threading operation.
For well water saving again of cleaning performance, the utility model adopts gas, the drip washing of water built-up type; General four pipes that adopt, the first pipe tracheae, the residual water of taking out of from rinse bath with steel (containing more impurity in residual water) is purged clean, the second pipe water pipe, the oxymuriate that cleaning tape steel face is residual or vitriol (oxymuriate is easier to clean), the 3rd pipe water pipe, whether the cleaning quality depending on front water pipe determines open-minded, the 4th pipe tracheae, purges dry band steel face clear water, in order to avoid dilution refined solution.
Band steel goes out after purifying liquid level, and the utility model is provided with gas sweep module, contributes to water saving, saves purifying agent and is with steel dry.
The theory or the principle that below several features of the utility model are related to are simply reported:
1, (hydrochloric acid) pickling (mainly) chemical equation: Fe+2HCl=FeCl2+H2^
(sulfuric acid) pickling (mainly) chemical equation: Fe+H2SO4=FeSO4+H2^
(salt) pickling (mainly) chemical reaction molecular formula: 2Fe+2HCl=2FeCl+H2
From the generation of the visible hydrogen of molecular formula, estimating of molecular weight can draw the output of hydrogen.
From the above-mentioned reaction formula proportion of strip pickling acid consumption speed, known hydrogen gas production rate.
Strip pickling area is large, and acid tank is long, so the more worth recovery of hydrogen output.
The utility model hydrogen recovery also contributes to acid mist condensation.Placing without compression of cascade and the high cap of acid tank, has ensured that in cap, hydrogen gathering is safe.
2, acid mist emission speed: to fluid molecule amount, with corresponding to airborne saturated vapo(u)r pressure component under fluid temperature, with unit surface water vapour vaporator rate, relevant with evaporation area etc.
3, water cleans principle:
Mass transfer process meets Fourier's law: dq ∝ dv w △ c
Be rate of mass transfer and rinsing liquid movement velocity, with the rinsing water yield, with workpiece and rinse water in the concentration difference of required cleaning material, be associated.
The utility model air-blowing is swept and drip washing assembly, can significantly expand the concentration difference of required cleaning material in workpiece and rinse water, therefore can reduce water loss.
Technical scheme 1: recyclable hydrogen is the water-saving strip pickling line of pump drainage acid mist not, and forward (FWD) carrying roller is positioned at tank front end; Tank pressure roller is positioned at tank; Insert in the water of tank the lower end of the shrouding of end-plate lower end plug-in water sealing assembly; Forward (FWD) is spacing and alter course assembly between tank and acid tank; Acid tank forward (FWD) pressure roller and acid tank go out with pressure roller to lay respectively at the front and rear in acid tank; The high cap of acid tank forward (FWD) pressure roller, many high caps of acid tank and acid tank go out to be with the high cap water seal of pressure roller to cover on acid tank mouth, and acid tank forward (FWD) pressure roller and acid tank are gone out to jacket with pressure therein; Hydrogen series winding pipe goes out by the high cap of acid tank forward (FWD) pressure roller, many high caps of acid tank and acid tank the hydrogen pipe valve being all equipped with the high cap of pressure roller and is communicated with, and hydrogen is exported to user; Go out to be with spacing and alter course assembly between acid tank and rinse bath; Residual sour supporting plate acid tank and go out to be with spacing and changed course assembly between; Follow by overflow water sealing assembly; Rinse bath pressure roller is positioned at rinse bath; Air-blowing sweep and drip washing arrangement of components between rinse bath pressure roller and groove between roller; Purifying groove is after rinse bath; Above purifying groove is adjacent with rinse bath, be provided with roller between groove, purifying groove pressure roller is positioned at purifying groove, and gas sweep module is positioned at before band carrying roller.
Technical scheme 2: recyclable hydrogen is the water-saving strip pickling line of pump drainage acid mist not, differs from technical scheme 1 part and is: forward (FWD) end and go out these two ends of band edge and all adopt end-plate lower end plug-in water sealing assembly shutoff acid mist.The advantage of technical scheme 2 is can be without water service pump, has deducted the area of the molten acid mist of cascade, energy-saving acid.Shortcoming is may be not too convenient while producing adjustment.
Technical scheme 3: recyclable hydrogen is the water-saving strip pickling line of pump drainage acid mist not, differs from scheme 1 and scheme 2 parts are: forward (FWD) end and go out these two ends of band edge and all adopt overflow water sealing assembly shutoff acid mist.
The utility model compared with background technology, the one, the height space of utilizing high hat to form, the gaseous state thing that pickling is produced covers and separates up and down, realize the recovery of hydrogen, and hydrogen recovery also contributes to acid mist condensation; The 2nd, not pump drainage acid mist; Closing cover, cover in, acid mist in: generate--saturated-condensation-generation-running balance; The 3rd, water saving, energy-conservation, joint consumptive material, environmental protection: the utility model has been save the acid mist treatment tower of water consumption consumptive material power consumption; The drainage of most condensation acid solution is returned to acid tank, and favourable to saving acid, acid tank water seal water is also difficult for acidifying; Adopt air-blowing to sweep and the thin water wash of multitube fan stream shower nozzle, can significantly expand the concentration difference of required cleaning material in workpiece and rinse water, can reduce drip washing water consumption; The 4th, purifying groove goes out the increase air-blowing of band place to be swept, and contributes to water saving, saves purifying agent and is with steel dry; The 5th, placing without compression of cascade and the high cap of acid tank, has ensured the safety that in cap, hydrogen is assembled.
Brief description of the drawings
(Fig. 1 a, Fig. 1 are b) the not front views of the water-saving strip pickling line of pump drainage acid mist of recyclable hydrogen to Fig. 1.
Fig. 2 is the vertical view structural representation of Fig. 1.
Fig. 3 is that in Fig. 2, A, to stagewise cutaway view, illustrates shrouding lower end plug-in water sealing assembly.
Fig. 4 is that in Fig. 1, B, to analysing and observe, illustrates the high cap of acid tank.
Fig. 5 is that in Fig. 4, I, to analysing and observe, illustrates under high cap and amplifies along local.
Fig. 6 is that in Fig. 1, C is to analysing and observe, and the high cap of diagram acid tank pressure roller coordinates.
Fig. 7 is that in Fig. 2, D is to stagewise cutaway view, and the high cap of diagram acid tank pressure roller connects and oversleeve position view with changed course jacket.
Fig. 8 is that in Fig. 1, E, to analysing and observe, illustrates modified roller upper limit.
Fig. 9 is that in Fig. 8, G, to analysing and observe amplification, illustrates modified roller saturating roller footpath place " wet group's formula " dynamic seal.
Figure 10 is that in Fig. 1, F, to analysing and observe, illustrates mobile trolley pickling and two kinds of working positions of threading.
Figure 11 is II enlarged diagram in Figure 10, and diagram air-blowing is swept and drip washing assembly amplifies.
Figure 12 is to be respectively Fig. 1 a and Fig. 1 b and Fig. 2 a and Fig. 2 b with Figure 13 entirety master looks schematic diagram, wherein: 1 forward (FWD) carrying roller; 2 tanks; 3 tank pressure rollers; 4 end-plate lower roll plug-in water sealing assemblies: 4.1 condensation downflow system cappings, 4.2 upper plates, 4.3 side plates, 4.5 acidproof rubber seal parts, 4.6 shroudings; 5 forward (FWD)s spacing and changed course assembly; 6 acid tanks; 7 acid tank forward (FWD) pressure rollers; The high cap of 8 acid tank forward (FWD) pressure roller; 9 hydrogen tandem tubes; The high cap of 10 acid tank (many): 10.1 hydrogen pipe valves, 10.2 gas composition analyzers, 10.3 high cap seat boards, the dirty plate of 10.4 condensation, 10.5 water seal boards; 11 acid tanks go out to be with pressure roller; 12 acid tanks go out to be with the high cap of pressure roller: 12.1 minute-pressure indicator gauges, 12.2 acid tank pressure rollers " wet group's formula " dynamic sealing assembly; 13 residual sour supporting plates; 14 arm holes: 14.1 arm hole flanges, 14.2 even refer to acidproof arm cover; 15 transparent windows; 16 go out to be with spacing and changed course assembly: 16.1 upper limit pedestal caps, the dirty coaming plate of 16.2 condensation, 16.3 water-sealed components, 16.4 upper limit axles, 16.5 mounting brackets, 16.6 modified rollers; 17 modified rollers " wet group's formula " dynamic sealing assembly: 17.1 water filling pipe valves, 17.2 upper semi-circle trim rings, 17.3 acidproof soft silks are rolled into a ball, 17.4 hydrolock rising pipes, 17.5 lower half circle trim rings, 17.6 acid-resisting rubber pads; 18 overflow water sealing assemblies: 18.1 overflow waters are sealed up plate, 18.2 overflow water seal side plates, 18.3 liquid levels, 18.4 cascades, 18.5 water pumps; 19 rinse bath pressure rollers; 20 rinse baths; 21 air-blowings are swept and drip washing assembly: 21.1 mobile trolleys, 21.2 second gas scavenging ducts, 21.3 second drip washing pipes, 21.4 first drip washing pipes, 21.5 first gas scavenging ducts, 21.6 fan flow nozzles; Roller between 22 grooves; 23 purifying grooves; 24 purifying groove pressure rollers; 25 gas sweep module; 26 go out to be with carrying roller.
Embodiment
Embodiment 1: with reference to accompanying drawing 1-13.The not water-saving strip pickling line of pump drainage acid mist of a kind of recyclable hydrogen, forward (FWD) carrying roller 1 is positioned at tank 2 front ends; Tank pressure roller 3 is positioned at tank 2; Insert in the water of tank 2 lower end of the shrouding 4.6 of end-plate lower end plug-in water sealing assembly 4; Forward (FWD) is spacing and alter course assembly 5 between tank 2 and acid tank 6; Acid tank forward (FWD) pressure roller 7 and acid tank go out with pressure roller 11 to lay respectively at the front and rear in acid tank 6; Many of the high cap 8 of acid tank forward (FWD) pressure roller, the high cap 10(of acid tank) and acid tank to go out to be with high cap 12 water seals of pressure roller to cover on 6 mouthfuls of acid tanks upper, and go out to be with pressure roller 11 to cover therein acid tank forward (FWD) pressure roller 7 and acid tank; Hydrogen series winding pipe 9 is by many of high acid tank forward (FWD) pressure roller cap 8, the high cap 10(of acid tank) and acid tank go out the hydrogen pipe valve 10.1 being all equipped with the high cap 12 of pressure roller and be communicated with, hydrogen is exported to user; Residual sour supporting plate 13 acid tank 6 and go out to be with spacing and changed course assembly 16 between; Cover wall arranges arm hole 14 and transparent window 15; Go out to be with spacing and alter course assembly 16 between acid tank 6 and rinse bath 20; Roller is stretched and is adopted " wet group's formula " dynamic sealing assembly 17 with the dynamic seal of cover wall; Follow by overflow water sealing assembly 18; Rinse bath pressure roller 19 is positioned at rinse bath 20; Air-blowing is swept and drip washing assembly 21 is arranged between rinse bath pressure roller 19 and groove between roller 22; Purifying groove 23 is after rinse bath 20; Above purifying groove 23 is adjacent with rinse bath 20, be provided with roller 22 between groove, purifying groove pressure roller 24 is positioned at purifying groove 23, and gas sweep module 25 is positioned at before band carrying roller 26.Many of the high cap 8 of acid tank forward (FWD) pressure roller, the high cap 10(of acid tank), acid tank goes out to be with the high cap 12 of pressure roller to be all designed to high hat, from high cap upper end recover hydrogen, in high cap, lower end is acid mist condenser zone.Under high cap, be inverted U-shaped along periphery, high cap seat board 10.3 is sitting in acid tank 6 master plates and is communicated with on water eliminator, the dirty plate 10.4 of condensation is integrated with high cap wall is same, in order to after acid mist condensation along flowing back to acid tank 6 under limit: the dirty plate 10.4 of condensation is long high cap seat board 10.3 times, inclination when having limited high cap and being subject to side force, water seal board 10.5 inserts in the U-shaped tank of acid tank 6 master plates and water eliminator formation, and the acid mist that sees through gap is carried out to water seal.End-plate lower end plug-in water sealing assembly 4 is made up of condensation downflow system capping 4.1, upper plate 4.2, side plate 4.3, opening welding flange 4.4, acidproof rubber seal part 4.5, shrouding 4.6 etc., and insert in tank 2 water the lower end of the end-plate 4.6 of sealed attachment; Can be by whole port acid mist shutoff.Condensation downflow system capping 4.1 has manhole plate function in addition.Spacing and the changed course assembly 5 of forward (FWD), go out with the roller of modified roller spacing and changed course assembly 16 to stretch, when through cover sidewall, adopt modified roller " wet silk group a formula " dynamic sealing assembly 17; " wet group's formula " dynamic sealing assembly 17 is by water filling pipe valve 17.1, upper semi-circle trim ring 17.2, acidproof soft group 17.3, hydrolock rising pipe 17.4, lower half circle trim ring 17.5, acid-resisting rubber pad 17.6 formations such as grade; Hydrolock rising pipe 17.4 irrigating gate height are lower than lower end, roller footpath, and the silk of supporting suitable width is vertically rolled into a ball, and fused like this acid solution is unlikely to cross flow vertically, and rising pipe water seal can prevent the middle acid mist that leaks of acidproof soft silk group.Acid tank forward (FWD) pressure roller 7, acid tank go out with the pressure roller roller of pressure roller 11 to stretch, and when through cap wall, adopt acid tank pressure roller " wet group's formula " dynamic sealing assembly 12.2, and its dynamic sealing method is identical with modified roller " silk group formula wets " dynamic sealing assembly 17.Go out the upper limit axle 16.4 with the modified roller top in spacing and changed course assembly 16, be connected into one with upper limit pedestal cap 16.1 and mounting bracket 16.5 settings of its top, the power upwards departing from steel is born by mounting bracket 16.5, protect acidproof cover body; The high-order modified roller 16.6 of arranging makes to be with in steel face liquid return groove, and upper limit pedestal cap 16.1 has manhole plate function in addition, and the dirty coaming plate 16.2 of condensation guides condensation acid solution to splash in cover, and water-sealed component 16.3 does not leak acid mist.Spacing and the changed course assembly 5 of forward (FWD) with go out to be with spacing and assembly 16 structures of altering course are identical.Air-blowing is swept and drip washing assembly 21 is positioned at the top at rinse bath 20 rear portions; Gas sweep module 25 is positioned at the top at purifying groove 23 rear portions; Air-blowing is swept and the gentle sweep module 25 of drip washing assembly 21 is all arranged on mobile trolley; Air-blowing is swept and drip washing assembly 21 is made up of mobile trolley 21.1, second gas scavenging duct 21.2, second drip washing pipe 21.3, first drip washing pipe 21.4, first gas scavenging duct 21.5 and fan flow nozzle 21.6.In the time of leader tape and pickling, may need the sidewall locations of giving one a leg up, arm hole 14 is set, will even refer to the arm running-on and cover outside sealed attachment of acidproof arm cover 14.2 by arm hole flange 14.1, and transparent window 15 is set.
Its recyclable hydrogen is the method for the water-saving strip pickling line of pump drainage acid mist not: first through forward (FWD) carrying roller, 1 changed course enters tank 2 to band steel, in tank pressure roller 3 lower roll surface processes, enter plug-in water sealing assembly 4 regions, shrouding lower end, under the state submerging in water with steel, shrouding 4.6 is by the spatial integrity shutoff on its ingress's water surface, then be with upwards and changed course assembly 5 spacing through forward (FWD) of steel, alter course through modified roller, enter acid tank 6 downwards, go out the lower roll surface with pressure roller 11 through acid tank forward (FWD) pressure roller 7 and acid tank, on passage in transit region, have the high cap 8 of acid tank forward (FWD) pressure roller in vain, hydrogen series winding pipe 9, many of the high cap 10(of acid tank), acid tank goes out to be with the high cap 12 of pressure roller, in residual sour supporting plate 13 overhead processes, upwards through going out to be with spacing and changed course assembly 16, after modified roller changed course, enter overflow water sealing assembly 18 regions, and enter rinse bath 20 downwards, through rinse bath pressure roller 19 lower roll surfaces, under the state submerging in water with steel, cascade 18.4 is fused by the acid mist touching in its port, shutoff acid mist, be with subsequently steel to be upward through that air-blowing is swept and drip washing assembly 21, alter course through roller 22 between groove, enter purifying groove 23 downwards, from purifying groove pressure roller 24 lower roll surfaces through after, be upward through gas sweep module 25, finally by going out to be with carrying roller 26 to alter course, finish pickling process.
Embodiment 2: on the basis of embodiment 1, utilize band steel to be immersed in rinse bath 20, seal up plate 18.1 and overflow water seal side plate 18.2 forms simple space at this submergence section liquid level 18.3 and the overflow water of overflow water sealing assembly 18, the top-down cascade 18.4 in this space being pumped by water pump 18.5, the fused acid mist touching, makes this port overflow without acid mist.
Preparation work before producing:
By spacing forward (FWD) and changed course assembly 5 upper limit pedestal cap, go out with upper limit pedestal cap 16.1 and take apart from the mounting bracket being positioned at separately, high acid tank forward (FWD) pressure roller cap 8 and acid tank are gone out with the connecting parts of the high cap 12 of pressure roller to take apart and shift out, remove condensation downflow system capping 4.1, remove the high cap 10 of acid tank, then reveal mouth from each, successively leader tape is passed along strip pickling position by nylon rope order.Then will be with steel to introduce acid tank 6 imports by nylon rope, check errorless after, above-mentioned lid and cap are installed, are built.After heating, acid solution is injected, and opens water pump 18.5 simultaneously.
Produce:
Band steel first alters course through forward (FWD) carrying roller 1, enter tank 2, in tank pressure roller 3 lower roll surface processes, enter plug-in water sealing assembly 4 regions, shrouding lower end, under the state submerging in water with steel, shrouding 4.6 is by the spatial integrity shutoff on its ingress's water surface, then be with upwards and changed course assembly 5 spacing through forward (FWD) of steel, alter course through modified roller, enter acid tank 6 downwards, go out to be with pressure roller 11 lower roll surfaces through acid tank forward (FWD) pressure roller 7 lower roll surfaces and acid tank, way in through region on have the high cap 8 of acid tank forward (FWD) pressure roller in vain, hydrogen series winding pipe 9, the high cap 10 of acid tank, acid tank goes out to be with the high cap 12 of pressure roller, in residual sour supporting plate 13 overhead processes, upwards through going out to be with spacing and changed course assembly 16, after modified roller changed course, enter overflow water sealing assembly 18 regions, and enter rinse bath 20 downwards, through rinse bath pressure roller 19 lower roll surfaces, under the state submerging in water with steel, spatial integrity shutoff on cascade, be with subsequently steel to be upward through that air-blowing is swept and drip washing assembly 21, alter course through roller 22 between groove, enter purifying groove 23 downwards, from purifying groove pressure roller 24 lower roll surfaces through after, be upward through gas sweep module 25, finally by going out to be with carrying roller 26 to alter course, finish pickling process.
It is to be understood that: although above-described embodiment is to the mentality of designing of the present utility model detailed text description of contrasting; but these text descriptions; just the simple text of the utility model mentality of designing is described; instead of restriction to the utility model mentality of designing; any combination, increase or amendment that does not exceed the utility model mentality of designing, all falls in protection domain of the present utility model.

Claims (9)

1. the not water-saving strip pickling line of pump drainage acid mist of recyclable hydrogen, is characterized in that: forward (FWD) carrying roller (1) is positioned at tank (2) front end; Tank pressure roller (3) is positioned at tank (2); Insert in the water of tank (2) lower end of the shrouding (4.6) of end-plate lower end plug-in water sealing assembly (4); Forward (FWD) spacing and changed course assembly (5) be positioned between tank (2) and acid tank (6); Acid tank forward (FWD) pressure roller (7) and acid tank go out with pressure roller (11) to lay respectively at the front and rear in acid tank (6); The high cap of acid tank forward (FWD) pressure roller (8), many high caps of acid tank (10) and acid tank go out to be with the high cap of pressure roller (12) water seal to cover on acid tank (6) mouth, and go out to be with pressure roller (11) to cover therein acid tank forward (FWD) pressure roller (7) and acid tank; Hydrogen series winding pipe (9) goes out the high cap of acid tank forward (FWD) pressure roller (8), many high caps of acid tank (10) and acid tank with all equipped hydrogen pipe valve (10.1) connections of the high cap of pressure roller (12), and hydrogen is exported to user; Residual sour supporting plate (13) is positioned at acid tank (6) and goes out to be with between spacing and changed course assembly (16); Cover wall arranges arm hole (14) and transparent window (15); Go out to be with spacing and changed course assembly (16) be positioned between acid tank (6) and rinse bath (20); Roller is stretched and is adopted " wet group's formula " dynamic sealing assembly (17) with the dynamic seal of cover wall; Follow by overflow water sealing assembly (18); Rinse bath pressure roller (19) is positioned at rinse bath (20); Air-blowing is swept and drip washing assembly (21) is arranged between rinse bath pressure roller (19) and groove between roller (22); Purifying groove (23) at rinse bath (20) afterwards; Be provided with roller between groove (22) at purifying groove (23) and the adjacent top of rinse bath (20), purifying groove pressure roller (24) is positioned at purifying groove (23), and gas sweep module (25) is positioned at band carrying roller (26) above.
2. the not water-saving strip pickling line of pump drainage acid mist of recyclable hydrogen according to claim 1, it is characterized in that: the high cap of acid tank forward (FWD) pressure roller (8), many high caps of acid tank (10), acid tank go out to be with the high cap of pressure roller (12) to be all designed to high hat, from high cap upper end recover hydrogen, in high cap, lower end is acid mist condenser zone.
3. the not water-saving strip pickling line of pump drainage acid mist of recyclable hydrogen according to claim 1 and 2, it is characterized in that: under high cap, be inverted U-shaped along periphery, high cap seat board (10.3) is sitting in acid tank (6) master plate and is communicated with on water eliminator, the dirty plate of condensation (10.4) is integrated with high cap wall is same, in order to flowing back to acid tank (6) along under limit after acid mist condensation; The dirty plate of condensation (10.4) is lower long at high cap seat board (10.3), the inclination when having limited high cap and being subject to side force, and water seal board (10.5) inserts in the U-shaped tank that acid tank (6) master plate and water eliminator form, to seeing through the acid mist implementation water seal in gap.
4. the not water-saving strip pickling line of pump drainage acid mist of recyclable hydrogen according to claim 1, it is characterized in that: end-plate lower end plug-in water sealing assembly (4) is made up of condensation downflow system capping (4.1), upper plate (4.2), side plate (4.3), opening welding flange (4.4), acidproof rubber seal part (4.5), shrouding (4.6), insert in tank (2) water the lower end of the end-plate (4.6) of sealed attachment; Can be by whole port acid mist shutoff, condensation downflow system capping (4.1) has manhole plate function in addition.
5. the not water-saving strip pickling line of pump drainage acid mist of recyclable hydrogen according to claim 1, it is characterized in that: utilize band steel to be immersed in rinse bath (20), seal up plate (18.1) and overflow water seal side plate (18.2) forms simple space at the overflow water of this submergence section liquid level (18.3) and overflow water sealing assembly (18), the top-down cascade in this space (18.4) being pumped by water pump (18.5), the fused acid mist touching, makes this port overflow without acid mist.
6. the not water-saving strip pickling line of pump drainage acid mist of recyclable hydrogen according to claim 1, it is characterized in that: the spacing and changed course assembly (5) of forward (FWD), go out with the roller of modified roller spacing and changed course assembly (16) to stretch, when through cover sidewall, adopt modified roller " wet group's formula " dynamic sealing assembly (17); Modified roller " wet group's formula " dynamic sealing assembly (17) is rolled into a ball (17.3), hydrolock rising pipe (17.4), lower half circle trim ring (17.5) by water filling pipe valve (17.1), upper semi-circle trim ring (17.2), acidproof soft silk, and acid-resisting rubber pad (17.6) forms; Hydrolock rising pipe (17.4) irrigating gate height is lower than lower end, roller footpath, and the silk of supporting suitable width is vertically rolled into a ball, and fused like this acid solution is unlikely to cross flow vertically, and rising pipe water seal can prevent the middle acid mist that leaks of acidproof soft silk group; Acid tank forward (FWD) pressure roller (7), acid tank go out with the pressure roller roller of pressure roller (11) to stretch, and when through cap wall, adopt acid tank pressure roller " wet group's formula " dynamic sealing assembly (12.2), and its dynamic sealing method is identical with modified roller " silk group formula wets " dynamic sealing assembly (17).
7. the not water-saving strip pickling line of pump drainage acid mist of recyclable hydrogen according to claim 1, it is characterized in that: go out the upper limit axle (16.4) with the modified roller top in spacing and changed course assembly (16), be connected into one with upper limit pedestal cap (16.1) and mounting bracket (16.5) setting of its top, the power upwards departing from steel is born by mounting bracket (16.5), protect acidproof cover body; The high-order modified roller (16.6) of arranging makes to be with in steel face liquid return groove, upper limit pedestal cap (16.1) has manhole plate function in addition, the dirty coaming plate of condensation (16.2) guiding condensation acid solution splashes in cover, water-sealed component (16.3) does not leak acid mist, the spacing and changed course assembly (5) of forward (FWD) with go out to be with spacing and assembly (16) structure of altering course is identical.
8. the not water-saving strip pickling line of pump drainage acid mist of recyclable hydrogen according to claim 1, is characterized in that: air-blowing is swept and drip washing assembly (21) is positioned at the top at rinse bath (20) rear portion; Gas sweep module (25) is positioned at the top at purifying groove (23) rear portion; Air-blowing is swept and the gentle sweep module of drip washing assembly (21) (25) is all arranged on mobile trolley; Air-blowing is swept and drip washing assembly (21) is made up of mobile trolley (21.1), second gas scavenging duct (21.2), second drip washing pipe (21.3), first drip washing pipe (21.4), first gas scavenging duct (21.5) and fan flow nozzle (21.6).
9. the not water-saving strip pickling line of pump drainage acid mist of recyclable hydrogen according to claim 1, it is characterized in that: in the time of leader tape and pickling, may need the sidewall locations of giving one a leg up, arm hole (14) is set, to even refer to the arm running-on and cover outside sealed attachment of acidproof arm cover (14.2) by arm hole flange (14.1), and transparent window (15) is set.
CN201320621410.9U 2013-10-10 2013-10-10 Non-pumping-discharging acid mist water-saving type strip steel pickling line capable of recycling hydrogen gas Expired - Lifetime CN203715730U (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103590061A (en) * 2013-10-10 2014-02-19 蔡满芝 Water-saving type strip steel pickling line and method capable of recycling hydrogen and without pumping and discharging acid mist
CN104894584A (en) * 2015-06-03 2015-09-09 江苏兴隆防腐设备有限公司 Tank body of PPH pickling tank
CN106757295A (en) * 2015-11-19 2017-05-31 新日铁住金工程技术株式会社 The control method of electrolytic clean unit and electrolytic clean unit
CN114075673A (en) * 2021-11-23 2022-02-22 上海先予工业自动化设备有限公司 Low-emission pickling device

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103590061A (en) * 2013-10-10 2014-02-19 蔡满芝 Water-saving type strip steel pickling line and method capable of recycling hydrogen and without pumping and discharging acid mist
CN103590061B (en) * 2013-10-10 2016-04-06 蔡满芝 Recyclable hydrogen is the water-saving strip pickling line of pump drainage acid mist and using method thereof not
CN104894584A (en) * 2015-06-03 2015-09-09 江苏兴隆防腐设备有限公司 Tank body of PPH pickling tank
CN106757295A (en) * 2015-11-19 2017-05-31 新日铁住金工程技术株式会社 The control method of electrolytic clean unit and electrolytic clean unit
CN106757295B (en) * 2015-11-19 2020-05-19 日铁工程技术株式会社 Electrolytic cleaning device and control method for electrolytic cleaning device
CN114075673A (en) * 2021-11-23 2022-02-22 上海先予工业自动化设备有限公司 Low-emission pickling device

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