CN203170315U - Gas plasma discharge reactor loaded with salt catalysts - Google Patents
Gas plasma discharge reactor loaded with salt catalysts Download PDFInfo
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- CN203170315U CN203170315U CN 201320068858 CN201320068858U CN203170315U CN 203170315 U CN203170315 U CN 203170315U CN 201320068858 CN201320068858 CN 201320068858 CN 201320068858 U CN201320068858 U CN 201320068858U CN 203170315 U CN203170315 U CN 203170315U
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Abstract
The utility model discloses a gas plasma discharge reactor loaded with salt catalysts. The gas plasma discharge reactor comprises an electrode I, a dielectric barrier plate, a catalyst layer I, a discharge space, a catalyst layer II and an electrode II which are arranged sequentially from top to bottom, wherein the discharge space is at least provided with a gas inlet and a gas outlet; the electrode I is connected to one output end of a high-voltage power supply through a metal lead I; the electrode II is connected to the other output end of the high-voltage power supply through a metal lead II; the waveform of the voltage output by the high-voltage power supply is pulse shape or alternating current shape; the peak value of the voltage is between 100 V and 150 kV; the catalyst layer I and the catalyst layer II consist of oxysalt which is sulfate, nitrate, carbonate, phosphate, titanate, ferrate, manganate, vanadate or chromate; and the oxysalt comprises one or more than two of metals such as calcium, zinc, potassium, magnesium or copper and the like.
Description
Technical field
The present invention relates to a kind of plasma discharge reactor, especially a kind of gas plasma discharge reactor of load salt catalyst; The gas plasma discharge reactor of this load salt catalyst both can be used for the purification of vehicle exhaust, flue gas, atmosphere, room air and various industrial exhaust gas, also can be used for the ozone preparation.
Background technology
Plasma reactor divides by electrode structure, can be divided into coaxial center of circle type (as Fig. 9), face-face type (as Figure 10), pin-face type (as Figure 11) and pin-pin type (as Figure 12).These 4 kinds of plasma reactors have only gas between electrode.If be added with dielectric impedance between the electrode, then can be divided into coaxial center of circle medium blocking type (as Figure 13), tubulose dielectric impedance filled-type (as Figure 14), face-face medium blocking type (as Figure 15 and Figure 16) again and along face medium blocking type (as Figure 17).Among Fig. 9～Figure 17, between two electrodes of plasma reactor gas is arranged, when high voltage is added to two electrodes, can in the gas of two electrodes, form discharge space.Can produce a large amount of active chemistries during gas discharge, these chemical substances are used to various uses, are used to prepare ozone as oxygen atom.Yet, because various secondary chemical reaction very easily take place active chemistry, the service efficiency of active chemistry is reduced.
Summary of the invention
The technical problem to be solved in the present invention provides a kind of gas plasma discharge reactor that can efficiently utilize the load salt catalyst of active chemistry.
In order to solve the problems of the technologies described above, the invention provides a kind of gas plasma discharge reactor of load salt catalyst, the electrode I that comprises external high voltage power supply and be arranged in order from top to bottom, dielectric impedance plate, catalyst layer I, discharge space, catalyst layer II and electrode II; At least be provided with an air inlet and a gas outlet on the described discharge space; Described electrode I is connected to an output of high voltage source by the plain conductor I, and the electrode II is connected to the another one output of high voltage source by the plain conductor II; The voltage waveform of described high voltage source output is pulse shape or exchanges shape, voltage peak at 100V between the 150kV; Described catalyst layer I and catalyst layer II constitute by oxysalt, and described oxysalt is sulfate, nitrate, carbonate, phosphate, titanate, ferrite, manganate, vanadate or chromate; The metal that comprises in the described oxysalt is one or two or more kinds in calcium, zinc, potassium, magnesium, copper, iron, sodium, aluminium, tin, nickel, cobalt, antimony, cadmium, bismuth, chromium, manganese, strontium and the barium.
As the improvement to a kind of gas plasma discharge reactor of load salt catalyst: described electrode I and electrode II be shaped as cylinder type, plate or ball-type.
As the further improvement to a kind of gas plasma discharge reactor of load salt catalyst: the material of described electrode I and electrode II is iron, copper, silver, gold, platinum, aluminium, titanium, magnesium, manganese, lead, tin, graphite, stainless steel, copper alloy or aluminium alloy.
As the further improvement to a kind of gas plasma discharge reactor of load salt catalyst: the distance between described electrode I and the electrode II is 0.1 millimeter～50 centimetres.
As the further improvement to a kind of gas plasma discharge reactor of load salt catalyst: the material of described dielectric impedance plate is the compound of metal oxide, inorganic material, organic material or metal oxide, inorganic material and organic material; Described metal oxide is aluminium oxide, titanium oxide, zinc oxide, iron oxide, zirconia, chromium oxide, nickel oxide or magnesia; Inorganic material is silica, glass or mica; Organic material is plastics or rubber.
As the further improvement to a kind of gas plasma discharge reactor of load salt catalyst: described dielectric impedance plate be shaped as the plate that film that compactness film, compactness plate, porous membrane, porous plate, compactness and porous combine or compactness and porous combine; The thickness of described dielectric impedance plate is 10 nanometers to 10 millimeter.
A kind of using method of gas plasma discharge reactor of load salt catalyst is as follows: gas enters discharge space from the air inlet of discharge space, by leaving discharge space from the gas outlet behind the discharge space; Described electrode I and electrode II are applied to electric field on the gas of discharge space by the voltage of high voltage source output, make gas generation electric discharge phenomena; The oxygen atom that generates in the electric field of discharge space is absorbed by 2 oxygen atoms in the oxysalt molecule of catalyst layer I and catalyst layer II and forms a salt that has oxygen atom to absorb; There are reactions such as salt that oxygen atom absorbs and material that can be oxidized such as carbon, hydrocarbon, oxygen to generate carbon monoxide, water or ozone.
The gas plasma discharge reactor of load salt catalyst of the present invention is provided with catalyst layer I and the catalyst layer II that is made of oxysalt; In electrode I and electrode II connection high voltage source, electrode I and electrode II apply electric field by the high voltage source output voltage to the gas in the discharge space, make that the gas in the discharge space discharges.To between the 150kV, voltage waveform is pulse shape or exchanges shape voltage peak at 100V; In discharge space, feed gas by air inlet, gas leaves discharge space from the gas outlet after by discharge space.Oxygen carriers such as the oxygen molecule that contains in the gas, water are decomposed into oxygen atom by discharge, and the oxygen atom of generation is absorbed by 2 oxygen atoms in the oxysalt molecule and forms a salt that has oxygen atom to absorb; There are reactions such as salt that oxygen atom absorbs and material that can be oxidized such as carbon, hydrocarbon, oxygen to generate carbon monoxide, water or ozone.Under the acting in conjunction of adopting the electric field between oxysalt and electrode I and the electrode II, improved the utilization ratio of active chemistry, greatly improve gas purification efficiency.
Description of drawings
Below in conjunction with accompanying drawing the specific embodiment of the present invention is described in further detail.
Fig. 1 is the primary structure schematic diagram of the gas plasma discharge reactor of load salt catalyst of the present invention;
Fig. 2 is the primary structure schematic diagram of salt catalyst reactor module 400 among Fig. 1;
Fig. 3 is the right side structural representation of Fig. 2;
Fig. 4 is the structural representation of Fig. 1 in engine tail gas purification is handled;
Fig. 5 is second kind of structural representation of salt catalyst reactor module 400 among Fig. 1;
Fig. 6 is the third structural representation of salt catalyst reactor module 400 among Fig. 1;
Fig. 7 is the 4th kind of structural representation of salt catalyst reactor module 400 among Fig. 1;
Fig. 8 is the relative effect schematic diagram of the purification of the PM among the embodiment 2;
Fig. 9 is first kind of existing plasma reactor configurations schematic diagram (comprising electrode I 102, electrode II 103 and discharge space 101);
Figure 10 is second kind of existing plasma reactor configurations schematic diagram (comprising electrode I 202, electrode II 203 and discharge space 201);
Figure 11 is the third existing plasma reactor configurations schematic diagram (comprising electrode I 302, electrode II 303 and discharge space 301);
Figure 12 is the 4th kind of existing plasma reactor configurations schematic diagram (comprising electrode I 402, electrode II 403 and discharge space 401);
Figure 13 is the 5th kind of existing plasma reactor configurations schematic diagram (comprising outer tubular electrode 502, inner tubular electrode 503, discharge space 501 and tubulose dielectric impedance 504);
Figure 14 is the 6th kind of existing plasma reactor configurations schematic diagram (comprising plate electrode I 602, plate electrode II 603, discharge space 601 and tabular medium barrier plate 604);
Figure 15 is the 7th kind of existing plasma reactor configurations schematic diagram (comprising plate electrode I 702, plate electrode II 703, discharge space 701 and tabular medium barrier plate 704);
Figure 16 is the 8th kind of existing plasma reactor configurations schematic diagram (comprising that hollow edged electrode 802, excellent loading electrode 803, discharge space 801 and spherical medium stop 804);
Figure 17 is the 9th kind of existing plasma reactor configurations schematic diagram (comprising that electrode 902, plate electrode 903, discharge space 901 and tabular medium stop 904).
The specific embodiment
A kind of gas plasma discharge reactor of load salt catalyst comprises electrode I, electrode II, dielectric impedance plate, catalyst layer I and catalyst layer II; In the space between electrode I and the electrode II dielectric impedance plate is set, the catalyst layer I is set on the dielectric impedance plate, face the catalyst layer I, in the electrode II catalyst layer II is set, catalyst layer I and catalyst layer II are provided with discharge space; When in use, electrode I and electrode II are connected high voltage source, by after the acting in conjunction gas by discharge space being carried out discharge process between the electric field that produces between electrode I and the electrode II and catalyst layer I and the catalyst layer II.
Specified the concrete structure of gas plasma discharge reactor of load salt catalyst of the present invention and the method for use by following three embodiment.
Embodiment 1, as Fig. 1, Fig. 2 and shown in Figure 3, a kind of gas plasma discharge reactor of load salt catalyst comprises salt catalyst reactor module 400 and stainless steel reactor container 9; Salt catalyst reactor module 400 as shown in Figures 2 and 3, comprise the salt catalyst layer III 33 that is arranged in order from top to bottom, dielectric impedance plate III 23, electrode I 11, dielectric impedance plate I 21, salt catalyst layer I 31, salt catalyst layer II 32, dielectric impedance plate II 22, electrode II 12, dielectric impedance plate IV 24 and salt catalyst layer IV 34, both sides, front and back between dielectric impedance plate I 21 and the dielectric impedance plate II 22 interfix (namely by discharge space dividing plate I 61 and discharge space dividing plate II 62 by discharge space dividing plate I 61 and discharge space dividing plate II 62 respectively, isolate discharge space 4 between dielectric impedance plate I 21 and dielectric impedance plate II 22, discharge space 4 is with import and the outlet as gas communication of the two ends, the left and right sides that do not have discharge space dividing plate I 61 and discharge space dividing plate II 62); The left end of stainless steel reactor container 9 is provided with air inlet 7, the right-hand member of stainless steel reactor container 9 is provided with gas outlet 8, be provided with some groups of salt catalyst reactor modules 400 in the internal cavities of stainless steel reactor container 9, between the dielectric impedance plate III 23 of one group of salt catalyst reactor module 400 and the dielectric impedance plate IV 24 of other one group of salt catalyst reactor module 400 all discharge space dividing plate I 61 and the discharge space dividing plate II 62 by other interfix, and form other discharge space 4.
The material of above-described electrode I 11 and electrode II 12 is iron, copper, silver, gold, platinum, aluminium, titanium, magnesium, manganese, lead, tin, graphite, stainless steel, copper alloy or aluminium alloy.The material that the electrode I 11 of the gas plasma discharge reactor of load salt catalyst of the present invention and electrode II 12 adopt is stainless steel.Distance between electrode I 11 and the electrode II 12 is 0.1 millimeter～50 centimetres, and electrode I 11 and electrode II 12 all adopt writing board shape, are of a size of 90x95x0.1mm
3
The material of above-described dielectric impedance plate I 21, dielectric impedance plate II 22, dielectric impedance plate III 23 and dielectric impedance plate IV 24 is the compound of metal oxide, inorganic material, organic material or metal oxide, inorganic material and organic material.Metal oxide is aluminium oxide, titanium oxide, zinc oxide, iron oxide, zirconia, chromium oxide, nickel oxide or magnesia; Inorganic material is silica, glass or mica; Organic material is plastics or rubber.The material that dielectric impedance plate I 21 among the present invention, dielectric impedance plate II 22, dielectric impedance plate III 23 and dielectric impedance plate IV 24 adopt is that purity is 96% aluminium oxide, is of a size of 115x115x1mm
3Dielectric impedance plate I 21, dielectric impedance plate II 22, dielectric impedance plate III 23 and dielectric impedance plate IV 24 be shaped as the plate that film that compactness film, compactness plate, porous membrane, porous plate, compactness and porous combine or compactness and porous combine; The thickness of dielectric impedance plate I 21, dielectric impedance plate II 22, dielectric impedance plate III 23 and dielectric impedance plate IV 24 is 10 nanometers to 10 millimeter.At least be provided with a gas vent and a gas feed on the discharge space 4.
The material of discharge space dividing plate I 61 and discharge space dividing plate II 62 is (115 x, 10 x t) mm
3Alumina plate or micarex, t is thickness, the span of t is (material that is discharge space dividing plate I 61 and discharge space dividing plate II 62 be in the dielectric impedance sheet material matter a kind of) between 0.1 millimeter to 20 millimeters.The discharge space dividing plate I 61 that adopts among the present invention and the material of discharge space dividing plate II 62 are 115 x, 10 x 0.5mm
3Alumina plate.
Above-described salt catalyst layer III 33, salt catalyst layer I 31, salt catalyst layer II 32 and salt catalyst layer IV 34 all are oxysalts; Oxysalt is sulfate, nitrate, carbonate, phosphate, titanate, ferrite, manganate, vanadate or chromate; The metal that contains in the oxysalt is the mixture that calcium, zinc, potassium, magnesium, copper, iron, sodium, aluminium, tin, nickel, cobalt, antimony, cadmium, bismuth, chromium, manganese, strontium, barium or calcium, zinc, potassium, magnesium, copper, iron, sodium, aluminium, tin, nickel, cobalt, antimony, cadmium, bismuth, chromium, manganese, strontium or barium are formed.Oxysalt can mix the surface that is present in electrode I 11, electrode II 12 or dielectric impedance plate with other material.Above-described other material comprises noble metal or oxide.Noble metal is gold, silver and platinum, and oxide is aluminium oxide, nickel oxide, magnesia, zinc oxide, titanium oxide, iron oxide, chromium oxide, manganese oxide or silica.
When reality is used, connect metal stainless steel lead II 52 on the electrode I 11, electrode II 12 metal stainless steel lead I 51, an other end of metal stainless steel lead I 51 and metal stainless steel lead II 52 is connected with two outputs of high voltage source 300 respectively, by high voltage source 300 output voltages, the output voltage waveforms of high voltage source 300 can be pulse shape or exchange shape, voltage peak at 100V between the 150kV.
Enter the gas plasma discharge reactor gas inside of load salt catalyst of the present invention after electrode I 11 and 12 discharges of electrode II, chemical reaction takes place in gas, thereby reach the effect that purifies harmful substance or make utility.The gas plasma discharge reactor gas inside that enters the load salt catalyst can contain the liquid or solid particle.
Step is as follows when reality is used:
1, electrode I 11 is connected with high voltage source 300 with metal stainless steel lead I 51 by metal stainless steel lead II 52 respectively with electrode II 12.
2, be loaded on electrode I 11 and the electrode II 12 by high voltage source 300 output high-tension electricities, make that the discharge space 4 between electrode I 11 and the electrode II 12 forms an electric field, the gas in the discharge space 4 is ionized the back and produces electronics and ion.
Electronics (being original electronics that just exists in the electronics that produces after the ionization or the gas) obtains energy under electric field action, then with gas in molecule or atomic collision molecule or atom are decomposed.Cause various chemical reactions (the catalytic oxidation mechanism of salt as follows) by resolving into living various chemical substances:
1, the absorption reaction of oxygen atom:
2, oxygen atom emit reaction:
In the above formula,
Be oxysalt; A is sulphur, nitrogen, carbon, phosphorus, titanium, iron, manganese, vanadium or chromium; M is calcium, zinc, potassium, magnesium, copper, iron, sodium, aluminium, tin, nickel, cobalt, antimony, cadmium, bismuth, chromium, manganese, strontium or barium;
Be the absorption of oxygen atom on oxysalt; B is that carbon, hydrocarbon or oxygen etc. can oxidized materials; BO is the oxidation material of carbon, hydrocarbon or oxygen; O is oxygen atom.
For exchanging shape, positive pulse, negative pulse, positive negative pulse stuffing or negative positive pulse, the absolute value of voltage peak is at 100 volts to 150 kilovolts by high voltage source 300 added voltage waveforms, and the absolute value of voltage peak commonly used is at 1 kilovolt to 10 kilovolts.
Gas in the gas plasma discharge reactor that feeds load salt catalyst shown in Figure 1 is oxygen-containing gas (as air or oxygen), oxygen molecule is resolved into oxygen atom by electronics, the reaction of oxygen atom and oxygen molecule generates ozone then, from the gas that the gas plasma discharge reactor of load salt catalyst comes out, ozone is arranged, so the gas plasma discharge reactor of load salt catalyst can be used as ozone generator.
Embodiment 2, as shown in Figure 1, Figure 2, Figure 3 and Figure 4, a kind of gas plasma discharge reactor of load salt catalyst, concrete structure is as described in the embodiment 1, in the present embodiment, salt catalyst layer III 33, salt catalyst layer I 31, salt catalyst layer II 32 and salt catalyst layer IV 34 are sulfate, and sulfate comprises magnesium sulfate (MgSO
4), potassium sulfate (K
2SO
4), zinc sulfate (ZnSO
47H
2O), calcium sulfate (CaSO
42H
2O) or aluminum sulfate (Al
2(SO
4)
3H
2O).
In the time of concrete use, step is as follows:
1, the gas plasma discharge reactor with the load salt catalyst is placed in the thermostat, control gas temperature (thermostat control); Electrode I 11 is connected with high voltage source 300 with metal stainless steel lead II 52 by metal stainless steel lead I 51 respectively with electrode II 12.
2, be positive negative pulse stuffing and negative positive pulse by high voltage source 300 added voltage waveforms, the absolute value of voltage peak is at 1 kilovolt to 10 kilovolts.
3, under the described voltage of step 2, feed the gas that contains particle (be particulate matter, hereinafter to abbreviate PM as, main component is carbon and hydrocarbon) by air inlet 7.
4, the gas in step 3 is through behind the discharge space 4, and the oxygen molecule in the gas is broken down into oxygen atom, and oxidation reaction takes place for oxygen atom and PM, makes the PM oxidation generate carbon dioxide and carbon monoxide.Thereby reach the purpose of particulate matter.
5, purified gas is discharged by gas outlet 8.
The following stated is that PM tests the clean-up effect of specifically enumerating by the gas plasma discharge reactor of load salt catalyst of the present invention:
The PM layer of collecting is coated on surface in salt catalyst layer I 31 and salt catalyst layer II 32 again from the tail gas of engine 200.The amount of salt catalyst layer I 31 and salt catalyst layer II 32 is 0.01 milligram/centimetre of particle
2, the amount of PM layer is 0.2 milligram/centimetre
2Gas is through behind the discharge space 4, and the oxygen molecule in the gas is broken down into oxygen atom, and oxidation reaction takes place for oxygen atom and PM, makes the PM oxidation generate carbon dioxide and carbon monoxide.Result of the test as shown in Figure 8.
Embodiment 3, as shown in Figure 1, Figure 2, Figure 3 and Figure 4, a kind of gas plasma discharge reactor of load salt catalyst; Application aspect the pollutant purification processing such as the nitrogen oxide (NOx) in engine 200 tail gas, black smoke (containing a large amount of PM) or imperfect combustion hydrocarbon.
The structure of the gas plasma discharge reactor of load salt catalyst is as described in the embodiment 1, the air inlet 7 of the gas plasma discharge reactor of load salt catalyst is connected with the exhaust port 201 of automobile engine 200, generator 100(or the battery of high voltage source 300 and automobile) be connected, by generator 100(or the battery of automobile) the electric power input is provided.
Concrete implementation step is as follows:
1, the tail gas of engine 200 generations enters stainless steel reactor container 9 by exhaust port 201 through air inlet 7;
2, the gas plasma discharge reactor of load salt catalyst is handled vehicle exhaust, is example with imperfect combustion hydrocarbon, carries out purified treatment.
3, contain oxygen in the tail gas of engine 200, through being broken down into oxygen atom after discharge space 4 discharges in the stainless steel reactor container 9.
4, oxygen atom and water (containing water in the gas) reaction generates hydroxyl radical free radical.
5, oxygen atom and hydroxyl radical free radical have high oxidability, and the imperfect combustion hydrocarbon in the vehicle exhaust (as hydrocarbon and particle) is oxidized to carbon monoxide, carbon dioxide and water.
6, carbon monoxide, carbon dioxide and water are discharged by exhaust outlet 8.
That the gas plasma discharge reactor of load salt catalyst of the present invention also comprises is plate, cylinder type or these several structures of ball-type, respectively as described in embodiment 4, embodiment 5 and the embodiment 6.
Embodiment 5, as shown in Figure 6, a kind of gas plasma discharge reactor of plate load salt catalyst, the discharge space 77(that comprises the gas plasma discharge reactor of plate electrode I 71, plate electrode electrode II 72, plate dielectric impedance plate I 73, plate dielectric impedance plate II 74, plate salt catalyst layer I 75, plate salt catalyst layer II 76 and a kind of plate load salt catalyst only refers to the discharge space 77 among Fig. 6).
Embodiment 6, as shown in Figure 7, the gas plasma discharge reactor of the load salt catalyst that another is plate, the discharge space 86(that comprises the gas plasma discharge reactor of another plate electrode I 81, the electrode electrode II 82 that another is plate, the dielectric impedance plate I 85 that another is plate, the salt catalyst layer I 83 that another is plate, the salt catalyst layer II 84 that another is plate and the load salt catalyst that another is plate only refers to the discharge space 86 among Fig. 7).
At last, it is also to be noted that what more than enumerate only is a specific embodiment of the present invention.Obviously, the invention is not restricted to above embodiment, many distortion can also be arranged.All distortion that those of ordinary skill in the art can directly derive or associate from content disclosed by the invention all should be thought protection scope of the present invention.
Claims (6)
1. the gas plasma discharge reactor of load salt catalyst; External high voltage power supply; It is characterized in that: comprise the electrode I, dielectric impedance plate, catalyst layer I, discharge space, catalyst layer II and the electrode II that are arranged in order from top to bottom;
At least be provided with an air inlet and a gas outlet on the described discharge space;
Described electrode I is connected to an output of high voltage source by the plain conductor I, and the electrode II is connected to the another one output of high voltage source by the plain conductor II;
The voltage waveform of described high voltage source output is pulse shape or exchanges shape, voltage peak at 100V between the 150kV;
Described catalyst layer I and catalyst layer II constitute by oxysalt, and described oxysalt is sulfate, nitrate, carbonate, phosphate, titanate, ferrite, manganate, vanadate or chromate;
The metal that comprises in the described oxysalt is one or two or more kinds in calcium, zinc, potassium, magnesium, copper, iron, sodium, aluminium, tin, nickel, cobalt, antimony, cadmium, bismuth, chromium, manganese, strontium and the barium.
2. the gas plasma discharge reactor of load salt catalyst according to claim 1 is characterized in that: described electrode I and electrode II be shaped as cylinder type, plate or ball-type.
3. the gas plasma discharge reactor of load salt catalyst according to claim 1, it is characterized in that: the material of described electrode I and electrode II is iron, copper, silver, gold, platinum, aluminium, titanium, magnesium, manganese, lead, tin, graphite, stainless steel, copper alloy or aluminium alloy.
4. the gas plasma discharge reactor of load salt catalyst according to claim 1, it is characterized in that: the distance between described electrode I and the electrode II is 0.1 millimeter～50 centimetres.
5. the gas plasma discharge reactor of load salt catalyst according to claim 1, it is characterized in that: the material of described dielectric impedance plate is the compound of metal oxide, inorganic material, organic material or metal oxide, inorganic material and organic material; Described metal oxide is aluminium oxide, titanium oxide, zinc oxide, iron oxide, zirconia, chromium oxide, nickel oxide or magnesia; Inorganic material is silica, glass or mica; Organic material is plastics or rubber.
6. the gas plasma discharge reactor of load salt catalyst according to claim 1 is characterized in that: described dielectric impedance plate be shaped as the plate that film that compactness film, compactness plate, porous membrane, porous plate, compactness and porous combine or compactness and porous combine;
The thickness of described dielectric impedance plate is 10 nanometers to 10 millimeter.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103120922A (en) * | 2013-02-06 | 2013-05-29 | 浙江工商大学 | Gas plasma discharging reactor loaded with salt catalyst and application method |
| CN103752412A (en) * | 2013-12-31 | 2014-04-30 | 浙江富春江环保热电股份有限公司 | Spike electrode for plasma catalytic reactor, and plasma catalytic reactor comprising same |
| CN108043182A (en) * | 2017-12-15 | 2018-05-18 | 浙江工商大学 | A kind of electric discharge elementary cell stopped using multimedium and reactor and waste gas processing method |
-
2013
- 2013-02-06 CN CN 201320068858 patent/CN203170315U/en not_active Expired - Fee Related
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103120922A (en) * | 2013-02-06 | 2013-05-29 | 浙江工商大学 | Gas plasma discharging reactor loaded with salt catalyst and application method |
| CN103120922B (en) * | 2013-02-06 | 2015-06-24 | 浙江工商大学 | Gas plasma discharging reactor loaded with salt catalyst and application method |
| CN103752412A (en) * | 2013-12-31 | 2014-04-30 | 浙江富春江环保热电股份有限公司 | Spike electrode for plasma catalytic reactor, and plasma catalytic reactor comprising same |
| CN108043182A (en) * | 2017-12-15 | 2018-05-18 | 浙江工商大学 | A kind of electric discharge elementary cell stopped using multimedium and reactor and waste gas processing method |
| CN108043182B (en) * | 2017-12-15 | 2020-08-04 | 海宁蓝光环保科技有限公司 | Discharge basic unit adopting multi-dielectric barrier, reactor and waste gas treatment method |
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