CN202924990U - Quick high-acid-value oil deacidifying device - Google Patents
Quick high-acid-value oil deacidifying device Download PDFInfo
- Publication number
- CN202924990U CN202924990U CN2012205705965U CN201220570596U CN202924990U CN 202924990 U CN202924990 U CN 202924990U CN 2012205705965 U CN2012205705965 U CN 2012205705965U CN 201220570596 U CN201220570596 U CN 201220570596U CN 202924990 U CN202924990 U CN 202924990U
- Authority
- CN
- China
- Prior art keywords
- molecular sieve
- acid
- packed column
- water
- esterifier
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 239000002253 acid Substances 0.000 title claims abstract description 36
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 90
- 239000002808 molecular sieve Substances 0.000 claims abstract description 27
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000002994 raw material Substances 0.000 claims abstract description 10
- 239000004519 grease Substances 0.000 claims description 32
- 230000002378 acidificating effect Effects 0.000 claims description 11
- 239000003054 catalyst Substances 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 24
- 238000005886 esterification reaction Methods 0.000 abstract description 20
- 230000032050 esterification Effects 0.000 abstract description 19
- 238000006243 chemical reaction Methods 0.000 abstract description 9
- 239000007788 liquid Substances 0.000 abstract description 9
- 238000009833 condensation Methods 0.000 abstract description 3
- 230000005494 condensation Effects 0.000 abstract description 3
- 150000002148 esters Chemical class 0.000 abstract description 3
- 230000002441 reversible effect Effects 0.000 abstract description 3
- 239000003225 biodiesel Substances 0.000 abstract 1
- 238000005265 energy consumption Methods 0.000 abstract 1
- 238000004064 recycling Methods 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 5
- 239000003921 oil Substances 0.000 description 4
- 239000002551 biofuel Substances 0.000 description 3
- 125000005456 glyceride group Chemical group 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- 244000052616 bacterial pathogen Species 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 239000008157 edible vegetable oil Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000010773 plant oil Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000005180 public health Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Images
Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The utility model discloses a quick high-acid-value oil deacidifying device. The quick high-acid-value oil deacidifying device comprises a condensation pipe, an esterification reactor, a molecular sieve packed column and the like, wherein the bottom of the condensation pipe is connected with the top of the molecular sieve packed column and is connected with the bottom of the esterification reactor by a pipeline, so as to bring out water produced in an esterification reaction in a gaseous form with methanol vapour and condense gaseous water into liquid water, and water is absorbed timely by the molecular sieve packed column, so that the reversible reaction is carried out in an ester generation direction, the aim of quickly deacidifying oil with a high acid value is achieved, liquid methanol returns to the esterification reactor to continuously participate in reaction, circulating and recycling of methanol are realized, and the high-acid-value oil is deacidified into raw material applicable to the cup of biodiesel. The quick high-acid-value oil deacidifying device disclosed by the utility model has the advantages of simple structure, high efficiency, low energy consumption and the like.
Description
Technical field
The utility model relates to the quick deacidification device of a kind of grease, and the particularly quick deacidification device of a kind of high-acid value grease belongs to the chemical industry equipment field.
Background technology
Acid number is one of important indicator of reflection animal-plant oil quality, and acid number surpasses certain limit and means that grease is not suitable for eating, and is called high-acid value grease, (mainly contains: the waste grease after fried food as discarded food oils; The grease that the food and drink water drain reclaims, namely what is often called sewer oil or tear oil), the long-term deposit of grease surpasses the rotten grease of quality guaranteed period acidifying and reclaim the grease that obtains etc. from the various oil foot of edible oil factory and all possess this feature.High-acid value grease atmosphere pollution and environment are often come into the market after processing through simple decolouring, deodorization, depickling again by illegal retailer, owing to containing a large amount of germs and carcinogenic substance, public health are caused very big harm.Yet, for the preparation of biofuel, be but the resource of high-quality with these high-acid value greases.At present, need to carry out esterification acid reduction when utilizing preparing biological diesel fuel by high-acid-value grease processes, esterification is reversible reaction, generally reaction is carried out not thorough, according to reaction equilibrium theory, improve transformation efficiency, need to separate a kind of composition from resultant or make in reactant a kind of excessive method of composition that the reaction positive dirction is carried out.If the water that esterification is generated removes or provide excessive methyl alcohol that reaction is carried out to the direction that generates ester timely, therefore, the water that how above esterification is generated in time removes, and is significant to realizing the quick esterification acid reduction of high-acid value grease.
Summary of the invention
The utility model purpose is to provide the quick deacidification device of high-acid value grease that a kind of speed of response is fast, transformation efficiency is high.
The technical solution of the utility model is: the quick deacidification device of high-acid value grease comprises esterifier 1, prolong 2, molecular sieve packed column 3, an acidic catalyst head tank 4, methanol feedstock tank 5 and glyceride stock tank 6; Esterifier 1 is connected with molecular sieve packed column 3 by prolong 2, the bottom of molecular sieve packed column 3 is connected to the bottom of esterifier 1 by pipeline, an acidic catalyst hold-up vessel 4, methanol feedstock hold-up vessel 5 and high-acid value grease raw material storage tanks are connected and are connected with esterifier 1.
Prolong described in the utility model 2 is cylindrical tubulation structure, and the lower end is connected with molecular sieve packed column 3 by pipeline, and methanol steam and water vapor enter the top of prolong 2 from pipeline, is condensed into liquid state through prolong 2 and enters into molecular sieve packed column 3.
Molecular sieve packed column 3 described in the utility model is one to be filled with the right cylinder of molecular sieve, and its upper end joins by conduit and condenser 2, and the lower end is passed into the bottom of esterifier 1 by pipeline; Methanol steam and water vapor are liquefied as liquid methanol and water under the effect of prolong 2, during by molecular sieve packed column 3, with moisture absorption, remaining liquid methanol is got back to sustainable participation esterification in esterifier 1 through pipeline.
working process of the present utility model and principle are: according to proportioning raw materials, respectively with the catalyzer in an acidic catalyst hold-up vessel 4, methyl alcohol in methanol feedstock hold-up vessel 5, high-acid value grease in high-acid value grease head tank 6 is added in esterifier 1, start simultaneously condenser 2 and esterifier 1 is heated, glyceride stock and methyl alcohol carry out esterification under the effect of an acidic catalyst, the water that excessive methyl alcohol and esterification generate with the steam form from esterifier 1 out, arrive the top of prolong 2 by pipeline, the liquefaction of methanol vapor and water vapour is liquid first alcohol and water under the effect of prolong 2, enter into molecular sieve packed column 3, molecular sieve absorbs water, methyl alcohol is got back to sustainable participation esterification in esterifier 1 through pipeline, thereby the water of having realized one of product of producing in esterification is constantly shifted out esterifier, reached the quick deacidification purpose of high-acid value grease.
The utility model is taken with the form of gaseous state the water that esterification generates out of with methanol steam, and be condensed into liquid water, during by molecular sieve packed column with moisture absorption, this reversible reaction is carried out to the direction that generates ester, reach the purpose of the quick deacidification of high-acid value grease, liquid methanol is got back to sustainable participation reaction in esterifier, has realized the cycling and reutilization of methyl alcohol; High-acid value grease becomes the raw material that is fit to this glass biofuel through deacidification, that this device has is simple in structure, efficient is high, low power consumption and other advantages.
Description of drawings
Fig. 1 is the utility model structural representation;
In figure: the 1st, esterifier; The 2nd, prolong; The 3rd, molecular sieve packed column; The 4th, an acidic catalyst hold-up vessel; The 5th, the methanol feedstock hold-up vessel; The 6th, the high-acid value grease raw material storage tanks.
Embodiment
Below in conjunction with drawings and Examples, the utility model is described further, but protection domain of the present utility model is not limited to described content.
As shown in Figure 1, the esterification device for preparing biofuel comprises esterifier 1, prolong 2, molecular sieve packed column 3, an acidic catalyst head tank 4, methanol feedstock tank 5, glyceride stock tank 6; Esterifier 1 is connected with molecular sieve packed column 3 by prolong 2, prolong 2 is columned tubulation structure, its lower-left end is that the condensing water inlet upper right side is the outlet of water of condensation, its bottom is connected with molecular sieve packed column 3 by pipeline, molecular sieve packed column 3 is one to be filled with the right cylinder of molecular sieve, and its lower end is passed into the bottom of esterifier 1 by pipeline; An acidic catalyst hold-up vessel 4, methanol feedstock hold-up vessel 5 and high-acid value grease raw material storage tanks are connected and are connected with esterifier 1.
during use, according to proportioning raw materials respectively with the catalyzer in an acidic catalyst hold-up vessel 4, methyl alcohol in methanol feedstock hold-up vessel 5, high-acid value grease in high-acid value grease head tank 6 is added in esterifier 1, start simultaneously prolong 2 and esterifier 1 is heated, high-acid value grease raw material and methyl alcohol carry out esterification under the effect of an acidic catalyst, the water that excessive methyl alcohol and esterification generate with the steam form from the top of esterifier 1 out, arrive the top of prolong 2 by conduit, the liquefaction of methanol vapor and water vapour is liquid first alcohol and water under the effect of prolong 2, enter into molecular sieve packed column 3, molecular sieve absorbs water, methyl alcohol is got back to sustainable participation esterification in esterifier 1 through pipeline, thereby the water of having realized one of product of producing in esterification is constantly shifted out esterifier, reach the purpose of the quick deacidification of high-acid value grease.
Claims (3)
1. quick deacidification device of high-acid value grease, it is characterized in that: it comprises esterifier (1), prolong (2), molecular sieve packed column (3), an acidic catalyst hold-up vessel (4), methanol feedstock hold-up vessel (5) and high-acid value grease raw material storage tanks (6), esterifier (1) is connected with molecular sieve packed column (3) by prolong (2), the bottom of molecular sieve packed column (3) is connected to the bottom of esterifier (1) by pipeline, an acidic catalyst hold-up vessel (4), methanol feedstock hold-up vessel (5) is connected 6 with the high-acid value grease raw material storage tanks) be connected with esterifier (1).
2. the quick deacidification device of high-acid value grease according to claim 1, it is characterized in that: prolong (2) is cylindrical tubulation structure.
3. the quick deacidification device of high-acid value grease according to claim 1, it is characterized in that: molecular sieve packed column (3) is for being filled with the right cylinder of molecular sieve.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012205705965U CN202924990U (en) | 2012-11-01 | 2012-11-01 | Quick high-acid-value oil deacidifying device |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012205705965U CN202924990U (en) | 2012-11-01 | 2012-11-01 | Quick high-acid-value oil deacidifying device |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN202924990U true CN202924990U (en) | 2013-05-08 |
Family
ID=48214973
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012205705965U Expired - Fee Related CN202924990U (en) | 2012-11-01 | 2012-11-01 | Quick high-acid-value oil deacidifying device |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN202924990U (en) |
-
2012
- 2012-11-01 CN CN2012205705965U patent/CN202924990U/en not_active Expired - Fee Related
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20130508 Termination date: 20141101 |
|
| EXPY | Termination of patent right or utility model |