CN202829757U - Device for treating surfactant-containing wastewater - Google Patents

Device for treating surfactant-containing wastewater Download PDF

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Publication number
CN202829757U
CN202829757U CN 201220125622 CN201220125622U CN202829757U CN 202829757 U CN202829757 U CN 202829757U CN 201220125622 CN201220125622 CN 201220125622 CN 201220125622 U CN201220125622 U CN 201220125622U CN 202829757 U CN202829757 U CN 202829757U
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China
Prior art keywords
tank
active agent
coagulation
surface active
pump
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Expired - Lifetime
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CN 201220125622
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Chinese (zh)
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李朝林
刘鹏
崔海波
陆钢
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Dongguan Dao Hui Environmental Protection Polytron Technologies Inc
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李朝林
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  • Physical Water Treatments (AREA)
  • Treatment Of Water By Oxidation Or Reduction (AREA)

Abstract

The utility model provides a device for treating surfactant-containing wastewater. The device comprises a pretreatment tank, a main reaction tank, a coagulation and flocculation tank, a sedimentation tank, a pump power system, a dosing system and a full-automatic control system, wherein the pretreatment tank is connected with one end of the main reaction tank, the other end of the main reaction tank is connected with one end of the coagulation and flocculation tank, and the other end of the coagulation and flocculation tank is connected with the sedimentation tank; the dosing system is connected with the pretreatment tank, the main reaction tank and the coagulation and flocculation tank; and the full-automatic control system is connected with the pump power system and the dosing system through signals. The device has the advantages of being mild in reaction, thorough in degradation of pollutants, stable in treatment effect, high in effluent control rate, free of secondary pollution, compact in structure and small in occupied area.

Description

A kind of surface active agent wastewater treatment unit that contains
Technical field
The utility model discloses a kind of oxidation unit, and particularly a kind of wet oxidation device that adopts ultraviolet catalytic is used for sewage treatment area.
Background technology
Tensio-active agent is a kind ofly can reduce capillary organic compound, have the effects such as dispersion, emulsification, solubilising, foaming, washing, lubricated, anticorrosion and sterilization, almost in all industries application is arranged, and can great improvement of production process and product performance.Along with the continuous expansion of its range of application, its consumption is increase year after year also, the whole world year usage quantity above ten million ton.Most of tensio-active agents belong to the bio-refractory material, if not treated, directly enter water body, will produce severe contamination to water body, and are larger to animals and plants and the chronic toxic action of human body, and the ecosystem is caused serious harm.Therefore, the processing that contains surface active agent wastewater more and more is subject to the attention of scientific research circle and industry member.The treatment process of surface active agent wastewater is a lot, commonly used have foamet, absorption method, Coagulation Method, catalytic oxidation and some biological methods etc., but because surface active agent wastewater belongs to high concentrated organic wastewater, there are the shortcomings such as processing time period is long, processing is thorough, complex procedures, secondary pollution in traditional treatment process.We have proposed to come with a kind of ultraviolet catalytic wet oxidation technique the novel method of the tensio-active agent that exists in the degrading waste water.Ultraviolet catalytic wet oxidation technique is a kind of wet-type oxidation technology that can carry out at normal temperatures and pressures, its ultimate principle is to introduce UV-light, oxygenant and catalyzer in reaction system, utilizes their extremely strong concerted catalysis oxygenizement oxidations, the tensio-active agent in the degradation water.Finally, not only can improve the biodegradability of waste water, and can realize the tensio-active agent permineralization innoxious by further oxidation.
The utility model content
The purpose of this utility model provides a kind of device that contains surface active agent wastewater, can realize the processing of surface active agent wastewater and innoxious.
The utility model comprises a kind of surface active agent wastewater treatment unit that contains, and described device comprises pretreatment pool, main reaction pond, coagulation-flocculation pond, four main water treating ponds of settling tank, also comprises pump power system, medicine system and full-automatic control system; Described pre-treatment is connected with an end in described main reaction pond, and the other end in described main reaction pond is connected with an end in described coagulation-flocculation pond, and the other end in described coagulation-flocculation pond is connected with described settling tank; Described medicine system is connected with described pretreatment pool, described main reaction pond and described coagulation-flocculation pond; Described full-automatic control system is connected by signal with described pump power system, described medicine system.
Described pretreatment pool is provided with temperature-control device, aerating apparatus, tank gage and pH meter.
Described main reaction pond is provided with temperature-control device, aerating apparatus, tank gage and ultraviolet source lamp.
Described coagulation-flocculation pond is provided with aerating apparatus, tank gage and pH meter.
Described settling tank is provided with tank gage and magnetic valve.
Described ultraviolet source lamp is low pressure ultraviolet lamp or middle pressure ultraviolet lamp.
Described pump power system is impeller pump or surge pump.
Described medicine system comprises dosing tank and dosing pump, and dosing pump adopts peristaltic pump or electromagnetic pump.
Described full-automatic control system comprises automatic operation panel and Controlling System two portions.
Concrete, this device can have been realized completely automated operation, can realize the whole process automatization of surface active agent wastewater from original water inlet to final qualified discharge.The preparation work of wherein carrying out for the reaction conditions needs that satisfy main reaction.For the final residual catalyst that separates in the waste water, guarantee the qualified discharge of water outlet by the precipitation operation.In the whole water treatment procedure, the conveying of waste water adopts the water pump of automatization control to finish.Adding of all medicines adopts the liquid dosing pump to add.
Concrete, being provided with ultraviolet source in the main reactor, the reaction tank bottom is provided with aerating apparatus, temperature-control device, pH meter, tank gage, and the chemicals dosing plant of dosing tank and dosing pump composition.Above assembly and device all can send instruction by automatic control panel, by its operation of Controlling System implementation and operation.
Concrete, described fully automated operation is to send instruction by the automatic operation panel, Controlling System and the operation of corresponding device common implementing.
The beneficial effects of the utility model are: (1) needs to compare with the reaction conditions of high pressure (0.5-20MPa) at high temperature (150-350 ℃) with the conventional catalyst wet oxidation process, the utility model is because the introducing of ultraviolet ray and catalyzer can make wet oxidation reaction carry out under the mild conditions of normal temperature and pressure.
(2) the utility model adopts completely automated operation, give and use the user of surface active agent waste water treatment facility to bring great convenience, and saved the cost of employing professional operator, and the financial loss of having avoided a lot of human operational errors to bring, will obtain the favor of more medium-sized and small enterprises and like future.
(3) oxygenant that adopts of the utility model is one or more the combination in air, oxygen, ozone, hydrogen peroxide, the Peracetic Acid, and low price is easy to use.In addition because the adding of UV-light so that the utilization ratio of oxygenant obviously improves, thus with traditional Catalytic Wet Oxidation reacting phase ratio, the throwing amount of having saved oxygenant.
(4) introduce simultaneously UV-light and catalyzer in the reaction system, utilize their concerted catalysis oxygenizement, the concentrated surfactant Organic Pollutants in Wastewater is resolved into CO 2With harmless compositions such as water, and has simultaneously the effect of deodorizing, decolouring and sterilization and disinfection.
To sum up, device technique described in the utility model have reaction temperature and, the plurality of advantages such as processing efficiency is high, degraded is thorough, level of automation is high, floor space is little, have very high utility model value, have a extensive future.
Below in conjunction with the drawings and specific embodiments the utility model is described further.
Description of drawings
Fig. 1 is the utility model schematic flow sheet.
Among the figure, 2-pretreatment pool, 3 main reaction ponds, 4-coagulation-flocculation pond, the 5-settling tank, 6-produces bucket, the 7-temperature-control device, 8-aerating apparatus, 9-ultraviolet source, the 10-tank gage, 11-pH meter, 12-dosing tank, the 13-dosing pump, 14-Controlling System, 15-automatic operation panel, the 16-work box, the 17-magnetic valve.
Embodiment
The present embodiment is the utility model preferred implementation, and other all its principles are identical with the present embodiment or approximate with basic structure, all within the utility model protection domain.
As shown in Figure 1, the utility model provides a kind of surface active agent wastewater treatment unit that contains, described device comprises pretreatment pool, main reaction pond, coagulation-flocculation pond, four main water treating ponds of settling tank, pump power system, medicine system and full-automatic control system.
Described pretreatment pool is provided with temperature-control device, aerating apparatus, tank gage and pH meter.
Described main reaction pond is provided with temperature-control device, aerating apparatus, tank gage and ultraviolet source lamp.
1, described coagulation-flocculation pond is provided with aerating apparatus, tank gage and pH meter.
2, described settling tank is provided with tank gage and magnetic valve.
3, described ultraviolet source lamp is low pressure ultraviolet lamp or middle pressure ultraviolet lamp.
4, described pump power system is impeller pump or surge pump.
5, described medicine system comprises dosing tank and dosing pump, and dosing pump adopts peristaltic pump or electromagnetic pump.
6, described full-automatic control system comprises automatic operation panel and Controlling System two portions, sends instruction by the automatic operation panel, and the Controlling System implementation and operation is realized the full-automation operation of whole wastewater treatment process.
Concrete, the utility model main body is comprised of a pretreatment pool 2, main reaction pond 3, coagulation-flocculation pond 4, settling tank 5, and they all adopt strong corrosion resistant and temperature-resistant material to process.The power of whole water treatment system is finished by water pump 1, Controlling System 14 its automatic open and close of control.Pretreatment pool 2 is mainly used in the pre-treatment to pending waste water heats, acid-basicity is regulated and added catalyzer.Be provided with temperature-control device 7, aerating apparatus 8, tank gage 10 and pH meter 11 in the pretreatment pool 2.PH meter 11 can be according to predefined numerical value, and control dosing pump 13 adds the soda acid medicament, automatically is adjusted to target setting.Temperature-control device 7 also can be realized the automatically accurately control to wastewater temperature equally.Tank gage 10 can feed back to Controlling System constantly with liquid level, thereby realizes the accurate control to liquid level.Aerating apparatus 8 also is by its automatic open and close of pre-set time variable control.Be pumped in the main reaction pond 3 through pretreated waste water, be provided with temperature-control device 7, aerating apparatus 8, ultraviolet source 9 and tank gage 10 in it, ultraviolet source 9 is by pre-set its automatic open and close of operation sequence control of Controlling System 14, guarantee to react and open at first light source, the reaction times is closed light source when finishing.Oxygenant in the dosing tank 12 is added in the main reaction pond 3 by dosing pump 13, Controlling System 14 its dosages of control.Be pumped into after the wastewater treatment in the coagulation-flocculation pond 4, be provided with aerating apparatus 8, tank gage 10 and pH meter 11 in it, Controlling System 14 is according to pre-set pH value, add the soda acid medicament by dosing pump 13, pH meter 11 feeds back waste water ph constantly, after reaching target value, close dosing pump 13, realize the desired pH condition of coagulation-flocculation operation.Next, waste water is pumped in the settling tank 5, is provided with tank gage 10 in it, magnetic valve 17.Through after certain sedimentation time, Controlling System 14, is regularly opened and is produced bucket 6 valves discharge mud the clear water device for transferring of handling well by preseting instruction opens solenoid valve 17.The utility model adopts full automatic operation scheme, and therefore, said process all sends instruction by automatic operation panel 15, is implemented by the above-mentioned operation of Controlling System 14 controls.Work box 16 is used for stocking equipment part and the common tool that daily need is safeguarded.
The below will be described further the utility model with several specific exampless:
Embodiment one: adopt the waste water that produces in the utility model treat surface promoting agent manufacturing enterprise production process:
Get 4 liters of certain high concentrated organic wastewaters of showing to produce in the work agent factory production processes (through measuring its COD CrConcentration is 38032mg/L) put into pretreatment pool 2, regulate pH value to 7, adding simultaneously self-control Cu is that nanocatalyst is to 5g/L concentration, then enter in the reaction tank 3, adding concentration is 30% hydrogen peroxide 400mL, adopt the mechanical stirring mode to stir, open the 80W ultraviolet lamp and start reaction, carry out oxidative degradation.The COD of different degradation times CrMeasurement result shows, the reaction times is the COD of 60min, 90min, 150min and 270min sample CrDegradation rate is respectively 70.3%, 76.9%, 96.3% and 99.4%, last water outlet COD CrBe 214mg/L.
If other conditions are the same, but turn off ultraviolet lamp, the COD of 60min, 90min, 150min and 270min sample CrDegradation rate is respectively 30.3%, 46.9%, 56.3% and 66.5%, is starkly lower than device of the present utility model.
Embodiment two: adopt the utility model degraded consumption electronic product factory Cleaning Wastewater:
Its COD of actual Cleaning Wastewater 4L(of certain Electronics Factory CrConcentration is 2619mg/L) be pumped in the pretreatment pool 2 by the utility model automatic equipment, regulate pH to 4, temperature to 35 degree, and add the self-control Fe, Cu be that ionic catalyst is to 2g/L(mass ratio Fe:Cu=2:1), then be pumped in the main reaction pond 3, and add 30% hydrogen peroxide to 10g/L concentration, open simultaneously the 80W ultraviolet lamp and start this oxidizing reaction, with the air flow quantity aeration of 50L/min.The COD of different degradation times CrMeasurement result shows, the reaction times is the COD of 30min, 90min and 120min sample CrDegradation rate is respectively 53.8%, 76.6%, 96.4% last water outlet COD CrBe 93mg/L.In addition, BOD behind the processing 30min 5/ CODcr rises to 0.36 from 0.11 of former water, and biodegradability obviously improves.
Embodiment three: adopt the utility model degraded five metals source mill Cleaning Wastewater:
With 4 liters of certain Cleaning Wastewater (its COD of five metals source mill CrConcentration is 13032mg/L) be pumped in the pretreatment pool 2 by the utility model automatic equipment, regulate pH value to 6.5, adding simultaneously self-control Fe, P is that the granule type nanocatalyst is to 5g/L concentration, then be pumped in the main reaction pond 3, and add Peracetic Acid to 11g/L concentration, open simultaneously the 80W ultraviolet lamp and start this oxidizing reaction, and be aided with the air flow quantity aeration of 50L/min.The COD of different degradation times CrMeasurement result shows, the reaction times is the COD of 30min, 90min and 150min sample CrDegradation rate is respectively 19.2%, 52.3%, 99.5%, and last water outlet CODCr is 60.1mg/L; When processing to 90min, sampling records the BOD of waste water 5/ CODcr 0.12 rises to 0.30 before be untreated, and biodegradability obviously improves.
If other conditions are the same, but turn off ultraviolet lamp, the COD of 30min, 60min and 150min sample CrDegradation rate is respectively 6.1%, 15.4%, 21.5%, is starkly lower than the device of this device utility model.

Claims (8)

1. one kind contains the surface active agent wastewater treatment unit, it is characterized in that: described device comprises pretreatment pool, main reaction pond, coagulation-flocculation pond, four main water treating ponds of settling tank, also comprises pump power system, medicine system and full-automatic control system; Described pre-treatment is connected with an end in described main reaction pond, and the other end in described main reaction pond is connected with an end in described coagulation-flocculation pond, and the other end in described coagulation-flocculation pond is connected with described settling tank; Described medicine system is connected with described pretreatment pool, described main reaction pond and described coagulation-flocculation pond; Described full-automatic control system is connected by signal with described pump power system, described medicine system.
2. described a kind of surface active agent wastewater treatment unit that contains according to claim 1, it is characterized in that: described pretreatment pool is provided with temperature-control device, aerating apparatus, tank gage and pH meter.
3. described a kind of surface active agent wastewater treatment unit that contains according to claim 1, it is characterized in that: described main reaction pond is provided with temperature-control device, aerating apparatus, tank gage and ultraviolet source lamp.
4. described a kind of surface active agent wastewater treatment unit that contains according to claim 1, it is characterized in that: described coagulation-flocculation pond is provided with aerating apparatus, tank gage and pH meter.
5. described a kind of surface active agent wastewater treatment unit that contains according to claim 1, it is characterized in that: described settling tank is provided with tank gage and magnetic valve.
6. described a kind of surface active agent wastewater treatment unit that contains according to claim 3, it is characterized in that: described ultraviolet source lamp is low pressure ultraviolet lamp or middle pressure ultraviolet lamp.
7. described a kind of surface active agent wastewater treatment unit that contains according to claim 1 is characterized in that: described pump power system is impeller pump or surge pump.
8. described a kind of surface active agent wastewater treatment unit that contains according to claim 1, it is characterized in that: described medicine system comprises dosing tank and dosing pump, dosing pump adopts peristaltic pump or electromagnetic pump.
CN 201220125622 2012-03-29 2012-03-29 Device for treating surfactant-containing wastewater Expired - Lifetime CN202829757U (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104386852A (en) * 2014-10-23 2015-03-04 浙江卓锦工程技术有限公司 High-concentration surface-active-agent wastewater treating technology
CN107857408A (en) * 2017-12-08 2018-03-30 暨南大学 PPCPs purifier and processing method in a kind of drinking water source
CN108892297A (en) * 2018-08-28 2018-11-27 何旭红 A kind of oxidation equipment and its catalysed oxidation processes

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104386852A (en) * 2014-10-23 2015-03-04 浙江卓锦工程技术有限公司 High-concentration surface-active-agent wastewater treating technology
CN107857408A (en) * 2017-12-08 2018-03-30 暨南大学 PPCPs purifier and processing method in a kind of drinking water source
CN107857408B (en) * 2017-12-08 2023-05-19 暨南大学 Purifying device and treatment method for PPCPs in drinking water source
CN108892297A (en) * 2018-08-28 2018-11-27 何旭红 A kind of oxidation equipment and its catalysed oxidation processes

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Legal Events

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C14 Grant of patent or utility model
GR01 Patent grant
ASS Succession or assignment of patent right

Owner name: DONGGUAN DOHILL ENVIRONMENTAL PROTECTION TECHNOLOG

Free format text: FORMER OWNER: LI CHAOLIN

Effective date: 20140528

C41 Transfer of patent application or patent right or utility model
COR Change of bibliographic data

Free format text: CORRECT: ADDRESS; FROM: 518000 SHENZHEN, GUANGDONG PROVINCE TO: 523808 DONGGUAN, GUANGDONG PROVINCE

TR01 Transfer of patent right

Effective date of registration: 20140528

Address after: 523808 Guangdong province Dongguan Songshan Lake high tech Industrial Development Zone No. 9 Keyuan pine floor 411A room

Patentee after: Dongguan Dohill Environmental Protection Technology Co., Ltd.

Address before: 121 8D, 518000 village, Futian District, Shenzhen, Guangdong, Yitian

Patentee before: Li Chaolin

CP03 Change of name, title or address
CP03 Change of name, title or address

Address after: 523808 Block B, Block 6, International Finance IT Research and Development Center, Songshan Lake High-tech Industrial Development Zone, Dongguan City, Guangdong Province, Negative First to Second Floors

Patentee after: Dongguan Dao Hui environmental protection Polytron Technologies Inc

Address before: 523808 Guangdong province Dongguan Songshan Lake high tech Industrial Development Zone No. 9 Keyuan pine floor 411A room

Patentee before: Dongguan Dohill Environmental Protection Technology Co., Ltd.

CX01 Expiry of patent term
CX01 Expiry of patent term

Granted publication date: 20130327