CN202754811U - Separation impurity-removing device of white mud/ carbide slag-ypsum process desulfuration gypsum slurry - Google Patents

Separation impurity-removing device of white mud/ carbide slag-ypsum process desulfuration gypsum slurry Download PDF

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Publication number
CN202754811U
CN202754811U CN 201220347937 CN201220347937U CN202754811U CN 202754811 U CN202754811 U CN 202754811U CN 201220347937 CN201220347937 CN 201220347937 CN 201220347937 U CN201220347937 U CN 201220347937U CN 202754811 U CN202754811 U CN 202754811U
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gypsum
separation
communicated
steel basin
outlet
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CN 201220347937
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莫建松
刘兴利
程常杰
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Zhejiang Tianlan Environmental Protection Technology Co Ltd
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Zhejiang Tianlan Environmental Protection Technology Co Ltd
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Abstract

The utility model discloses a separation impurity-removing device of white mud/ carbide slag-gypsum process desulfuration gypsum slurry. The separation impurity-removing device comprises a one-stage separation groove separating device and a two-stage separating groove separating device, the one-stage separation groove separating device and the two-stage separating groove separating device respectively comprise a stirring groove and a settling groove, the bottoms and the middle of the stirring grooves are communicated with the bottoms and the middle of the settling grooves. A stirring paddle, a slurry pipe and a circulation pipe are arranged inside each stirring groove, the bottom of each stirring groove is provided with a slurry outlet, a suspension liquid outlet is arranged in the middle of each settling groove, and a slurry outlet of the one-stage settling groove one-stage separating device is communicated with a slurry pipe of the two-stage settling groove two-stage separating device. According to the separation impurity-removing device, the characteristics of different settling speeds of black suspended solids in the gypsum slurry and gypsum particles are utilized, a two-stage suspension stirring settling separating device is utilized to remove the black suspended solids in the gypsum slurry, the gypsum moisture content is kept less than 10 % stably, the gypsum purity is more than 90%, and the quality of white mud/ carbide slag-gypsum process desulfuration gypsum is effectively improved.

Description

The separation, impurity removal device of a kind of white clay/acetylene sludge-gypsum process desulphurization gypsum slurries
Technical field
The utility model relates to the flue gas desulfurization technique field, is specifically related to the separation, impurity removal device of a kind of white clay/acetylene sludge-gypsum process desulphurization gypsum slurries.
Background technology
Do in the white clay of sweetening agent/acetylene sludge-gypsum process flue gas desulfurization course with white clay/carbide slag, water-insoluble impurity in white clay/carbide slag and from the constantly accumulation in the absorption tower of the grey branch in the flue gas, form particle diameter below 45 μ m, true density is at 1.5~1.8g/cm 3Between the black suspension mixture, be called for short the black suspension thing.The black suspension thing is accumulated in the gypsum slurries, has reduced the stability of desulfuration efficiency and desulphurization system.After the black suspension thing enters dewatering system with the desulfurated plaster discharge, because the hydrocyclone separation technology poor effect, during the dehydration of vacuum band filter, the black suspension thing can stick on filter cloth, the gypsum surface, make the gypsum dehydration difficult, gypsum purity reduces simultaneously, and quality descends.
Notification number is dewatering and the device that the Chinese invention patent of CN1325419C discloses a kind of flue gas desulfurization gypsum slurry, next door at desulfuration absorbing tower connects drying tower, the gypsum slurries vent pipe of desulfuration absorbing tower bottom is connected to the spraying plant on drying tower top through the gypsum overboard pump, the first tributary pipe of former flue, booster fan through series connection, parget water sub-controller or smoke distributor are communicated to the mouth that advances of drying tower bottom, the drying tower bottom is provided with the gypsum displacer, the second tributary manifold of the pipe of drying tower and former flue closes, and being communicated to the mouth that advances of desulfuration absorbing tower, the smoke-uptake of desulfuration absorbing tower is connected with chimney.This device takes full advantage of former flue gas heat, finish the dehydration of desulfurated plaster slurries with lower energy consumption, hydrocyclone and the vacuum belt machine of conventional dehydration system have been saved, be applicable to the gypsum dehydration technique of wet desulfurization of flue gas by limestone-gypsum method technique, if this technique is used for the gypsum slurries dehydration of white clay/carbide slag-gypsum wet sulfur removal technology, because black suspension impurity lock outlet capacity is stronger in the gypsum slurries of white clay/carbide slag sulfur removal technology, hot flue gas can not effectively be removed this part moisture, so this technique is not suitable for the dehydration of the gypsum slurries of white clay/carbide slag-gypsum wet sulfur removal technology.
Publication number is that the Chinese patent of CN102071587A discloses a kind of method of removing black colloid substances in papermaking white mud of flue gas desulfurization absorbent, this invention is carried out the desulfurization pre-treatment to white clay, white clay is through changing the steps such as stock tank, vibratory screening apparatus, ultrasonic cleaning equipment, size-mixing tank, black jelly in the white clay is discharged with the rinse water overflow, and purity improves.Make sweetening agent with white clay after the pre-treatment, gypsum qualitt improves.Publication number is that the Chinese patent of CN102351232A discloses a kind of technique of removing ferrosilicon in the carbide slag slurries, it is the magnetic field of 0.05-0.5T by magneticstrength that carbide slag slurry sieves rear, remove ferrosilicon particle wherein, the black impurity in the desulfurated plaster is produced in the desulfurization of minimizing carbide slag, improves the quality of gypsum.Above-mentioned two kinds for the treatment of processs all are that sweetening agent is processed, and make it meet the requirement of flue gas desulfurization technique.But because white clay/and the carbide slag pre-treating technology is used limitedly, uses lessly in white clay/acetylene sludge-gypsum process flue gas desulfurization technique, and impurity affects problem to white clay/acetylene sludge-gypsum process flue gas desulphurization system and gypsum qualitt and still exists in white clay/carbide slag.
The utility model content
The utility model provides the separation, impurity removal device of a kind of white clay/acetylene sludge-gypsum process desulphurization gypsum slurries, utilize the gypsum particle characteristics different from black suspension thing subsidence rate in the gypsum slurries, adopt two-stage to suspend and stir black suspension thing in the settling separation device removal gypsum slurries, guarantee that the gypsum water ratio is stabilized in below 10%, gypsum purity effectively improves the quality of white clay/acetylene sludge-gypsum process desulphurization gypsum greater than 90%.
The separation, impurity removal device of a kind of white clay/acetylene sludge-gypsum process desulphurization gypsum slurries comprises flash trapping stage device and secondary separation device, and described flash trapping stage device and secondary separation device include:
Steel basin and subsider that bottom and middle part are communicated with mutually;
Stirring rake, slurry pipe and circulating pipe are set in the described steel basin, and described steel basin bottom is provided with the slurries outlet;
Described subsider middle part is provided with the suspension outlet;
The slurries outlet of described flash trapping stage device is communicated with the slurry pipe of described secondary separation device.
Because the foreign matter content of white clay/carbide slag is very high, contain a lot of black suspension things in the gypsum slurries of white clay/acetylene sludge-gypsum process desulphurization technology, these black suspension thing particle diameters are about 0~45 μ m, and settling velocity still still possesses certain settling character not as gypsum.Utilize the gypsum particle in the gypsum slurries different with the subsidence rate of black suspension thing, stir settlement separate with the black suspension Impurity removal in the gypsum slurries by two-stage.
In the flash trapping stage device, be deposited to the slurries bottom at the lower gypsum particle of low mixing speed (60-200rpm), the black suspension thing then is suspended in the black suspension of upper strata, because slurries are in whipped state, enter black suspension having the part gypsum near the interfacial position of black suspension, therefore subsider is set, upper strata black suspension after stirring is introduced in the subsider, again sedimentation again settles down the part gypsum particle that enters in the black suspension and is back in the slurries of steel basin bottom.
About 70% the separated removal of black suspension thing in the gypsum slurries that the flash trapping stage device separates, the underflow slurries are delivered in the secondary separation device, simultaneously by circulating pipe delivery cycle water or process water, same, under low mixing speed (60-200rpm), gypsum and black suspension thing are finished secondary separation, after separation finishes, remaining 30% the black suspension thing is separated removes in the gypsum slurries, and the underflow slurries are sent into the gypsum that dewaters to get in the vacuum band filter.
Be communicated with by curve bend between described subsider and the described steel basin bottom, inverted vacuum breaker is set in this curve bend.
Gravitate; the gypsum particle that settles down in subsider can be in curve bend flows back to the suspension steel basin very smoothly; but described steel basin and subsider bottom and middle part all are communicated with; impact is stressed; bottom tie point pressure is larger; when liquid level in the subsider reduced, slurries preferentially flowed into subsider from the bottom tie point.Therefore, in described curved bend pipeline section, inverted vacuum breaker is set, prevents adverse current, the interior upper strata suspension overflow of steel basin is advanced in the subsider.
Be communicated with by the inclination upflow tube between the middle part of described subsider and described steel basin, the entrance of described inclination upflow tube is communicated with steel basin, outlet is communicated with subsider, and entrance is higher than outlet.
The angle of described inclination upflow tube and vertical plane is 30~50 degree.
The distance of the entrance of described inclination upflow tube and steel basin bottom is 2/5~4/5 of steel basin diameter, and described suspension outlet is positioned at 10~30cm place, top of inclination upflow tube outlet.
There is not stirring action in the subsider, gypsum particle and black suspension thing all can sedimentations in subsider for the black suspension of having carried like this part gypsum particle, the black suspension that enters subsider from steel basin is tilted to current downflow, when entering subsider, below the outlet of inclination upflow tube, form turbulent flow, the turbulent flow that forms in the subsider can make sedimentation part black suspension thing Eddy diffusion rise and to enter inclination upflow tube outlet upper area, then discharge from the suspension outlet.
It is 5~45 ° gathering section that described subsider bottom has the angle of inclination, and the height of this gatherings section is 1/10~1/5 of subsider height, and this is communicated with on drawing section bottom and described curve bend in.The diameter of propeller blade of described stirring rake is 3/5~4/5 of steel basin diameter, and the distance bottom steel basin is 5~20cm.The bottom slurries can both fully be stirred.
Described slurry pipe forms concentric or eccentric structure with the stir shaft of stirring rake, and the bottom outlet is positioned at 10~20cm place, blade top of stirring rake.
Reduce the steel basin inner assembly to the interference of stirring rake blade, make the black suspension separation surface steady, thereby reduce the content near black suspension separation surface position gypsum.
Described stirring rake can be the model that is conducive to arbitrarily solid-liquid separation, can be two leaf oars, three leaf oars and other number of sheets oars.
Stirring rake is avoided in the bottom outlet of described circulating pipe, is lower than the entrance of described inclination upflow tube, and recirculated water can be mixed with described gypsum slurries to greatest extent.
The utility model also is provided with a suspension treatment trough, and described suspension treatment trough is communicated with the suspension outlet of flash trapping stage device and secondary separation device and the entrance of circulating pipe by pipeline respectively.In the suspension treatment trough, the sedimentation of black suspension thing, the clear liquor of removing the black suspension thing recycles as recirculated water.
But black suspension thing settling velocity is slow, makes in the recirculated water of recycling to contain the black suspension thing that part is not removed.Therefore, preferably, cylinder barrel shaped is arranged on described suspension treatment trough top, turbination is arranged in the bottom, the stage casing of described suspension treatment trough cylinder barrel shaped is provided with 2~3 layers every stream baffle plate or conduit, the pipeline that is communicated with described suspension outlet is positioned at described baffles or conduit below, and the pipeline that is communicated with the entrance of described circulating pipe is positioned at described top every stream baffle plate or conduit.
In the black suspension treatment trough, the black suspension thing is in every stream baffle plate or vessel layers below, and slowly deposition is finally discharged from the mud discharging mouth.Every stream baffle plate or vessel layers the black suspension thing is helped settlement action, when black suspension was passed through every stream baffle plate or conduit, the black suspension thing settled down, and clear liquor enters every stream baffle plate or conduit top, uses as recirculated water.
Described every the stream baffle plate be set to be parallel to each other some every flow, and have the angles of 30~60 degree with vertical direction, and be provided with carriage, all are fixed on this carriage every the two ends of flow.Described conduit, the some inclining tubes that comprise the back up pad of horizontal positioned and run through this back up pad, all inclining tubes are parallel to each other and have 30~60 angles of spending with vertical direction.Adjacent two layers is mutually 30~60 degree angles every the inclining tube every flow or adjacent two layers conduit that flows baffle plate and puts.
Described steel basin sidewall is provided with vision slit, and the upper end of described vision slit is higher than described inclination upflow tube entrance 10~15cm, and the lower end is lower than described inclination upflow tube entrance 30~35cm.Observe black suspension separation surface situation by vision slit, when separation surface be lower than under the inclination upflow tube entrance along the time, can regulate by increasing mixing speed, otherwise, as the same.
Per-cent described in the utility model is not in the situation that there is specified otherwise all to refer to mass percent.
The beneficial effects of the utility model:
Existing gypsum slurry separation plant includes only a suspension steel basin or one-level hydrocyclone, and after separation finished, perhaps the gypsum loss was serious, and perhaps the difficulty of the gypsum treatment after the sedimentation also easily causes separation efficiency low.The utility model arranges the two-stage tripping device to be separated, and can to greatest extent the black suspension impurity in the gypsum slurries be separated, and improves the purity of gypsum, reduces the water ratio of gypsum.
Description of drawings
Fig. 1 is structural representation of the present utility model;
Fig. 2 is the sectional view of the utility model tripping device;
Fig. 3 is the vertical view of the utility model tripping device;
Fig. 4 is the sectional view of the utility model suspension treatment trough;
Fig. 5 is the structural representation of subsider among Fig. 2, curve bend and vacuum breaker part.
Embodiment
As shown in Figure 1, the separation, impurity removal device of a kind of white clay/acetylene sludge-gypsum process desulphurization gypsum slurries comprises flash trapping stage device 1, secondary separation device 2, vacuum band filter 3 and suspension treatment trough 4.
Flash trapping stage device 1 is identical with the structure of secondary separation device 2, as shown in Figures 2 and 3, comprises steel basin 102 and subsider 111 that bottom and middle part are communicated with mutually.
Steel basin 102 is the tubular groove, and the bottom is provided with slurries outlet 106, and the center of steel basin 102 arranges stirring rake 105, stirring rake 105 adopts three leaf oars, the diameter of blade be steel basin 102 diameter 4/5, stir shaft is positioned at the center place of steel basin 102, the top links to each other with drive-motor.
Slurry pipe 103 arranges with stir shaft is concentric, and it is horn-like that bottom opening becomes, and is positioned at 15cm place, blade top, and circulating pipe 101 is close to slurry pipe 103 outlet of a little higher than slurry pipe 103 of outlet at bottom is set.
Subsider 111 is the tubular groove that arranges near steel basin 102, its top is concordant with the top of steel basin 102, the bottom has the gathering section that the pitch angle is 30 degree, the height of this gathering section is 1/5 of whole steel basin height, draw the section bottom at this and be communicated with the bottom of steel basin 102 by the curve bends 108 of central angle less than 90 degree, inverted vacuum breaker 107 is set this curve bend 108 is interior.
The middle part of steel basin 102 is communicated with by inclination upflow tube 110 with the middle part of subsider 111, the entrance of inclination upflow tube 110 is communicated with steel basin 102, and the distance apart from steel basin 102 bottoms is 3/5 of steel basin 102 diameters, the outlet of inclination upflow tube 110 is communicated with subsider 111, inclination upflow tube 110 is 45 degree with the angle of vertical plane, and entrance is higher than outlet.
The 20cm place that is higher than 110 outlets of inclination upflow tube at subsider 111 arranges suspension outlet 109, sidewall at steel basin 102 arranges vision slit 112, the upper end of vision slit 112 is higher than on inclination upflow tube 110 entrances along 15cm, and it is lower to 30cm that the lower end is lower than 110 outlets of inclination upflow tube.
The structure of suspension treatment trough 3 as shown in Figure 4, cylinder barrel shaped is arranged on top, and turbination is arranged in the bottom, is provided with 3 layers in the cylinder barrel shaped section every stream baffle plate 301, all insert every the below of stream swash plate 301 bottom of two sewer pipes 302, and obconic bottom arranges mud discharging mouth 303.
Be fixed on some on this carriage every stream baffle plate 301 by carriage and two ends and form every flow, all are parallel to each other and have the angles of 45 degree with vertical direction every flow, and adjacent two layers is put every flow mutually in angle of 45 degrees every the stream baffle plate.
As shown in Figure 1, the outlet of the slurries of flash trapping stage device 1 is communicated with the entrance of the slurry pipe of secondary separation device 2 by pipeline, and the slurries outlet of secondary separation device 2 is communicated with the slurries entrance of vacuum band filter 3; The outlet of the suspension of flash trapping stage device 1 and secondary separation device 2 is communicated with the sewer pipe 302 of suspension treatment trough 3 respectively, the circulating pipe of flash trapping stage device 1 and secondary separation device 2 respectively by pipeline be communicated to suspension treatment trough 3 every flowing swash plate 301 tops.
Between vacuum band filter 4 and suspension treatment trough 3, also be provided with pipeline and be communicated with, the waste liquid in the vacuum band filter 4 is sent back in the suspension treatment trough 3 process, also have additional the technique water pipe in the secondary separation device 2, the deficiency of replenishment cycles water.
Technical process of the present utility model is as follows:
Gypsum slurries A from white clay/acetylene sludge-gypsum process desulphurization technology delivers to flash trapping stage device 1 by slurry pipe, opens and stirs, and mixing speed 60~200rpm makes gypsum slurries be in the suspension stratification state.Continue to carry gypsum slurries, when the gypsum slurries liquid level reaches inclination upflow tube entrance, continue to increase the calcium plaster liquid measure.Afterwards, observe layering situation and the interfacial position of gypsum slurries by vision slit, suitably adjust mixing speed.When the gypsum slurries liquid level in the steel basin is 1.2~1.5 times of steel basin diameter, open the valve that the outlet of this grade separation device slurries and suspension export, the slurries outflow of taking advantage of a situation enters respectively in suspension treatment trough 3 and the secondary separation device 2.
The process water that has in advance 1/2 height in the secondary separation device 2 after gypsum slurries enters, is opened and is stirred, and opens simultaneously the process water at secondary separation device place.Other operations are with flash trapping stage device 1, when the gypsum slurries liquid level in the steel basin is 1.2~1.5 times of steel basin diameter, open the valve that this grade separation device slurries outlets and suspension export, the slurries outflow of taking advantage of a situation enters respectively in suspension treatment trough 3 and the vacuum band filter 4.
Black suspension from the suspension outlet enters suspension treatment trough 3, in suspension treatment trough 3, sewer pipe 302 vertically inserts 3 layers every flowing baffle plate below 301, the black suspension thing deposits in suspension treatment trough 3, form with flocs unit is deposited in mud discharging mouth 303, open mud discharging mouth 303, discharge black suspension thing B.Send in the two-stage tripping device as recirculated water by the clear liquor of having clarified every stream baffle plate 301 and to recycle.
Gypsum slurries from secondary separation device 2 dewaters at vacuum band filter 4, gypsum tailings C after dehydration is finished enters gypsum stacking place, then outward transport is processed or recycling, and part filtrate is delivered to the 3 interior storages of suspension treatment trough by vacuum band filter filtrate line, and part filtrate effluxes.
When in the suspension treatment trough 3 enough clear liquors being arranged, the process water of closing the secondary separation device place, ON cycle water.When recirculated water is not enough, can opens the process water D at suspension treatment trough 3 places or again open the process water at secondary separation device place.
When slurries enter the flash trapping stage device 1 from thionizer, serum density is moderate, generally do not need to pass into recirculated water, gypsum slurries is finished flash liberation in flash trapping stage device 1, when entering secondary separation device 2, concentrate because gypsum slurries has passed through one-level, need in secondary separation device 2, to pass into recirculated water or process water continuously, reduce the concentration of gypsum slurries, make the black suspension thing with floating entering in the black suspension waterborne, finally discharge from the slurries outlet of secondary separation device.
The black suspension substrate concentration is not high in slurries, perhaps when black suspension thing content requirement is not high in the gypsum, can not enable secondary separation device, can open the recirculated water of flash trapping stage device this moment, make recirculated water produce certain washing action, the separation efficiency of suitable increase flash trapping stage device to gypsum slurries.When recirculated water is not enough, can open the process water D at suspension treatment trough 3 places.In the continuous agitation of stirring rake, the black suspension thing in the gypsum constantly floats, and finally discharges from the slurries outlet.
When not opening secondary separation device 2, the outlet of the slurries of flash trapping stage device 1 directly links to each other with vacuum band filter 4 by pipeline, and gypsum dehydration is discharged.
Embodiment 1
From the gypsum slurries A of white clay-gypsum sulfur removal technology, serum density 1.13g/cm 3, solid content 26% adopts said apparatus and technique separation, impurity removal, and wherein the mixing speed of flash trapping stage device is 90rpm, and the mixing speed of secondary separation device is 90rpm, gained gypsum C water ratio 8.13%, purity 94.9%, black suspension thing content 0.31%.
Embodiment 2
From the gypsum slurries A of white clay-gypsum sulfur removal technology, serum density 1.08g/cm 3, solid content 20% adopts said apparatus and technique, only open the flash trapping stage device, while ON cycle water or process water, wherein the mixing speed of flash trapping stage device is 90rpm, gained gypsum C water ratio 10.59%, purity 91.3%, black suspension thing content 1.03%.
Embodiment 3
From the gypsum slurries A of acetylene sludge-gypsum process desulphurization technology, serum density 1.08g/cm 3, solid content 20% adopts said apparatus and technique separation, impurity removal, and wherein the mixing speed of flash trapping stage device is 90rpm, and the mixing speed of secondary separation device is 90rpm, gained gypsum C water ratio 9.76%, purity 92.7%, black suspension thing content 0.65%.
Embodiment 4
From the gypsum slurries A of acetylene sludge-gypsum process desulphurization technology, serum density 1.13g/cm 3, solid content 26% adopts said apparatus and technique, only open the flash trapping stage device, while ON cycle water or process water, wherein the mixing speed of flash trapping stage device is 90rpm, gained gypsum C water ratio 12.02%, purity 88.5%, black suspension thing content 1.15%.

Claims (8)

1. the separation, impurity removal device of white clay/acetylene sludge-gypsum process desulphurization gypsum slurries comprises flash trapping stage device and secondary separation device, it is characterized in that,
Described flash trapping stage device and secondary separation device include:
Steel basin (102) and subsider (111) that bottom and middle part are communicated with mutually;
Stirring rake (105), slurry pipe (103) and circulating pipe (101) are set in the described steel basin (102), and described steel basin (102) bottom is provided with slurries outlets (106);
Described subsider (111) middle part is provided with suspension and goes out (109);
The slurries outlet of described flash trapping stage device is communicated with the slurry pipe of described secondary separation device.
2. separation, impurity removal device according to claim 1, it is characterized in that, described subsider (111) and described steel basin (102) are communicated with by curve bend (108) between the bottom, and inverted vacuum breaker (107) is set in this curve bend (108).
3. separation, impurity removal device according to claim 2, it is characterized in that, be communicated with by inclination upflow tube (110) between the middle part of described subsider (111) and described steel basin (102), the entrance of described inclination upflow tube (110) is communicated with steel basin (102), outlet is communicated with subsider (111), and described entrance is higher than outlet.
4. separation, impurity removal device according to claim 3, it is characterized in that, the distance of the entrance of described inclination upflow tube (110) and steel basin (102) bottom is 2/5~4/5 of steel basin (102) diameter, and described suspension outlet (109) is positioned at 10~30cm place, top of inclination upflow tube (110) outlet.
5. separation, impurity removal device according to claim 4 is characterized in that, the diameter of propeller blade of described stirring rake (105) is 1/2~4/5 of steel basin (102) diameter, and the distance bottom steel basin (102) is 5~20cm.
6. separation, impurity removal device according to claim 5, it is characterized in that, it is 5~45 ° gathering section that described subsider (111) bottom has the angle of inclination, and the height of this gatherings section is 1/10~1/5 of subsider height, and this is communicated with on drawing section bottom and described curve bend in.
7. separation, impurity removal device according to claim 6, it is characterized in that, described slurry pipe (103) forms concentric or eccentric structure with the stir shaft of stirring rake (105), and the bottom outlet is positioned at 10~20cm place, blade top of stirring rake (105).
8. the described separation, impurity removal device of arbitrary claim according to claim 1~7, it is characterized in that, also be provided with a suspension treatment trough (3), described suspension treatment trough (3) is communicated with the suspension outlet of flash trapping stage device and secondary separation device and the entrance of circulating pipe by pipeline respectively.
CN 201220347937 2012-07-18 2012-07-18 Separation impurity-removing device of white mud/ carbide slag-ypsum process desulfuration gypsum slurry Expired - Fee Related CN202754811U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102765741A (en) * 2012-07-18 2012-11-07 浙江天蓝环保技术股份有限公司 Separating and purifying device and method of white mud/carbide slag-gypsum process desulphurization gypsum slurry

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102765741A (en) * 2012-07-18 2012-11-07 浙江天蓝环保技术股份有限公司 Separating and purifying device and method of white mud/carbide slag-gypsum process desulphurization gypsum slurry

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Granted publication date: 20130227

Termination date: 20200718