CN202751930U - System adopting mordenite to absorb nitric oxides - Google Patents

System adopting mordenite to absorb nitric oxides Download PDF

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Publication number
CN202751930U
CN202751930U CN2012204664258U CN201220466425U CN202751930U CN 202751930 U CN202751930 U CN 202751930U CN 2012204664258 U CN2012204664258 U CN 2012204664258U CN 201220466425 U CN201220466425 U CN 201220466425U CN 202751930 U CN202751930 U CN 202751930U
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China
Prior art keywords
absorber
cooling tower
cooling
adsorption
communicated
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Expired - Fee Related
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CN2012204664258U
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Chinese (zh)
Inventor
李华
胡登燕
郑传勇
黄银忠
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Sichuan Stong Omex Environmental Engineering Co Ltd
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Sichuan Stong Omex Environmental Engineering Co Ltd
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Priority to CN2012204664258U priority Critical patent/CN202751930U/en
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Abstract

The utility model discloses a system adopting mordenite to absorb nitric oxides. The system comprises a pre-processing system, an absorption and desorption system and a cooling collection system which are connected in sequence. The pre-processing device comprises a fan, an acid pump, a cooling tower and a screen mesh filter, wherein the fan, the cooling tower and the screen mesh filter are sequentially connected, the acid pump is connected with the bottom of the cooling tower, the fan is at the same time connected to a pipe network of the cooling rower, and the screen mesh filter is communicated with the absorption and desorption system. The system and the method of the system can be operated continuously, adsorbents are recycled repeatedly, using amount of the adsorbents is small, absorption efficiency is high, and recycling benefits are good.

Description

Adopt the system of modenite nitric oxide adsorption
Technical field
The utility model relates to the nitrogen oxide process field, especially relates to the system that adopts the modenite nitric oxide adsorption.
Background technology
Nitrogen oxide comprises multiple compounds, such as nitrous oxide, nitric oxide, nitrogen dioxide, nitrogen trioxide, dinitrogen tetroxide and dinitrogen pentoxide etc.Except nitrogen dioxide, other nitrogen oxide are all extremely unstable, meet light, wet or thermal change becomes nitrogen dioxide and nitric oxide, and nitric oxide becomes again nitrogen dioxide.Therefore, what contact in the occupational environment is that several admixture of gas often are called the smoke of gunpowder (gas), is mainly nitric oxide and nitrogen dioxide, and take nitrogen dioxide as main.Nitrogen oxide all has toxicity in various degree, under the high-temp combustion condition, and NO XMainly the form with NO exists, the NO of initial discharging XMiddle NO accounts for 95%.But NO very easily reacts with airborne oxygen in atmosphere, generates NO 2So, NO in the atmosphere XGenerally with NO 2Form exist.Airborne NO and NO 2By photochemical reaction, mutually transform and reach balance.Large or when having cloud and mist to exist in temperature, NO 2The the second important acid that further forms in the acid rain with the hydrone effect divides---nitric acid (HNO 3).When having catalyst to exist, as add suitable meteorological condition, N0 2The speed that is transformed into nitric acid is accelerated.Particularly work as NO 2With SO 2When existing simultaneously, mutually catalysis, the speed that forms nitric acid is faster, main applicable ammonia and nitrogen oxide generation chemical reaction neutralize nitrogen oxide in the industry, produce nitrogen and water after ammonia and the decompose nitrogen oxides reaction, but ammoniacal liquor volatilizees easily, cause secondary pollution, the adsorbent that the adsorption method for purifying nitrogen oxide is commonly used at present has molecular sieve, activated carbon, silica gel, mud coal etc., absorption method is because the adsorbent adsorption capacity is little, and the adsorbent use amount is large, and equipment is huge, regeneration period is long, and the efficient of absorption is low.
The utility model content
The purpose of this utility model has been to overcome the shortcoming and defect of above-mentioned prior art, and a kind of system that adopts the modenite nitric oxide adsorption is provided, and this system can move continuously, and the regeneration period is short, and adsorbent is reused, good absorbing effect.
The purpose of this utility model is achieved through the following technical solutions: the system that adopts the modenite nitric oxide adsorption, comprise the preprocessing system, adsorption-desorption system and the cooling gathering system that connect successively, described preprocessing system comprises blower fan, sour pump, cooling tower and wire gauzee filter; Wherein blower fan, cooling tower and wire gauzee filter link to each other successively, and sour pump links to each other with the bottom of cooling tower, and connect simultaneously blower fan on the pipe network of cooling tower, wire gauzee filter and adsorption-desorption system connectivity.The Main Function of wire gauzee filter is air-flow to be arranged evenly and with particle hold back.
Further, described adsorption-desorption system comprises absorber and the heater that is communicated with absorber, and absorber is communicated with wire gauzee filter and cooling gathering system simultaneously.
Further, described absorber comprises absorber one, absorber two, absorber three and absorber four, absorber one, absorber two, absorber three and absorber four all are communicated with heater, wire gauzee filter and cooling gathering system, and absorber one, absorber two, absorber three and absorber four lay respectively at the place, foursquare four angles centered by heater.The quantity of absorber is according to the needs of production setting, but at least will be set to four.
Further, described cooling gathering system comprises cooler, sour measuring tank and spinner flowmeter, and the three links to each other successively, and cooler is communicated with absorber one, absorber two, absorber three and absorber four simultaneously.
The acid measuring tank is used for measuring the quantity that absorber produces nitric acid, output for the accurate Calculation system is helpful, and spinner flowmeter claims spinner flowmeter, the device of flow is calculated in (position) that is located at the rotatable parts in the direct current pipeline by measurement, the handled easily personnel are to the control of flow, in the collection of subsequent operation to acid.
The nitric acid temperature that sucks out through the adsorption-desorption For Solutions of Systems is higher, must be cooled to 20 ℃ through cooling tower, collects behind sour measuring tank and spinner flowmeter.
In sum, the beneficial effects of the utility model are: this system and method thereof can be moved continuously, and adsorbent is the repetition regeneration, and the adsorbent use amount is little, and adsorption efficiency is high, recycles profitable.
Description of drawings
Fig. 1 is system schematic of the present utility model.
Mark and corresponding parts title in the accompanying drawing: 1-blower fan; 2-sour pump; 3-cooling tower; 4-wire gauzee filter; 5-absorber one; 6-absorber two; 7-absorber three; 8-absorber four; 9-heater; 10-cooler; 11-sour measuring tank; 12-spinner flowmeter.
The specific embodiment
Below in conjunction with embodiment and accompanying drawing, the utility model is described in further detail, but embodiment of the present utility model is not limited only to this.
Embodiment:
As shown in Figure 1, adopt the system of modenite nitric oxide adsorption, comprise the preprocessing system, adsorption-desorption system and the cooling gathering system that connect successively, described preprocessing system comprises blower fan 1, sour pump 2, cooling tower 3 and wire gauzee filter 4; Wherein blower fan 1, cooling tower 3 and wire gauzee filter 4 link to each other successively, and sour pump 2 links to each other with the bottom of cooling tower 3, and connect simultaneously blower fan 1 and lead on the pipe network of cooling tower 3 wire gauzee filter 4 and adsorption-desorption system connectivity.Acid pump 2 extracts the cooling tower 3 inner acid that generate, the waste gas that blower fan 1 is carried cleans, go out impurity such as dust in the waste gas, the acid in the cooling tower 3 is the formation soluble in water of part waste gas, collects in the bottom of cooling tower 3, adopt sour pump 2 to extract, can either prevent the acid precipitation that produces easily in the cooling tower 3, cause the reduction of cooling tower 3 efficient, can avoid occurring again corrosion phenomenon, prolonged service life, wire gauzee filter 4 even gas distribution and trapped particles things.
The heater 9 that described adsorption-desorption system comprises absorber and is communicated with absorber, and absorber is communicated with wire gauzee filter 4 and cooling gathering system simultaneously.Pass into the thermals source such as hot-air in the heater 9, with being communicated with by the open and close valve gate control between the absorber.
Described absorber comprises absorber 1, absorber 26, absorber 37 and absorber 48, absorber 1, absorber 26, absorber 37 and absorber 48 all are communicated with heater 9, wire gauzee filter 4 and cooling gathering system, and absorber 1, absorber 26, absorber 37 and absorber 48 lay respectively at the place, foursquare four angles centered by heater 9.Absorber 1, absorber 26, absorber 37 and absorber 48 are identical with distance between the heater 9, when carrying out the operation of links, the identical intermittent duty time can be arranged, so that the operation of system realization continuously, the part can not occur and walk empty phenomenon generation.
Described cooling gathering system comprises cooler 10, sour measuring tank 11 and spinner flowmeter 12, and the three links to each other successively, and cooler 10 is communicated with absorber 1, absorber 26, absorber 37 and absorber 48 simultaneously.Salpeter solution in the absorber is passed into sour measuring tank 11 after being cooled to 20 ℃ by cooler 10, and the volume of the nitric acid that sour measuring tank 11 flows through mensuration enters into the speed that spinner flowmeter 12 control nitric acid flow again, and the handled easily personnel are to the collection of nitric acid.
Take aforesaid way, just can realize preferably the utility model.

Claims (4)

1. adopt the system of modenite nitric oxide adsorption, it is characterized in that: comprise the preprocessing system, adsorption-desorption system and the cooling gathering system that connect successively, described preprocessing system comprises blower fan (1), sour pump (2), cooling tower (3) and wire gauzee filter (4); Wherein blower fan (1), cooling tower (3) and wire gauzee filter (4) link to each other successively, and sour pump (2) links to each other with the bottom of cooling tower (3), and connect simultaneously blower fan (1) on the pipe network of cooling tower (3), wire gauzee filter (4) and adsorption-desorption system connectivity.
2. the system of employing modenite nitric oxide adsorption according to claim 1, it is characterized in that: the heater (9) that described adsorption-desorption system comprises absorber and is communicated with absorber, and absorber is simultaneously with wire gauzee filter (4) with cool off gathering system and be communicated with.
3. the system of employing modenite nitric oxide adsorption according to claim 2, it is characterized in that: described absorber comprises absorber one (5), absorber two (6), absorber three (7) and absorber four (8), absorber one (5), absorber two (6), absorber three (7) and absorber four (8) all with heater (9), wire gauzee filter (4) and cooling gathering system are communicated with, and absorber one (5), absorber two (6), absorber three (7) and absorber four (8) lay respectively at the place, foursquare four angles centered by heater (9).
4. the system of employing modenite nitric oxide adsorption according to claim 3, it is characterized in that: described cooling gathering system comprises cooler (10), sour measuring tank (11) and spinner flowmeter (12), the three links to each other successively, and cooler (10) is communicated with absorber one (5), absorber two (6), absorber three (7) and absorber four (8) simultaneously.
CN2012204664258U 2012-09-14 2012-09-14 System adopting mordenite to absorb nitric oxides Expired - Fee Related CN202751930U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102836614A (en) * 2012-09-14 2012-12-26 四川四通欧美环境工程有限公司 System and method for adsorbing nitrogen oxides by use of mordenite

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102836614A (en) * 2012-09-14 2012-12-26 四川四通欧美环境工程有限公司 System and method for adsorbing nitrogen oxides by use of mordenite
CN102836614B (en) * 2012-09-14 2014-07-23 四川四通欧美环境工程有限公司 Method for adsorbing nitrogen oxides by use of mordenite

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Granted publication date: 20130227

Termination date: 20140914

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