CN202638293U - Woven reinforced hollow fiber membrane - Google Patents

Woven reinforced hollow fiber membrane Download PDF

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Publication number
CN202638293U
CN202638293U CN 201220252421 CN201220252421U CN202638293U CN 202638293 U CN202638293 U CN 202638293U CN 201220252421 CN201220252421 CN 201220252421 CN 201220252421 U CN201220252421 U CN 201220252421U CN 202638293 U CN202638293 U CN 202638293U
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CN
China
Prior art keywords
hollow fiber
fiber film
fiber membrane
utility
model
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CN 201220252421
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Chinese (zh)
Inventor
陈亦力
牛雪莲
代攀
孟莎莎
李锁定
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Beijing Originwater Membrane Technology Co Ltd
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Beijing Originwater Membrane Technology Co Ltd
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Priority to CN 201220252421 priority Critical patent/CN202638293U/en
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Publication of CN202638293U publication Critical patent/CN202638293U/en
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Abstract

The utility model discloses a woven reinforced hollow fiber membrane which comprises hollow fiber membrane yarns, wherein every three hollow fiber membrane yarns are integrated into a bundle, and a layer of net structure is woven on the external surface of each bundle of hollow fiber membrane yarns. External support fiber weaving is conducted on the membrane bundles integrated by the three hollow fiber membrane yarns, and the weaving is sparse; compared with that the external support weaving is conducted on the single hollow fiber membrane yarn, the weaving efficiency is improved greatly, woven fiber raw materials required for supporting are greatly decreased correspondingly, and the cost for producing the raw materials, production equipment cost and labor cost are further lowered.

Description

The fibrage enhancement type hollow fiber film
Technical field
The utility model relates to sewage treatment area, and specifically, the utility model relates to a kind of fibrage enhancement type hollow fiber film for membrane bioreactor.
Background technology
Polymer hollow tunica fibrosa advantage is that specific area is large, loading density is high, volume is little, treatment effeciency is high, production technology is simple, has been widely applied to the fields such as the processing of municipal wastewater, middle water reuse, medication chemistry now.Because the immanent structure of polymer hollow tunica fibrosa is loose structure, thereby its mechanical strength is not high, self-supporting hollow-fibre membrane tensile strength and bend resistance intensity are lower, its hot strength is generally in the 5MPa, when in the more serious separation of damage ratio and concentrated field, using, especially when using the air concussion cleaning method, the problems such as fracture of wire appear easily.
When doughnut film diameter was thinner, the anti-pull-off force of hollow-fibre membrane was little; When doughnut film filament diameter is thicker, because doughnut belongs to self-supporting, for keeping certain anti-flattening, must strengthen the wall thickness of hollow-fibre membrane, not only increased the production cost of hollow-fibre membrane, and the degree that the doughnut film-strength improves is limited, and more prior is that unit effective film area significantly reduces, and increases the engineering operation cost.
In order to expand the scope of application of hollow-fibre membrane in engineering of water treatment, improve the mechanical strength of polymer hollow tunica fibrosa, preparation can be used for the hollow fiber composite membrane of external pressure and inner pressed filtration simultaneously, the people such as Yoon have proposed macromolecular fibre and casting solution are carried out the compound method for preparing hollow fiber composite membrane in patent (WO03/097221), by the autonomous channel fiber and casting solution are incorporated into respectively the spinning head outlet, when contacting film forming with core liquid, casting solution carries out compound preparation hollow fiber composite membrane, but because contact and recombination time are short, Compound Degree is limited, only have the part fiber dispersion in casting solution and adhesive force very weak, cause fiber that the humidification of hollow-fibre membrane is weakened.
Xu again first-class people (application number 201110243287.7) by carrying out long fibre and casting solution compound in advance, and long fibre is positioned in the casting solution, and suitably increase long stapled tractive force and realize long fibre distributing with fully compound in order and in hollow-fibre membrane with stretching, thereby the hollow fiber composite membrane for preparing a kind of long fiber reinforcement, the mechanical strength of the hollow fiber composite membrane that makes with the method can improve 3-5 doubly.But the spinning head complex structure that the method is used, interface binding power control and technology controlling and process are difficult for realizing, the bending of long fibre in casting solution easily occur in preparation process, thereby weaken the intensity of hollow fiber composite membrane.
The people's such as Chen Yili outer support enhancement type hollow fiber film (application number 201220001563.9) is by improving the doughnut film strength at the high-intensity network structure of the outer continuous continual braiding of hollow-fibre membrane, compare with the method for in the spinning casting solution, adding fiber, easily make resulting doughnut film-strength much larger than in the spinning casting solution, adding the resulting doughnut film-strength of fiber, but production efficiency reduces, the cost of raw material increases, and causes the masking cost to increase considerably.
For the prior art above shortcomings, the utility model is proposed.
The utility model content
In view of problems of the prior art, the fibrage enhancement type hollow fiber film that the purpose of this utility model is to provide a kind of and is widely used, technique is simple, cost is low.
For realizing above-mentioned utility model purpose, the technical scheme that the utility model provides is: a kind of fibrage enhancement type hollow fiber film, comprise hollow fiber film thread, hollow fiber film thread per three integrated a branch of, the outer surface of every a branch of hollow fiber film thread is woven with one deck network structure.
Described network structure is to be formed by the high-speed knitter braiding by polyester filament, and the number of spindles of high-speed knitter is the 4-32 ingot, and bipatch is 5-50mm.
The external diameter of described hollow fiber film thread is 1mm-5mm, and the wall thickness of hollow fiber film thread is 0.1mm-1mm.
The other optimal technical scheme that the utility model provides is, described network structure is to be formed by the braiding of crochet hook machine by polyester filament, and cancellated knitting density is the 4-20 order, and the pin number of described crochet hook machine is the 3-12 pin.
The beneficial effects of the utility model are: greatly improved the doughnut film strength because the outer layer fiber braiding strengthens body, permeability and separation performance and the strength character of film body are separated, therefore, in film-forming process, reduced the content that is used for guaranteeing film silk mechanics material of main part, the masking cost is significantly reduced, and the masking composition and engineering is simplified more.
Guaranteeing to reach film silk working strength, when satisfying service requirement, production efficiency is greatly improved.The utility model is to 3 film Shu Jinhang outer support fibrages that hollow-fibre membrane is integrated, weave sparse, with respect to single hollow fiber film thread is woven outer support, braid efficiency greatly improves, required passive braided fiber raw material are reduced greatly, and raw materials for production, production equipment and cost of labor further reduce;
With respect to former hollow-fibre membrane, the method does not cause the change of hollow fiber membrane filter performance, its original loading density changes little, in the situation that guarantee its original hollow-fibre membrane serviceability, increasing in the production cost situation of seldom measuring, just can widen the use field of hollow-fibre membrane, prolong engineering service life, reduce operation, maintenance and replacement cost.
Outer weaving and raw material selection aspect select fiber softer, excellent elasticity to carry out sparse braiding, are conducive to improve hollow-fibre membrane and swing, and improve the effect of cleaning, thereby can reduce the gas consumption when cleaning, and reduce the engineering operation cost.
Description of drawings
When considered in conjunction with the accompanying drawings, by the following detailed description of reference, can more completely understand better the utility model and easily learn wherein many advantages of following, but accompanying drawing described herein is used to provide further understanding of the present utility model, consist of a part of the present utility model, illustrative examples of the present utility model and explanation thereof are used for explaining the utility model, do not consist of to improper restriction of the present utility model, wherein:
Fig. 1 is structural representation of the present utility model;
Fig. 2 is the cutaway view of Fig. 1;
Fig. 3 is the structural representation of another embodiment of the present utility model;
Fig. 4 is the cutaway view of Fig. 3.
The specific embodiment
Below in conjunction with accompanying drawing embodiment of the present utility model is described.
Embodiment 1:
Fig. 1 is structural representation of the present utility model; Fig. 2 is the cutaway view of Fig. 1; As shown in Figure 1, 2, the present embodiment adopts polyvinyl chloride (PVC) as film silk 1, the external diameter 1.5mm of film silk 1, wall thickness 0.25mm.Per three film silks are integrated a branch of, adopt braider at the outside of a branch of hollow-fibre membrane (3) braiding one deck network structure 2.The fiber filament that adopts is the 60D/1F polyester monofilament, and the number of spindles of braider is 8 ingots, and bipatch is 20mm, and the external diameter of hollow fiber membrane bundle is 4.2mm, and the thickness that outer braiding strengthens body is 0.5mm, and tensile force is 42N.
The external diameter of hollow-fibre membrane can be 1mm-5mm.The wall thickness of hollow-fibre membrane can be 0.1mm-1mm.The number of spindles of braider can be the 4-32 ingot, and bipatch can be 5mm-50mm.
The maximum stretching force of fibrage enhancement type hollow fiber film can be 300N.
Embodiment 2:
Fig. 3 is the structural representation of another embodiment of the present utility model; Fig. 4 is the cutaway view of Fig. 3; As shown in Figure 3, Figure 4, the present embodiment adopts polyvinyl chloride (PVC) as film silk 1, the external diameter 1.6mm of film silk 1, wall thickness 0.5mm.Per three film silks are integrated a branch of, adopt cloche at the outside of hollow-fibre membrane tow braiding one deck network structure 2.The fiber filament that adopts is the 60D/1F polyester monofilament, and the pin number of cloche is 3 pins, and knitting density is 6 pin orders.The external diameter of fibrage enhancement type hollow fiber film bundle is 4.2mm, and the thickness that outer braiding strengthens body is 0.5mm, and hot strength is 20N.
The external diameter of hollow-fibre membrane can be 1mm-5mm.The wall thickness of hollow-fibre membrane can be 0.1mm-1mm.The pin number of cloche can be the 3-12 pin, and knitting density can be 4-20 pin order.
The maximum stretching force of fibrage enhancement mode PVDF hollow-fibre membrane is 200N.
The film silk of the utility model enhancement type hollow fiber film can adopt polysulfones, polyether sulfone, Kynoar or polyvinyl chloride material, and the outer surface network structure of the utility model enhancement type hollow fiber film is by the terylene of 20D-1000D, polyamide fibre, polypropylene fibre, viscose rayon or fiberglass braided or knitting forming.
The above embodiment; it is preferred embodiment of the present utility model; be not to limit the utility model practical range; therefore all according to the described apparent change of the utility model claim; and other does not break away from the change of the utility model essence, all should be included within the protection domain of the present utility model.

Claims (4)

1. a fibrage enhancement type hollow fiber film comprises hollow fiber film thread, it is characterized in that, described hollow fiber film thread per three integrated a branch of, the outer surface of every a branch of hollow fiber film thread is woven with one deck network structure.
2. fibrage enhancement type hollow fiber film according to claim 1 is characterized in that, described network structure is to be formed by the braider braiding by polyester filament, and the number of spindles of high-speed knitter is the 4-32 ingot, and bipatch is 5-50mm.
3. fibrage enhancement type hollow fiber film according to claim 1 is characterized in that, the external diameter of described hollow fiber film thread is 1mm-5mm, and the wall thickness of hollow fiber film thread is 0.1mm-1mm.
4. outer support enhancement type hollow fiber film according to claim 1 is characterized in that, described network structure is to be formed by the braiding of crochet hook machine by polyester filament, and cancellated knitting density is the 4-20 order, and the pin number of described crochet hook machine is the 3-12 pin.
CN 201220252421 2012-05-30 2012-05-30 Woven reinforced hollow fiber membrane Expired - Lifetime CN202638293U (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103055707A (en) * 2013-01-09 2013-04-24 浙江开创环保科技有限公司 Production method and device for woven hollow fiber membranes
CN107904734A (en) * 2017-11-22 2018-04-13 哈尔滨工业大学 A kind of high-strength, High-elasticity conductive fiber and preparation method thereof
CN107952369A (en) * 2016-10-14 2018-04-24 中国科学院大连化学物理研究所 A kind of hollow fiber membrane contactors and its application
CN109572073A (en) * 2018-12-07 2019-04-05 天津工业大学 A kind of outer surface or inner surface conductivity type hollow membrane and preparation method
US10906006B2 (en) 2017-10-12 2021-02-02 Tianjin Polytechnic University Homogeneous fiber reinforced PVDF hollow fiber membrane and preparation method thereof

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103055707A (en) * 2013-01-09 2013-04-24 浙江开创环保科技有限公司 Production method and device for woven hollow fiber membranes
CN103055707B (en) * 2013-01-09 2015-09-02 浙江开创环保科技股份有限公司 A kind of production method and process units thereof weaving rear hollow-fibre membrane
CN107952369A (en) * 2016-10-14 2018-04-24 中国科学院大连化学物理研究所 A kind of hollow fiber membrane contactors and its application
CN107952369B (en) * 2016-10-14 2020-06-09 中国科学院大连化学物理研究所 Hollow fiber membrane contactor and application thereof
US10906006B2 (en) 2017-10-12 2021-02-02 Tianjin Polytechnic University Homogeneous fiber reinforced PVDF hollow fiber membrane and preparation method thereof
CN107904734A (en) * 2017-11-22 2018-04-13 哈尔滨工业大学 A kind of high-strength, High-elasticity conductive fiber and preparation method thereof
CN109572073A (en) * 2018-12-07 2019-04-05 天津工业大学 A kind of outer surface or inner surface conductivity type hollow membrane and preparation method

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C14 Grant of patent or utility model
GR01 Patent grant
TR01 Transfer of patent right

Effective date of registration: 20190322

Address after: 101499 No.1 Building, 61 Youth Road, Huairou District, Beijing 0323

Patentee after: Shuichuang (Beijing) Technology Co., Ltd.

Address before: 100407 No. 4 South Second Street, Paradise Park, Yanqi Economic Development Zone, Huairou District, Beijing

Patentee before: Beijing Bishui Yuanmo Science and Technology Co., Ltd.

TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20190506

Address after: 100407 No. 4 South Second Street, Paradise Park, Yanqi Economic Development Zone, Huairou District, Beijing

Patentee after: Beijing Bishui Yuanmo Science and Technology Co., Ltd.

Address before: 101499 No.1 Building, 61 Youth Road, Huairou District, Beijing 0323

Patentee before: Shuichuang (Beijing) Technology Co., Ltd.

TR01 Transfer of patent right
CX01 Expiry of patent term

Granted publication date: 20130102

CX01 Expiry of patent term