CN202594831U - Online reproducible iron-carbon microelectrolysis continuous wastewater treatment device - Google Patents
Online reproducible iron-carbon microelectrolysis continuous wastewater treatment device Download PDFInfo
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- CN202594831U CN202594831U CN 201120502851 CN201120502851U CN202594831U CN 202594831 U CN202594831 U CN 202594831U CN 201120502851 CN201120502851 CN 201120502851 CN 201120502851 U CN201120502851 U CN 201120502851U CN 202594831 U CN202594831 U CN 202594831U
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Abstract
The utility model discloses an online reproducible iron-carbon microelectrolysis continuous wastewater treatment device. The main body of the device is a barrel type tower, wherein the tower is divided into an upper cover, an upper shell, a middle tower body and a tower base, the adjacent joints of the upper cover, the upper shell, the middle tower body and the tower base are connected through high-temperature-resistant organosilicone sealing gaskets, and the tower body is separated into an upper area, a middle area and a lower area through a meshed cover plate and a meshed clapboard; and the device is characterized in that the middle area is positioned in the middle tower body which is made of a high/low-temperature-resistant ceramic material, is used for filling scrap iron and activated carbon, and is a core part of iron-carbon microelectrolysis continuous wastewater treatment; an electromagnetic heating sleeve is arranged outside the middle tower body and is used for rapidly heating the scrap iron in the middle area; the lower area is a tower base area and is mainly used for collecting and discharging waste residue, introducing waste water and aerating; and the upper area is a clear-water-discharging, gas-discharging and filler-filling area. By the device, dynamic continuous water treatment can be performed, iron-carbon scrap is not discharged, a small amount of filler is replaced, and treatment cost is low.
Description
Technical field
The utility model relates to the little electrolysis wastewater water treatment device of iron charcoal, particularly a kind of can the little electrolysis organic waste water of online regenerated iron charcoal apparatus for continous treatment.
Background technology
Iron charcoal micro-electrolysis method is to utilize Principles of Metal Erosion, the technology of handling through the microcell waste water that forms iron and carbon.This method uses waste iron filing to be raw material, and " treatment of wastes with processes of wastes against one another ", with low cost, and also use range is wide, treatment effect is good, long service life.Since mining company's invention iron charcoal micro-electrolysis treatment waste water technology is ruled together by Japan, there have been many inventors to utilize this principle in the world, developed various wastewater treatment equipments through original creation design, improvement flow process etc.Yet; Existing iron carbon micro electrolyser all various defect can occur in use for some time, and the most outstanding is: 1, stopping composition (iron filings and gac) lumps, occurs channeling easily; Or whole little electrolysis zone stops up, the waste water difficulty is passed through, and reduces processing efficiency greatly; Though 2 have the design fluidized-bed can solve obstruction, caking phenomenon, this method will keep that power consumption is big, stopping composition runs off easily; 3, iron charcoal micro-electrolysis method mainly is little electrolytic oxidation to the handling principle of organic waste water, and its principle is:
(1) because the electromotive force of iron and carbon has notable difference, iron filings that in electrolyte solution, are in contact with one another and carbon constitute numerous small galvanic cells, and iron is corroded as anode, and carbon is as negative electrode; Fe constantly loses electronics and becomes Fe
2+Get into solution, the electron transport that loses is to the surface of carbon, H in solution
+When concentration is higher, H
+Surperficial electron gain at carbon reacts; Under oxygen atmosphere, O
2At carbon surface electron gain generation chemical reaction.Electrode reaction is following:
1., anode (Fe): Fe-2e → Fe
2+
2., negative electrode (C): 2H
++ 2e → 2 [H] → H
2
When aerobic: negative electrode: O
2+ H
2O+4e → 4OH
Fenton reaction: O also can take place under the sour environment
2+ 2H
++ 2e=H
2O
2
Fe
2+?+?H
2O
2?=?Fe（OH）
2+?+?OH*
Contain N, S, O, P, the equiatomic organism of As, N, S, O, P, last not one-tenth key lone-pair electron ability and the Fe of As
2+On outer unoccupied orbital form co-ordination bond; Form baroque macromolecule complex, reduced water-solublely, make these organism have certain colloid property, can be able to deposition through the adsorption bridging effect and remove.
But organism is except at Fe
2+On absorption need the time short outside, those difficulties are attracted to Fe
2+On organism have only by oxidation removal, oxidising process needs the long period, must be adsorbed on the gac earlier, and then generated acid by the OH* free-radical oxidn, last and Fe
2+Or Fe
3+Generate sedimentable matter, and obtain handling.The problem that two aspects might occur like this:
If 1 waste strength is very high, after charcoal absorption was saturated, system had little time all to decompose adsorbed organism, and organism unnecessary in the waste water certainly will directly pass through device, got rid of from the exit, so just can't reach the purpose of processing!
Can't be if contain in 2 waste water by the organism of the little electrolytic waste water treatment equipment degraded of this iron charcoal, this organism also can only along with gac constantly adsorbs, finally be reached capacity by charcoal absorption.Continue to handle, then unnecessary organism also can directly pass through device, gets rid of from the exit.
With regard to above-mentioned situation, we adopt the way of changing stopping composition (gac+iron filings) usually, and this has following three aspect shortcomings:
1, the waste material of whole device must all be changed, and waste material is changed difficulty, wastes time and energy.
2, the waste material that changes because contain iron filings, toxic organic compound, organism molysite, is seen off and please Activated Carbon Production producer be regenerated, and has both damaged the other side's equipment easily, also can cause environmental pollution to the other side again, and therefore general producer all is reluctant to accept.
3, the stopping composition that changes has not just become solid refuse as if not dealing carefully with, and not only cause secondary pollution, and cost is very high.
Summary of the invention
In view of the above problems, the purpose of the utility model is to provide
A kind of can the continuous wastewater treatment equipment of the online little electrolysis of regenerated iron charcoal, the continuous wastewater treatment equipment of the little electrolysis of this iron charcoal solves and exists in the little electrolytic waste water treatment equipment of present iron charcoal: waste material is changed difficulty, and the waste material of wasting time and energy, changing is difficult to send outside regeneration, solid refuse and causes secondary pollution, problem that cost is high.
The technical scheme of the utility model is:
A kind of can the continuous wastewater treatment equipment of the online little electrolysis of regenerated iron charcoal, apparatus main body is one barrel of formula tower body, tower body is divided into: and loam cake, upper housing, middle part body of the tower and tower base, the adjacent of loam cake, upper housing, middle part body of the tower and tower base is connected with high temperature resistant organosilicon gasket; Separate three big zones, upper, middle and lower by netted cover plate and netted dividing plate in the tower body; It is characterized in that: central region is within the middle part body of the tower with the high-low temperature resistant ceramic material; Be used to fill waste iron filing and gac; Be the continuous wastewater treatment of the little electrolysis of iron charcoal core, the middle part body of the tower is outside equipped with the electromagnetism heating jacket, is used for the waste iron filing rapid heating in the central region; Lower region is the tower base district, mainly is that waste residue collection and discharging, waste water get into, aeration, is provided with waterwater entrance, aeration opening, slag-drip opening, but each inlet all is provided with the valve switch; Upper area is clear water discharging, gaseous emission, the additional zone of filler, is provided with clear water output, loam cake, SV, aeration and regeneration off gases outlet, upper housing.
The device of the utility modelComprise that mainly slag-drip opening, netted dividing plate, waste iron filing (piece, rod, nail, pearl, silk), gac, clear water output, loam cake (can open; Be convenient to feed in raw material), SV, aeration and regeneration off gases outlet, electromagnetism heating jacket, waterwater entrance, aeration opening, netted cover plate, upper housing, middle part body of the tower, tower base; It is characterized in that: this can the continuous wastewater treatment equipment main body of the little electrolysis of online regenerated iron charcoal be one barrel of formula tower body; Tower body is divided into: loam cake, upper housing, middle part body of the tower and tower base; Wherein the middle part body of the tower is by the high-low temperature resistant ceramic material, and the adjacent of loam cake, upper housing, middle part body of the tower and tower base is connected with high temperature resistant organosilicon gasket; Separate three big zones, upper, middle and lower by netted cover plate and netted dividing plate in the tower body: central region is within the middle part body of the tower with ceramic material; Being used to fill waste iron filing (piece, rod, nail, pearl, silk) and gac, is the continuous wastewater treatment of the little electrolysis of iron charcoal core; The middle part body of the tower of ceramic material is outside equipped with the electromagnetism heating jacket, is used for ground waste iron filing (piece, rod, nail, pearl, silk) rapid heating in the central region; Lower region is the tower base district, mainly is that waste residue collection and discharging, waste water get into, aeration, is provided with waterwater entrance, aeration opening, slag-drip opening, but each inlet all is provided with the valve switch; Upper area is clear water discharging, gaseous emission, the additional zone of filler, is provided with clear water output, loam cake (can open, be convenient to feed in raw material), SV, aeration and regeneration off gases outlet, upper housing.
The principle of the utility model is:
1, wastewater treatment: waste water is behind the waterwater entrance access to plant; In aeration opening; Under the situation that the slag-drip opening valve is all closed, up flow through central region, iron charcoal little electrolysis zone generation redox reaction or absorption reaction at the middle part (its principle as previously mentioned) by base; Objectionable impurities in the waste water (organism, heavy metal etc.) is degraded and generates throw out (organic molysite etc.) and slowly gather the tower bottom zone, is regularly cleaned out by slag-drip opening; Reacted clear water slowly by the top clean water outlet discharge (if also contain tiny jello in the clear water, can by outer other device of clean water outlet as: coagulation basins etc. carry out second-stage treatment).
2, according to the little electrolysis principle of iron charcoal: in the wastewater treatment process of this tower, need oxygen element, therefore, after waste water gets into tower body, just open the aeration opening valve and carry out aeration (air or oxygen), so that the redox reaction requisite oxygen to be provided.
3, manipulation of regeneration: the iron charcoal zone at tower middle part is after wastewater treatment after a while; When the absorption of iron filings and gac is tending towards state of saturation (it is fixed to look effluent quality); And can close waterwater entrance, aeration opening, slag-drip opening valve, and to open the middle part outer electromagnetism heating jacket of body of the tower and carry out contactless quick waste iron filing (piece, rod, nail, pearl, silk) heating the inside, temperature can be elevated to 100～700 ℃ rapidly from normal temperature; Because rate of heating is fast; The liquid water of periphery was heated up, is gasified in moment, and the high temperature gas flow that is produced simultaneously also heats gac rapidly, made the liquid water and the also instantaneous expansion gasification of organic solute of gac the inside; The non-volatile organism of gac the inside absorption makes gac reach the regeneration purpose at high temperature by charing at last." aeration and the regeneration off gases outlet " of the regeneration off gases (high temperature water gas and the organism of taking out of) that adds thermogenesis in addition through loam cake is discharged to other emission-control equipment (as: cuvette, condensing and recycling device, incinerator etc.) and carries out aftertreatment; SV is mainly used in explosion-proof.
4, in above-mentioned rapid heat-processed, some be adsorbed on the gac with iron filings on organic molysite also can under the high temperature oxygen-free environment, take place:
(R)n-Fe?
?Fe?+?C?+?H
2O?+CO
2
The oxidized iron filings of gac the inside absorption have also obtained reduction like this, can participate in iron charcoal micro-electrolysis reaction again and handle waste water.
5, above-mentioned 3,4 liang of processes, not only regenerated gac and iron filings, and often regeneration will lack the also common relatively iron carbon micro electrolyser of the waste residue that sinks to territory, tower base area.If from saving, the user also can transfer to the little electrolysis zone of iron charcoal top to the organic molysite that is deposited to the tower bottom zone, together regeneration (principle is the same).So just there is not solid refuse to produce.If the tower bottom sediment is too many, transfer to the regeneration of tower central area to it, cause the subsequent wastewater treatment quality easily, we do stopping composition use or landfill after also can putting into other device calcination process to the waste residue that clears from slag-drip opening again.
The utility model has the advantages that: can the continuous wastewater treatment equipment of the online little electrolysis of regenerated iron charcoal be a kind of dynamic successive water treatment device originally 1,, can continuously handle waste water.2, the filler of whole device needn't all be changed, and just adds inside at a distance from for some time again and just can.3, not having iron charcoal waste material to see off please Activated Carbon Production producer regenerated situation.4, solid refuse do not discharge or discharge few, can secondary pollution, 4, filler changes less, processing cost is low.
Description of drawings
Fig. 1 is the structural representation of the utility model embodiment " a kind of can the continuous wastewater treatment equipment of the online little electrolysis of regenerated iron charcoal ".
Embodiment
With reference to accompanying drawing 1: a kind of of the utility model embodiment can the continuous wastewater treatment equipment of the online little electrolysis of regenerated iron charcoal, comprises 1, slag-drip opening, and 2, netted dividing plate, 3, waste iron filing (piece, rod, nail, pearl, silk), 4, gac; 5, clear water output, 6, loam cake (can open, be convenient to feed in raw material), 7, SV; 8, aeration and regeneration off gases outlet, 9, the electromagnetism heating jacket, 10, waterwater entrance, 11, aeration opening; 12, netted cover plate, 13, upper housing, 14, the middle part body of the tower, 15, tower base.
[0012]Present embodiment is described can the continuous wastewater treatment equipment of the online little electrolysis of regenerated iron charcoal, and its structure comprises:
1., apparatus main body is a cylindrical tower body, tower body is divided into: loam cake 6, upper housing 13, middle part body of the tower 14 and tower base 15.
2. the loam cake of tower, upper housing, tower base are made by metallic substance.The middle part body of the tower is by the high-low temperature resistant ceramic material, and the adjacent of loam cake, upper housing, middle part body of the tower and tower base is connected with high temperature resistant organosilicon gasket
③。Separate three big zones, upper, middle and lower by netted cover plate 12 and netted dividing plate 2 in the tower body: central region is within the middle part body of the tower 14 with ceramic material; Being used to fill waste iron filing 3 (piece, rod, nail, pearl, silk) and gac 4, is the continuous wastewater treatment of the little electrolysis of iron charcoal core.
4. the middle part body of the tower of ceramic material is outside equipped with electromagnetism heating jacket 9, is used for the waste iron filing in the central region 3 rapid heating such as (piece, rod, nail, pearl, silks).
5. lower region is the tower base district in the tower, mainly is that waste residue collection and discharging, waste water get into, aeration, is provided with waterwater entrance 10, aeration opening 11, slag-drip opening 1, but each inlet all is provided with the valve switch.
6. upper area is clear water discharging, gaseous emission, the additional zone of filler, is provided with clear water output, loam cake 6 (can open, be convenient to feed in raw material), SV 7, aeration and regeneration off gases outlet 8, upper housing 13.
The described a kind of principle of work that can the continuous wastewater treatment equipment of the online little electrolysis of regenerated iron charcoal of the utility model embodiment:
1, wastewater treatment: waste water is behind the waterwater entrance access to plant; In aeration opening; Under the situation that the slag-drip opening valve is all closed, up flow through central region, iron charcoal little electrolysis zone generation redox reaction or absorption reaction at the middle part (its principle as previously mentioned) by base; Objectionable impurities in the waste water (organism, heavy metal etc.) is degraded and generates throw out (organic molysite etc.) and slowly gather the tower bottom zone, is regularly cleaned out by slag-drip opening; Reacted clear water slowly by the top clean water outlet discharge (if also contain tiny jello in the clear water, can by outer other device of clean water outlet as: coagulation basins etc. carry out second-stage treatment).
2, according to the little electrolysis principle of iron charcoal: in the wastewater treatment process of this tower, need oxygen element, therefore, after waste water gets into tower body, just open the aeration opening valve and carry out aeration (air or oxygen), so that the redox reaction requisite oxygen to be provided.
3, manipulation of regeneration: the iron charcoal zone at tower middle part is after wastewater treatment after a while; When the absorption of iron filings and gac is tending towards state of saturation (it is fixed to look effluent quality); And can close waterwater entrance, aeration opening, slag-drip opening valve, and to open the middle part outer electromagnetism heating jacket of body of the tower and carry out contactless quick waste iron filing (piece, rod, nail, pearl, silk) heating the inside, temperature can be elevated to 100～700 ℃ rapidly from normal temperature; Because rate of heating is fast; The liquid water of periphery was heated up, is gasified in moment, and the high temperature gas flow that is produced simultaneously also heats gac rapidly, made the liquid water and the also instantaneous expansion gasification of organic solute of gac the inside; The non-volatile organism of gac the inside absorption makes gac reach the regeneration purpose at high temperature by charing at last." aeration and the regeneration off gases outlet " of the regeneration off gases (high temperature water gas and the organism of taking out of) that adds thermogenesis in addition through loam cake is discharged to other emission-control equipment (as: cuvette, condensing and recycling device, incinerator etc.) and carries out aftertreatment; SV is mainly used in explosion-proof.
4, in above-mentioned rapid heat-processed, some be adsorbed on the gac with iron filings on organic molysite also can under the high temperature oxygen-free environment, take place:
(R)n-Fe?
?Fe?+?C?+?H
2O?+CO
2
The oxidized iron filings of gac the inside absorption have also obtained reduction like this, can participate in iron charcoal micro-electrolysis reaction again and handle waste water.
5, above-mentioned 3,4 liang of processes, not only regenerated gac and iron filings, and often regeneration will lack the also common relatively iron carbon micro electrolyser of the waste residue that sinks to territory, tower base area.If from saving, the user also can transfer to the little electrolysis zone of iron charcoal top to the organic molysite that is deposited to the tower bottom zone, together regeneration (principle is the same).So just there is not solid refuse to produce.If the tower bottom sediment is too many, transfer to the regeneration of tower central area to it, cause the subsequent wastewater treatment quality easily, we do stopping composition use or landfill after also can putting into other device calcination process to the waste residue that clears from slag-drip opening again.
Claims (1)
1.
A kind of can the continuous wastewater treatment equipment of the online little electrolysis of regenerated iron charcoal, apparatus main body is one barrel of formula tower body, tower body is divided into: and loam cake, upper housing, middle part body of the tower and tower base, the adjacent of loam cake, upper housing, middle part body of the tower and tower base is connected with high temperature resistant organosilicon gasket; Separate three big zones, upper, middle and lower by netted cover plate and netted dividing plate in the tower body; It is characterized in that: central region is within the middle part body of the tower with the high-low temperature resistant ceramic material, is the continuous wastewater treatment of the little electrolysis of iron charcoal core, and the middle part body of the tower is outside equipped with the electromagnetism heating jacket, is used for the waste iron filing rapid heating in the central region; Lower region is the tower base district, mainly is that waste residue collection and discharging, waste water get into, aeration, is provided with waterwater entrance, aeration opening, slag-drip opening, but each inlet all is provided with the valve switch; Upper area is clear water discharging, gaseous emission, the additional zone of filler, is provided with clear water output, loam cake, SV, aeration and regeneration off gases outlet, upper housing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201120502851 CN202594831U (en) | 2011-12-06 | 2011-12-06 | Online reproducible iron-carbon microelectrolysis continuous wastewater treatment device |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201120502851 CN202594831U (en) | 2011-12-06 | 2011-12-06 | Online reproducible iron-carbon microelectrolysis continuous wastewater treatment device |
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| Publication Number | Publication Date |
|---|---|
| CN202594831U true CN202594831U (en) | 2012-12-12 |
Family
ID=47312389
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201120502851 Expired - Fee Related CN202594831U (en) | 2011-12-06 | 2011-12-06 | Online reproducible iron-carbon microelectrolysis continuous wastewater treatment device |
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|---|---|
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109264833A (en) * | 2018-11-30 | 2019-01-25 | 广州握胜环保科技有限公司 | A kind of device making iron-carbon micro-electrolytic material automatic regeneration |
| CN110211721A (en) * | 2019-07-11 | 2019-09-06 | 中国工程物理研究院应用电子学研究所 | A kind of drying device and drying means for reactor core wastewater treatment based on microwave |
| CN110252425A (en) * | 2019-07-03 | 2019-09-20 | 中国科学院生态环境研究中心 | A kind of activation method inactivating iron-carbon micro-electrolysis filler |
-
2011
- 2011-12-06 CN CN 201120502851 patent/CN202594831U/en not_active Expired - Fee Related
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109264833A (en) * | 2018-11-30 | 2019-01-25 | 广州握胜环保科技有限公司 | A kind of device making iron-carbon micro-electrolytic material automatic regeneration |
| CN110252425A (en) * | 2019-07-03 | 2019-09-20 | 中国科学院生态环境研究中心 | A kind of activation method inactivating iron-carbon micro-electrolysis filler |
| CN110211721A (en) * | 2019-07-11 | 2019-09-06 | 中国工程物理研究院应用电子学研究所 | A kind of drying device and drying means for reactor core wastewater treatment based on microwave |
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|---|---|---|---|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20121212 Termination date: 20141206 |
|
| EXPY | Termination of patent right or utility model |