Condensing dioxygen method desulfurization and denitrification integral device
Technical field
The utility model relates to and a kind of the burning and exhausting flue gas is carried out the device of purified treatment, relates in particular to a kind of condensing dioxygen method desulfurization and denitrification integral device.
Background technology
Worldwide, it is main energy sources that most of developing countries are still with coal, and China is one of them, and coal accounts for China's primary energy production and consumption ratio always more than 70%, coal combustion exhaust such as sulfur dioxide SO
2, nitrogen oxide NO
X, pollutants such as PM, heavy metal are serious day by day to the influence that environment produces, and SO wherein
2, NO
XBe the main protozoa that acid rain forms,, fundamentally administer SO in acid rain problem serious day by day today
2, NO
XDischarging imperative.
At present, be used for the technology and the equipment of coal burning flue gas desulfurization, denitration and flue gas ash removal, most still independent exploitations, separately technical system and technological process formed.For example: coal-burning boiler is for SO at present
2Control adopt wet flue gas desulfurizer in a large number, efficient can reach more than 95%; For NO
XControl, conventional control method has: stove internal combustion control comprises low NO
XBurner Technology, low oxygen combustion, air classification such as burns again at burning back selective on-catalytic SNCR of control and selectivity catalysis SCR technology.Burning control is the low NO of low-cost high-efficiency with the SNCR technology
XControl technology, but removal efficiency generally only can reach 50%-65%.Therefore, in order to reach the requirement of environment protection emission, promptly remove the SO in the flue gas
2, NO
XAnd dust; Coal-burning boiler need be equipped with independently desulfurization and denitrating system more than two covers at least; Sometimes even also need set up special cleaner, so, the complete equipment system is huge, complicated, efficiency is low; And floor space is big, investment is high, operating cost is also very high, is not easy to use.
Simultaneously, for gas denitrifying technology, conventional control method has: the control of stove internal combustion comprises low NO
XBurner Technology, low oxygen combustion, air classification burns etc. again; Burning back selective on-catalytic SNCR of control and selectivity catalysis SCR technology.Burning control is the low NO of low-cost high-efficiency with the SNCR technology
XControl technology, but removal efficiency generally only can reach 50%-65%.For the emission request of increasingly stringent from now on, certainly will seek and remove technology more efficiently.SCR is the lowest NO in the present commercial technology
XControl technology can reach the denitration efficiency more than 80%, but its initial investment is at 490-1250/kw, and very expensive, operating cost is approximately 2100~2800 yuan of/ton NO
X, if on the basis of wet desulphurization, introduce the SCR technology again, certainly will increase huge investment and operating cost, lose more than gain.
This shows; Adopt more than two covers independently desulfurization and denitrating system; Not only flue gas purifying equipment is complicated, floor space is big, construction and operating cost are high, and these independently desulfurization, denitration and dust pelletizing system reasonably combined realizes that efficient operation also exists many difficulties.So studying incorporate multiple efficiently pollutant comprehensively removes device and just seems particularly important.
The utility model content
The purpose of the utility model is to provide a kind of condensing dioxygen method desulfurization and denitrification integral device; It passes through a set of equipment; Adopt to do wet method the flue gas of coal-burning boiler is carried out desulfurization, denitration and dedusting, have efficiency height, stable, small investment, advantages such as operating cost is low, applicability is strong, the treatment of wastes with processes of wastes against one another, non-secondary pollution and by-product resource.
For reaching this purpose, the utility model adopts following technical scheme:
A kind of condensing dioxygen method desulfurization and denitrification integral device; Comprise the boiler room exhaust opening, first order dry-type dedusting equipment, air-introduced machine, second level wet-scrubbing equipment, synthesis desulfurating denitrating tower and the chimney that connect successively through flue; The flue that said first order dry-type dedusting equipment links to each other with air-introduced machine is provided with the ozone filling apparatus; The liquid-inlet of said second level wet-scrubbing equipment, synthesis desulfurating denitrating tower all links to each other with circulating water pool; The liquid outlet of said second level wet-scrubbing equipment links to each other with the deposition pond, and the liquid outlet in said synthesis desulfurating denitrating tower, deposition pond all links to each other with circulating water pool, and the liquid outlet of said circulating water pool links to each other with crystallizing tower; The liquid outlet of said crystallizing tower links to each other with circulating water pool, forms closed circuit.
Further; Said ozone filling apparatus comprises oxygenerator, ozone generator and ozone generator electrical control cubicles; Said oxygenerator links to each other with ozone generator with the ozone generator electrical control cubicles, and said ozone generator links to each other with flue between first order dry-type dedusting equipment and the air-introduced machine.
Further, said first order dry-type dedusting equipment is a centicell unit, further is preferably ceramic multicyclone deduster.
Further, plastic construction is adopted in said deposition pond, and is arranged on wet-scrubbing equipment bottom, the second level.
Further, be provided with the multiple tracks spraying layer in the said synthesis desulfurating denitrating tower, its top is provided with demister, and inwall is provided with the high-temperature resistant anti-corrosive coating.
Further; The liquid-inlet of said second level wet-scrubbing equipment links to each other with circulating water pool through first water pump; The liquid-inlet of said synthesis desulfurating denitrating tower links to each other with circulating water pool through second water pump; The liquid outlet of said circulating water pool links to each other with crystallizing tower through the 3rd water pump, and said first water pump, second water pump and the 3rd water pump all are arranged on the circulating water pool, and said circulating water pool is provided with aeration pump and absorbent feeding device.
Further, said second level wet-scrubbing equipment is dedusting/condensing tower, and said dedusting/condensing tower inwall adopts enamel or stainless steel to process, and is provided with the high-temperature resistant anti-corrosive coating.
Further, said absorbent feeding device comprises slaking jar and spiral automatic charging equipment, and said slaking jar links to each other with circulating water pool through the spiral automatic charging equipment.
Further, said crystallizing tower and flue inwall are provided with the high-temperature resistant anti-corrosive coating.
The beneficial effect of the utility model does, said condensing dioxygen method desulfurization and denitrification integral device, and it adopts ozone filling flue oxidation nitrogen oxide at a low price, adds magnesia MgO and gets into circulation as sulfur dioxide in flue gas SO
2, nitrogen oxide NO
XAbsorbent; Thereby reach the effect of desulphurization denitration; Realized that multiple pollutant comprehensively removes the integrated of device, and have efficiency height, stable, small investment, advantage such as operating cost is low, applicability is strong, the treatment of wastes with processes of wastes against one another, non-secondary pollution and by-product resource; Adopt low price nitrogen oxide such as ozone oxidation NO, it is swift in response, and efficient is high; The ozone filling point is arranged on the air-introduced machine front, makes ozone mix, the quick oxidation reaction of low price nitrogen oxide is had facilitation preferably, also can reduce the corrosiveness that wet desulphurization causes air-introduced machine simultaneously through air-introduced machine; Adopt ceramic multicyclone deduster, can effectively go out dust in the flue gas, its efficiency of dust collection is high; Through the setting of dedusting/condensing tower, flue gas is played the effect of cooling, realize the effect of two-stage dust removal simultaneously; Through the setting in deposition pond, the recirculated water that makes dedusting/condensing tower come out is just got back in the circulating water pool through behind the layering and precipitating, has guaranteed the cleaning of circulating water pool; Dedusting/condensing tower inwall adopts enamel or stainless steel to process, and its resistance to elevated temperatures is good, and acid-alkali-corrosive-resisting, and tower body itself has been formed good protective effect, has prolonged the service life of dedusting/condensing tower; The multiple tracks spraying layer is set in the synthesis desulfurating denitrating tower, plays the further effect of cooling of flue gas, be beneficial to magnesia MgO and sulfide, nitrogen oxide generation neutralization reaction in the water simultaneously, the raising reaction efficiency is realized desulphurization denitration efficiently; Synthesis desulfurating denitrating tower top is provided with demister, and it utilizes gas-liquid separation device that the moisture in the flue gas is removed, and makes that discharged flue gas is up to standard and from chimney, emits; Circulating water pool is provided with the absorbent feeding device, makes MgO in the slaking jar, form saturated Mg (OH)
2Solution improves denitrification efficiency greatly; Adopt the spiral automatic charging equipment, can realize the auto feed of absorbent, automaticity improves greatly; Circulating water pool is provided with aeration pump, fully guarantees the suspension of MgO in recirculated water, further improves denitrification efficiency; Inwall through dedusting/condensing tower, synthesis desulfurating denitrating tower and crystallizing tower; And the flue inwall is provided with the high-temperature resistant anti-corrosive coating, makes its resistance to elevated temperatures good, and acid-alkali-corrosive-resisting; Tower body and flue itself have been formed good protective effect; Prolonged the service life of tower body and flue, and only needed that repair coating is damaged to get final product during annual test, plant maintenance is convenient; Adopt the design of circulating water pool, improved the utilization rate of water, reduced the discharging of waste water.
Description of drawings
Fig. 1 is the vertical view of the condensing dioxygen method desulfurization and denitrification integral device that provides of the utility model specific embodiment;
Fig. 2 be among Fig. 1 A to view;
Fig. 3 be among Fig. 1 B to view.
Among the figure:
1, boiler room, 2, ceramic multicyclone deduster, 3, air-introduced machine, 4, dedusting/condensing tower, 5, the synthesis desulfurating denitrating tower, 6, chimney; 7, oxygenerator, 8, ozone generator, 9, the ozone generator electrical control cubicles, 10, id-motor, 11, circulating water pool; 12, deposition pond, 13, crystallizing tower, 14, demister, 15, first water pump, 16, second water pump; 17, the 3rd water pump, 18, aeration pump, 19, the slaking jar, 20, the spiral automatic charging equipment, 21, flue.
The specific embodiment
Further specify the technical scheme of the utility model below in conjunction with accompanying drawing and through the specific embodiment.
Shown in Fig. 1~3; Said condensing dioxygen method desulfurization and denitrification integral device comprises boiler room 1 exhaust opening, first order dry-type dedusting equipment, air-introduced machine 3, second level wet-scrubbing equipment, synthesis desulfurating denitrating tower 5 and the chimney 6 that connect successively through flue 21.Wherein: first order dry-type dedusting equipment is a centicell unit, further is preferably ceramic multicyclone deduster 2; Second level wet-scrubbing equipment dedusting/condensing tower 4.
Further, the flue 21 that links to each other with air-introduced machine 3 of ceramic multicyclone deduster 2 is provided with the ozone filling apparatus.Wherein: the ozone filling apparatus comprises oxygenerator 7, ozone generator 8 and ozone generator electrical control cubicles 9; Oxygenerator 7 links to each other with ozone generator 8 with ozone generator electrical control cubicles 9, and ozone generator 8 links to each other with flue 21 between ceramic multicyclone deduster 2 and the air-introduced machine 3.
Further; The liquid-inlet of dedusting/condensing tower 4, synthesis desulfurating denitrating tower 5 all links to each other with circulating water pool 11; The liquid outlet of dedusting/condensing tower 4 links to each other with deposition pond 12, and the liquid outlet in synthesis desulfurating denitrating tower 5, deposition pond 12 all links to each other with circulating water pool 11, and the liquid outlet of circulating water pool 11 links to each other with crystallizing tower 13; The liquid outlet of crystallizing tower 13 links to each other with circulating water pool 11, thereby forms closed circuit.Wherein: the liquid-inlet of dedusting/condensing tower 4 links to each other with circulating water pool 11 through first water pump 15; The liquid-inlet of synthesis desulfurating denitrating tower 5 links to each other with circulating water pool 11 through second water pump 16; The liquid outlet of circulating water pool 11 links to each other with crystallizing tower 13 through the 3rd water pump 17, and first water pump 15, second water pump 16 and the 3rd water pump 17 all are arranged on the circulating water pool 11.
Further, circulating water pool 11 is provided with aeration pump 18 and absorbent feeding device.Wherein, the absorbent feeding device comprises slaking jar 19 and spiral automatic charging equipment 20, and slaking jar 19 links to each other with circulating water pool 11 through spiral automatic charging equipment 20.
Preferably:
Air-introduced machine 3 links to each other with id-motor 10, and drives its rotation through id-motor 10.
Plastic construction is adopted in deposition pond 12, and is arranged on dedusting/condensing tower 4 bottoms.
Be provided with the multiple tracks spraying layer in the synthesis desulfurating denitrating tower 5, and be provided with demister 14 at its top.
Dedusting/condensing tower 4 inwalls adopt enamel or stainless steel to process.
The inwall of dedusting/condensing tower 4, synthesis desulfurating denitrating tower 5 and crystallizing tower 13, and flue 21 inwalls all are provided with the high-temperature resistant anti-corrosive coating.
During work:
The flow direction of flue gas is in this equipment:
Flue gas gets into first order dry-type dedusting equipment-ceramic multicyclone deduster 2 after the exhaust opening of boiler room 1 comes out; Flue gas can be removed the dust in the flue gas efficiently through the ceramic cyclone in the centicell unit, and efficiency of dust collection can reach about 80-90%.
Flue gas gets into the ozone filling point that is provided with before the air-introduced machine 3; Oxygenerator 7 is sent into the oxygen that makes in the ozone generator 8; Ozone generator electrical control cubicles 9 control ozone generators 8 start; Begin to prepare ozone, and the ozone that makes is sent in the flue 21 between ceramic multicyclone deduster 2 and the air-introduced machine 3.This moment, ozone was oxidized to the low price nitrogen oxide such as NO in the flue gas higher nitrogen oxides NO that can react with MgO
X, the process experiment can know that the reaction of ozone and low price nitrogen oxide is very rapid, accomplishes basically at 2 seconds internal reactions.Its chemical equation is:
NO+O
3=NO
2+O
2
Flue gas gets into air-introduced machine 3 then; Before this equipment air-introduced machine 3 is installed in the main body desulphurization plant; Make ozone mix, the quick oxidation reaction of low price nitrogen oxide is had facilitation preferably, also can reduce the corrosiveness that wet desulphurization causes air-introduced machine 3 simultaneously through air-introduced machine 3.Air-introduced machine 3 is sent into flue gas in dedusting/condensing tower 4 under the drive of id-motor 10.
It is because through the flue gas behind the air-introduced machine 3, maximum temperature can reach 200-240 ℃, for this reason that dedusting/condensing tower 4 is set; This tower is set, and the recirculated water through in the spray circulating water pool 11 not only can play cooling-down effect; Can also realize two-stage dust removal, dust removal efficiency is reached more than 95%; Condensed flue-gas temperature drops to about 120 ℃, helps getting into the temperature control behind the synthesis desulfurating denitrating tower 5; Dedusting/condensing tower 4 inwalls adopt enamel technology or select pure stainless steel to make, and can anti-ly surpass 600 ℃ of high temperature, and acid and alkali-resistance are corrosion-resistant, and tower body itself has been formed good protection effect, and reached more than 10 years the service life of dedusting/condensing tower 4.And the recirculated water of dedusting/condensing tower 4 sprays possesses certain desulfurization, the effect of denitration, learns that through test the desulfurization degree of dedusting/condensing tower 4 can reach more than 30%, and the denitration rate can reach about 30%.
The flue-gas temperature of coming out from dedusting/condensing tower 4 is about 120 ℃; Spray through multiple tracks after getting into synthesis desulfurating denitrating tower 5, temperature is controlled at about 70 ℃ again, proves through repetition test; 70 ℃ just in time is the optimum temperature of sulfide and nitrogen oxide and magnesia MgO reaction; Synthesis desulfurating denitrating tower 5 is core components of desulphurization denitration equipment, and after flue gas gets into synthesis desulfurating denitrating tower 5, the spray system of sidewall will add magnesian recirculated water and spray in the tower body through shower nozzle; Magnesia MgO in the water and sulfide and nitrogen oxide generation neutralization reaction, thus realize desulfurization, denitration.Confirm that through experiment back repeatedly synthesis desulfurating denitrating tower 5 can be gone out the sulfide more than 60% and about 55% nitrogen oxide in the flue gas.Flue gas utilizes gas-liquid separation device that the moisture in the flue gas is removed through demister 14 then, and last flue gas up to standard is from chimney 6 dischargings.Its desulfurization, denitration chemical equation are:
MgO+H
2O=Mg(OH)
2
Mg(OH)
2+SO
2=MgSO
3
Mg(OH)
2+SO
3=MgSO
4
2Mg(OH)
2+4NO
2=Mg(NO
3)
2+Mg(NO
2)
2+2H
2O
Mg(OH)
2+N
2O
3=Mg(NO
2)
2+H
2O
Mg(OH)
2+N
2O
5=Mg(NO
3)
2+H
2O
The flow direction of recirculated water is in this equipment:
Recirculated water gets in the sprinkling equipment of dedusting/condensing towers 4 and sprays through first water pump 15, the recirculated water that comes out from dedusting/condensing tower 4 is introduced into external deposition pond 12, just gets back to circulating water pool 11 through behind the layering and precipitating.Guarantee the cleaning of circulating water pool 11, also can clear up the dust of from flue gas, removing very easily simultaneously;
Recirculated water gets in the sprinkling equipment of synthesis desulfurating denitrating towers 5 and sprays through second water pump 16, the recirculated water that comes out from synthesis desulfurating denitrating tower 5 gets into the circulating water pool 11 again;
Aeration pump 18 has been installed in the circulating water pool 11, can be guaranteed fully that magnesia MgO suspends in recirculated water, thereby the desulfuration efficiency of the equipment of assurance also continues to be oxidized to magnesium sulfate and magnesium nitrate with magnesium sulfite in the recirculated water and magnesium nitrite simultaneously;
In dedusting/condensing tower 4 and synthesis desulfurating denitrating tower 5; After sulfide and nitrogen oxide and the magnesia MgO reaction; Part generates magnesium sulfite and magnesium nitrite, and in circulating water pool 11, through aeration pump 18 it is carried out aeration, and then continues to be oxidized to magnesium sulfate and magnesium nitrate.Its chemical equation is:
2MgSO
3+O
2=2MgSO
4
Mg(NO
2)
2+O
2=Mg(NO
3)
2
Circulating water pool 11 is squeezed into the recirculated water that is dissolved with a large amount of magnesium sulfate and magnesium nitrate in the crystallizing tower 13 through the 3rd water pump 17; When the magnesium sulfate that dissolves in the recirculated water and magnesium nitrate reach finite concentration; Separate out by the foreign material in the water, magnesium sulfate and magnesium nitrate through settler; Process epsom salt crystal and magnesium nitrate hexahydrate crystal, continue to squeeze into the recirculated water of high-concentration sulfuric acid magnesium and magnesium nitrate then, let crystallizing tower 13 upper strata low concentration recirculated water overflows get back in the circulating water pool 11 simultaneously.Its chemical equation is:
MgSO
4+7H
2O=MgSO
4·7H
2O
Mg(NO
3)
2+6H
2O=Mg(NO
3)
2·6H
2O
The recirculated water utilization rate of this equipment is high, and except evaporation loss, unknown losses is few, only needs to replenish the water smoke part moisture loss of discharging with flue gas, all recycles of all the other moisture.
During the operation of absorbent feeding device:
Magnesia MgO feeds an amount of water and steam earlier in slaking jar 19, and about 80 ℃, stirs, and this moment, MgO can have the saturated Mg (OH) of 20% water-soluble formation
2Solution can improve desulfurization, denitration efficiency greatly.In circulating water pool 11, add absorbent through spiral automatic charging equipment 20 then.Its chemical equation is:
MgO+H
2O=Mg(OH)
2
Simultaneously this equipment can be according to the actual conditions auto feed of recirculated water, and the concrete operations mode is the pH value of on-line monitoring recirculated water, when the PH of recirculated water 7 when above, slaking jar 19 and spiral automatic charging equipment 20 are in resting state; When pH value less than 7 the time, slaking jar 19 starts with spiral automatic charging equipment 20 automatically, greater than 7 o'clock, slaking jar 19 and spiral automatic charging equipment 20 stopped automatically until the pH value of recirculated water.
The absorbent feeding device only need be debugged when mounted; In advance in slaking jar 19, put into an amount of magnesia and can realize auto feed; And get final product regularly cleaning PH meter sensing chieftain, can save reinforced waste and causing the underproof puzzlement of fume emission because of timely feeding in raw material.
Said condensing dioxygen method desulfurization and denitrification integral device; It passes through a set of equipment; Adopt to do wet method the flue gas of coal-burning boiler is carried out desulfurization, denitration and dedusting, have efficiency height, stable, small investment, advantages such as operating cost is low, applicability is strong, the treatment of wastes with processes of wastes against one another, non-secondary pollution and by-product resource.