CN202482102U - Improved light-catalyzed reaction device for water treatment - Google Patents

Improved light-catalyzed reaction device for water treatment Download PDF

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Publication number
CN202482102U
CN202482102U CN2012200475488U CN201220047548U CN202482102U CN 202482102 U CN202482102 U CN 202482102U CN 2012200475488 U CN2012200475488 U CN 2012200475488U CN 201220047548 U CN201220047548 U CN 201220047548U CN 202482102 U CN202482102 U CN 202482102U
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China
Prior art keywords
cylindrical shell
taper type
type cylindrical
frustum
water treatment
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Expired - Lifetime
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CN2012200475488U
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Chinese (zh)
Inventor
丁叶民
马建锋
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JIANGSU XINGCHEN ENVIRONMENTAL PROTECTION GROUP CO Ltd
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JIANGSU XINGCHEN ENVIRONMENTAL PROTECTION GROUP CO Ltd
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Priority to CN2012200475488U priority Critical patent/CN202482102U/en
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Abstract

The utility model aims at providing a light-catalyzed reaction device for water treatment, which comprises a frustum-shaped cylinder body arranged axially horizontally, wherein blades and cones are respectively uniformly fixedly arranged on the inner wall and the outer wall of the frustum-shaped cylinder body, two ends of the frustum-shaped cylinder body are provided with net-shaped end sockets and hollow shafts, quartz tubes are arranged in the hollow shafts and are internally provided with ultraviolet light sources, and TiO2 coatings are loaded on the inner side of the frustum-shaped cylinder body, the surfaces of the blades, the surfaces of the cones, and the net-shaped end sockets. The frustum-shaped cylinder body of the light-catalyzed reaction device is beneficial to liquid flowing to form a liquid film without water drops; the area of the liquid film can be enlarged due to the radially-arranged blades; and the ultraviolet light source is arranged inside the frustum-shaped cylinder body to ensure that laser is not lost without wasting, the cones arranged outside the frustum-shaped cylinder body can continuously develop a function under the action of daylight, and can be radiated by means of an ultraviolet light for catalysis at night or under the condition of poor daylight, and the water treatment effect is remarkable.

Description

A kind of modified form photocatalytic reaction device that is used for water treatment
Technical field
The utility model relates to a kind of modified form photocatalytic reaction device that is used for water treatment, belongs to technical field of sewage in the environment protection.
Background technology
Traditional water treatment method efficient is low, cost is high, have secondary pollution problems, the solution that waste water control can not get always.The development of nanotechnology and application thoroughly solve this difficult problem probably.1972, A.Fujishima and K.Honda were at n N-type semiconductorN TiO 2Found the photoelectrocatalysis Decomposition of water on the electrode, TiO 2Oxidation activity is higher, and chemicalstability is good, and to the human non-toxic evil, cost is low, and is pollution-free, applied range, thereby paid attention to most, be present most widely used nano-photocatalyst material, also be the environmental type catalyzer that has the exploitation future most.
Research shows, nano-TiO 2Can handle multiple toxic compounds, can with the hydro carbons in the water, halohydrocarbon, acid, tensio-active agent, dyestuff, itrogenous organic substance, organic phosphorous insecticide, wood preservative and fuel wet goods soon complete oxidation be CO 2, H 2Innoxious substances such as O.But nano-photo catalytic TiO up to the present 2Technology is not used widely aspect wastewater treatment yet, mainly is because the nano particle separation difficulty does not have the simple treatment facility that is suitable for.
In the carrier surface load, can solve the problem of particle separation through nano particle.But when load had the carrier of nano particle to be soaked in the water, the solution that exciting light must see through thicker (often more than several centimetres) just can shine on the catalyzer.And in fact; No matter be at ultraviolet region or visible region; Organic solution (especially with the look organic wastewater) all can have photoabsorption in various degree, and this will certainly cause exciting light light loss in various degree, makes the light intensity that arrives catalyst surface descend; Thereby make the productive rate in light induced electron and hole descend, finally make the degradation efficiency of pollutent reduce.Patent CN100509639C discloses a kind of ramp type photo electrocatalysis reactor, can obtain the light-catalyzed reaction of water thin film promotion preferably, but lamp places the swash plate outside, has the loss of light.Equally, CN101774661A, CN102030387A, CN101993129A several patents disclosed method all is the side that excitation light source is positioned over the catalyst cupport plate, has the loss of luminous energy.In order to improve degradation efficiency, can only improve the power of excitation light source, so just increased operation energy consumption.
The utility model content
The purpose of the utility model is the deficiency to prior art, and a kind of modified form photocatalytic reaction device that is used for water treatment is provided.Lower part of taper type cylindrical shell places pending waste water in this device, and continuous rolling can form thin liquid film, and the taper type cylindrical shell helps liquid-flow, and the blade of radial installation can enlarge liquid film area in the taper type cylindrical shell.Be located at the intravital ultraviolet source of taper type tube and can guarantee the exciting light waste of not running off, the taper type cylindrical shell outside then is provided with the cone that is coated with the carried catalyst coating, can utilize daylight to carry out catalyzed reaction under the sunshine condition having.
The purpose of the utility model can realize through following technical scheme:
A kind of photocatalytic reaction device that is used for water treatment; Comprise axial horizontally disposed taper type cylindrical shell; Evenly be installed with blade and cone on the inner and outer wall of said taper type cylindrical shell respectively, the two ends of said taper type cylindrical shell are equipped with netted end socket and tubular shaft, are provided with silica tube in the described tubular shaft; Be provided with ultraviolet source in the described silica tube, equal load has TiO on the surface of the inboard of said taper type cylindrical shell, the surface of blade and cone and the netted end socket 2Coating.
The above-mentioned photocatalytic reaction device that is used for water treatment, its outside that is described taper type cylindrical shell also is provided with ultraviolet source.
The above-mentioned photocatalytic reaction device that is used for water treatment, it is that the lateral tilt angle alpha of described taper type cylindrical shell is 10 °~20 °.
The above-mentioned photocatalytic reaction device that is used for water treatment, it is that described blade and cone are welded on respectively on the inner and outer wall of said taper type cylindrical shell.As a kind of preferred version, described blade has the 6-10 sheet, be welded on radially on the inwall of taper type cylindrical shell, a side of said blade from the inwall of taper type cylindrical shell to extending to apart from silica tube 2~4cm place with the vertical direction of taper type cylindrical shell hub.
During operation, lower part of taper type cylindrical shell is placed pending waste water, open the ultraviolet source that is located in the silica tube, rotated by driven by motor taper type cylindrical shell, rotating speed is at 25~30 rev/mins.
The beneficial effect of the utility model:
The taper type cylindrical shell continuous rolling of the utility model device can form thin liquid film; The taper type cylindrical shell helps liquid-flow and forms liquid film, rather than water droplet, and the blade that the taper type cylinder inboard wall is provided with radially can enlarge liquid film area; Ultraviolet source places the taper type barrel can guarantee the exciting light waste of not running off, and the outer cone that is provided with of taper type cylindrical shell can continue to play a role under the effect of daylight, also can under the not strong situation of night or daylight, be aided with ultra violet lamp catalysis.
Evidence: for containing the waste water of gold orange II concentration at 105mg/L, the clearance that continues processing 2h water outlet gold orange II afterwards through this equipment reaches 94%.
Description of drawings
Fig. 1 is the structural representation of the utility model device;
Fig. 2 is the schematic internal view after the netted end socket of taper type cylindrical shell is opened;
Fig. 3 is that the back schematic internal view is launched in taper type cylindrical shell side;
Fig. 4 is a taper type cylindrical shell perspective view;
Fig. 5 is that the outside synoptic diagram in back is launched in taper type cylindrical shell side.
Embodiment
As shown in Figure 1; A kind of photocatalytic reaction device that is used for water treatment; Comprise axial horizontally disposed taper type cylindrical shell 1; Evenly be installed with blade 6 and cone 7 on the inner and outer wall of said taper type cylindrical shell 1 respectively, the two ends of said taper type cylindrical shell are equipped with netted end socket 2 and tubular shaft 3, are provided with silica tube 4 in the described tubular shaft 3; Be provided with ultraviolet source 9 in the described silica tube 4, equal load has TiO on the surface of the surface of the inboard of said taper type cylindrical shell 1, blade 6 and cone 7 and the netted end socket 2 2Coating.The outside of described taper type cylindrical shell 1 also is provided with ultraviolet source 8.
As a kind of preferred version, described taper type cylindrical shell 1 lateral tilt angle alpha is 10 °~20 °.
Described blade 6 is welded on respectively on the inner and outer wall of said taper type cylindrical shell 1 with cone 7.Described blade 6 has the 6-10 sheet, be welded on radially on the inwall of taper type cylindrical shell 1, a side of said blade 6 from the inwall of taper type cylindrical shell 1 to extending to apart from silica tube 42~4cm place with the vertical direction of taper type cylindrical shell 1 hub.Described cone 7 has 6-10 row evenly to be welded on the outer wall of taper type cylindrical shell 1.
During operation; Taper type cylindrical shell 1 axial level is placed sewage lagoon 5, the lower part that makes taper type cylindrical shell 1 as much as possible place pending waste water, open ultraviolet source 9; Drive tubular shaft 3 by motor 10 and rotate with taper type cylindrical shell 1, rotating speed is at 25~30 rev/mins.
Evidence: for containing the waste water of gold orange II concentration at 105mg/L, the clearance that continues processing 2h water outlet gold orange II afterwards through this equipment reaches 94%.

Claims (5)

1. photocatalytic reaction device that is used for water treatment; It is characterized in that comprising axial horizontally disposed taper type cylindrical shell (1); Evenly be installed with blade (6) and cone (7) on the inner and outer wall of said taper type cylindrical shell (1) respectively; The two ends of said taper type cylindrical shell are equipped with netted end socket (2) and tubular shaft (3); Be provided with silica tube (4) in the described tubular shaft (3), be provided with ultraviolet source (9) in the described silica tube (4), the surface of the surface of the inboard of said taper type cylindrical shell (1), blade (6) and cone (7) and netted end socket (2) are gone up equal load has TiO 2Coating.
2. the photocatalytic reaction device that is used for water treatment according to claim 1 is characterized in that the outside of described taper type cylindrical shell (1) also is provided with ultraviolet source (8).
3. the photocatalytic reaction device that is used for water treatment according to claim 1 is characterized in that the lateral tilt angle alpha of described taper type cylindrical shell (1) is 10 °~20 °.
4. the photocatalytic reaction device that is used for water treatment according to claim 1 is characterized in that described blade (6) and cone (7) are welded on respectively on the inner and outer wall of said taper type cylindrical shell (1).
5. according to claim 1 or the 4 described photocatalytic reaction devices that are used for water treatment, it is characterized in that described blade (6) has the 6-10 sheet, is welded on the inwall of taper type cylindrical shell (1) radially; One side of said blade (6) from the inwall of taper type cylindrical shell (1) to extending to apart from silica tube (4) 2~4cm places with the vertical direction of taper type cylindrical shell (1) hub.
CN2012200475488U 2012-02-14 2012-02-14 Improved light-catalyzed reaction device for water treatment Expired - Lifetime CN202482102U (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
CN2012200475488U CN202482102U (en) 2012-02-14 2012-02-14 Improved light-catalyzed reaction device for water treatment

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105000622A (en) * 2015-01-14 2015-10-28 苏州科技学院 Photocatalytic reactor
CN111875131A (en) * 2020-07-27 2020-11-03 四川春语环保科技有限公司 UV photodissociation-Me micro-electrolysis-Ee electrolysis combined catalytic oxidation treatment wastewater and waste liquid system
CN113526608A (en) * 2021-04-06 2021-10-22 郑州轻工业大学 Photocatalysis sterilization and disinfection device

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105000622A (en) * 2015-01-14 2015-10-28 苏州科技学院 Photocatalytic reactor
CN111875131A (en) * 2020-07-27 2020-11-03 四川春语环保科技有限公司 UV photodissociation-Me micro-electrolysis-Ee electrolysis combined catalytic oxidation treatment wastewater and waste liquid system
CN113526608A (en) * 2021-04-06 2021-10-22 郑州轻工业大学 Photocatalysis sterilization and disinfection device
CN113526608B (en) * 2021-04-06 2022-11-25 郑州轻工业大学 Photocatalysis sterilization and disinfection device

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