CN202474113U - Soft-package lithium-ion battery with air guide device - Google Patents

Soft-package lithium-ion battery with air guide device Download PDF

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Publication number
CN202474113U
CN202474113U CN2012200654011U CN201220065401U CN202474113U CN 202474113 U CN202474113 U CN 202474113U CN 2012200654011 U CN2012200654011 U CN 2012200654011U CN 201220065401 U CN201220065401 U CN 201220065401U CN 202474113 U CN202474113 U CN 202474113U
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China
Prior art keywords
ion battery
lithium ion
battery
operated device
flexible packing
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Expired - Lifetime
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CN2012200654011U
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Chinese (zh)
Inventor
史雪锋
刘伟利
黄辉
王秀丽
史顺君
陈鹏
陈永祥
许�鹏
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Yixing Xinchi Energy Technology Co., Ltd
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Sharp Point Of Jiangsu Speeds In Green Power Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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Abstract

The utility model discloses a soft-package lithium-ion battery with an air guide device. The soft-package lithium-ion battery comprises a battery pole core, a shell for encapsulating the battery pole core and an electrolyte. The air guide device comprises an air guide pipe penetrating through the shell and a plastic coat wrapping the air guide pipe externally, wherein one end of the plastic coat is hermetically connected with the shell, and the other end of the plastic coat extends out of the end face of the air guide pipe to form an extension part for heat sealing. By additionally arranging the air guide device, if the soft-package lithium-ion battery is aerated, air can be guided conveniently; and air can be discharged from the battery in both the formation procedure and use procedure of the battery, so that the battery is ensured to keep working; simultaneously, after the air guide device is used, the battery can be supplemented with the electrolyte, so that the service life and performance of the battery are improved.

Description

A kind of flexible packing lithium ion battery that has gas operated device
Technical field
The utility model relates to the flexible packing lithium ion battery field, is specifically related to a kind of flexible packing lithium ion battery that has gas operated device.
Background technology
Lithium ion battery has that specific energy density height, average output voltage are high, power output is big, self discharge is little, memory-less effect, efficiency for charge-discharge are high, have extended cycle life, operating temperature range is wide and numerous outstanding advantages such as green non-pollution; Since early 1990s succeeds in developing, become the best battery system of present combination property.Along with continuing to bring out of battery design improvement of Manufacturing Technology and new material; The range of application of lithium ion battery is constantly expanded; Obtained using widely in every field at present; Especially development in recent years new forms of energy industrial field rapidly, lithium ion battery more is regarded as the basis and the primary study target of new forms of energy development.
Divide from the shell mechanism of lithium ion battery, common in the market have kinds such as aluminium alloy, stainless steel, plastics and aluminum-plastic composite membrane flexible package.Flexible packing lithium ion battery combines the distinct advantages on the profile packing of basic chemical property and polymer Li-ion battery of liquid lithium ionic cell.Usually; Flexible packing lithium ion battery comprises Battery Pole Core, is used to encapsulate the shell and the electrolyte of this Battery Pole Core, and the preparation process comprises: put well by the top-down order of positive plate-barrier film-negative plate-barrier film; Process Battery Pole Core through reeling; Then adopt the shell of aluminum-plastic composite membrane on the medium that adopts the liquid electrolyte similar between both positive and negative polarity, to transmit, profile packing, again through technology such as inject electrolyte, seal as this flexible packing lithium ion battery as lithium ion with liquid lithium ionic cell; Obtain flexible packing lithium ion battery, the part that positive plate, negative plate pass shell is respectively positive pole ear, negative lug.Flexible packing lithium ion battery has outstanding advantages such as manufacturing process is simple, the battery specific energy density is high, volume is little, has occupied main status in consumer electronics field, and annual increase of production is rapid.In recent years, along with the development of electric automobile, electric bicycle, energy-storage system etc., flexible packing lithium ion battery has also obtained paying close attention to widely and fast development at big capacity and electrokinetic cell field.
Compare with hard packaging lithium ionic cells such as adopting aluminium alloy or stainless steel casing; Flexible packing lithium ion battery all has clear superiority at aspects such as specific energy density, volume and costs; But also have some inborn deficiencies in the flexible packing lithium ion battery production process, as battery change into cyclic process in the inflatable problem just be difficult to solve.According to statistics, some producer is in the process of producing flexible packing lithium ion battery, and the battery ratio that inflatable takes place is up to more than 40%, and is if add the battery that in recycling process, produces inflatable, higher than regular meeting.Compare with hard packaging lithium ionic cell, flexible packing lithium ion battery is because structure is very compact, and the flexible packing lithium ion battery volume inside is very little, if flexible packing lithium ion battery produces little of gas in formation process, will cause the appearance of ballooning.And along with the flexible packing lithium ion battery cycle-index increases, the inner gas that produces can increase gradually, so the ballooning of flexible packing lithium ion battery can be more serious, will cause the flexible packing lithium ion battery can't operate as normal and scrap.
From present flexible packing lithium ion battery production flow analysis; After in case the flexible packing lithium ion battery fluid injection is sealed; Just can't carry out follow-up adjustment or maintenance to flexible packing lithium ion battery again, in case problems such as inflatable drum shell or insufficient electrolyte occur, the flexible packing lithium ion battery processing of can only scrapping or demote; Have no idea to remedy, had a strong impact on the qualification rate and the quality of flexible packing lithium ion battery.Through strictness control production technology and environment, though can reduce the flexible packing lithium ion battery ballooning, can't thoroughly eliminate, still there are the substandard products battery of significant proportion and waste product battery to produce, thereby cause the production cost of enterprise significantly to increase.
Utility model patent ZL201020546139.3 discloses a kind of flexible packing lithium ion battery; To flexible packing lithium ion battery change into follow-up use in have the problem of ballooning, on packaging film, be provided with airbag, this airbag can be used for carrying the gas that produces in the inflatable process; And between underseal limit and airbag, locate to be provided with otch; When flexible packing lithium ion battery shifted between multiple working procedure, the stress that is arranged so that place, position, angle of otch significantly reduced, and prevented that flexible packing lithium ion battery from the breakage of position, angle taking place; Avoid the pollution that causes because of electrolyte leakage, guarantee the security performance of flexible packing lithium ion battery.The existence of airbag can make place, position, angle damaged easily; Can reduce the breakage of place, position, angle to a certain extent through otch being set at place, position, angle; But the breakage of position, angle place still difficulty avoid and its intensity of otch heat-sealing back not good, simultaneously, this flexible packing lithium ion battery structure is also compact inadequately; The battery volume increases, and aluminum-plastic packaged cost increases.In addition; Airbag is because still be arranged on the battery, and after producing gas in the battery operated process, airbag has carried a part of gas as buffer unit; Suitably reduced inner pressure of battery; But can't in time the gas of inside battery be discharged, battery comprises that airbag still can expand, and is a kind of halfway palliative.
The utility model content
The utility model provides a kind of flexible packing lithium ion battery that has gas operated device, on existing flexible packing lithium ion battery basis, has increased gas operated device, can make things convenient for flexible packing lithium ion battery air guide after the ballooning to occur.
A kind of flexible packing lithium ion battery that has gas operated device; Comprise Battery Pole Core, be used to encapsulate the shell and the electrolyte of this Battery Pole Core; Described gas operated device comprises the wireway that runs through said shell; And be wrapped in the outside plastic wrapper of said wireway, and an end of this plastic wrapper is connected with said body seal, and the other end extends the extension that the end face of wireway is formed for sealing.
This gas operated device just can be realized air guide through simple structure, than the situation that increases airbag, can reduce packaging cost and cost of transportation so that the utility model has the flexible packing lithium ion battery compact conformation of gas operated device.
As preferably; Described Battery Pole Core has negative lug, the positive pole ear that passes shell; Because negative lug and positive pole ear will have certain distance just to have battery performance preferably; Described gas operated device is arranged between negative lug and the positive pole ear, thereby makes the flexible packing lithium ion battery compact conformation that has gas operated device, and convenient the use.
As preferably, described wireway is a stainless steel tube, and wireway is used for air guide and support; On the one hand; Because easy deformation when plastic wrapper seals in the flexible packing lithium ion battery production process, stainless steel tube can play good supporting role, prevents the distortion of gas operated device; On the other hand, stainless steel tube has certain corrosion-resisting function to electrolyte, prolongs the useful life of gas operated device.Further preferred, described wireway is 304 stainless steel tubes or 316 stainless steel tubes, and these stainless steel tubes have better corrosion resistance to electrolyte.
As preferably, described plastic wrapper is polyethylene (PE) plastic wrapper or polypropylene (PP) plastic wrapper, and the plastic wrapper of these materials can be better and the shell heat-sealing, has better sealing property after the heat-sealing.
Because gas operated device is in the use in later stage, need be with extension piecemeal excision heat-sealing again, the length of extension there is not special qualification; Can set as required; As preferably, the length of described extension is 5mm~20mm, so that rationally practicing thrift under the condition of cost; Satisfy the requirement of using, and make things convenient for the utility model to have the encapsulation and the transportation of the flexible packing lithium ion battery of gas operated device.Further preferred, the length of described wireway is 5mm~15mm, and the length of described plastic wrapper (length that comprises extension) is 15mm~25mm.
As preferably, the internal diameter of described wireway is 0.1mm~2.0mm, and external diameter is 0.2mm~3.0mm, can select other wireway of capillary level for use, and described wireway is further selected stainless steel capillary for use, can adopt the commercially available prod.The wireway of above-mentioned size; Both can realize the function of air guide and support; The structure that can make the utility model have the flexible packing lithium ion battery of gas operated device again keeps compact, and in transportation and use, can avoid the influence of electrolyte to gas operated device.
Correspondingly, for can be better and wireway compound, the internal diameter of described plastic wrapper cooperates with the external diameter of wireway, can seal better in order to make plastic wrapper and shell, generally adopts heat-sealing, the pipe thickness of described plastic wrapper is 0.2mm~1.0mm.
A kind of preparation method who has the flexible packing lithium ion battery of gas operated device prepares simple, easy to implement.
The described preparation method who has the flexible packing lithium ion battery of gas operated device may further comprise the steps:
The wireway that 1) will scribble lug glue inserts in the thermoplastic plastic wrapper, treats the surface-coated lug glue of plastic wrapper cooling contraction back at plastic wrapper, obtains gas operated device;
Wireway carried out alligatoring processing with the outer surface of wireway before scribbling lug glue, the two ends polishing removes deburring, in order to increase the air-tightness between wireway and the plastic wrapper, the special-purpose lug glue of wireway surface-coated lithium ion battery; Sealing during for the plastic wrapper that increases gas operated device and shell heat-sealing is at the surface-coated lug glue of plastic wrapper;
2) when the shell heat-sealing of flexible packing lithium ion battery; After gas operated device in the step 1) being installed on the heat seal limit of shell, with the heat-sealing of heat seal limit, after changing into through battery; With the extension heat-sealing of plastic wrapper, obtain having the flexible packing lithium ion battery of gas operated device.
Compared with prior art, the utlity model has following advantage:
The utility model has the flexible packing lithium ion battery of gas operated device; On existing flexible packing lithium ion battery basis; Increased gas operated device; In formation process, the gas that can in time inside battery be produced is discharged outside the battery through gas operated device at the flexible packing lithium ion battery that has gas operated device, prevents the generation of battery inflatable drum shell phenomenon.After battery changes into, can adopt the extension end sealing of version, keep the whole sealing that has the flexible packing lithium ion battery of gas operated device plastic wrapper.
The utility model has the flexible packing lithium ion battery of gas operated device; In use; If the high battery inflatable drum shell phenomenon that produces of voltage rise in generation gas causes in cyclic process; Can be in time the top of the extension of plastic wrapper be cut, discharge inner unnecessary gas, eliminate the inflatable drum shell phenomenon of battery; Recover to adopt heat-sealing method that the extension top of plastic wrapper is sealed once more again after the normal profile of battery, the flexible packing lithium ion battery that makes the utility model have gas operated device works on.Simultaneously, adopt this gas operated device after, can realize that battery is replenished fluid injection to be safeguarded, improves battery service life and performance.
The flexible packing lithium ion battery that the utility model has gas operated device is fit to be applied to all kinds of big capacity flexible packing lithium ion batteries; Be particularly useful for adopting in the big capacity flexible packing lithium ion batteries as positive electrode such as LiFePO4, LiMn2O4 and ternary material; Can effectively eliminate the inflatable drum shell phenomenon that battery produces in the production and the course of work; Increased substantially the qualification rate that the utility model has the flexible packing lithium ion battery of gas operated device; Realization has the flexible packing lithium ion battery after-teeming electrolyte of gas operated device to the utility model; Prolong the utility model have gas operated device flexible packing lithium ion battery working life with improved reliability, help the popularization and the utilization of product, have broad application prospects.
This has the preparation method of the flexible packing lithium ion battery of gas operated device, prepares simply, easy to implement, helps suitability for industrialized production, helps promotion and application, has favorable economic benefit.
Description of drawings
Fig. 1 has the structural representation of the flexible packing lithium ion battery of gas operated device for the utility model;
Fig. 2 is the cross section structure sketch map of the gas operated device of the utility model.
Embodiment
As shown in Figure 1; The flexible packing lithium ion battery that has gas operated device for the utility model; Comprise Battery Pole Core, be used to encapsulate shell 4, electrolyte and the gas operated device 2 of this Battery Pole Core; Battery Pole Core has negative lug 1, the positive pole ear 3 that passes shell, and gas operated device 2 is arranged between negative lug 1 and the positive pole ear 3.
As depicted in figs. 1 and 2, gas operated device 2 comprises the wireway 21 that runs through shell 4, and the plastic wrapper 22 that is wrapped in wireway 21 outsides; One end and the shell 4 of this plastic wrapper 22 are tightly connected; Can specifically adopt heat-sealing to be connected and sealed, the other end extends the extension that the end face of wireway 21 is formed for sealing, and the length of extension is 5mm~20mm; After battery changes into, can adopt the extension end sealing of version with plastic wrapper 22.
Wireway 21 can be selected stainless steel tube for use, and is preferred, can select 304 stainless steel tubes or 316 stainless steel tubes for use, and the internal diameter of wireway 21 is 0.1mm~2.0mm, and external diameter is 0.2mm~3.0mm, and the length of wireway is 5mm~15mm, can select stainless steel capillary for use.The internal diameter of plastic wrapper 22 cooperates with the external diameter of wireway 21; For plastic wrapper 22 and shell 4 can be sealed better; The general employing seals; Plastic wrapper 22 is polyethylene (PE) plastic wrapper or polypropylene (PP) plastic wrapper, and the pipe thickness of plastic wrapper 22 is 0.2mm~1.0mm, and the length of plastic wrapper 22 (length that comprises extension) is 15mm~25mm.
The described preparation method who has the flexible packing lithium ion battery of gas operated device, this flexible packing lithium ion battery structure that has gas operated device can see figures.1.and.2, and may further comprise the steps:
1) outer surface with wireway 21 carries out alligatoring processing, and the two ends polishing removes deburring, and applies lug glue, the wireway 21 after obtaining handling at the outer surface of wireway 2;
2) with plastic wrapper 22 be heated to softening after, put into the wireway 21 after step 1) is handled, treat that plastic wrapper 22 cooling after-contraction obtain gas operated device 2, again the surface-coated lug glue of the plastic wrapper in gas operated device 2 22;
3) when shell 4 heat-sealings of flexible packing lithium ion battery; With step 2) in gas operated device 2 be installed on the heat seal limit 5 of shell 4 after, with 5 heat-sealings of heat seal limit, after changing into through battery; With the extension heat-sealing of plastic wrapper 22, obtain having the flexible packing lithium ion battery of gas operated device.
In the preparation process, before battery changed into, the extension of plastic wrapper 22 did not seal, and can in time the inner gas that produces in the battery formation process be discharged outside the battery through gas operated device 2, prevented the generation of battery inflatable drum shell phenomenon.After battery changes into, can adopt the extension end sealing of version with plastic wrapper 22, keep the whole sealing that has the flexible packing lithium ion battery of gas operated device.If the high battery inflatable drum shell phenomenon that produces of voltage rise in generation gas causes in recycling process; Can be in time the top of the extension of plastic wrapper 22 be cut; Discharge inner unnecessary gas; Eliminate the inflatable drum shell phenomenon of battery, recover to adopt heat-sealing method that the extension top of plastic wrapper 22 is sealed once more again after the normal profile of battery, the flexible packing lithium ion battery that has gas operated device is worked on.Simultaneously, adopt this gas operated device 2 after, can realize that battery is replenished fluid injection to be safeguarded, improves battery service life and performance.
Embodiment 1
A kind of preparation method who has the flexible packing lithium ion battery of gas operated device, this flexible packing lithium ion battery structure that has gas operated device can see figures.1.and.2, and may further comprise the steps:
1) choose 304 stainless steel tubes as wireway 21, its internal diameter is 0.5mm, and external diameter is 0.8mm; Length is 10mm, and the outer surface of this 304 stainless steel tube is carried out alligatoring processing, the two ends polishing; Remove deburring; And apply lug glue at the outer surface of this 304 stainless steel tube, the special-purpose lug glue of lithium ion battery that lug glue selects for use Japanese letterpress company to produce, the wireway 21 after obtaining handling;
2) choosing internal diameter is 0.7mm; External diameter is 1.5mm; Length be the vinyon overcoat of 20mm as plastic wrapper 22, with this plastic wrapper 22 be heated to 50 ℃ softening after, put into the wireway 21 after step 1) is handled; Treat that plastic wrapper 22 cooling after-contraction obtain gas operated device 2, the more special-purpose lug glue of lithium ion battery of the surface-coated of the plastic wrapper in gas operated device 2 22 Japan letterpress company production;
3) when shell 4 heat-sealings of flexible packing lithium ion battery; With step 2) in gas operated device 2 be installed on the heat seal limit 5 of shell 4 after, with 5 heat-sealings of heat seal limit, after changing into through battery; With the extension heat-sealing of plastic wrapper 22, obtain having the flexible packing lithium ion battery of gas operated device.

Claims (9)

1. flexible packing lithium ion battery that has gas operated device; Comprise Battery Pole Core, be used to encapsulate the shell and the electrolyte of this Battery Pole Core; It is characterized in that described gas operated device comprises the wireway that runs through said shell, and be wrapped in the outside plastic wrapper of said wireway; One end of this plastic wrapper is connected with said body seal, and the other end extends the extension that the end face of wireway is formed for sealing.
2. the flexible packing lithium ion battery that has gas operated device according to claim 1 is characterized in that, described Battery Pole Core has negative lug, the positive pole ear that passes shell, and described gas operated device is arranged between negative lug and the positive pole ear.
3. the flexible packing lithium ion battery that has gas operated device according to claim 1 is characterized in that, described wireway is a stainless steel tube.
4. the flexible packing lithium ion battery that has gas operated device according to claim 3 is characterized in that, described wireway is 304 stainless steel tubes or 316 stainless steel tubes.
5. the flexible packing lithium ion battery that has gas operated device according to claim 1 is characterized in that, described plastic wrapper is vinyon overcoat or polypropylene plastics overcoat.
6. the flexible packing lithium ion battery that has gas operated device according to claim 1 is characterized in that, the length of described extension is 5mm~20mm.
7. the flexible packing lithium ion battery that has gas operated device according to claim 6 is characterized in that, the length of described wireway is 5mm~15mm, and the length of described plastic wrapper is 15mm~25mm.
8. the flexible packing lithium ion battery that has gas operated device according to claim 1 is characterized in that, the internal diameter of described wireway is 0.1mm~2.0mm, and external diameter is 0.2mm~3.0mm.
9. the flexible packing lithium ion battery that has gas operated device according to claim 1 is characterized in that, the pipe thickness of described plastic wrapper is 0.2mm~1.0mm.
CN2012200654011U 2012-02-27 2012-02-27 Soft-package lithium-ion battery with air guide device Expired - Lifetime CN202474113U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102593401A (en) * 2012-02-27 2012-07-18 江苏锋驰绿色电源有限公司 Flexible package lithium ion battery with air guide device and method for preparing flexible package lithium ion battery

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102593401A (en) * 2012-02-27 2012-07-18 江苏锋驰绿色电源有限公司 Flexible package lithium ion battery with air guide device and method for preparing flexible package lithium ion battery
CN102593401B (en) * 2012-02-27 2014-12-03 江苏锋驰绿色电源有限公司 Flexible package lithium ion battery with air guide device and method for preparing flexible package lithium ion battery

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Date Code Title Description
C14 Grant of patent or utility model
GR01 Patent grant
TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20201120

Address after: 214266, No. 82, new middle road, Xinzhuang Industrial Complex, Wuxi, Jiangsu, Yixing

Patentee after: Yixing Xinchi Energy Technology Co., Ltd

Address before: 214266 Xinzhuang street, Yixing, Jiangsu, Wuxi

Patentee before: JIANGSU FENGCHI GREEN POWER SUPPLY Co.,Ltd.

CX01 Expiry of patent term
CX01 Expiry of patent term

Granted publication date: 20121003